Pesticide Application Practices Research Articles

Pesticide application behavior in green tea cultivation and risk assessment of tea products: a case study of Rizhao green tea.

Previous research on pesticides in green tea mainly focused on detection technology but lacked insights into pesticide use during cultivation. To address this gap, a survey was conducted among Rizhao green tea farmers. The survey results showed that most tea farmers were approximately 60years old and managed small, scattered tea gardens (< 0.067ha). Notably, tea farmers who had received agricultural training executed more standardized pesticide application practices. Matrine and thiazinone are the most used pesticides. A total of 16 types of pesticides were detected in the tested green tea samples, with 65% of the samples containing residues of at least one pesticide. Notably, higher levels of residues were observed for bifenthrin, cyfluthrin, and acetamiprid. The presence of pesticide residues varied significantly between seasons and regions. The risk assessment results indicated that the hazard quotient (HQ) values for all 16 pesticides detected in green tea were < 1, suggesting that these residue levels do not pose a significant public health concern.

Dietary risk assessment of drinking water and fish from cultivated wetlands of Ndop

ABSTRACT This study evaluated pesticide exposure practices, and the potential health risks of drinking water and consuming fish from the cultivated wetlands of Ndop, Cameroon. Six hundred and twenty-six questionnaires were conveniently administered to farmers (≥ 26 years old) in a cross-sectional study to assess exposure practices and dietary risks. The Chi-square and Pearson correlation coefficients were used to establish relationships between variables. The PRIMET model was used to predict a worst-case dietary risk. The pesticide handling practices of 90% of farmers were inadequate. Chlorpyriphos, lambda-cyhalothrin, fipronil, and paraquat dichloride posed a possible dietary risk at recommended and applied doses, with chlorpyrifos having the highest exposure toxicity ratio (ETRdiet = 36.72). Paraquat dichloride, fipronil, and lambda-cyhalothrin posed a possible dietary risk at 26.3%, 58.3%, and 62.2% of their recommended concentrations, respectively. Remarkably, the dietary risk for cypermethrin was acceptable at 5.8 times its recommended dose (ETRdietR = 0.29). The significant positive correlation (p = 0.000) between PECfish and ETRdiet, suggests a possible health risk of consuming fish and drinking water harvested from the wetlands, thus the need for replacing pesticides posing possible risks at lower or recommended concentrations with less toxic alternatives and to train farmers on pesticide application practices.

Characterization of herbicide use practices in cereal agroecosystems in western Burkina Faso

The use of pesticides often leads to environmental contamination above acceptable levels. The level of contamination is related to poor pesticide application practices, in addition to the properties of pesticides and soil characteristics. The primary objective of this study was to characterize herbicides and their application practices in cereal crops in the regions of Hauts-Bassins, Sud-Ouest, Cascades, and Boucle du Mouhoun in Burkina Faso. A semi-structured questionnaire was used to collect and extract data from 617 cereal farmers in the four regions. During the survey, the identified herbicides were characterized using pesticide property databases. The survey shows that most cereal farmers in the regions are illiterate (58.18%) and have not received any training in pesticide use (84.28%). Only a small percentage of farmers (1.3%) consult technical services for the selection of herbicides to be used. The survey also revealed that 60% of farmers leave empty herbicide containers in the wild, 39.93% use water sources to clean sprayers, and 17.83% use them to prepare the spray mixture. A total of 25 active ingredients were identified in 117 commercial herbicide products with a total use of 8100 litres and 280 kg. Of the listed herbicides, 45.37% were not approved by the Sahel Pesticide Committee (CSP). Among the non-approved herbicides, 27.78% contained paraquat, atrazine, and acetochlor, which the CSP bans. The study shows that farmers do not follow good practices when using herbicides, which can contaminate different environmental compartments and cause harmful effects to non-target organisms.

