Petroleum-based Products Research Articles

Characterization of anti bacterial biocomposite films based on poly lactic acid and prosopis juliflora bark powder

Biocomposites can be a solution for environmental pollution and sustainability by acting as an alternative to petroleum-based products used in the field of packaging and biomedical applications. Herein, an attempt to valorize the potential of Prosopis juliflora plant to fabricate Polylactic acid (PLA) based biocomposites. The biocomposites comprised of Prosopis juliflora bark powder (PJBP) and PLA were fabricated by solution casting method with various weight percentages (Wt%) of PJBP. PJBP/PLA films show uniform functional group interactions through FTIR analysis. The 25 % PJBP/ PLA biocomposite shows the highest crystalline size of 8.9 nm. The 25 wt% included PJBP increases the thermal stability by 6.9 %, surface roughness by 212 %, and tensile strength by 45.5 % compared to PLA film. The 25 % PJBP film shows increment in the water absorption and water vapor permeability test. In addition, the antibacterial behavior of 25 % PJBP bio composite shows higher inhibition zones against the gram-positive and gram-negative pathogens. Biocomposite films with PJBP content show 40 % degradation in soil for degradation analysis. This PLA/25 % PJBP biodegradable film can be used as an alternative for petroleum-based products in the field of packaging as well as the biomedical field.

Catalytic Biolubricant Production from Canola Oil Through Double Transesterification with Methanol and Neopentyl Glycol

In the current environmental scenario, the proposal of alternatives for petroleum-based products has considerably increased, with the aim of looking for bioproducts with interesting properties such as biodegradability, sustainability and efficiency, among others. In this sense, the role of biolubricants is promising, offering a wide range of possibilities through different methods and operating conditions. Specifically, double transesterification could be a suitable process in a biorefinery context. The aim of this work was to produce a biolubricant through double transesterification with methanol and neopentyl glycol (NPG) under different reaction conditions by using homogeneous catalysis (sodium methoxide). Different catalyst concentrations, among other changes in reaction conditions (temperature ranging between 100 and 140 °C and NPG/FAME ratios between 0.5 and 2), were used, obtaining high conversion values (96%) and a final product with a high viscosity (20.7 cSt), which allows for its use as engine oil (SAE 5W). In conclusion, biodiesel and biolubricant production was feasible through homogeneous catalysis, proving the feasibility of this process at the laboratory scale. Further studies, including the use of different heterogeneous catalysts, as well as the implementation of this process at a semi-industrial scale, are recommended.

Preparation of natural adhesives with high-strength and low temperature fast-curing properties

The development of natural adhesives to substitute petroleum-based products is crucial for sustainable progress. However, the bond strength of most existing natural adhesives still falls short of that of commercially available adhesives and the curing process often demands prolonged high-temperature treatment. Herein, we prepared pure natural adhesives using gelatin (GE), tung oil (TO), and dopamine (DA) as the main raw materials. The shear strength of the adhesive to wood reached up to 6.35 MPa, a significant improvement over most natural wood adhesives reported. Additionally, the tensile strength of the adhesive to wood reached 10.50 MPa, which is comparable to commercially available neoprene-phenolic wood adhesives (9.99 MPa) and cyanoacrylate instant adhesives (9.48 MPa). In addition, the natural adhesive prepared by us exhibits fast curing performance at room temperature and can be fully cured in only 12 min, which is significantly better than the commercially available adhesive. The adhesives prepared in this study also possessed excellent reversible curing properties, antimicrobial properties, low toxicity, and degradability. These characteristics offer new insights for the advancement and dissemination of natural adhesives.

Deep eutectic solvent (DES) pretreatment and lignin regeneration for the development of a bamboo leaf-based bioplastic.

