Fabrication Of Perovskite Films Research Articles

Effect of Guanidinium Salt for Stress-Relaxation and Interfacial Engineering in Antisolvent Free Perovskite Solar Cells Fabricated Under Air Ambient.

In perovskite solar cells, the presence of stress and defects at interfaces promotes performance degradation and poor stability of the devices. The formation of these defects is more prominent in two-step antisolvent-free perovskite film fabrication. This study addresses these challenges by introducing guanidine sulfate (Gua-S) at the tin oxide/formamidinium lead iodide perovskite interface, fabricated without antisolvent under ambient air. Interfacial Gua-S enhanced morphology by forming bonds between uncoordinated Pb2+ ions and I- vacancies at the interface and showed improvement in the crystallinity and quality of the perovskite film. Microstructural stress analysis indicated a substantial reduction in stress, decreasing from 50.6 to 20.72 MPa with the application of Gua-S. Moreover, the Gua-S treated solar cells showed significant improvements and achieved an open circuit voltage of 1.08 V and 22.34% efficiency. Further, electrochemical impedance spectroscopic analysis showed improved built-in potential, carrier lifetime, and charge recombination lifetime for treated devices. The devices retained over 87% of the initial power conversion efficiency after 2000 hours of operation. This comprehensive study addresses the fundamental issues of interfacial stress and defects in perovskite solar cells and demonstrates the efficacy of Gua-S salt in enhancing both the structural and functional aspects of the antisolvent-free device fabrication process.

Synergistic Modulation of Sn2+ Oxidation and Perovskite Crystallization Induced by 4-Hydroxypyridine for Stable Lead-Free Solar Cells.

Tin perovskites present promising alternatives to lead perovskites, offering comparable optoelectronic properties alongside environmentally friendly characteristics. However, the rapid crystallization and easy oxidation of Sn2+ lead to poor film quality, further constraining the device performance. Here, 4-hydroxypyridine (4-HP) is introduced into the tin perovskite precursor for fabrication of high-quality tin perovskite films. 4-HP could modulate the colloidal size of prenucleation perovskite clusters in the precursor, thus inducing fast nucleation and retarding the crystal growth rate of tin perovskite through the formation of chemical interaction between nitrogen of pyridine and Sn2+ ions. Furthermore, the hydroxyl group on the pyridine ring contributes to suppressing the oxidation of Sn2+. As a result, the power conversion efficiency (PCE) of the devices based on 4-HP increases up to 11.3%. The stability of the unencapsulated devices shows significant improvement, retaining 100% of their initial PCEs after 2000 h of storage in N2 with 50-100 ppm of O2. This research presents a novel approach to the synchronized regulation of tin perovskite crystallization and the suppression of Sn2+ oxidation.

Enhanced Homogeneity in Perovskite Photovoltaic Films via Antisolvent Extraction of a Methylamine-Based Gel Precursor.

Solution-processed perovskite solar cells (PSCs) are at the forefront of next-generation photovoltaics, exhibiting outstanding photoelectric performance and cost-effective manufacturing. However, the prevalent use of polar aprotic solvents such as N,N-dimethylformamide and dimethyl sulfoxide in the preparation of perovskite precursor solution hinders complete solvent removal during film formation. Their high boiling points and strong coordinating abilities lead to solvated intermediates and heterogeneous perovskite crystal nucleation, particularly in the absence of the antisolvent-assisted crystallization. To address this, we developed a methylamine (MA)-based gel dispersion system that significantly improves the uniformity of perovskite films. By employing ethyl acetate (EA) antisolvent extraction, the gel precursor is extracted from a solution of MAI and PbI2 in MA ethanol, which is then diluted in pure acetonitrile (ACN) solvent to form a clear perovskite precursor solution. Benefiting from the highly volatile nature of the ACN-based gel perovskite precursor solution and its rich concentration of high-valent PbIn2-n coordination compounds, this approach enables the fabrication of high-quality MAPbI3 perovskite films, yielding PCEs of 21.34% for PSC and 19.77% for a 5 × 5 cm2 mini-module. This MA-based gel perovskite precursor strategy offers a promising avenue for potential applications in the scalable manufacture of PSCs.

