Water Permeability Coefficient Research Articles

Soil-water retention capacity of expansive soil improved through enzyme induced carbonate precipitation-eggshell powder

Enzyme Induced Carbonate Precipitation (EICP) has been extensively investigated as a promising approach to improve engineering properties of soil, while Eggshell Powder (ESP) is an agricultural waste that effectively fills soil pores. The ESP provides abundant nucleation at sites for the EICP process, further promoting the effective precipitation of calcium carbonate. The research presented in this paper investigated the Soil Water Characteristic Curves (SWCC), permeability coefficient, and microstructure of expansive soil before and after EICP and EICP+ESP modification. A series of laboratory experiments were conducted, including soil water characteristic tests, permeability tests and Scanning Electron Microscopy (SEM). The results proved that the addition of EICP and EICP+ESP into natural expansive soil resulted in a gradual decline in air entry value, residual water content, and permeability coefficient, indicating an increase in water retention capacity and a decrease in permeability. Furthermore, with the intrusion of EICP and EICP+ESP, the contact between particles becomes smoother, and the soil pores become more equally distributed. Ultimately, there was an enhancement in water retention capacity of the natural expansive soil. This study emphasizes the synergistic potential of combining EICP and EICP+ESP as stabilizing additives to enhance the water retention capacity of expansive soil. Moreover, the reuse of ESP provides a sustainable solution for the resource utilization of agricultural waste and the improvement of expansive soil using bio-inspired methods.

Enhancing structural durability in marine concrete piles with initial defects: RS-AAT-induced advection to suppress chloride ion penetration

Chlorine-induced corrosion in unsaturated, cracked, and delaminated reinforced concrete structures is a major cause of lifespan decline in marine wet and dry zones. Reverse-seepage and Saturation based Active Anti-corrosion Technology (RS-AAT) has the scientific basis and application potential to solve this problem due to its unique saturation and reverse-seepage effects provided by structural construction means. This study introduces an analytical framework for understanding time-dependent chloride ion permeation in concrete pipe piles, incorporating the combined impact of cracks, delamination, and RS-AAT anti-corrosion approach. The analytical approach is validated through finite element method simulations and a comprehensive 90-day indoor experiment, which simulate marine submerged and tidal conditions. Extensive parametric analysis further elucidates advection-induced suppression of chloride ion diffusion by RS-AAT in cracked and delaminated conditions, considering chloride ion diffusion coefficient and water permeability coefficient, reverse-seepage pressure, initial crack characteristics and centrifugal stratification. Results show that RS-AAT substantially inhibits chloride ion penetration and lengthens the lifespan of concrete piles, even initially cracked or delaminated. This work provides a basis for RS-AAT’s application and optimization as an innovative approach to enhancing marine concrete infrastructure.

Evaluation of textile effluent treatment plant sludge as supplementary cementitious material in concrete using experimental and machine learning approaches

The growing demand for readymade garments is leading to the production of a large amount of textile effluent sludge (TES) from wastewater treatment plants, which is currently disposed of as backfill, causing land and groundwater contamination. This scenario has prompted researchers to explore the use of industrial waste, such as TES, as a supplementary cementitious material (SCM) to mitigate the carbon footprint of cement production. Therefore, this study aims to investigate the fresh, mechanical, non-destructive characteristics, and predictive modeling of mechanical strengths of TES-based concrete. Machine learning models, including random forest (RF) and artificial neural networks (ANN), were utilized to predict compressive and tensile strengths from various input variables. This study also evaluated the alkalinity, specific gravity, oxide content, and surface area of TES. The findings showed a pH of 9.4 and a CaO content of 33.3 %, indicating TES's potential as an SCM. The research further investigated the properties of concrete with 5–20 % cement-replaced TES, using a total binder content of 488.1 kg/m3 and a water-binder ratio of 0.32. The fresh state properties of the 5–15 % TES incorporated concrete produced normal density concrete, with a slump of 100 ± 20 mm, Kelly ball penetration of 45 ± 7 mm, a compaction factor of 0.92 ± 0.05, and a fresh density of 2464 ± 152 kg/m3. At 28 days, concrete with 15 % TES replacement showed a compressive strength of 25.6 MPa and a tensile strength of 2.88 MPa, achieving 76 % of the strength activity index and 72 % of the relative tensile strength. However, the 15 % TES concrete displayed a water permeability coefficient of 4.4 × 10−12 m/s and an electrical resistivity of 31.5 kΩ cm, compared to the control mix's 2.0 × 10−12 m/s and 37.7 kΩ cm. However, the hardened properties declined significantly after replacing 15 % of cement with TES. The mechanical properties were also estimated using ultra pulse velocity and rebound hammer tests, showing a coefficient of determination (R2) higher than 0.87. The RF model demonstrated superior performance with an R2 value of 0.8802 for compressive strength and 0.8518 for tensile strength, outperforming the ANN model's R2 values of 0.8126 and 0.695, respectively. Scanning electron microscopy confirmed the consistent development of hydration products in the TES-enhanced concrete samples.

