Periods Of Volcanic Quiescence Research Articles

RECONSTRUCTING KUNGURIAN (CISURALIAN, PERMIAN) TERRESTRIAL ENVIRONMENTS WITHIN A MEGACALDERA IN THE SOUTHERN ALPS (N-ITALY) USING LITHOFACIES ANALYSIS, PALYNOLOGY AND STABLE CARBON ISOTOPES

During the Permian, climate experienced a change from icehouse to greenhouse conditions. Few multidisciplinary studies have investigated Kungurian (late Cisuralian) tropical terrestrial ecosystem and climate changes. Here, we apply an interdisciplinary approach to two alluvial-lacustrine successions of the Athesian Volcanic Group (Southern Alps, northern Italy) deposited in a Kungurian megacaldera during periods of volcanic quiescence. Sedimentological analysis combined with palynofacies studies allowed the reconstruction of the depositional environments. The study of sporomorph assemblages and stable organic carbon isotopes provided information on plant communities and the climate context. Two different depositional environments were present in the megacaldera: one proximal and one more distal with respect to the source, distinguished by a slightly different composition of the sediments, palynofacies and organic carbon isotopes. The plant community in the area was dominated by xeromorphic-hygromorphic taxa. The δ13Corgvalues are comparable to those of other Cisuralian continental organic matter and plants. The stable carbon isotope values show a small variability, which correlates weakly, but significantly, with the abundance of xeromorphic elements. All observations support deposition during semiarid to arid climate conditions, typical of the mid-late Cisuralian in the area.

Lithostratigraphy, Lithogeochemistry, and Tectono-Magmatic Framework of the ABM Replacement-Style Volcanogenic Massive Sulfide (VMS) Deposit, Finlayson Lake District, Yukon, Canada

Abstract The Upper Devonian ABM deposit is a bimodal-felsic, replacement-style volcanogenic massive sulfide (VMS) deposit within the Finlayson Lake district in Yukon, Canada. The deposit is hosted by predominantly felsic volcanic rocks of the upper Kudz Ze Kayah formation that were deposited in an active back-arc basin in three sequences consisting of interbedded felsic volcaniclastic rocks and argillites, and felsic lava flows and domes, and felsic and mafic sills. The felsic rocks fall into two groups, Felsic A and Felsic B (FA and FB), based on immobile elements and their ratios. Relative to the FB group, the FA group has high Zr concentrations (>550 ppm) and generally higher contents of high field strength elements. The FA/FB chemostratigraphy roughly coincides with the lithostratigraphic sequences. Sequence 2 hosting the mineralization consists of FB felsic rocks; the hanging-wall Sequence 3 and footwall Sequence 1 felsic rocks have FA signatures. An argillite lens, recording a period of volcanic quiescence, occurs at the upper contact of Sequence 2. From reconstruction of the basin architecture, two sets of synvolcanic faults are inferred. The synvolcanic faults were interpreted based on thickness changes of volcanosedimentary units and the distribution of coherent rocks. During breaks in volcanism, synvolcanic faults acted as conduits for upwelling hydrothermal fluids, which were diverted laterally into unconsolidated volcaniclastic rocks and formed the replacement-style VMS mineralization. Although the mineralized lenses are hosted by FB felsic rocks, their replacement-style nature implies that the mineralizing processes occurred during the break in volcanism and were genetically associated with the overlying FA felsic volcanic rocks.

A millimeter-scale insight into formation mechanism of lacustrine black shale in tephra deposition background

To reveal the role of tephra in the deposition of black shale during periods of volcanic activity, we performed lithostratigraphic and geochemical analyses on 14 horizontally sliced samples drilled from a 2-cm-thick black shale interval in the lower Ch7 Member of the Upper Triassic Yanchang Formation, southern Ordos Basin. Results indicate that fewer plankton is preserved during tephra deposition than during periods of volcanic quiescence. With the decrease of volcanic activities and tephra deposition, the abundance of redox-sensitive trace elements (RSTEs) and biolimiting elements increases, while terrigenous elements gradually decrease, resulting in the improvement of organic matter (OM) preservation. Paleoenvironmental proxies suggest that the climate during the Late Triassic was generally warm and humid. However, subsequent intense volcanic eruptions may have caused climatic cooling that affected the water column, resulting in enhanced salinity, primary production, water stratification, and bottom water anoxia, leading to enhanced organic carbon production and preservation. Primary productivity and redox conditions controlled the accumulation of organic carbon. Although physical and chemical reactions relating to the deposition of tephra into water are short-lived, climate change induced by volcanic eruptions is the critical cause of black shale formation.