Studying the effect of ambient temperature variations on perovskite precursor film formation using different antisolvents

This study investigates the sensitivity of two antisolvents to ambient temperature fluctuations during the fabrication of triple-cation perovskite thin films. Chlorobenzene (CB) and ethyl acetate (EA) were employed as antisolvents in the preparation of perovskite solar cells (PSCs) under identical ambient temperature variation conditions. The experimental results reveal that the quality of the perovskite films does not exhibit a consistent trend in response to ambient temperature changes depending on the antisolvent used. When CB was used as the antisolvent, the highest-performing device, produced at an ambient temperature of 18 °C, achieved a power conversion efficiency (PCE) of 19.9 %. In contrast, when EA was employed as the antisolvent, the highest-performing device was fabricated at 25 °C, reaching a PCE of 20.5 %. Furthermore, when the ambient temperature exceeded 30 °C, all films prepared with either antisolvent exhibited significant cracking, indicating that elevated temperatures adversely affect perovskite film formation. To further investigate the mechanism through which ambient temperature affects the film-forming process, antisolvents at varying temperatures were used during perovskite film preparation to simulate transient temperature increases during formation. This study reveals that the impact of ambient temperature variations on perovskite film formation does not exhibit a uniform trend but is significantly influenced by the choice of antisolvent. Moreover, this work offers valuable insights for optimizing the fabrication of high-quality perovskite thin films.

Nanofiber Space-Confined Fabrication of High-Performance Perovskite Films for Flexible Conversion of Fluorescence Quantum Yields in LED Applications.

Perovskite is an advanced optoelectronic semiconductor material that has garnered significant attention in recent years. However, its drawback lies in its environmental instability, limiting its practical applications. To tackle this issue, this research delved into the idea of creating a space-confined structure and used electrospinning to produce a film of perovskite nanocomposite fibers. By effectively encapsulating perovskite nanocrystals into a polymer matrix, the perovskite could be shielded from water and oxygen in the environment, thereby reducing the likelihood of perovskite decomposition and enhancing the stability of its structure and properties. This study examined the influence of material composition and the spinning process on the nanofiber structure to create good spatial confinement. This strategy resulted in a high photoluminescence quantum yield of over 80% and a long-term environmental stability of as long as 1000 h over 90% of the original PLQY. By harnessing the flexibility of the composite fibers, this study demonstrated the potential applications and performance of this nanocomposite film in flexible quantum fluorescence conversion for LED applications.

Controllable Crystallization of Perovskite Films during the Blade-Coating Fabrication Process for Efficient and Stable Solar Cells

The scalable production of high-quality perovskite thin films is pivotal for the industrialization of perovskite thin film solar cells. Consequently, the solvent system employed for the fabrication of large-area perovskite films via coating processes has attracted significant attention. In this study, a solvent system utilizing a volatile solvent as the primary reagent has been developed to facilitate the rapid nucleation of volatile compounds. While adding the liquid Lewis base dimethylformamide (DMF) can help to improve the microstructure of perovskite films, its slow volatilization renders the crystal growth process uncontrollable. Based on the solvent system containing DMF and ethanol (EtOH), introducing a small amount of NH4Cl increases the proportion of the intermediate phase in the precursor films. This not only results in a controllable growth process for the perovskite crystals but also contributes to the improvement of the film microstructure. Under the simulated illumination (AM1.5, 1000 W/m2), the photoelectric conversion efficiency (PCE) of the inverted solar cells has been improved to 20.12%. Furthermore, after 500 hours of continuous illumination, the photovoltaic device can retain 95.6 % of the initial, indicating that the solvent system is suitable for the scalable fabrication of high-quality FAPbI3 thin films.

