We theoretically investigate on the evolution of spatiotemporal chaos under the influence of Raman gain, in an optical ring microresonator. The dynamics of the system is shown to be governed by the Lugiator–Lefever equation, with an additional real and imaginary Raman gain term. In the absence of pump field intensity and Raman gain, we observe an increase in the amplitude and frequency of the traveling optical field as the pump detuning frequency increases. However this field gradually vanishes as time increases, owing to the intra-cavity loss. By exploring an appropriate ansatz which incorporate a chirping parameter, the modified Lugiator–Lefever equation is transformed to a set of four coupled first-order nonlinear ordinary differential equations. Fixed point stability analysis strongly suggest that variation in Raman gain has the propensity of inducing the co-existence of bright and dark solitons in the anomalous dispersion regime. Results of numerical simulations underscore that the structural profiles of the optical field amplitude are greatly modified by the Raman effects. Variation in Raman gain equally leads to a bifurcation analysis of the system, in which the Lyapunov exponent diagrams reveal regions of period doubling and chaos. We finally observe that for a fixed value of the real part of Raman gain coefficient, an increase in the effects of soliton self-frequency shift generally drives the system to chaotic regime.