Assessment of rice growers’ exposure to pesticides applied in Kelantan, Malaysia

There is a clear need for more information on occupational exposure to pesticides on smallholder farms in developing countries. This study investigates the exposure of rice growers to pesticides through the use of knapsack/backpack sprayers, a widespread practice in developing countries such as Malaysia. We collected pesticide application information from 23 rice growers using face-to-face interviews and questionnaires. We used the information to predict total daily exposure to individual active substances across a rice-growing season using selected exposure models. We then compared the estimates with toxicity thresholds to determine the potential risks. The 23 rice growers cultivated between 0.6 and 3.8 hectares of rice and applied pesticides on three and 13 spray days across the season, using up to eight active substances on individual days. Individuals had estimated average daily exposures to individual substances between 4.1x10-3 and 1.3x10-1 mg kg-bw-1 day-1, with dermal exposure accounting for 89 – 99.6% of total exposure. Overall, 28% of the 408 applications’ exposure exceeded the toxicity threshold. This was due to highly toxic pesticides and growers not wearing gloves while working. Health risks can be reduced by providing training and information on pesticide product selection and application practices.

Analisis Risiko Kandungan Timbal (Pb) pada Air Sumur Kawasan Pertanian di Kenagarian Simpang Tanjung Nan IV Kabupaten Solok

Farmers in the Nagari Simpang Tanjung Nan IV, Solok Regency, are using synthetic pesticides to achieve good agricultural results. Inappropriate pesticide application practices, such as mixing multiple types of pesticides simultaneously, using incorrect dosages, and spraying more than three times a day, have become commonplace. Residents living next to their farmlands have wells as their primary source of clean drinking water, which are located within the agricultural area. This situation poses a contamination risk to the community. The objective of this research is to analyze the risk of lead (Pb) content in well water within the agricultural area of Kenagarian Simpang Tanjung Nan IV. The research design employs the Environmental Health Risk Analysis (ARKL) method. The research findings indicate that Pb concentrations in the water range from 6,735 mg/L to 53,492 mg/L, exceeding the quality standards set by the Ministry of Health Regulation No. 32 of 2017. A significant portion of the population frequently experiences health issues, with an intensity of 66.7%. The average lifetime Risk Quotient (RQ) is 1.11, indicating a risk of pesticide poisoning in the community. Therefore, it is recommended that the community limits the use of pesticides and uses boiled water for daily consumption in an effort to minimize the danger of exposure to heavy metal Pb entering the body through water.

Status of Pesticide Use among Thyme (Thymus vulgaris) Crop Farmers in North West Bank, Palestine

The data were collected to diagnose the current status of pesticide use on thyme crops (Thymus vulgaris). In total, 111 questionnaires were used to calculate the means, standard deviation, and percentages of farmers’ responses. Chi-square (χ2) and T-tests were employed to test the associations between pesticide application practices and demographic variables, recipients of extension, sources of farmer information, production, and marketing. The results showed that 69.7% of farmers used 23 insecticides, and 11.8% of the pesticides were not suitable for pest control. Additionally, 73.5% were not compatible with the safety period. There was a 29.2% increase in pesticide concentration from the recommended amount and a 32.4% increase in the number of spraying times during the season. Farmer commitment to pesticide use instructions was moderate, with a mean of 2.8 ± 0.68. In total, 51.4% of farmers received extension services, and 47.2% relied on their local experience for pesticide practices. Extension services influenced the overused dose. Most farmers did not participate in specialized courses or field days, and no regulatory extension was carried out by institutions for them. They did not adhere to a production guide or obtain a quality certificate. The application of different pesticides did not increase the productivity of thyme. The study findings revealed alarming trends in current farmer practices, with significant implications for crop, farmers, and consumer safety. They underscore the pressing need for targeted interventions, including improved extension services and increased farmer awareness to promote responsible pesticide use.