Unified Crystal Phase Control with MACl for Inducing Single-Crystal-Like Perovskite Thin Films in High-Pressure Fusion Toward High Efficiency Perovskite Solar Cell Modules.

Perovskite solar cells, recognized for their high photovoltaic conversion efficiency (PCE), cost-effectiveness, and simple fabrication, face challenges in PCE improvement due to structural defects in polycrystalline films. This study introduces a novel fabrication method for perovskite films using methylammonium chloride (MACl) to align grain orientation uniformly, followed by a high-pressure process to merge these grains into a texture resembling single-crystal perovskite. Employing advanced visual fluorescence microscopy, charge dynamics in these films are analyzed, uncovering the significant impact of grain boundaries on photo-generated charge transport within perovskite crystals. A key discovery is that optimal charge transport efficiency and speed occur in grain centers when the grain size exceeds 10µm, challenging the traditional view that efficiency peaks when grain size surpasses film thickness to form a monolayer. Additionally, the presence of large-sized grains enhances ion activation energy, reducing ion migration under light and improving resistance to photo-induced degradation. In application, a perovskite solar cell module with large grains achieve a PCE of 22.45%, maintaining performance with no significant degradation under continuous white LED light at 100 mA cm-2 for over 1000h. This study offers a new approach to perovskite film fabrication and insights into optimizing perovskite solar cell modules.

Humidity Effects on Cs0.17FA0.83Pb(I0.83Br0.17)3 Thin Films for Carbon-based Perovskite Solar Cells

Org anic-inorganic hybrid perovskites have captivated the attention of researchers worldwide due to their remarkable potential for low-cost, high-efficiency solar cells. However, the reliance on controlled environments, such as dry boxes, poses a significant barrier for smaller laboratories wishing to participate in perovskite research. In this study, we investigate the influence of ambient humidity of Cs0.17FA0.83Pb(I0.83Br0.17)3 during the film formation process. Our experiments involved the fabrication of perovskite films using spin-coating techniques under different controlled humidity conditions with identical precursor preparation. The results revealed a significant decrease in film thickness under higher humidity, accompanied by a noticeable alteration in perovskite grain morphology, suggesting a complex interplay between humidity and grain formation. Furthermore, the photovoltaic performance of device with perovskite film formed in different humidity was measured. Surprisingly, despite the challenges posed by high humidity during fabrication, the solar cell efficiency only moderately decreased from 13.17% to 9.55% in average, indicating a remarkable potential of the Cs0.17FA0.83Pb(I0.83Br0.17)3 perovskite formula under adverse ambient conditions. These findings hint at the feasibility of their application in real-world, ambient air conditions, paving the way for their integration into diverse environmental settings, enabling a wider research community to engage in the exciting realm of perovskite solar cell technology.

Enhancing lead-free photovoltaic performance: Minimizing buried surface voids in tin perovskite films through weakly polar solvent pre-treatment strategy

Buried interfacial voids have always been a notorious phenomenon observed in the fabrication of lead perovskite films. The existence of interfacial voids at the buried interface will capture the carrier, suppress carrier transport efficiencies, and affect the stability of photovoltaic devices. However, the impact of these buried interfacial voids on tin perovskites, a promising avenue for advancing lead-free photovoltaics, has been largely overlooked. Here, we utilize an innovative weakly polar solvent pre-treatment strategy (WPSPS) to mitigate buried interfacial voids of tin perovskites. Our investigation reveals the presence of numerous voids in tin perovskites during annealing, attributed to trapped dimethyl sulfoxide (DMSO) used in film formation. The WPSPS method facilitates accelerated DMSO evaporation, effectively reducing residual DMSO. Interestingly, the WPSPS shifts the energy level of PEDOT:PSS downward, making it more aligned with the perovskite. This alignment enhances the efficiency of charge carrier transport. As the result, tin perovskite film quality is significantly improved, achieving a maximum power conversion efficiency approaching 12% with only an 8.3% efficiency loss after 1700 h of stability tests, which compares well with the state-of-the-art stability of tin-based perovskite solar cells.