The excessive utilization of petroleum-based plastic products has led to a pervasive environmental and human health threat. In response, the adoption of bioplastics derived from biomass has emerged as the foremost alternative to conventional plastics, owing to their inherent biodegradability and sustainability. The present study demonstrates the preparation of a biodegradable and cost-effective lignocellulosic bioplastic by utilizing dissolving bamboo leaf powder with deep eutectic solvents (DES) and regenerating lignin in situ. The DES was synthesized through a one-step heating and stirring method using choline chloride (ChCl) and anhydrous oxalic acid. The crystallinity of the bioplastics is enhanced by DES pretreatment, thereby improving the internal structural order of the material. Moreover, lignin regeneration reduces the pore size within the bioplastics and contributes to a more compact internal structure. The prepared lignocellulosic bioplastics exhibit remarkable mechanical strength, with a tensile strength of 113MPa. Additionally, they demonstrate good water stability, as evidenced by a contact angle of 55.52°. Moreover, these bioplastics possess an exceptional biodegradability with a degradation rate exceeding 98% after 60days. This study presents an innovative approach for the high-value utilization of bamboo leaf resources.

Enhancing mechanical performance and water resistance of Careya-Banana fiber epoxy hybrid composites through PLA coating and alkali treatment

The ongoing research focuses on exploring the potential of Careya arborea (CA) fiber, banana fiber (BF), and epoxy composites as sustainable alternatives to petroleum-based products and synthetic fibers. The aim is to enhance the interfacial bonding and overall performance of these composites while reducing reliance on traditional materials. The study investigates the adhesion between CA fiber, BF (both chemically treated), and epoxy with polylactic acid (PLA) coating. Specifically, it examined how the PLA coating affects the mechanical properties, including tensile strength, flexural strength, impact resistance, and water absorption behavior, of the fabricated composites. Mechanical characterizations of the composite specimens are conducted following ASTM standards. The PLA-coated and NaOH-treated specimens significantly improved their tensile strength (20.56%) and flexural strength (16.7%), and significantly reduced their water absorption capacity (by 47.6%) compared to the untreated ones. These findings highlight the promise of using treated natural fibers and PLA coatings to create more sustainable and high-performance composite materials.

Straw Tar Epoxy Resin for Carbon Fiber-Reinforced Plastic: A Review.

The massive consumption of fossil fuels has led to the serious accumulation of carbon dioxide gas in the atmosphere and global warming. Bioconversion technologies that utilize biomass resources to produce chemical products are becoming widely accepted and highly recognized. The world is heavily dependent on petroleum-based products, which may raise serious concerns about future environmental security. Most commercially available epoxy resins (EPs) are synthesized by the condensation of bisphenol A (BPA), which not only affects the human endocrine system and metabolism, but is also costly to produce and environmentally polluting. In some cases, straw tar-based epoxy resins have been recognized as potential alternatives to bisphenol A-based epoxy resins, and are receiving increasing attention due to their important role in overcoming the above problems. Using straw tar and lignin as the main raw materials, phenol derivatives were extracted from the middle tar instead of bisphenol A. Bio-based epoxy resins were prepared by replacing epichlorohydrin with epoxylated lignin to press carbon fiber sheets, which is a kind of bio-based fine chemical product. This paper reviews the research progress of bio-based materials such as lignin modification, straw pyrolysis, lignin epoxidation, phenol derivative extraction, and synthesis of epoxy resin. It improves the performance of carbon fiber-reinforced plastic (CFRP) while taking into account the ecological and environmental protection, so that the epoxy resin is developed in the direction of non-toxic, harmless and high-performance characteristics, and it also provides a new idea for the development of bio-based carbon fibers.

Liquefaction optimization of grape pulp using response surface methodology for biopolyol production and bio-based polyurethane foam synthesis.

Both environmental and economic disadvantages of using petroleum-based products have been forcing researchers to work on environmentally friendly, sustainable, and economical alternatives. The purpose of this study is to optimize the solvothermal liquefaction process of grape pomace using response surface methodology coupled with a central composite design. After investigating the physicochemical properties of the liquified products (biopolyol) in detail, a bio-based rigid polyurethane foam (RPUF) was synthesized and characterized. The hydroxyl and acid numbers and viscosity values of all the biopolyols were analyzed. According to variance analysis results (%95 confidence range), both the reaction temperature and catalyst loading were determined as significant parameters on the liquefaction yield (LY). The model was validated experimentally in the following reaction conditions: 4.25% catalyst loading, 50 min reaction time, and 165 °C reaction temperature, which yields an LY of 81.3%. The biopolyols produced by the validation experiment display similar characteristics (hydroxyl number: 470.5 mg KOH/g; acid number: 2.31 mg KOH/g; viscosity: 1785 cP at 25 °C) to those of commercial polyols widely preferred in the production of polyurethane foam. The physicochemical properties of bio-based foam obtained from the biopolyol were determined and the thermal conductivity, closed-cell content, apparent density, and compressive strength values of bio-based RPUF were 31.3 mW/m·K, 71.1%, 33.4 kg/m3, and 105.3 kPa, respectively.