Knowledge, attitude and practices of farmers and experts about the effects of pesticide residues on agricultural product users and ecosystems: A case of Fogera District, Ethiopia

Pesticides are chemicals used to control different types of pests. Though pesticides played a role in improving the quantity and quality of production, they have been threatening ecosystems and posed effects on humans in different parts of the world. Unfortunately, there were no studies made about the effects of pesticide residues on ecosystems and consumers in the Fogera District of Amhara Region, Ethiopia. Hence, the main objective of this study was to understand the knowledge, attitude, and practices of respondents about the effects of pesticide residues on ecosystems and consumers. A cross-sectional survey complemented by focus group discussions and field observations was used to gather the required data for the study. The close-ended data were analyzed using descriptive statistics, logistic regressions, and independent t-test, and data from open-ended questions were grouped and summarized based on their similarities. The findings of the study confirmed that there was significant knowledge, attitude, and practices difference between farmers and consumers about the effects of pesticide residues on ecosystems and humans. Farmers used highly toxic pesticides to control pests and improve the glossiness of vegetables and khat. Though they didn’t use the sprayed vegetables for their home consumption, some of the farmers deliberately supplied pesticide-sprayed vegetables without worrying about the negative effects of the pesticides on the consumers. There were also fishing practices from rivers after intoxicating the fish using the pesticide sprayed feed. This, in turn, might poison individuals who consume the fish. In general, pesticide application practices and consumption of pesticide-sprayed foodstuffs and surface water might pose serious health risks to ecosystems and humans. To minimize the negative effects of pesticides, rigorous awareness-raising on the effects and management of pesticides, enforcement of laws, delineation of the pesticide free buffer zone for waters, the establishment of a clear pesticide supply chain to the end users, ecosystem assessment and food safety monitoring schemes are highly required.

Generalizable consistency of soil quality standards for pesticides: Modeling perspectives

Soil quality standards for pesticides play a crucial role in protecting plants and preventing potential health hazards to humans. Here we discuss modeling approaches to define pesticide soil quality standards from two effect endpoints, which ensures consistency throughout the entire pesticide life cycle from application to human exposure assessment. Given that pesticides are applied in a pulse-like emission pattern and their soil concentrations change over time, both a ceiling legal limit and an average legal limit for pesticide soil quality standards should apply to the initial pesticide application practice and the potential human health effect. The timing intervals for pesticide application and the dissipation half-life in the soil can be used to quantify the relationship between the ceiling and average legal limits. By analyzing primary exposure pathways related to soil contamination, the average legal limit can be linked to theoretical human health risks, which requires a comprehensive evaluation for an adequate safety margin, including human interactions with soil, exposure assessment of soil pesticides, and allocation exposure assessment. To establish acceptable human health risks, the average legal limit can be determined, and the ceiling legal limit can be estimated based on the quantitative relationship between the ceiling and average legal limits. Additionally, we discuss situation-specific factors, including climate-pattern and behavior-pattern factors, to define pesticide soil quality standards to further complete the modeling framework. We hope insights presented in this paper will assist regulatory agencies worldwide in defining pesticide soil quality standards that meet their specific regulatory needs throughout the entire pesticide life cycle.

Pesticides in the hydrogeo-environment: a review of contaminant prevalence, source and mobilisation in India.

Chemical pesticides in the hydrogeological system are a global concern as they pose a severe threat to humans and other organisms. In agriculture, around 4.12 million tonnes of pesticides were used globally in 2018, which is 50% more than in the 1990s. Various pesticides detected in the hydrogeological system of India since the 1990s have been documented and reviewed to understand the prevalence, source, history and degradation pathways. This review contributes to a better understanding of existing pesticide pollution and the state of hydrogeological resource deterioration. Small to excess levels of pesticide residues were detected in groundwater, surface water, soil, and sediments. Pesticides that were most commonly and predominantly found in the hydrogeological system were HCHs, DDTs, endosulfan, heptachlor, drins (aldrin, dieldrin, endrin), chlordane etc. β and γ-HCH isomers among HCHs, whereas p,p'-DDT and p,p'-DDE among the DDTs were detected most prevalently. In many regions, pesticide residue levels in water have exceeded the maximum residue limits of WHO and BIS, while those in soils and sediments have exceeded the threshold effect level and probable effect level. Higher pesticide residues were detected in the water resources of rural agricultural areas compared to peri-urban or urban areas. A positive correlation of pesticide residues between water resources and soil has been observed in some regions, suggesting a similar contamination source. Diagnostic ratios of pesticides reveal their source, history and degradation pathways. Diagnostic ratios observed in various studies conducted in India suggest historical as well as recent use of banned pesticides. Strengthening current policies and regulations, monitoring pesticide use, changes in pesticide application practices, awareness among farmers, and the use of prominent removal techniques are necessary to tackle pesticide contamination in India.