Anethole Regulated Crystallization for High Efficiency Carbon‐Based Perovskite Solar Cells

AbstractTwo‐step sequential deposition is a widespread technique for the fabrication of perovskite films, renowned for its better control of the crystallization process. However, achieving a well‐controlled and complete reaction of PbI2 by organic ammonium salts remains a key challenge. Previous studies have predominantly focused on regulating the properties of the PbI2 layer while paying less attention to the high reactivity of organic ammonium salts. In this study, the natural molecule anethole is first explored to control perovskite crystallization during two‐step sequential deposition, focusing on the reactivity modulation of organic formamidine ion (FA+). It is demonstrated that FA+ exhibits strong hydrogen bond interactions with anethole, inhibiting the high reactivity of FA+ and effectively delaying the rapid reaction between FAI and PbI2. This decelerates the crystallization kinetics of perovskite films, facilitating the orderly and complete reaction of PbI2 by FAI while suppressing detrimental δ‐phase formation. Consequently, FA‐based perovskite films with high crystallinity, preferred orientation, and low defect state density are obtained. The fabricated planar hole transport layer‐free carbon electrode perovskite solar cells deliver an efficiency of 20.41% (certified efficiency of 20.0%), which is a new record for this kind of solar cell.

Collaborative Fabrication of High-Quality Perovskite Films for Efficient Solar Modules through Solvent Engineering and Vacuum Flash System.

The vacuum flash solution method has gained widespread recognition in the preparation of perovskite thin films, laying the foundation for the industrialization of perovskite solar cells. However, the low volatility of dimethyl sulfoxide and its weak interaction with formamidine-based perovskites significantly hinder the preparation of cell modules and the further improvement of photovoltaic performance. In this study, we describe an efficient and reproducible method for preparing large-scale, highly uniform formamidinium lead triiodide (FAPbI3) perovskite films. This is achieved by accelerating the vacuum flash rate and leveraging the complex synergism. Specifically, we designed a dual pump system to accelerate the depressurization rate of the vacuum system and compared the quality of perovskite film formed at different depressurization rates. Further, to overcome the limitations posed by DMSO, we substituted N-methylpyrrolidone as the ligand solvent, creating a stable intermediate complex phase. After annealing, it can be transformed into a uniform and pinhole-free FAPbI3 film. Due to the superior quality of these films, the large area perovskite solar module achieved a power conversion efficiency of 22.7% with an active area of 21.4 cm2. Additionally, it obtained an official certified efficiency of 22.1% with an aperture area of 22 cm2, and it demonstrated long-term stability.

Controlled Crystal Growth of All-Inorganic CsPbI2Br via Sequential Vacuum Deposition for Efficient Perovskite Solar Cells.

Vacuum deposition of perovskites is a promising method for scale-up fabrication and uniform film growth. However, improvements in the photovoltaic performance of perovskites are limited by the fabrication of perovskite films, which are not optimized for high device efficiency in the vacuum evaporation process. Herein, we fabricate CsPbI2Br perovskite with high crystallinity and larger grain size by controlling the deposition sequence between PbI2 and CsBr. The nucleation barrier for perovskite formation is significantly lowered by first evaporating CsBr and then PbI2 (CsBr-PbI2), followed by the sequential evaporation of multiple layers. The results show that the reduced Gibbs free energy of CsBr-PbI2, compared with that of PbI2-CsBr, accelerates perovskite formation, resulting in larger grain size and reduced defect density. Furthermore, surface-modified homojunction perovskites are fabricated to efficiently extract charge carriers and enhance the efficiency of perovskite solar cells (PeSCs) by modulating the final PbI2 thickness before thermal annealing. Using these strategies, the best PeSC exhibits a power conversion efficiency of 13.41% for a small area (0.135 cm2), the highest value among sequential thermal deposition inorganic PeSCs, and 11.10% for a large area PeSC (1 cm2). This study presents an effective way to understand the crystal growth of thermally deposited perovskites and improve their performance in optoelectronic devices.