Marine carbonate sedimentation in volcanic settings

Abstract Carbonate sediments have been produced and deposited in areas of active volcanism since at least the Paleoarchean. Despite early recognition of a significant relationship between volcanism and marine carbonate systems, research in this field has been largely neglected. With increasing recognition of the accelerating effects and significance of anthropogenically driven climate change on the ocean–atmosphere system, the time is ripe for studying volcanism-influenced carbonates as a natural analogue for future environmental scenarios. We undertake a detailed assessment of the state-of-the-science in our understanding of these systems. We identify significant bilateral division in approaches, with the geological and biological communities rarely interacting. The study of ancient volcanic-carbonate systems, in particular, appears to have ‘fallen between two stools’ with both the volcanic and sedimentological communities shying away from studying these cross-disciplinary systems. Observations of recent volcanic–carbonate interactions are challenging; long periods of volcanic quiescence are punctuated by brief episodes of activity. Recent developments in robust remotely deployable instrumentation offer an opportunity to safely undertake sustained monitoring of these systems before, during and after eruptions. Informed assessment of the likely responses of carbonate ecosystems to future climatic challenges requires the initiation of an integrated, collaborative, cross-disciplinary approach to studying the complex interactions within these challenging mixed depositional systems.

Petrography and provenance of beach sands from volcanic oceanic islands: Cabo Verde, Atlantic Ocean

ABSTRACT Volcaniclastic deposits have been extensively analyzed in several settings in the Pacific and circum-Pacific area. Recent volcaniclastic products from Atlantic oceanic islands offer another opportunity to add new data and be an important key to a better understanding of volcanic imprints on the sedimentary record. The Cabo Verde archipelago is an Atlantic Oceanic plateau with late Oligocene to Holocene volcanism. Outcrops consist mainly of mafic and strongly alkaline and ultra-alkaline volcanic (pyroclastic and lava flows) and less abundant intrusive rocks with minor carbonatites and carbonate sedimentary rocks, constituting a multiple-provenance assemblage for the sandy beaches surrounding the islands. Currently, climate is semiarid to hyperarid with ephemeral and intermittent streams. Thirty-six samples of beach sand from six principal Cabo Verde Islands were selected for petrographic inspection. On average, beach sands constitute a volcanolithic petrofacies. A relative increase in carbonate limeclasts and bioclasts dilutes the pure volcaniclastic contribution mainly on the older island beaches (Sao Vicente, Sal, and Boa Vista). The major components of Cabo Verde beach sands are highly variable; in general, composition is a function of island morphological evolution and age. Thus, beaches of the younger islands (Sao Nicolau, Santiago, and Fogo) consist mainly of volcanic lithic fragments, and monomineralic grains of dense minerals such as olivine, pyroxene, and amphibole, and single grains of plagioclase and anorthoclase. By contrast, beaches of older eastern islands (Sal, Boa Vista, and Sao Vicente) contain more calcareous bioclasts, micritic and/or sparitic sedimentary lithic grains. The presence of carbonate grains suggests provenance from shallow carbonate platforms developed during periods of volcanic quiescence. Cabo Verde volcanic sandy fractions are composed mostly of black, brown, and orange glassy volcanic particles exhibiting microlitic, lathwork, and vitric textures. Volcanic particles with lathwork textures are linked to mafic provenance assemblages (nephelinites, basanites, and tephrites). The content of glassy particles is nearly constant in all beaches, and both hydroclastic and epiclastic processes are reflected in these populations of glassy grains. Boa Vista, Sao Vicente, and Santiago beaches contain higher proportions of sideromelane, linked to recent coastal volcanism, and lower proportions of orange and black glassy particles. The concentration of orange glass particles in the beaches of Santiago Island is higher than in the other island beaches. These orange glassy textures have been preserved even if they were sourced from the intensely altered Ancient Eruptive Complex, representing the pre-Miocene seamount stage of Santiago Island. A very small percentage of altered labile monocrystalline grains such as olivine and the paucity of altered volcanic components reflect the weathering-limited erosion regime of the islands. The exposed phonolitic lava flows that occupy only a minor surface part of the inland source produce particles with microlitic texture in sand beaches. Thus, this texture is not exclusive to andesitic, basaltic, and basaltic andesites sources, suggesting the need for a review of these particles as source-sensitive provenance signals.