Cambodian rice farmers’ knowledge, attitudes, and practices (KAPs) regarding insect pest management and pesticide use

ABSTRACTInsect pests are a serious problem for rice farmers in Cambodia, threatening livelihoods and food security. To protect their yields, farmers are dependent on broad-spectrum pesticides, which has led to a pesticide ‘lock-in’ scenario. Our study aimed to better understand farmers’ current pest management practices and the underlying knowledge and attitudes driving these behaviours. We surveyed rice farming households (n = 168) from five different villages in Battambang Province, Cambodia. Survey respondents considered insect pests to be the most significant cause of yield loss. Respondents depended solely on chemical insecticides to manage insect pests. Combinations of agronomic and pesticide application practices contributed to pesticide dependency, including high seeding rate, insecticide timing and application rate. Additionally, 77% of respondents misidentified the beneficial lady beetle, Micraspis discolor, as a pest. Respondents indicated a desire for education and training on pest and beneficial arthropod identification, safe pesticide use, and improved cropping practices. We suggest critical areas for education and training are damage thresholds of local pests, the role of natural enemies, and improved awareness of pesticide toxicity and exposure. Promoting local knowledge sharing to engage and empower farmers to make informed decisions about their own pest management can forge a pathway away from pesticide dependency.

DEVELOPMENT AND FABRICATION OF AGRICULTURAL PEST CONTROL SYSTEM

Research is “creative and systematic work undertaken to increase the stock of knowledge”. It involves the collection, organization and analysis of information to increase understanding of a topic or issue. Efficient use of pesticides can helpful to control plant pests and diseases to increasethe crop yields. The use of agrochemicals can effectively enhance the quantity and quality of crop;however, it increases the environmental risks in recent years. Pesticide application utilizes the to a significant percentage of the production cost. During chemical plant protectionpractices, over application of pesticide or inefficient spraying equipment may cause serious issueson human healthand the environment. Effective pesticide application is a critical activity during crop production season that requires efficient spraying machinery with proper calibration as well as relevant regulations to reduce off-target spray deposition. Thus, the significant among all the factors which are influencing the degree of off-target spray deposition is the design and application spraying technology Conventional agricultural pesticide application practices havedeveloped a contradiction among the yield enhancement, cost effectiveness and environmental protection. Therefore, pesticides have to be applied using suitable spraying systems to avoid adverse effects on environment as well as human health. Thus, in recent decades, spraying methods and technologieshave been undergoing continuous evolution. Conventional sprayerswere very laborious and International Journal of Scientific Research in Engineering and Management (IJSREM) Volume: 07 Issue: 01 | January - 2023 Impact Factor: 7.185 ISSN: 2582-3930 © 2023, IJSREM | www.ijsrem.com DOI: 10.55041/IJSREM17568 | Page 2 requirevery heavy machinery to operating them in the field. They increasethe application amount because of no proper application method for spraying nozzles, crop foliage detection, and weather parameters. advancement in spray application technologies increase crop production and increase pesticide efficiency on weed and insects in the field. Spray loss in the form ofspray drift, weather effects, target detection, and control flow nozzles problem solved by advancedpesticide applicationtechnologies. The time-consuming problem for tank refilling is reduced withultra-low volume sprayers and fine droplet spray nozzles. With time the crop maintaining technology-advance fromweeds and pest, detection to spray application nozzles. The objective of this chapter is to highlight the attachments conceived by both electronics and mechanical components which implies for the working of agricultural spraying machine.