Porous concrete modification with silica fume and ground granulated blast furnace slag: Hydraulic and mechanical properties before and after freeze-thaw exposure

This study investigates the effects of incorporating silica fume (SF) and ground granulated blast furnace slag (GBFS), both individually and in hybrid combinations, on various properties of porous concrete (PC) were evaluated under room conditions and after freeze-thaw (F-T) cycles. The hardened density (HD), water permeability coefficient (k), apparent porosity (AP), as well as compressive strength (CS), splitting tensile strength (STS), and flexural strength (FS) at 7, 28, and 120 days. Additionally, the impact of SF and GBFS on the mass loss (ML), residual compressive strength (RCS), residual splitting tensile strength (RSTS), and residual flexural strength (RFS) of PC samples subjected to 30, 60, 120, and 180 freeze-thaw (F-T) cycles was analyzed. The findings revealed that the addition of SF and GBFS decreased the AP and k values of PC samples under room conditions. Furthermore, these materials significantly improved the CS, STS, and FS properties of PC samples, especially at the 28-day and 120-day marks, owing to their enhanced pozzolanic activity over time. SF and GBFS also contributed to higher RCS, RSTS, and RFS values in PC samples after F-T cycles compared to the control samples. This was due to their effective gap-filling properties and the formation of additional calcium-silicate-hydrate (C-S-H) gels within the matrix. Additionally, SF and GBFS led to slightly higher RDME values in the C1-C6 samples than in the control samples following F-T cycles. However, SF and GBFS did not have a significant impact on reducing the ML values of PC samples after F-T cycles.

The Production of Porous Asphalt Mixtures with Damping Noise Reduction and Self-Healing Properties through the Addition of Rubber Granules and Steel Wool Fibers.

Conventional asphalt roads are noisy. Currently, there are two main types of mainstream noise-reducing pavements: pore acoustic absorption and damping noise reduction. However, a single noise reduction method has limited noise reduction capability, and porous noise-reducing pavements have a shorter service life. Therefore, this paper aimed to improve the noise-damping performance of porous asphalt mixture by adding rubber granules and extending its service life using electromagnetic induction heating self-healing technology. Porosity and permeability coefficient test, Cantabro test, immersion Marshall stability test, freeze-thaw splitting test, a low-temperature three-point bending experiment, and Hamburg wheel-tracking test were conducted to investigate the pavement performance and water permeability coefficients of the mixtures. A tire drop test and the standing-wave tube method were conducted to explore their noise reduction performance. Induction heating installation was carried out to study the heating rate and healing performance. The results indicated that the road performance of the porous asphalt mixture tends to reduce with an increasing dosage of rubber granules. The road performance is not up to the required standard when the dosage of rubber granules reaches 3%. The mixture's performance of damping and noise tends to increase with the increase of rubber granule dosage. Asphalt mixtures with different rubber granule dosages have different noise absorption properties, and the mixture with 2% rubber granules has the best overall performance (a vibration attenuation coefficient of 7.752 and an average absorption factor of 0.457). The optimum healing temperature of the porous asphalt mixture containing rubber granules and steel wool fibers is 120 °C and the healing rate is 74.8% at a 2% rubber granule dosage. This paper provides valuable insights for improving the noise reduction performance and service life of porous asphalt pavements while meeting road performance standards.