Complex Interactions Between Large Igneous Province Emplacement and Global‐Temperature Changes During the Cenomanian‐Turonian Oceanic Anoxic Event (OAE 2)

AbstractSuper greenhouse temperatures at the onset of the Cenomanian‐Turonian oceanic anoxic event (OAE 2) have been widely linked with large igneous province (LIP) volcanic activity. However, the extent to which volcanism influenced subsequent climate changes throughout OAE 2, such as global cooling during the Plenus Cold Event (PCE) early in the OAE, and the subsequent return to very warm conditions through the second part of the crisis remain less clear. Here, new osmium‐isotope (187Os/188Os) data are presented from the northeastern margin of the proto‐North Atlantic Ocean (ODP Leg 174AX Bass River, NJ, USA). The results are consistent with previously published OAE 2 records and are similarly interpreted as documenting LIP activity while further demonstrating the ability to use osmium‐isotope stratigraphy as a global chemostratigraphic marker in open‐ocean records. Correlations of 187Os/188Os and sea‐surface temperature trends at Bass River and other sites show that the earliest PCE cooling coincided with intense volcanism, but that LIP activity began to decline during or soon after the cold pulse. These temporal relationships support previous hypotheses that the PCE was regionally diachronous and likely caused by enhanced carbon sequestration via organic‐matter burial and silicate weathering, rather than a period of volcanic quiescence, while the persistently warm conditions later in OAE 2 were linked to reduced silicate weathering rather than sustained volcanism. These findings highlight the complex interactions between LIP emplacement and climate responses during OAE 2, reemphasizing the need for similar correlations between volcanism and paleotemperature proxy data for other major events in Earth's history.

Geochemistry of lavas from Aegina and Poros (Aegean Arc, Greece): Distinguishing upper crustal contamination and source contamination in the Saronic Gulf area

Pliocene (Phase 1) deposits from the volcanic centres of Aegina and Poros (western Aegean Arc) consist of andesitic-dacitic lava flows and domes with mafic enclaves, whereas basaltic-andesitic and rhyolitic lava flows were emplaced during the early Pleistocene Phase 2 and its precursor activity. Fifty-nine new whole rock analyses of lavas and enclaves show geochemical characteristics in keeping with their continental arc setting, with a significant spread in Sr-Nd-Hf-Pb isotope compositions and a strong crustal imprint (e.g. 87Sr/86Sr 0.7041–0.7076). Unlike other Aegean volcanic centres, the Phase 1 deposits show high Ba concentrations and high Ba/Th ratios. These are unlikely to be a signature of fluid-mediated metasomatism of the mantle wedge; subduction of barite-enriched sediments appears a more plausible option. The amount of sediment added to the mantle wedge is ca. 4%. High 208Pb/204Pb relative to 206Pb/204Pb, especially for the Poros lavas, points towards contamination with continental crust similar to the basement of Ios. First-order modelling shows that up to 35% crustal contamination took place. Additionally, crystal fractionation, magma mixing and crystal accumulation shaped the whole rock geochemistry. Similar to the neighbouring island of Methana, the widest isotopic variation is seen in the early Pleistocene deposits, reflecting remobilisation of magma from the previous volcanic episode by isotopically more primitive mafic magmas after a period of volcanic quiescence. The isotopic contrast between the volcanic centres of the Saronic Gulf and those of Santorini and Kos-Nisyros further west is likely related to the geometry and physical characteristics of the subducting slab and mantle wedge, rather than the actual amount of sediments subducted or their composition.

Lithofacies architecture, composition, and age of the Carboniferous Teplice Rhyolite (German–Czech border): Insights into the evolution of the Altenberg-Teplice Caldera

The Teplice Rhyolite (TR) intra-caldera deposits of the Altenberg-Teplice Caldera (ATC, Central Europe) were investigated by lithofacies analysis, stratigraphy, and whole-rock chemistry as well as laser ablation U–Pb zircon dating. The aim was to demonstrate that the joint application of these methods can discern complex stratigraphy of ancient volcanic successions, susceptible to erosion and alteration, taking the TR as case study. The TR was regarded as a formation and divided into nine members that represent three main eruptions, each one separated by periods of volcanic quiescence. The first two eruptions mainly portrayed opening and clearing of vents, which were dominated by lithic-rich ignimbrites with lateral lithofacies changes (fiamme-rich to crystal-rich) covered by lava flows/domes. Eruption style was low pyroclastic fountaining alternated with effusive lava outpour. A sustained buoyant eruption column was exclusively interpreted at the outset of the second eruption based on the presence of a basal fallout deposit. The third eruption recorded three different phases: further vent opening, a waxing phase, and final lava extrusion. The vent opening phase was similar to those occurred in previous eruptions. The waxing phase produced voluminous, massive, poorly-sorted, very crystal-rich (>50vol.%) ignimbrites, exhibiting progressive increase in crystal contents with height and chemical composition variations that indicate deposition by progressive aggradation. Low pyroclastic fountaining formed these high-particle concentration currents that waxed and reached quasi-steady conditions. Eruption ended with extrusion of a lava flow. The TR ignimbrites were emplaced hot and were partially to densely welded, as evidenced by eutaxitic texture, deformed glass shards, spherulites, perlitic cracks, and microcrystalline to granophyric textures. Horizontal and vertical lithofacies variations in pyroclastic deposits, together with progressive infill and association between TR feeding systems and faulting, demonstrate that eruptions developed through several fissure vents or faults. A volcanic explosivity index of 7 was estimated according to a minimum ejecta volume of ∼320km3 (DRE). Volcanic architecture of the TR can be linked to sequential caldera subsidence that occurred synchronously with progressive deposition. Regional faulting (NE–SW-trending rhyolitic dykes) related to ATC feeding conduits suggests that progressive subsidence and final trap-door caldera collapse, possibly with a piece-meal component (faulted caldera floor), originated from post-Variscan tensional stress regime (∼NNW–SSE direction). The TR Formation has a general rhyolitic composition with A-type granite affinities and a normal chemical zoning. U–Pb zircon dating yielded ages from 323 to 312Ma, which, compared to age data from other ATC rocks, indicate that the TR was generated within a time span of ∼325–317Ma.