Preparation and Properties of Rosin-based Anthraquinone Fluorescent Waterborne Polyurethane.

Fluorescent polyurethane has been widely used as fluorescent probes and switches due to its diverse structure and properties, but most of them are solvent-based and synthesized from petroleum-based products. A new type of rosin-based anthraquinone fluorescent waterborne polyurethane (WPU-DAAQ) with good and stable fluorescence properties was synthesized by reacting rosin modified ester (RAG) as a diol and 2, 6-diaminoanthraquinone (DAAQ) as a fluorescent agent with diisocyanate. The structure of WPU-DAAQ was characterized by Fourier transform infrared spectroscopy, UV-vis absorption spectroscopy, and hydrogen magnetic resonance spectroscopy. The fluorescence properties, water resistance, and solvent resistance of WPU-DAAQ were tested. The results showed that DAAQ was successfully grafted onto the polyurethane molecular chain. The fluorescence intensity of WPU-DAAQ increases and then decreases with increasing excitation wavelengths, and increases with the increase of solvent ether content, and is significantly enhanced compared to DAAQ. The dispersion stability was good with the increase of DAAQ. The introduction of DAAQ into polyurethane improved the thermal stability, hydrophobicity, and solvent resistance of WPU-DAAQ. Therefore, WPU-DAAQ is a new type of fluorescent waterborne polyurethane with stable dispersion properties, good fluorescent properties, heat resistance and water resistance.

Phenolation to Improve Hardwood Kraft Lignin for Wood Adhesive Application.

Lignins, naturally occurring aromatic polymers with phenylpropane units, are promising bio-based alternatives for petroleum-based products. Resole-type phenol formaldehyde (PF) adhesive is commonly used in wood composites requiring durability and weather-proofness. However, PF adhesive is a petroleum-based product. The objective of this study is to transform the low-reactivity hardwood kraft lignin (KL) as the phenol substitute in the PF adhesive formulation by acidic phenolation. The variations in the molecular weights, chemical structures, and functional groups in lignins were investigated before and after the phenolation. The results indicate that the KL can be cleaved, and phenols are crosslinked onto KL to produce phenolated kraft lignin (PKL) under the suitable phenolation condition, heating 3/5 (w/w) of KL/phenol at 90 °C for 2 h with 5% H2SO4 as the catalyst. Resole-type PKL-PF adhesives can be directly synthesized after the phenolation in the same reactor. Plywood laminated with this adhesive obtains satisfactory strength and low formaldehyde emission. This not only reduces the usage of petroleum-based phenol but also increases the reactivity and applications for hardwood KL.

Production, optimization, and characterization of biodiesel from almond seed oil using a bifunctional catalyst derived from waste animal bones and almond shell

The search for environmentally friendly alternatives to conventional fossil fuels has been intensified by the global shift toward sustainable energy sources. With over 95% of the fuel market dominated by petroleum-based products, concerns regarding their limited biodegradability and high eco-toxicity have been escalated. In response, there is a growing demand for biobased solutions that can mitigate pollution and reduce greenhouse gas emissions. In this study, the synthesis of biodiesel from waste almond seed oil (WCO) was focused on, utilizing an innovative bifunctional catalyst derived from waste animal bones and almond shells. The efficacy of the catalyst synthesized from these unconventional materials was confirmed through rigorous characterization techniques, including scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier transform infrared (FTIR) spectroscopy, and Brunauer, Emmett, and Teller (BET) analysis. The physicochemical properties of WCO and the resulting biodiesel were evaluated according to ASTM D6751 and EN 14214 standards. To optimize the catalytic process, Box Behnken Design (BBD) was employed to explore the effects of key parameters: reaction temperature (40-60°C), reaction time (60-90 minutes), catalyst loading (0.5-1.5 wt%), and methanol-to-oil ratio (6:1-18:1). Remarkably, under optimal conditions, an impressive biodiesel yield of 86.2% was achieved. Specifically, the optimal parameters were a Methanol:Oil Ratio of 6.026, Catalyst Loading of 1.49917 wt%, Reaction Time of 66.8179 minutes, and Temperature of 59.9806°C. The potential of utilizing waste materials for sustainable biodiesel production is underscored by our findings. The bifunctional catalyst developed in this study represents a cost-effective and environmentally friendly alternative to conventional catalysts, contributing to cleaner fuel production methods.