Tailoring physicochemical properties of quaternized polystyrene-ethylene/butylene-styrene membrane for enhanced pervaporation desalination

Pervaporation offers unique advantages for desalination of hypersaline water using highly hydrophilic and selective membrane. Positively charged membrane is superior in repelling cations and preventing scaling through electrostatic repulsion. This study investigates the quaternization and crosslinking of block copolymer styrene-ethylene-butylene-styrene (SEBS) membrane and explores the potential of quaternized membrane for pervaporation desalination. A one-step immersion process was proposed to easily adjust the physicochemical properties of membrane using trimethylamine (TMA) and N,N,N′,N′-tetramethyl-1,6-hexanediamine (TMHDA) for ammonium grafting and crosslinking. Compared to the quaternization with TMA or TMHDA alone, the combination of TMA and TMHDA produces a synergistic effect, improving crosslinking efficiency and facilitating the grafting reaction. This results in high ion exchange capacity (IEC) values and a transformation of microphase separation structure with more interconnected hydrophilic domains. An ultrahigh water permeability coefficient of 0.6 × 106–1.2 × 106 Barrer and highly intrinsic salt rejection were obtained in treating 3.5–20 wt% NaCl solution. The thin film composite QEBS/nylon membranes showed a superior water flux of 116.5 kg·m−2·h−1 and salt rejection of >99.99 % in desalinating 5 wt% NaCl solution at 85 °C. Additionally, the membrane exhibited excellent long-term performance stability and resistance to acid and alkali environment, showing great potential for desalination of hypersaline water.

Long-Term Performance Evaluation and Fouling Characterization of a Full-Scale Brackish Water Reverse Osmosis Desalination Plant

Water scarcity in Tunisia’s semi-arid regions necessitates advanced brackish water desalination solutions. This study evaluates the long-term performance and fouling characteristics of the largest brackish water reverse osmosis desalination plant in southern Tunisia over a period of 5026 days. The plant employs two-stage spiral-wound membrane elements to treat groundwater with a salinity of 3.2 g L−1. The pre-treatment process includes oxidation, sand filtration, and cartridge filtration, along with polyphosphonate antiscalant dosing. Membrane performance was assessed through the analysis of operational data, standardization of permeate flow (Qps) and salt passage (SPs), and the calculation of water (A), solute (B), and ionic (Bj) permeability coefficients. Over the operational period, there was an increase in operating pressure, pressure drop, and permeate conductivity, accompanied by a gradual increase in SPs as well as in the solute B and ionic Bj permeability coefficients. The average B increased by 82%, reflecting a decrease in solute rejection over time. Additionally, the ionic permeability coefficients for both SO42− and Cl− ions increased, with Cl− showing an 88% increase and SO42− showing an 87% increase. The produced water’s salinity increased by 67%, indicating a significant loss of membrane performance. To identify the cause of these problems, membrane characterization was analyzed using visual inspection, X-ray fluorescence (XRF), and Fourier transform infrared spectroscopy (FTIR). The characterization revealed the complex nature of the foulants, with a predominant presence of calcium sulfate, along with minor quantities of calcite, dolomite, and silica. The extent of CaSO4 deposition suggests poor antiscaling efficiency, highlighting the critical importance of selecting an effective antiscalant to mitigate membrane fouling.

Theory-based cryopreservation mode of mesenchymal stromal cell spheroids

Cryopreservation of spheroids requires development of new improved methods. The plasma membranes permeability coefficients for water and cryoprotectants determine time characteristics of mass transfer through the cell membranes, and therefore the optimal modes of cells cryopreservation. Here we proposed an approach to cryopreservation of multicellular spheroids which considers their generalized characteristics as analogues of the membranes’ permeability coefficients of the individual cells. We have determined such integral characteristics of spheroids from mesenchymal stromal cells (MSCs) as osmotically inactive volume; permeability coefficients for water and Me2SO molecules and the activation energy of their penetration. Based on these characteristics, we calculated the osmotic behavior of multicellular spheroids under cooling conditions to select the optimal cooling rate. We also determined the optimal cooling rate of spheroids using the probabilistic model developed based on the two-factor theory of cryodamage. From the calculation it follows that the optimal cooling rate of the MSC-based spheroids is 0.75°С/min. To verify the obtained theoretical estimates, we conducted experiments on freezing MSC-based spheroids under different modes. The obtained results of primary viability screening indicate that freezing at a constant linear cooling rate of 0.75–1.0°С/min gives a good result. Theoretical prediction of the spheroid osmotic behavior during cooling provided the basis for experimental verification of varying the temperature to which slow cooling should be carried out before immersion in liquid nitrogen. Slow freezing of spheroids to −40 °C followed by immersion in liquid nitrogen was shown to preserve cells better than slow freezing to −80 °C. Obtained data allow more effective use of MSC-based spheroids in drug screening and regenerative medicine.