Not all Neoproterozoic iron formations are glaciogenic: Sturtian-aged non-Rapitan exhalative iron formations from the Arabian–Nubian Shield

Neoproterozoic iron formations are exposed in the Wadi Hamama area (Egypt) in the northwestern part of the Arabian–Nubian Shield. Mafic and felsic volcanic and volcaniclastic rocks of an intra-oceanic island-arc setting host multiple, thin iron-formation units. Major element compositions of the iron formation confirm a low detrital input, whereas the rare-earth elements and Y data suggest deposition related to an influx of low-temperature hydrothermal fluids. Unlike most Neoproterozoic banded iron formations, but similar to other iron-formation occurrences from the Arabian–Nubian Shield, the Nd isotopic compositions of the Wadi Hamama iron formations are predominantly mantle-like. SIMS U–Pb zircon ages of the host volcaniclastic units indicate that the age of iron-formation deposition is ca. 695 Ma, which is within the Sturtian epoch that is presumed to be a glacial event of global extent. Nevertheless, there is no robust evidence of any influence of Sturtian glaciation in the Arabian–Nubian Shield. Our results rather suggest that the iron formations in the area may have formed as low-temperature exhalites on the floor of an island-arc basin. The iron formations were deposited during periods of volcanic quiescence, with metals having been derived during low-temperature pervasive hydrothermal alteration of volcanic and volcaniclastic rocks exposed at the seafloor–seawater interface. Precipitation took place due to mixing of metal-bearing hydrothermal fluids and cold, oxygenated seawater. There is no need to invoke possible effects of global glaciation to explain the origin of the Sturtian-aged iron formations in the shield. Our study thus suggests that not all Neoproterozoic iron formations are necessarily linked to glacial events as the Hamama deposit represents a non-Rapitan exhalative iron formation.

Volcanic Radiative Forcing From 1979 to 2015

AbstractUsing volcanic sulfur dioxide emissions in an aerosol‐climate model, we derive a time series of global‐mean volcanic effective radiative forcing (ERF) from 1979 to 2015. For 2005–2015, we calculate a global multiannual mean volcanic ERF of −0.08 W/m2 relative to the volcanically quiescent 1999–2002 period, due to a high frequency of small‐to‐moderate‐magnitude explosive eruptions after 2004. For eruptions of large magnitude such as 1991 Mt. Pinatubo, our model‐simulated volcanic ERF, which accounts for rapid adjustments including aerosol perturbations of clouds, is less negative than that reported in the Intergovernmental Panel on Climate Change (IPCC) Fifth Assessment Report (AR5) that only accounted for stratospheric temperature adjustments. We find that, when rapid adjustments are considered, the relation between volcanic forcing and volcanic stratospheric optical depth (SAOD) is 13–21% weaker than reported in IPCC AR5 for large‐magnitude eruptions. Further, our analysis of the recurrence frequency of eruptions reveals that sulfur‐rich small‐to‐moderate‐magnitude eruptions with column heights ≥10 km occur frequently, with periods of volcanic quiescence being statistically rare. Small‐to‐moderate‐magnitude eruptions should therefore be included in climate model simulations, given the >50% chance of one or two eruptions to occur in any given year. Not all of these eruptions affect the stratospheric aerosol budget, but those that do increase the nonvolcanic background SAOD by ~0.004 on average, contributing ~50% to the total SAOD in the absence of large‐magnitude eruptions. This equates to a volcanic ERF of about −0.10 W/m2, which is about two thirds of the ERF from ozone changes induced by ozone‐depleting substances.