PhDMADBr assisted additive or interface engineering for efficient and stable perovskite solar cells fabricated in ambient air

The fabrication of high-quality perovskite films with low defect density in ambient air is an important approach to enhance the power conversion efficiency (PCE) and stability of perovskite solar cells (PSCs). In this paper, efficient and stable PSCs were fabricated in ambient air, and p-xylilenediamine bromide (PhDMADBr) assisted additive or interface engineering were carried out to modify perovskite films, which was dispersed into the electron transport layer (ETL) or deposited in the ETL/ perovskite interface. Notably, interaction between PhDMADBr and perovskite layer could reduce defect density and release residual stress of the active layer, which would induce a high-quality perovskite film, and accelerate the transport rate and prolong lifetimes of charge carriers, contributing to the PCE and stability of devices. As a result, compared with the PCE of the control device (22.54 %), the PhDMADBr modified target PSCs exhibited the enhanced PCE of 24.15 % and 23.74 % after additive or interface treatments in ambient air, respectively. Except the improvement of the PCE, PhDMADBr-based devices also presented the enhanced moisture stability. The average efficiency retained the 88 % or 84 % of initial efficiency after 120 h with RH of 40 ± 5 % for additive or interface modification, respectively. In contrast, the PCE of the control devices would decline to 51 % of initial efficiency after storage for 120 h.

Phosphonic Chloride Assisted Fabrication of Highly Emissive Mixed Halide Perovskite Films in Ambient Air for Blue Light-Emitting Diodes.

Blue perovskite light-emitting diodes (LEDs) have emerged as promising candidates for full-color display and lighting applications. However, the fabrication of blue-emitting perovskite films typically requires an inert environment, leading to increased complexity and cost in the manufacturing process, which is undesirable for applications of perovskite LEDs. Herein, we report a strategy to fabricate bright blue-emitting perovskite films in ambient air by incorporating phosphonic chlorides in a perovskite precursor solution. We used two different phosphonic chlorides, diphenylphosphonic chloride (DPPC) and phenylphosphonic dichloride (PPDC), and comparatively studied their effects on the properties of perovskite films and the blue LEDs. It is found that PPDC possesses a stronger chlorination ability due to higher hydrolysis reactivity; meanwhile, it has a stronger interaction with the perovskite compared to DPPC, resulting in an improved film quality and enhanced blue emission with a photoluminescence quantum yield of 45%, which represents the record value for the air-processed blue perovskite films. Blue perovskite LEDs are fabricated, and the emission wavelengths are effectively tuned by controlling the concentration of phosphonic chlorides. Benefiting from the optimized perovskite films with reduced nonradiative recombination and promoted charge injection and transport, the PPDC-derived blue perovskite LEDs exhibit improved performance with an external quantum efficiency of 3.3% and 1.2% for the 490 and 480 nm emission wavelength, respectively.

Precursor-Engineered Volatile Inks Enable Reliable Blade-Coating of Cesium-Formamidinium Perovskites Toward Fully Printed Solar Modules.