Structure regulation of PDMS coating on PTFE membrane surface to achieve efficient separation of gaseous peppermint aromatic water

This study harnessed polydimethylsiloxane (PDMS)-coated polytetrafluoroethylene (PTFE) composite (PDMS/PTFE) membranes for the separation of peppermint aromatic water in vapor state. The effects of the PDMS coatings’ morphology structure on the separation performance of the membrane were investigated. The vapor permeation process, selective-permeation mechanism, and membrane stability were explored. Results showed that the separation effect of the membranes depended on the degree of polymerization of PDMS coating. Almost no water molecules can pass through the membrane during the 6 h separation process, and the separation factor was as high as 668. The main pharmacodynamic components in the separated permeate were L-menthol, L-menthone, and menthyl acetate, accounting for 49.16 %, 26.3 %, and 5.46 %, respectively, which conformed to the standard of the European Pharmacopoeia. The parameters of membrane separation showed that the maximum permeability coefficients of L-menthol, L-menthone, menthyl acetate, and water were 40.80, 20.28, 4.211, and 0.3945, respectively, at 105 °C and 65 kPa. This finding indicated that the large difference in permeability coefficient was the key to the excellent selectivity of the PDMS/PTFE membrane for separating volatile pharmaceutical components and water molecules in the peppermint aromatic-water system.

Concentration properties of biopolymers via dead-end forward osmosis

Extracellular polymeric substances (EPSs) in excess sludge of wastewater treatment plants are valuable biopolymers that can act as recovery materials. However, effectively concentrating EPSs consumes a significant amount of energy. This study employed novel energy-saving pressure-free dead-end forward osmosis (DEFO) technology to concentrate various biopolymers, including EPSs and model biopolymers [sodium alginate (SA), bovine serum albumin (BSA), and a mixture of both (denoted as BSA-SA)]. The feasibility of the DEFO technology was proven and the largest concentration ratios for these biopolymers were 94.8 % for EPSs, 97.1 % for SA, 97.8 % for BSA, and 98.4 % for BSA-SA solutions. An evaluation model was proposed, incorporating the FO membrane's water permeability coefficient and the concentrated substances' osmotic resistance, to describe biopolymers' concentration properties. Irrespective of biopolymer type, the water permeability coefficient decreased with increasing osmotic pressure, remained constant with increasing feed solution (FS) concentration, increased with increasing crossing velocity in the draw side, and showed little dependence on draw salt type. In the EPS DEFO concentration process, osmotic resistance was minimally impacted by osmotic pressure, FS concentration, and crossing velocity, and monovalent metal salts were proposed as draw solutes. The interaction between reverse diffusion metal cations and EPSs affected the structure of the concentrated substances on the FO membrane, thus changing the osmotic resistance in the DEFO process. These findings offer insights into the efficient concentration of biopolymers using DEFO.

Application of a simplified Green-Ampt model to the Maga earthfill dam under rainfall conditions: A sensitivity analysis case of an infiltration model

The present paper applies a simplified Green-Ampt (GA) infiltration model for the numerical modelling of seepage processes within the body of the Maga earth dam, located in the Far-North Cameroon, under rainfall conditions. The parametrization approach makes possible the predictions of infiltrations parameters for various textures that constitute the body of earth dam and its vicinities. The effects of soil texture, permeability coefficient, rain intensity and initial moisture on infiltration rate and cumulative depth are investigated using numerical simulations carried out by running an Excel VBA code. A proposed optimization procedure of the literature is then used to improve the GA model parameters and accuracy of predictions. A case sensitivity analysis of the infiltration model parameters has also been made. Initial and saturated water contents, rain intensity and permeability coefficient at saturation have been identified as the most influents parameters for the model predictions, with obvious interactions between inputs. The contribution of main effects and interactions of above inputs ranges between 68.8 % and 90.03 % of the total variance. Comparisons of numerical results with the experimental ones obtained from the literature on real cases of simulated rainfall on main sub-Saharan soils have been done. The results show that numerical simulations underestimated 60 % and 56.25 % of the hydrodynamics parameters respectively for one and four simulated rain-sequence with relative errors (RE) ranging between −76.22 % and 300.25 %. The most representative results were obtained for 53.13 % of the predicted hydrodynamics parameters with RE value ranging between −23.90 % and 12.75 %. The obtained results proved that, the simplified GA model exhibited an acceptable accuracy in predicting seepage processes for ferruginous and degraded vertic soils. Therefore, the present study contributes to understand the role of numerical simulations tools in modelling and predicting subsurface phenomenon as seepage, for areas with high floods risks in a context of significant climate changes.