Investigating the properties of nanoparticles from heveabrasiliensis shell for coolant application in PEMFCs

Extensive consumption of petroleum-based products, which has resulted in energy depletion, prompted a need to seek alternative and renewable means of transportation. PEMFCs can achieve high power density, low operating temperatures, rapid start-up, and clean energy, making them ideal for transportation. Several studies have demonstrated that conventional cooling agents, such as water or water with ethylene glycol, do not dissipate heat efficiently in PEMFCs, resulting in deteriorating performance and a shortened operational lifespan over time. The incorporation of bio-sourced nanofluids as an alternative coolant for Proton Exchange Membrane (PEM) fuel cells is the newest venture to take over PEM fuel cell development. Utilizing bio-sourced nanofluids is being evaluated for elevating the heat conduction and decreasing the electrical conductivity of proton exchange membrane fuel cells (PEMFCs). The objective of this article is to investigate Hevea brasiliensis Shell (HBS)-based nanofluids dispersed in water and Ethylene glycol (EG) at varying concentrations of 0.1 vol%, 0.3 vol%, and 0.5 vol% by paying attention to improving heat transfer, extracting high electrical output, reducing pump loss, and increasing the longevity of cells. As an adverse effect, incorporating HBS at a 0.5 % volume concentration within an 80:20 mixture of water and ethylene glycol (W:EG) resulted in an 8 % improvement in heat transfer and a 77 % increase in electrical conductivity when compared to W:EG (80:20), which is promising as a pertinent cooling technique for PEMFC stacks.

One-pot molten strategy to synthesize tough bio-derived lignin-based photothermal elastomers for photoelectric driven and programmable shape memory

Utilizing renewable biomass as an alternative to petroleum-based products for the development of smart materials emerges as a pivotal strategy for sustainable development. However, the straightforward, rapid, and cost-effective deployment of biomass for novel smart material synthesis remains a formidable challenge. Herein, we employ a facile solvent-free one-pot strategy to develop a multifunctional smart biomass photothermal elastomer, which synthesized from the natural small molecule of α-lipoic acid (LA) and renewable lignin biopolymer without any chemical modification. The incorporation of lignin confers to the obtained elastomers superior mechanical strength, photothermal responsiveness, photothermal self-healing, and adhesive capabilities. Notably, the photothermal elastomers can be fully recycled and reused by simple thermal remodeling. As a proof of concept, the temperature difference generator can be driven to generate electricity utilizing the excellent photothermal effect of elastomers, highlighting its excellent light-heat-electricity conversion capability. Intriguingly, the photothermal elastomers exhibit light-driven shape memory effect, enabling to grasp objects by shape-programmed four-arm soft gripper under selective irradiation. This pioneering work not only demonstrates significant progress in high-value utilization of bio-derived lignin, but also opens up a new avenue for sustainable and innovative applications in advanced energy management devices and soft actuators.

Synthesis of Gemini-type imidazoline quaternary ammonium salt using by-product fatty acid as corrosion inhibitor for Q235 steel

Gemini-type imidazoline quaternary ammonium salt is a new type of environmentally friendly corrosion inhibitor has been widely used in engineering materials. However, most of them are hazardous/toxic compounds derived from petroleum-based products, which did harm to environment. In this work, an environmentally friendly Gemini-shaped imidazoline quaternary ammonium salt corrosion inhibitor (G211) was synthesized using cheap fatty acid recycled from dimer acid industry as feedstock. The corrosion inhibition effects of G211 on Q235 steel in 1 M HCl solution were investigated through weight loss experiments, potential polarization curves, and alternating current impedance spectroscopy experiments. The results show that the inhibition rate of G211 as a mixed-type inhibitor is up to 94.4% and the concentration drop as low as 500 ppm at 25 ℃. The adsorption of G211 on Q235 surface follows Langmuir adsorption isothermal curve. The chemical composition of the Q235 steel surface was analyzed through scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Furthermore, the possible corrosion inhibition mechanism of G211 on the surface of Q235 steel is proposed. This article not only presents an outstanding solution for safeguarding Q235 steel against corrosion but also introduces a feasible method for high-value utilization of monomer acid (MA).