Reliable fabrication of large-area perovskite films with antisolvent-free printing techniques requires high-volatility solvents, such as 2-methoxyethanol (2ME), to formulate precursor inks. However, the fabrication of high-quality cesium-formamidinium (Cs-FA) perovskites has been hampered using volatile solvents due to their poor coordination with the perovskite precursors. Here, this issue is resolved by re-formulating a 2ME-based Cs0.05FA0.95PbI3 ink using pre-synthesized single crystals as the precursor instead of the conventional mixture of raw powders. The key to obtaining high-quality Cs-FA films lies in the removal of colloidal particles from the ink and hence the suppression of colloid-induced heterogeneous nucleation, which kinetically facilitates the growth of as-formed crystals toward larger grains and improved film crystallinity. Employing the precursor-engineered volatile ink in the vacuum-free, fully printing processing of solar cells (with carbon electrode), a power conversion efficiency (PCE) of 19.3%, a T80 (80% of initial PCE) of 1000h in ISOS-L-2I (85°C/1Sun) aging test and a substantially reduced bill of materials are obtained. The reliable coating methodology ultimately enables the fabrication of carbon-electrode mini solar modules with a stabilized PCE of 16.2% (average 15.6%) representing the record value among the fully printed counterparts and a key milestone toward meeting the objectives for a scalable photovoltaic technology.

Passivating Defects via Retarding the Reaction Rate of FAI and PbI2 Enables Stable Perovskite Solar Cells.

The two-step sequential deposition strategy has garnered widespread usage in the fabrication of high-performance perovskite solar cells based on FAPbI3. However, the rapid reaction between FAI and PbI2 during preparation often leads to incomplete reactions, reducing the device efficiency and stability. Herein, we introduced a multifunctional additive, 2-thiophenyl trifluoroacetone (TTA), into the FAI precursor. The incorporation of TTA has proven to be highly effective in slowing the reaction rate between FAI and PbI2, resulting in increased perovskite formation and improved efficiency and stability of the devices. TTA's CF3 groups interact with FAI via hydrogen bonding, effectively suppressing FA+ defects. The S and C═O groups share lone pair electrons with uncoordinated Pb2+, leading to a reduction in perovskite film defects and suppressing nonradiative recombination. Additionally, the CF3 groups impart hydrophobicity, protecting the perovskite film from moisture-induced erosion. As a result, the TTA-modified perovskite film achieves a Champion efficiency of 23.42% compared to the control's 21.52, with 20.58% efficiency for a 25 cm2 solar module. Remarkably, the unencapsulated Champion device retains 86% of its initial PCE after 1080 h under dark conditions (60 ± 5 °C, 35 ± 5% RH), indicating enhanced long-term stability. These findings offer a promising and cost-effective tactic for high-quality perovskite film fabrication.

Advancements in perovskite solar cell efficiency through blade coating techniques and post-treatment optimization

Addition of lead chloride (PbCl2) improves the crystallization kinetics of perovskites by suppressing the formation of δ-phase during large-area perovskite film fabrication. However, this addition results in formation and accumulation of lead iodide (PbI2) platelet atop the film, which adversely affects carrier transport. To eliminate the negative effect of PbI2 accumulation and simultaneously obtain a dense, mirror-like perovskite film, a post-treatment method involving blade coating formamidinium iodide (FAI) under air atmosphere is used. Instead of being washed away, as reported in literatures using spin coating process, PbI2 platelets are converted into cesium lead halide perovskites (CsPbX3) through reaction with Cs and halide present in the original perovskite Cs0.22FA0.78Pb(I0.85Br0.15)3. An efficiency enhancement of (>10%) is achieved by FAI treatment, which does not require fast solvent removal or nitrogen (N2) atmospheres, indicating that FAI blade coating is an effective and straightforward method for the post-treatment of excess PbI2.

Fabricating Planar Perovskite Solar Cells through a Greener Approach.