Microstructure and transport properties of metakaolin-based geopolymers subjected to accelerated leaching

Towards the development of net-zero carbon concrete and the wider application of geopolymers, understanding the durability of geopolymers has become essential. However, knowledge on the evolution of microstructure and transport properties of the materials under aggressive conditions due to their interaction with external chemicals is limited. Therefore, this study investigated the leaching behaviors of metakaolin-based geopolymers with high water-to-binder (w/b) ratios under a 6 M NH4NO3 attack, focusing on their microstructure and transport properties. Microstructural insights were assessed through N2-adsorption, Mercury intrusion porosimetry, and water porosity analyses. After 28 days of leaching, total porosity slightly decreased, but pore size distribution (PSD) shifted towards larger pore sizes. The materials close to the exposed surface exhibited a relatively higher porosity and larger PSD than the deeper parts. The potential formation of Al(OH)3 and silica layers as a result of dealumination, confirmed by mass gain and SEM/EDS, contributed to the pore structural evolution. These alterations led to slight reductions in water permeability and CH4 diffusion coefficients but mostly increased the He diffusion coefficients of the geopolymers after 28-day leaching. These findings underscored the inherent microstructural characteristics of geopolymers (e.g., porosity, pore size distribution, and tortuosity) and the size of diffusing species as key factors shaping the transport properties. Notably, the permeability and diffusivity of both leached and intact geopolymers exhibited exponential correlations with the accessible porosity.

Features of the Formation of a Reinforcing Coating on Hydrogel Membranes Based on Polyvinylpyrrolidone Copolymers

This paper presents the study results of formation features of composite hydrogel/polyamide membranes obtained by modification of hydrogel films based on 2-hydroxyethylmethacrylate (HEMA) and polyvinylpyrrolidone (PVP) copolymers. The formation process of composite two-layer membranes was carried out in two stages: obtaining hydrogel membrane substrates followed by their modification with an ultra-thin layer based on a mixture of polyamide (PA) with PVP. The main task of the work was to investigate the possibility of forming a modifying PA/PVP coating on the surface of hydrogel films and to obtain composite hydrogel membranes with the required strength and osmotic permeability based on them. For the formation of composite two-layer membranes, PVP with MM = 12 × 103 g/mol and MM = 360 × 103 g/mol were used. Additional use of PVP in the modifying solution contributes to the process of its penetration into the hydrogel substrate. Together with the formation of a reinforcing layer, this ensures the obtainment of hydrogel films of increased strength, with the possibility of directional regulation of their diffusion permeability. It was found that the main factors affecting the nature of the interaction between the layers of the obtained composite films, as well as their physico-mechanical and sorption–diffusion properties, are the HEMA:PVP ratio in the original polymer–monomer composition (PMC), the formulation of the reinforcing layer, the duration of the modification process and the molecular weight of PVP in PMC and in the modifying solution. The strength and water content of two-layer composite hydrogel/polyamide membranes, as well as their salt and water permeability coefficients, are the highest in the case of using high-molecular weight PVP (MMPVP = 360 × 103 g/mol) and low-molecular weight (MMPVP = 12 × 103 g/mol) during the synthesis of the hydrogel substrate to obtain a PA-6/PVP solution for forming a reinforcing layer.

Service performance evaluation of light-transmitting concrete lane markings on highways based on accelerated pavement testing

Applying light-transmitting concrete (LTC) to highway lane markings is a novel idea to increase the visual recognition distance and promote traffic safety. However, compared to its excellent visual recognition performance, its service performance has received little attention in the current research. This paper conducted an accelerated pavement test to investigate the behaviour of rutting depth, British Pendulum Number (BPN) and water permeability coefficient of the LTC lane markings. The results show that rutting depth of LTC is lower than that of asphalt pavement. As a result, small height steps appeared at the seam of the two parts. For the anti-sliding performance represented by the BPN, the BPN of LTC gradually exceeds asphalt pavement and maintains a slightly higher value. For the water permeability coefficient, the LTC is almost un-permeable, avoiding water damage during service. According to these findings, the LTC lane markings meet the requirements of highway service performance. .