5-Hydroxymethylfurfural and its Downstream Chemicals: A Review of Catalytic Routes.

Biomass assumes an increasingly vital role in the realm of renewable energy and sustainable development due to its abundant availability, renewability, and minimal environmental impact. Within this context, 5-hydroxymethylfurfural (HMF), derived from sugar dehydration, stands out as a critical bio-derived product. It serves as a pivotal multifunctional platform compound, integral in synthesizing various vital chemicals, including furan-based polymers, fine chemicals, and biofuels. The high reactivity of HMF, attributed to its highly active aldehyde, hydroxyl, and furan ring, underscores the challenge of selectively regulating its conversion to obtain the desired products. This review highlights the research progress on efficient catalytic systems for HMF synthesis, oxidation, reduction, and etherification. Additionally, it outlines the techno-economic analysis (TEA) and prospective research directions for the production of furan-based chemicals. Despite significant progress in catalysis research, and certain process routes demonstrating substantial economics, with key indicators surpassing petroleum-based products, a gap persists between fundamental research and large-scale industrialization. This is due to the lack of comprehensive engineering research on bio-based chemicals, making the commercialization process a distant goal. These findings provide valuable insights for further development of this field.

Pea-like inspired design: Lignin nanospheres-mediated PVA film with high strength, low water evaporation permeability, strong UV resistance and anti-oxidation properties for extending food freshness

The excessive utilization of petroleum-based plastic products has inflicted significant harm upon the ecological and health problems, compelling individuals to continually seek renewable and biodegradable polymer materials as alternatives. Drawing inspiration from the structure of a natural pea pod, a unique interlocking packaging material based on a pea-like structure is obtained via green electrospinning and mild glutaraldehyde (GA) cross-linking method. Herein, polyvinyl alcohol (PVA) serves as a green protective layer encompassing the active lignin nanospheres (LNP) pod, forming a packaging film that prevents LNP migration. The LNP within the fibers can effectively shorten the fiber spacing, and when exposed to the GA vapor, they promote the bonding between neighboring fibers to form a tight interlock structure. Benefiting from the interlocking pea-like structure, the film exhibits excellent tensile strength (3.53 ± 0.02 MPa), wetting strength (1.92 ± 0.05 MPa), and outstanding water vapor barrier properties (3.27 ± 0.3 10−10 gm−1 s−1 Pa−1). Furthermore, the inclusion of LNP endows exceptional water resistance, UV-blocking capabilities, antibacterial and antioxidant properties, which can effectively prolong the storage life of perishable fruits. This eco-logical sustainable design holds tremendous potential in mitigating the burden on the environment, thus making a novel avenue for exploring alternatives to petroleum-derived plastics.

Microbial cell factory for butyl butyrate production: Knowledges and perspectives.

Butyl butyrate is a short-chain fatty acid ester (C8) with a fruity aroma. It has broad prospects in the fields of foods, cosmetics and biofuels. At present, butyl butyrate is produced by chemical synthesis in the industry, but it is highly dependent on petroleum-based products. The growing concerns regarding the future scarcity of fossil fuels have been strongly promoted the transition from traditional fossil fuels and products to renewable bioenergy and biochemicals. Therefore, it is necessary to develop a green biochemical technology to replace traditional petroleum-based materials. In recent years, microorganisms such as Escherichia coli and Clostridium have been engineered to serve as cell factories for the sustainable one-pot production of short-chain fatty acid esters, including butyl butyrate. This opinion highlights the recent development in the use of lipases and alcohol acyltransferases (AATs) for butyl butyrate production in microbial fermentation, as well as future perspectives.