High-quality perovskite thin films are typically produced via solvent engineering, which results in efficient perovskite solar cells (PSCs). Nevertheless, the use of hazardous solvents like precursor solvents (N-Methyl-2-pyrrolidone (NMP), dimethyl sulfoxide (DMSO), dimethylformamide (DMF), gamma-butyrolactone (GBL)) and antisolvents (chlorobenzene (CB), dibutyl ether (DEE), diethyl ether (Et2O), etc.) is crucial to the preparation of perovskite solutions and the control of perovskite thin film crystallization. The consumption of hazardous solvents poses an imminent threat to both the health of manufacturers and the environment. Consequently, before PSCs are commercialized, the current concerns about the toxicity of solvents must be addressed. In this study, we fabricated highly efficient planar PSCs using a novel, environmentally friendly method. Initially, we employed a greener solvent engineering approach that substituted the hazardous precursor solvents with an environmentally friendly solvent called triethyl phosphate (TEP). In the following stage, we fabricated perovskite thin films without the use of an antisolvent by employing a two-step procedure. Of all the greener techniques used to fabricate PSCs, the FTO/SnO2/MAFAPbI3/spiro-OMeTAD planar device configuration yielded the highest PCE of 20.98%. Therefore, this work addresses the toxicity of the solvents used in the perovskite film fabrication procedure and provides a promising universal method for producing PSCs with high efficiency. The aforementioned environmentally friendly approach might allow for PSC fabrication on an industrial scale in the future under sustainable conditions.

Unlocking the potential of antisolvent-free perovskite solar cells: Modulating crystallization and intermediates through a binary volatile additive strategy

High-quality perovskite polycrystalline thin films are generally achieved through antisolvent-assisted crystallization, a crucial process that facilitates desolvation. However, antisolvent method is limited by issues of toxicity and fabrication complexity. Here, we introduce a “binary volatile additive” strategy using methylammonium chloride (MACl) and trifluoroacetamide (TFAA) in dimethylformamide/N-methyl-2-pyrrolidone co-solvent system, enabling end-to-end management of antisolvent-free crystallization process. Combining in-situ characterizations and DFT calculations, we prove that TFAA adjusts coordination with perovskite intermediates, facilitating solvent removal and promoting the formation of nuclei, while MACl reduces the formation energy of α-phase formamidinium-based perovskite. Moreover, TFAA not only releases the residual strain caused by MACl, but also in combination with MACl, synergistically widens crystallization window and regulates ripening process, allowing for precise fabrication of homogeneous perovskite films with suppressed defects. By employing the “binary volatile additive” approach, we achieve perovskite solar cells with a power conversion efficiency up to 22.4% and elongated storage life (93% PCE retention over 1000 hours). Our study offers a simple and sustainable approach to produce high-quality perovskite films without the acquisition of antisolvent, streamlining the fabrication process.

Efficient and Stable Tin-Lead Mixed Perovskite Solar Cells Using Post-Treatment Additive with Synergistic Effects.

Inhibiting the oxidation of Sn2+ during the crystallization process of Sn-Pb mixed perovskite film is found to be as important as the oxidation resistance of precursor solution to achieve high efficiency, but less investigated. Considering the excellent reduction feature of hydroquinone and the hydrophobicity of tert-butyl group, an antioxidant 2,5-di-tert-butylhydroquinone (DBHQ) was introduced into Sn-Pb mixed perovskite films using an anti-solvent approach to solve this problem. Interestingly, we find that DBHQ can act as function alterable additive during its utilization. On the one hand, DBHQ can restrict the oxidation of Sn2+ during the crystallization process, facilitating the fabrication of high-quality perovskite film; on the other hand, the generated oxidation product 2,5-di-tert-butyl-1,4-benzoquinone (DBBQ) can functionalize as defect passivator to inhibit the charge recombination. As a result, this synergetic effect renders the Sn-Pb mixed PSC a power conversion efficiency (PCE) up to 23.0 %, which is significantly higher than the reference device (19.6 %). Furthermore, the unencapsulated DBQH-modified PSCs exhibited excellent long-term stability and thermal stability, with the devices maintaining 84.2 % and 78.9 % of the initial PCEs after aging at 25 °C and 60 °C for 800 h and 120 h under N2 atmosphere, respectively. Therefore, the functional alterable strategy provides a novel cornerstone for high-performance Sn-Pb mixed PSCs.