Influence of Self-Compound Enhancer on Physical Properties of Pervious Concrete

The new enhancer was a self-compound enhancer (SCE) made of silica fume, potassium lignosulfonate and sodium silicate. The performance of the mixed enhancer was analyzed in depth by X-ray diffraction spectrum analysis (XRD) and infrared spectroscopy (FTIR) techniques to determine the feasibility of SCE. The new pervious concretes (PCs) were prepared using Portland cement as a binder, gravel and c-brass aggregates as the coarse aggregates and SCE as a new enhancer. A series of laboratory experiments were carried out to study the influence of the different amounts of SCE on the compressive strength, water permeability coefficient and microstructure of cement hydration products of high-strength and high-permeability pervious concrete (HHPC). When the amount of SCE reached 3.8–4.0%, a maximum of the compressive strength of HHPC reached 31.33 MPa, and a maximum of the water permeability coefficient of HHPC reached 2.48 mm/s. At this time, a dense and solid network C-S-H was formed in the cement slurry, and the momentum of C-S-H divergence at the junction was very strong. The test results show that when SCE is used as a new enhancer, HHPC can form a perfect skeleton-void structure, which not only meets the engineering strength requirements, but also meets the requirements of eco-friendly water permeability and permeability. It is an environment-friendly concrete.

Measurements of the Permeability Coefficient of Waste Coal Ash under Hydrostatic Pressure to Identify the Feasibility of Its Use in Construction

The aim of this research was to measure the filtration properties of waste coal ash under the influence of hydrostatic pressure generated in a three-axial compression apparatus. The scope of work included determining the compactibility parameters, maximum bulk density and optimal moisture content. Permeability tests were performed for a sample with an average grain composition at three compaction indices IS: 0.964, 0.98 and 1.00. The hydrostatic pressure ranging from 0.5 to 1.8 bar corresponded to the layer depths from 2.17 to 7.83 m. Gradually increasing the pressure during the first loading cycle caused irreversible changes in the structure of the sample by local material agglomeration or grain interlocking. The water permeability coefficient was higher in the second loading cycle than in the first cycle. It was shown that waste coal ash cannot be used as a construction material on its own. To obtain constant filtration properties, the waste coal ash material should be doped, or an optimal compactionshould be used (IS = 1.00). The results presented in this study are important for assessing the use of waste coal ash for construction engineering purposes.

Influence of Mineral Admixtures on the Performance of Pervious Concrete and Microscopic Research

Pervious concrete is an innovative eco-friendly construction material. Through the application of mineral admixtures and microscopic analysis to optimize its performance and analyze its mechanisms, its traits as a sustainable building option may be further improved. This study primarily examines the impact of the optimal blend quantities of fly ash, silica fume, and reinforcing agent on the attributes, micro-morphology, and phase composition of porous concrete. The optimal admixture was chosen after analyzing the effects of various factors on the mix ratio and properties of permeable concrete. To understand the degree of impact, performance tests were conducted on the 28-day compressive strength, water permeability coefficient, and porosity. Furthermore, the micro-mechanisms of the admixtures and reinforcing agents on the properties of permeable concrete were analyzed from a microscopic point of view using scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. This research found that the advantageous properties of permeable concrete were enhanced by the simultaneous integration of appropriate quantities of fly ash, silica fume, and reinforcing agent. This resulted in a 28-day compressive strength of 18.33 MPa and a permeability coefficient of 8.27 mm/s. Compared with the unadulterated mineral admixture, the optimal admixture of fly ash, silica fume, and reinforcing agent at the same time increased the 28-day compressive strength by about double; the permeability coefficient was reduced by 36%, but it was still at a high level; and the measured porosity did not differ much from the designed porosity. Through thorough microanalysis, the hydration reaction was significantly improved, which could enhance the microstructure and pore structure of the concrete. This was supported by a substantial increase in the macroscopic compressive strength and a decrease in the water permeability coefficient, which were consistent with the aforementioned enhancement found in the microanalysis.