Evaluation of Liquid Atomization and Spray Drift Reduction of Hydraulic Nozzles with Four Spray Adjuvant Solutions

The droplet size distribution following pesticide application practices can significantly impact droplet drift and non-target organisms (animals and plants). However, the relationship among liquid sheet breakup, drop formation, and droplet drift is an area that has been studied over the past 65 years but is still not fully understood. The objectives of this study were severalfold: to examine the liquid sheet breakup following the use of different adjuvants (sodium dodecyl sulfate, aerosol OT, and silicone at 1%) and their effects on the drift via three commonly used commercial spray nozzles (XR, AIXR, and TXVK). The spray sheet and initial droplet size spectrum for each spray was detected by a particle image velocimetry (PIV) system, and the drift for each treatment was measured in a wind tunnel. The nozzle type and the spray solution were found to significantly affect the liquid sheet breakup characteristics. AIXR produced large droplets, and TXVK with short liquid sheet length produced more small droplets. All adjuvants used in these experiments increased the formation of large droplets upon atomization while simultaneously reducing driftable fines (e.g., drops %&lt;150 µm). The drift potential can be reduced by up to 66.1% when switching from a fine spray quality (TXVK) to a coarse spray quality (AIXR). The SDS adjuvant provided the most effective drift reduction for XR and TXVK nozzles showing reduced drift potential by 69.2% and 66.3%, respectively, while the silicone adjuvant showed the largest drift reduction for AIXR of 78.3%. The correlation between the liquid sheet length and DV0.5 was positive for XR and TXVK nozzles, and there was a significant positive correlation between %&lt;150 µm and drift potential for all nozzles. This work suggests that the drift can be reduced significantly by changing the nozzle type and adding pesticide adjuvant into spray solution, which provided data support for the drift reduction of plant protection drones.

Knowledge, perception, and pesticide application practices among smallholder cocoa farmers in four Ghanaian cocoa-growing regions.

Pesticides are widely used in Ghana, especially in cocoa farming. However, the practice is suboptimal and unsupervised. Incorrect use of these chemicals can seriously harm human health, the environment, and economies that rely on these farmers' output. The study assessed cocoa farmers' pesticide knowledge, practices, and risk perception. Four hundred and four cocoa farmers were chosen randomly from 26 communities in four cocoa-growing regions of Ghana to answer questions about their risk knowledge, awareness, and practices, including personal protective equipment, storage and disposal of leftover pesticides, and used containers. The study revealed that 87% of the respondents belonged to cooperatives and certification groups. There was a significant positive relationship between group membership and benefits derived from inputs and training in pesticide use. About 70% of insecticides used were approved by the Ghana Cocoa Board, with neonicotinoids and pyrethroids being the most highly used insecticide classes in cocoa farms. Although farmers claimed adequate pesticide knowledge, this did not translate into practice, with the majority exhibiting improper pesticide storage, application, and disposal practices. Farmers appeared to know a lot but lacked the skills and attitude to put their knowledge to use. The improper practices appear to manifest in a variety of health symptoms experienced by farmers as a result of chemical exposure. The findings from this study suggest that cocoa farmers in Ghana require adequate practical training and support on pesticide use to reduce their associated health risks, protect the environment and ensure sustainable cocoa production in the world's second-largest cocoa bean exporter.

Does pesticide use in agriculture present a risk to the terrestrial biota?

Inadequate pesticide application practices have many implications on human and environmental health. This research aimed at assessing pesticide risks on bees, non-target arthropods (NTAs) and earthworms, using PRIMET (Pesticide Risks in the Tropics to Man, Environment and Trade), a pesticide risk model, in the western highlands agro-ecological zone of Cameroon. For this purpose, information on pesticide usage stratagem (dosage, application interval and number of applications) and ecotoxicological properties (median lethal doses, persistence and no observable effect concentration) were gathered and entered into PRIMET to acquire the Predicted Exposure Concentration (PEC), No Effect Concentration (NEC) and Exposure Toxicity Ratio, ETR = PEC / NEC). The risk assessment revealed that the riskiest pesticides for earthworms were acetamiprid, glyphosate and imidacloprid with ETR values of 2963, 1667 and 419 respectively. For bees, acetamiprid, cypermethrin, emamectin benzoate, imidacloprid, and lambda-cyhalothrin were highly risky, with respective ETR values of 3252, 487, 278, 1383 and 295. The model predicted NTAs to be predominantly defenceless against cypermethrin and imidacloprid, as these compounds exhibited the topmost values of ETR of, 4.3 × 108 and 4.4 × 107, respectively. Other pesticides that were modelled to be highly risky to NTAs comprised chlorothalonil (ETR = 2076), cymoxanil (ETR = 1133), emamectin benzoate (ETR = 1700), lambda-cyhalothrin (ETR = 4900) and metalaxyl (ETR = 2303). Some compounds gave evidence of multi-level risks: imidacloprid exhibited high risk to all the organisms (earthworms, bees and NTAs); acetamiprid was risky to earthworms and bees, while cypermethrin, emamectin benzoate and lambda-cyhalothrin, were modelled to pose a risk to bees and NTAs. Regulating the use of these perilous pesticides should be encouraged in agroecosystems to protect environmental and human health.