Evolution of the northern Turkana Depression (East African Rift System, Kenya) during the Cenozoic rifting: New insights from the Ekitale Basin (28‐25.5 Ma)

Two sedimentary basins are identified in the Turkana Depression (East African Rift System, Kenya). One of them, the Ekitale Basin, is presented in detail. Located on the western rift shoulder of the northern Turkana Depression, the preserved portion of the Ekitale Basin is 3–5‐km wide and bordered by N40°–50° normal faults. These normal faults were inherited from the reactivation of pre‐existing basement structures. The Ekitale Basin is filled by the ~75‐m‐thick Topernawi Formation. The lower portion of the formation provides evidence that the basin was occupied by a lake, bordered by alluvial fans, and into which river‐derived turbiditic complexes were deposited. The upper portion is comprised of pyroclastic deposits, originating from volcanic activity, and interbedded with fluvial deposits emplaced during periods of volcanic quiescence. The Ekitale Basin opened just after 28 Ma and was abandoned prior to 25 Ma, placing it after the deposition of the Oligocene Traps (ca. 33.9–27 Ma) and prior to the rift climax (after 14 Ma). This syn‐rift basin largely impacts our understanding of the Cenozoic rift evolution in the Turkana Depression. It helps to identify, for the first time, the first pulse of extension of the Cenozoic rifting, revealing a two‐step rifting scenario for the northern Turkana Depression. The Ekitale Basin, and analogous syn‐rift basins, is believed to have developed from the reactivation of pre‐existing structures during a period of extension marked by low differential stress and a low amount of extension.

A proximal record of caldera-forming eruptions: the stratigraphy, eruptive history and collapse of the Palaeogene Arran caldera, western Scotland

Caldera-forming volcanic eruptions are among the most dangerous, and can generate extensive pyroclastic deposits and deliver ash into global atmospheric circulation systems. As calderas collapse, the eruptions can deposit thick proximal ignimbrite sequences and thinner ignimbrites more distally. However, the proximal record of caldera collapse is often obscured by later intrusions, volcanism, faults, alteration, water and sediments, which significantly limits our understanding of these eruptions. A Palaeogene caldera system in central Arran, western Scotland, preserves a rare proximal caldera-fill succession, the Arran Volcanic Formation. This caldera largely comprises highly heterogeneous ignimbrites and minor intra-caldera sedimentary rocks. The current level of erosion, and the general absence of faults, intrusions and sediments, allows a complex stratigraphy and collapse history to be determined, which can be linked to changing eruptive styles at a constantly evolving volcano. The first recorded phase was eruption of a homogeneous rhyolitic lava-like tuff, deposited from high temperature, high mass-flux pyroclastic density currents generated from low fountaining columns that retained heat. A succeeding phase of highly explosive Plinian eruptions, marked by a thick blanket of massive lapilli tuffs, was then followed by piston-like caldera collapse and erosion of steep caldera walls. Volcanism then became generally less explosive, with predominantly lava-like and eutaxitic tuffs and cognate spatter-rich agglomerates interbedded with non-homogenous lapilli tuffs. High topographic relief between distinct units indicate long periods of volcanic quiescence, during which erosive processes dominated. These periods are, in several places, marked by sedimentary rocks and evidence for surface water, which includes a localised basaltic-andesitic phreatomagmatic tuff. The caldera-forming eruptions recorded by the Arran Volcanic Formation provide an important insight into caldera collapse processes and proximal ignimbrite successions. The lack of thick autobreccias and lithic-rich lapilli- and block-layers indicates that subsidence was relatively gradual and incremental in this caldera, and not accompanied by catastrophic wall collapse during eruption. The relatively horizontal nature of the caldera-fill units and paucity of intra-caldera faulting indicate that piston subsidence was the dominant method of collapse, with a relatively coherent caldera floor bounded by a steeply dipping ring fault. Possible resurgence may have caused later doming of the floor and radial distribution of subsequent ignimbrites and sedimentary rocks. Our work emphasises the continued need for field studies of caldera volcanoes.

Volcanoclastic flow hazard assessment in highly populated areas: a GIS-based approach applied to Torre del Greco municipality (Somma-Vesuvius, Italy)

This paper presents a contribution to Volcanoclastic Flows hazard assessment in very densely populated volcanic areas by using a multidisciplinary study applied to the Torre del Greco area, a municipality close to the active Somma-Vesuvius volcano, in Italy. This study integrates and combines in a GIS environment several types of data: i) information on Volcanoclastic Flows recorded during the years 1906–2010, derived from historical chronicles and local reports; ii) rainfall data relative to the investigated period; iii) summary of the recent activity of Somma-Vesuvius (AD 1631–AD 1944) deriving from the scientific literature; iv) morphological and morphometric analyses derived from a very high resolution Digital Elevation Model developed in the years 2009–2012. The historical analysis of the spatial and temporal distribution of the Volcanoclastic Flows recorded in the Vesuvian area during the last 104 years indicates that the zone mostly affected by such phenomena is the south-western sector of Somma-Vesuvius, and in particular the Torre del Greco municipality, for which a specific database on paths and directions of the historical Volcanoclastic Flows was implemented. The analysis and comparison of all available data allowed us to: i) recognize that the source zone of Volcanoclastic Flows occurred in Torre del Greco was a funnel-shaped area located immediately SW of the Somma-Vesuvius caldera boundary and just above the most urbanized area of the town; ii) individuate the key morphometric parameters (slope and curvature) necessary for the potential triggering of Volcanoclastic Flows; and iii) investigate possible relationships between the fallout deposits of the Somma-Vesuvius main recent eruptions and the historical Volcanoclastic Flows of Torre del Greco. Although this approach represents only a starting point for studies aimed at the assessment and mitigation of Volcanoclastic Flows hazard, it can be applied in other volcanic zones having similar characteristics to the Somma-Vesuvius area. Moreover, it can be used not only during a period of volcanic quiescence when heavy and/or persistent rains are able to remobilize loose pyroclastic deposits, but also in syn-eruptive conditions.