Production of Transportation Fuels from Fischer–Tropsch Waxes: Distillation, Blending, and Hydrocracking

Nowadays, transportation fuels such as diesel or gasoline are standardly produced from crude oil refining. These petroleum-based products are gradually replaced by more environmentally friendly sources, such as Fischer–Tropsch diesel fractions and other biofuels. The present work reports the distillation of Fischer–Tropsch (FTS) waxes and its use for fuel production by (i) blending the FTS wax diesel fraction with fossil diesel (7:93; 15:85; 30:70; and 50:50 wt.%) and (ii) blending the FTS wax heavy fraction (360–700 °C) with vacuum gas oil (10–50 wt.%) followed by hydrocracking at industrial operating conditions (T = 420 °C, WHSV = 0.5–1.0 h−1, P = 10.0 MPa). The obtained products in both cases were analysed and compared with standard EN590 for petroleum-diesel fuels. Overall, our results point to the suitability of the distillation of FTS waxes for renewable fuel production, either by straight blending of the diesel petroleum-based products or co-hydrocracking of the heavy fraction with vacuum gas oil.

Model test on cooling performance of a new method for mitigating permafrost thaw around buried oil pipeline

Buried pipelines have been widely used to transport petroleum-based products over long distances in permafrost regions. Field observations reveal that they are endangered by rapid permafrost thawing and resulting massive soil movements, despite adopting some measures to protect pipeline foundation permafrost. A new mitigation technique is proposed to slow down the permafrost thawing ulteriorly. With this technique, a seasonal air-cooled embankment (SACE), mainly composed of a crushed rock layer, supports the pipeline and transfers the heat from the pipeline to ambient air in the cold seasons. A scale model test with the controlled air and oil temperatures was carried out to evaluate the proposed measure. The temperature and volumetric unfrozen water content of the permafrost subgrade beneath both the SACE and the direct-buried pipeline, as well as ground surface displacements, were measured during the whole testing process. A comparison of the hydrothermal process of the subgrade permafrost under the SACE and the direct-buried warm pipeline indicates that the proposed measure can substantially mitigate the rapid thawing of permafrost by controlling the geothermal regimes of the pipeline.

Tricks under Trade: How International Trade Both Facilitates and is Facilitated by Corporate Environmental Crime in the Waste and Hydrocarbon Sectors

Abstract Legal scholarship in the realm of international economic law has a blind spot: the practice of international trade. Cargo and container shipping is the blood and guts of international trade, and it is fuelled by bunker oil – a hydrocarbon mixture of the dirtiest petroleum-based products. Worryingly, there is empirical evidence of bunkers being intentionally contaminated with waste oils. This fraudulent contamination violates numerous international, national, and EU rules on waste management and poses immense risks to the health of planet and people alike. These same acts of fraud are also extremely profitable, and they facilitate the smooth functioning of our global economy. The fraud is itself not just incentivised in the tight-margins reality of international trade, but it is facilitated by the lack of proper legislation and the vulnerability of the existing means of enforcement in the areas where there is legislation to comply with. Economic operators often use falsified documents to market fuel oil that should be considered as waste. Systematic wrongdoing of this kind is detrimental to the environment and risks eroding the rule of law in both its formal and substantive conceptualisations.

Improving 5-(hydroxymethyl)furfural (HMF) tolerance of Pseudomonas taiwanensis VLB120 by automated adaptive laboratory evolution (ALE)

The aldehyde 5-(hydroxymethyl)furfural (HMF) is of great importance for a circular bioeconomy. It is a renewable platform chemical that can be converted into a range of useful compounds to replace petroleum-based products such as the green plastic monomer 2,5-furandicarboxylic acid (FDCA). However, it also exhibits microbial toxicity for example hindering the efficient biotechnological valorization of lignocellulosic hydrolysates. Thus, there is an urgent need for tolerance-improved organisms applicable to whole-cell biocatalysis. Here, we engineer an oxidation-deficient derivative of the naturally robust and emerging biotechnological workhorse P. taiwanensis VLB120 by robotics-assisted adaptive laboratory evolution (ALE). The deletion of HMF-oxidizing enzymes enabled for the first time evolution under constant selection pressure by the aldehyde, yielding strains with consistently improved growth characteristics in presence of the toxicant. Genome sequencing of evolved clones revealed loss-of function mutations in the LysR-type transcriptional regulator-encoding mexT preventing expression of the associated efflux pump mexEF-oprN. This knowledge allowed reverse engineering of strains with enhanced aldehyde tolerance, even in a background of active or overexpressed HMF oxidation machinery, demonstrating a synergistic effect of two distinct tolerance mechanisms.