Survey of pesticide application practices and technologies in Georgia agronomic crops

AbstractPesticide regulations and application technologies are changing rapidly due to rising concerns around off-target movement of pesticides and increased focus on improving the efficiency of pesticide applications. In order to conduct relevant applied research and develop educational programs related to pesticide application, it is necessary to understand the common application practices and technologies that growers use. A survey was conducted to assess common pesticide application practices and technologies used by Georgia growers. Both online and printed survey copies were distributed by county agricultural extension agents to growers in all 159 counties. A total of 186 responses representing agronomic crops in 65 counties were received and analyzed for results. Main results of this survey indicated that 1) 72% of respondents produced ≥200 ha of crops; 2) 29% of respondents received their information from university Extension personnel; 3) 42% of respondents used a separate sprayer for applications of dicamba, 2,4-D, or 2,4-DB; 4) 46% of respondents used sprayers with boom lengths ≥18.3 m; 5) 65% of respondents used ≥121 L/ha to apply pesticides; 6) 53% of respondents used three or more different nozzles on their spray booms throughout the season; 7) 68% of respondents used TeeJet® nozzles; 8) 65% of respondents used global positioning systems and rate controllers on their application equipment; 9) 66% of respondents recorded their pesticide application data on a notepad or diary; and 10) 39% of respondents reported that application accuracy is the biggest advantage of new spray technologies. Respondents also reported that weather, timing, and pesticide drift/regulations were their biggest application challenges and that more research is needed on topics such as rates, carrier volumes, pest control, chemicals and adjuvants. Information from this survey provides useful insights into the current application practices, technologies, and research needs of Georgia growers and will be used for developing appropriate research and educational efforts.

Environment to embryo: intersections of contaminant exposure and preimplantation embryo development in agricultural animals†.

Environmental impacts on reproductive function are well documented in humans, yet little information is known about the effects on large animals. The interface of environment and reproduction has evolved prudently with a concerted effort to ensure global food sustainability tightly integrated with the application of technological advances in agriculture production that include nutrient and resource management. Exposure to environmental toxicants through chemical pesticide application and industry practices has coincided with a decline in cattle and human fertility. The increased adoption of agriculture animals for human biomedical models further emphasizes the importance of understanding the consequences of livestock exposure to environmentally and physiologically relevant levels of contaminants to preimplantation embryo development. In addition, increased awareness of paternal contributions to the early embryo that include both genetic and nongenetic factors supports the need to define environmental interactions from gamete to genome. Herein we summarize current knowledge of common environmental contaminants on reproductive function including direct and indirect effects on embryo development success in livestock. Information obtained from a diverse number of species including humans is presented to illustrate gaps in knowledge within livestock directly pertaining to agriculture success, sustainability, clinical practice, and biomedical research.

Uptake and Translocation of a Silica Nanocarrier and an Encapsulated Organic Pesticide Following Foliar Application in Tomato Plants.