Depositional setting of the Late Archean Fe oxide- and sulfide-bearing chert and graphitic argillite in the Shaw Dome, Abitibi greenstone belt, Canada

Interbedded chert-rich exhalite and graphitic argillite are the only sedimentary rocks deposited in deep-water settings during long-lived hiatuses in mafic to ultramafic volcanism within the Hart area of the Shaw Dome in the Late Archean Abitibi greenstone belt in Canada. The Fe oxide- and sulfide-bearing, but predominantly cherty, exhalite lithological unit in the Hart area can be traced laterally to iron formation elsewhere in the Shaw Dome. Whole-rock as well as Fe and S isotope geochemistry suggest that the exhalite unit was formed as a result of direct precipitation from seawater, distally from hydrothermal centres. Fractionation of Fe isotopes through the precipitation of iron oxyhydroxides in a neutrally buoyant hydrothermal plume removed the heavier isotopes of Fe, resulting in the negative δ56Fe values observed in the exhalite in the Hart area. Archean seawater is generally considered to be anoxic, but moderate Mn enrichments (up to 1.87 wt% MnO) in exhalite along with negative Fe isotope values resulting from partial Fe(II) oxidation suggest the presence of oxygen in the upper part of the water column along the pathway of hydrothermal plumes from their source to the depositional site in the Abitibi greenstone belt. In contrast, the graphitic argillite contains abundant pyrite nodules and bands that exhibit systematic negative Fe isotope values, but does not show Mn enrichment. This unit likely formed in a zone of upwelling of nutrient-rich waters from deeper parts of the basin resulting in high organic productivity. Both exhalite and graphitic argillite have negative Δ33S values, suggesting that sulfur was derived from seawater sulfate, which is consistent with an anoxic atmosphere with sulfate aerosols produced by photochemical reactions. Combined, our data indicates disequilibrium between anoxic atmosphere and partially oxygenated upper part of the water column during periods of volcanic quiescence in the ∼2.7 Ga Abitibi greenstone belt supporting the existence of oxidized oases within the Archean ocean.

Focal mechanisms and size distribution of earthquakes beneath the Krafla central volcano, NE Iceland

AbstractSeismicity was monitored beneath the Krafla central volcano, NE Iceland, between 2009 and 2012 during a period of volcanic quiescence, when most earthquakes occurred within the shallow geothermal field. The highest concentration of earthquakes is located close to the rock‐melt transition zone as the Iceland Deep Drilling Project‐1 (IDDP‐1) wellbore suggests and decays quickly at greater depths. We recorded multiple swarms of microearthquakes, which coincide often with periods of changes in geothermal field operations, and found that about one third of the total number of earthquakes are repeating events. The event size distribution, evaluated within the central caldera, indicates average crustal values with b = 0.79 ± 0.04. No significant spatial b value contrasts are resolved within the geothermal field nor in the vicinity of the drilled melt. Besides the seismicity analysis, focal mechanisms are calculated for 342 events. Most of these short‐period events have source radiation patterns consistent with double‐couple (DC) mechanisms. A few events are attributed to non‐shear‐faulting mechanisms with geothermal fluids likely playing an important role in their source processes. Diverse faulting styles are inferred from DC events, but normal faulting prevails in the central caldera. The best fitting compressional and tensional axes of DC mechanisms are interpreted in terms of the principal stress or deformation rate orientations across the plate boundary rift. Maximum compressive stress directions are near‐vertically aligned in different study volumes, as expected in an extensional tectonic setting. Beneath the natural geothermal fields, the least compressive stress axis is found to align with the regional spreading direction. In the main geothermal field both horizontal stresses appear to have similar magnitudes causing a diversity of focal mechanisms.