Study on the design and laboratory investigation of permeable semi-rigid base material with large air voids

PurposeTo explore the economical and reasonable semi-rigid permeable base layer ratio, solve the problems caused by rainwater washing over the pavement base layer on the slope, improve its drainage function, improve the water stability and service life of the roadbed pavement and promote the application of semi-rigid permeable base layer materials in the construction of asphalt pavement in cold regions.Design/methodology/approachIn this study, three semi-rigid base course materials were designed, the mechanical strength and drainage properties were tested and the effect and correlation of air voids on their performance indexes were analyzed.FindingsIt was found that increasing the cement content increased the strength but reduced the air voids and water permeability coefficient. The permeability performance of the sandless material was superior to the dense; the performance of the two sandless materials was basically the same when the cement content was 7%. Overall, the skeleton void (sand-containing) type gradation between the sandless and dense types is more suitable as permeable semi-rigid base material; its gradation is relatively continuous, with cement content? 4.5%, strength? 1.5 MPa, water permeability coefficient? 0.8 cm/s and voids of 18–20%.Originality/valueThe study of permeable semi-rigid base material with large air voids could help to solve the problems of water damage and freeze-thaw damage of the base layer of asphalt pavements in cold regions and ensure the comfort and durability of asphalt pavements while having good economic and social benefits.

Cucurbit[6]uril builds a water channel for improving the water/salt selectivity of polybenzimidazole

Polybenzimidazole (PBI) has garnered significant interest in desalination due to its exceptional chemical stability and mechanical strength, but suffers from poor water permeability. In this work, different contents of hydroxylated Cucurbit [6]uril (CB [6] were added to PBI to build a “water transport channel”. The effects of CB [6] addition on the chemical structure and surface morphology were analyzed by FTIR, SEM, and Zeta potential, respectively. Based on the solution-diffusion model, the effect of CB [6] on the water/salt transport properties of PBI membranes was thoroughly investigated. The results show that appropriate CB [6] doping can enhance water sorption of PBI through the special “outer hydrophilic and inner hydrophobic cavity” structure, and boost water diffusion with the channeling effect of the hydrophobic CB [6] cavity. While the complexation between the carbonyl group in CB [6] and Na+ ions slightly increased salt sorption, the specific cavity structure of CB [6] can significantly decrease salt diffusion by blocking salt ions and increasing transport path tortuosity. The cavity effect of CB [6] was further confirmed by hybridizing CB [6] with biphenylsulfonyl-substituted PBI when the cavity can be occupied. Therefore, the introduction of CB [6] improves the water/salt diffusion selectivity and then the permeability selectivity of PBI. Notably, the PBI@CB [6] membrane with a 0.25 wt% CB [6] loading exhibited a 40-fold increase in water permeability coefficient compared to pure PBI, while experiencing only a slight decrease in salt permeability coefficient, water/salt selectivity almost exceeding the empirical upper bound line of polymers. This work provides a theoretical foundation for the development of high-performance desalination membranes based on macrocyclic molecules such as CB [6].

A dynamic system analysis study on the design of high-performance pervious concrete ratios

Abstract As permeable concrete contains more pores and larger pore size when improving its water permeability, it will affect its mechanical properties and durability, so it is of great significance to study the mixing ratio of porous concrete. Studying the mixing ratio of porous concrete is of great significance. The subject is studied in depth from the aspects of mechanical properties and water permeability, in order to prepare high-performance permeable concrete with high compressive strength and meet the requirements of infiltration. Firstly. Optimization of the performance of raw materials and mixing ratios of porous concrete, according to the aggregate gradation, aggregate particle size, and other factors on the mechanical properties of porous concrete, to determine its optimal aggregate mixing ratio. Three groups of high-performance pervious concrete specimens with different aggregate particle sizes and pore structures were examined for their real fine structure. Finally, after the preparation of high-performance pervious concrete was completed, the porosity, fractal dimension, equivalent diameter, contour coefficient, and roundness of the specimens were tested to investigate the effects of several factors mentioned above on the permeability coefficient and compressive strength properties of pervious concrete. The results show that the two-dimensional pore diameter is normally distributed, the diameter size is centrally distributed in the range of 0~10mm, and the number of pores in this range accounts for more than 70%. Gradually increasing aggregate particle size leads to an increase in the proportion of large pores inside the specimen. After the compressive strength test and porosity test, it was found that the water permeability coefficient of the porous concrete was the best for the single-grain limestone aggregate with the equivalent diameter range of 5~8mm. The results of this study have theoretical value in enriching and developing high-performance permeable concrete.