Pesticide nanoencapsulation and its foliar application are promising approaches for improving the efficiency of current pesticide application practices, whose losses can reach 99%. Here, we investigated the uptake and translocation of azoxystrobin, a systemic pesticide, encapsulated within porous hollow silica nanoparticles (PHSNs) of a mean diameter of 253 ± 73 nm, following foliar application on tomato plants. The PHSNs had 67% loading efficiency for azoxystrobin and enabled its controlled release over several days. Thus, the nanoencapsulated pesticide was taken up and distributed more slowly than the nonencapsulated pesticide. A total of 8.7 ± 1.3 μg of the azoxystrobin was quantified in different plant parts, 4 days after 20 μg of nanoencapsulated pesticide application on a single leaf of each plant. In parallel, the uptake and translocation of the PHSNs (as total Si and particulate SiO2) in the plant were characterized. The total Si translocated after 4 days was 15.5 ± 1.6 μg, and the uptake rate and translocation patterns for PHSNs were different from their pesticide load. Notably, PHSNs were translocated throughout the plant, although they were much larger than known size-exclusion limits (reportedly below 50 nm) in plant tissues, which points to knowledge gaps in the translocation mechanisms of nanoparticles in plants. The translocation patterns of azoxystrobin vary significantly following foliar uptake of the nanosilica-encapsulated and nonencapsulated pesticide formulations.

Extent of Pesticide Use and Application Practices in Small-Scale Farms of Kikome, Makueni County

Extent of Pesticide Use and Application Practices in Small-Scale Farms of Kikome, Makueni County

Validation of a methodology by LC-MS/MS for the determination of triazine, triazole and organophosphate pesticide residues in biopurification systems

Biopurification systems are useful in the management of pesticide residues and provide an option to dispose wastewaters of agricultural origin derived from pesticide application practices. The analysis of pesticide residues in the biopurification system biomixture is necessary to determine whether the removal of the target compounds occurs with reliable results. In this study, the pesticide extraction methodology was optimized and validated in a biomixture composed of coconut fiber, compost and soil, to determine a total of 43 molecules, distributed among triazines (10), triazoles (13) and organophosphates (20) using liquid chromatography coupled to a triple quadrupole mass spectrometer. For the validation, the parameters of linearity, matrix effect, limit of determination (LOD), specificity, selectivity, precision, trueness and robustness in the proposed biomixture were evaluated. The analyses of those parameters revealed satisfactory results of the method for most of the compounds, with the exception of diclorvos and ciromazine, for which the development of an alternative method is recommended. Once the extraction methodology was validated, the removal of eight molecules was assayed in a biopurification system used for the simultaneous treatment of a mixture of pesticide commercial formulations. Although most of the compounds were at least partially removed, none of them was eliminated at levels below the LOD. The removal pattern of ametryn, atrazine, chlorpyrifos, malathion and terbutryn was comparable to those obtained in other efficient biomixtures, and the highly recalcitrant triadimenol was eliminated; nonetheless, tebuconazole and diazinon were not significantly removed.

Risk perception and behavior in Egyptian adolescent pesticide applicators: an intervention study

BackgroundAdolescents are engaged in agricultural work, including pesticide application, around the world. Adolescent pesticide applicators are more likely to be exposed to pesticides than their adult counterparts because of their application practice and hygiene habits surrounding pesticide use. There is a need for low-cost interventions to reduce pesticide exposure. We evaluated a theoretically-based educational intervention to change perceptions about the risk of pesticide use and hygiene habits during and after pesticide application for adolescent and young adult pesticide applicators in Egypt.MethodsYoung adult and adolescent male pesticide applicators were given a one-hour educational intervention to inform them about the risk of pesticide use and how to reduce pesticide exposure. The median age of participants was 18 years old. Changes in perceived susceptibility and effectiveness were measured with a survey pre and post-intervention (n = 119) on the same day. The same survey (n = 95) was given 8-months post-intervention to identify sustained effects. Observational checklists of pesticide application practice were also completed during application seasons before and after the intervention.ResultsThere was an increase in the proportion of individuals who viewed pesticides as being a long-term health risk (74.7% pre-intervention to 97.9% post-intervention, McNemar test p < 0.001). This change remained significant when surveyed at the 8-month follow-up (90.5%, p < 0.001). There was also a sustained improvement regarding participants’ views of proper hygiene practice surrounding pesticide application. Applicators were observed wearing goggles, shoes, and masks more frequently post-intervention.ConclusionThis theoretically-based intervention is an example of a low-cost solution that can improve adolescents’ and young adults’ practices regarding pesticide application and personal hygiene practices during and after pesticide application. The intervention can be applied in other countries with similar safety culture surrounding pesticide application.