Fossil trees, tree moulds and tree casts in the Palaeocene Mull Lava Field, NW Scotland: context, formation and implications for lava emplacement

ABSTRACTMegafossils and macrofossils of terrestrial plants (trees, leaves, fruiting bodies, etc.) are found in sedimentary and pyroclastic units interbedded with lavas in many ancient lava fields worldwide, attesting to subaerial environments of eruption and the establishment of viable plant communities during periods of volcanic quiescence. Preservation within lava is relatively rare and generally confined to the more robust woody tissues of trees, which are then revealed in the form of charcoal, mineralised tissue or as trace fossil moulds (tree moulds) and casts of igneous rock (tree casts, s.s.).In this contribution, we document several such fossil trees (s.l.), and the lavas with which they are associated, from the Palaeocene Mull Lava Field (MLF) on the Isle of Mull, NW Scotland. We present the first detailed geological account of a unique site within the Mull Plateau Lava Formation (MPLF) at Quinish in the north of the island and provide an appraisal of the famous upright fossil tree – MacCulloch's Tree – remotely located on the Ardmeanach Peninsula on the west coast of the island, and another large upright tree (the Carsaig Tree) near Malcolm's Point in the district of Brolass, SW Mull; both occurring within the earlier Staffa Lava Formation (SLF). The taphonomy of these megafossils, along with palynological and lithofacies assessments of associated strata, allows speculation of likely taxonomic affinity and the duration of hiatuses supporting the establishment of forest/woodland communities. The Ardmeanach and Carsaig specimens, because of their size and preservation as upright (? in situ) casts enveloped by spectacularly columnar-jointed basaltic lava, appear to be unique. The aspect of these trees, the thickness of the enveloping lavas and the arrangement of cooling joints adjacent to the trees, implies rapid emplacement, ponding and slow, static cooling of voluminous and highly fluid basaltic magma. The specimens from Quinish include two prostrate casts and several prostrate moulds that collectively have a preferred orientation, aligning approximately perpendicular to that of the regional Mull Dyke Swarm, the putative fissure source of the lavas, suggesting local palaeo-flow was directed towards the WSW. The Quinish Lava is an excellent example of a classic pāhoehoe (compound-braided) type, preserving some of the best examples of surface and internal features so far noted from the Hebridean Igneous Province (HIP) lava fields.These Mull megafossils are some of the oldest recorded examples, remarkably well preserved, and form a significant feature of the island's geotourism industry.

Lithofacies architecture of basaltic andesite lavas and their interaction with wet-sediment: Port a’ Chroinn, Kerrera, NW Scotland

Lavas of the Lorne Plateau Volcanic Succession (LPVS) crop out on the island of Kerrera, NW Scotland, and were emplaced during the Devonian Period, synchronous with Old Red Sandstone (ORS) terrestrial sedimentation. These flows are discontinuously exposed for c. 3 km at Port a’ Chroinn, Kerrera, and typically comprise blocky, basal breccias, coherent, crystalline cores, and clinker flow tops, interpreted as basaltic andesite ’a’a lavas. Gradational zones are observed from coherent core, through highly vesicular core, to semi-coherent lava and normally graded clinker. Prismatically jointed, inflated pahoehoe lavas are also present, but have few characteristic morphological features. Localized domains of magma–sediment mingling occur at the bases of several lavas, with clasts of basaltic andesite within a sandstone matrix. These domains are interpreted as peperites, formed as lava flowed over and mingled with unconsolidated, wet sediment that had been deposited on the surfaces of underlying lavas during periods of volcanic quiescence.

A science & arts sensitization program in Chapultenango, 25 years after the 1982 El Chichόn eruptions (Chiapas, Mexico)

Volcanic risk perception may drastically decrease after eruptions and during periods of volcanic quiescence. Despite the fact that the adults in Chapultenango, a Zoque indigenous community near El Chichόn volcano (Chiapas, Mexico), lived through the 1982 Plinian eruptions, awareness of present volcanic risk is low. In particular, children, adolescents and young adults (born after 1982) should be informed about the activity of El Chichόn, as they are more likely to be affected by possible future eruptions. This grass roots level sensitization project uses a novel approach to poll risk perception and to transmit knowledge of El Chichόn volcano among 6- to 11-year old children by combining scientific information sessions with arts workshops. Similar scientific sessions, although without the arts workshops, were less efficient for the older age group (Secondary School students). Moreover, the local Proteccion Civil and Gobierno Municipal was invited to participate in a basic monitoring of El Chichόn volcano. A lack in continuity in local political terms presented the major barrier for an effective and self-sufficient following-up of the volcanic surveillance. The entire population of Chapultenango was involved during informal meetings and semi-scientific projections of their volcano, offering an alternative and more scientific view on El Chichόn's activity, often referenced in a more mystical-religious frame. It is experienced that the volcanologist is recognized as a highly trusted professional, bridging the gap between the official authorities and society.

Facies architecture, emplacement mechanisms and eruption style of the submarine andesite El Barronal complex, Cabo de Gata, SE Spain

El Barronal complex consists of a succession of andesite lavas and andesite volcaniclastic facies interbedded with carbonate and siliciclastic sedimentary rocks. Carbonate and siliciclastic rocks were deposited in a shallow-marine environment during periods of volcanic quiescence. Lavas consist of an inner coherent core grading outward into hyaloclastite breccia made of dense clasts that in turn grade into hyaloclastite breccia made of vesicular clasts, in massive to layered zones. Volcaniclastic facies contain clasts produced during explosive eruptions and reworked clasts from sources above wave base. Volcaniclastic facies were deposited from cold granular flows with different grain size populations. Stratigraphy and facies architecture at El Barronal suggest that a succession of several discrete eruptive events occurred with a similar cyclic pattern made of an initial explosive phase followed by effusive emplacement of lavas, in turn followed by a period of quiescence of volcanic activity. Hyaloclastic fragmentation of magma took place in the final stages of lava emplacement, allowing only for local disorganization of the jigsaw-fit texture.

VOLCANIC AND VOLCANICLASTIC ROCKS OF THE MESOARCHAEAN PONGOLA SUPERGROUP IN SOUTH AFRICA AND SWAZILAND: DISTRIBUTION, PHYSICAL CHARACTERISTICS, STRATIGRAPHY AND CORRELATIONS

The Mesoarchaean Pongola Supergroup is an exceptionally well-preserved succession of volcanic and sedimentary rocks that extends for 270 km close to the eastern margin of the Kaapvaal Craton in South Africa and Swaziland. It represents a volcano-sedimentary continental or epicontinental deposit that is one of the most extensive coherent Archaean terrains in the world, and the oldest of this extent. Its characteristics are unique amongst supracrustal terrains of this age and are unlike those of other Archaean greenstone belts. Its unique nature is that it marks the transition in southern African crustal development from preceding early greenstone belts, such as observed in the Barberton and Nondweni greenstone belts, to late Archaean basin formation on stable continental crust. The volcano-sedimentary succession of the Pongola Supergroup is divided into the lower, predominantly volcanic, Nsuze Group, which contains subsidiary but nonetheless important sedimentary formations, and the upper, dominantly sedimentary, Mozaan Group, which also contains several volcanic successions of highly variable forms and thicknesses. A basement high separates the Pongola Supergroup into a Northern Domain, which is relatively undeformed, and the Southern Domain, which is strongly deformed and folded. The focus of this paper is on the occurrence, field relations (with detailed maps), description and correlation of the volcanic rocks in both the Nsuze and Mozaan Groups in all areas of the Pongola Supergroup, focusing on 11 key areas in South Africa and Swaziland. The compositional range from basalt to rhyolite is remarkable, and this paper focuses on the distribution of different magma types and styles of eruption throughout the belt, including the first record of ultramafic compositions in the Pongola Supergroup. Ultramafic pyroclastic rocks in the Southern Domain contain highly vesicular fragments that may explain the absence of lava flows of the same composition. Volcanic styles transgress the entire length of the belt, with subaerial sheet flows and minor pillow development in the southern Nkandla region through to a possible continental marginal setting with both subaqueous and subaerial volcanism in the south of the Northern Domain and, finally, into a bimodal suite of felsic and mafic to intermediate volcanic rocks in the northernmost regions. Felsic ignimbrite volcanic rocks with abundant lithophysae are present in the central region. A 770 m-thick section of volcanic rocks that includes andesite and dacite compositions as well as fragmental and volcaniclastic units, including an ultramafic volcaniclastic deposit, is observed in a borehole section of the Tobolsk Formation of the Mozaan Group, that is completely overlain by Karoo sediments in the east. Cyclical episodes of volcanism, many of which were of an explosive nature, were interspersed with periods of rapidly deposited coarse-grained sediments in alluvial fans and braided rivers close to the continental margin. Carbonate formation, together with the development of stromatolites, took place during periods of volcanic quiescence, or reduced volcanic activity, in highly protected surrounds and in intertidal zones. Synchronous volcanism, sedimentation and deep erosion gave rise to the marked lateral variations in both subaerial and subaqueous deposits and marked lithologic variability. The largely volcaniclastic (with a high proportion of ultramafic component) Ndikwe Formation in the Southern Domain is enigmatic with contrasting suggested settings of an early phase of Pongola formation, or a later stage nappe structure, with a possible Mozaan Group time equivalence. No single tectonic setting, on modern day analogues, can explain all features of the Pongola volcano-sedimentary belt. Current evidence for the Nsuze Group is most consistent with a continental arc migrating into a continental rifted environment to the north. The overlying Mozaan Group is inferred to have formed in a cratonic basin following thermal relaxation after the preceding cycles of voluminous volcanism.