Thermal Energy Storage Performance Research Articles

Experimental and Simulation Study on Enhancing Thermal Energy Storage and Heat Transfer Performance of Ternary Chloride Eutectic Salt by Doping MgO Nanoparticles

Experimental and Simulation Study on Enhancing Thermal Energy Storage and Heat Transfer Performance of Ternary Chloride Eutectic Salt by Doping MgO Nanoparticles

Experimental study on the heat storage characteristics of rock bed heat storage system with different packing structure

Establishing energy storage systems can provide an effective solution to the challenges posed by the variability and intermittency of renewable energy sources. Among the available options for energy storage, rock-packed bed thermal energy storage systems are widely favored for their performance, cost-effectiveness, and reliability. The more compact the rock packing, the more adequate the heat exchange of the system; however, poorer permeability increases fluid friction losses and pressure drop, which is detrimental to heat transport within the system. The permeability and heat exchange of the system jointly determines its thermal energy storage performance. This study proposes a composite packing scheme utilizing intact rock slabs and broken rock to enhance the thermal energy storage performance of the packed bed. This approach aims to augment heat exchange efficiency and elevate energy storage density while maintaining the bed's commendable permeability. Heat injection and heat extraction experiments of rock beds were conducted to study the heat storage characteristics of the rock-packed bed thermal storage system under different packing structure. In addition, this study investigates the effect of different injection pressures on the storage and release of heat in the system. The results show that the volume of the pore space of the filled bed, serving as the primary domain for gas flow and gas-rock heat exchange, is a decisive factor affecting the packed bed's permeability and heat exchange performance. When the porosity of the packed bed increased from 5.5 % to 9.9 %, its permeability increased from 1.42 × 10−13 m2 to 3.20 × 10−13 m2, yet the thermal exchange efficiency declined from 67.2 % to 65.3 %. Reasonably arranging intact rock slabs and broken rock fill can alter the path of heat transfer within the packed bed, thereby effectively enhancing its heat storage and release performance. For the same pore volume conditions, the heat exchange efficiency of the packed bed is increased by about 10 % by increasing the number of layers of broken rock fill. Additionally, high gas injection pressures can facilitate heat storage and release processes, but it does not mean that this is more efficient. The research findings can guide the selection of packing and injection schemes in packed bed thermal energy storage systems.

Thermal performance investigation of microencapsulated phase change material enhanced with graphene nanoplatelets in double-glazing applications

Effective heat energy storage is crucial for thermal energy management. The utilization of latent heat storage methods is widely prevalent across various engineering applications for enhancing energy efficiency. In this study, the energy storage performances of Phase Change Materials (PCMs) achieved by incorporating graphene nanoplatelets into a microencapsulated PCM were experimentally analyzed for double-glazing applications. Changes in thermal energy storage and heat transfer performance by incorporating graphene nanoplatelets into the PCM at two different mass ratios (1 % and 0.1 %) were investigated. The results obtained from light intensity and temperature measurements, as well as thermal camera imaging, were evaluated together. The results support the contribution of graphene nanoplatelets addition to microencapsulated PCMs in enhancing thermal performance during both heating and cooling periods. Among the investigated cases, the highest mass ratio of 1 % graphene nanoplatelets addition led to a major 10 °C increase in peak temperature compared to the reference condition. In contrast, this increase in peak temperature was accompanied by a mere 14 % decrease in average light levels. This research underlines the potential of graphene-enhanced microencapsulated PCMs in optimizing thermal management systems for double-glazing applications, offering a promising pathway towards enhancing energy efficiency and thermal comfort in building environments.

Enhancing thermal energy storage efficiency at low temperatures with innovative macro-encapsulation of nano phase change material in cementitious composites

In this study, phase change material (PCM) was encapsulated in a novel aluminium-based macro-capsule and indirectly applied to cement-based mortar to address leakage issues and enhance thermal management. To further improve the thermal efficiency of the PCM, nanofluid technology was utilized by incorporating multi-walled carbon nanotubes (MWCNTs). Thermophysical property tests were conducted to evaluate the thermal properties and stability of the PCM/MWCNT composite. Additionally, thermal cycling tests of the cementitious composites with macro-encapsulated nano-PCM were performed to verify their thermal performance for thermal energy storage under varying ambient temperatures. The results confirmed that the thermal conductivity of the nano-PCM was more than 100 % greater than that of raw PCM. Furthermore, the high-efficiency thermal energy storage cementitious composite was able to maintain the temperature above 0°C when the ambient temperature was −5°C, demonstrating its superior thermal energy storage performance. This innovative approach highlights the potential of the PCM/MWCNT composite for effective thermal regulation in subzero climates, providing a robust solution for enhancing energy efficiency in challenging environmental conditions.

Influence of convection on the thermal storage performance of energy tunnels

The decarbonization of the built environment requires rapid growth in energy storage solutions due to the intermittent nature of most renewable energy sources. This paper focuses on the efficacy of so-called energy tunnels (i.e., tunnels equipped with pipe heat exchangers) used for underground thermal energy storage. By harnessing a 3-D thermo-hydraulic finite element model validated against full-scale experimental data, this work specifically explores seasonal, medium-temperature, thermal energy storage operations of energy tunnels. Numerical simulations are performed to unravel the influence of convection resulting from groundwater flows and airflows on the thermal energy storage performance of energy tunnels. The analyses address the impact of different groundwater flow velocities, air temperatures, and airflow velocities on the thermal losses and storage efficiency of energy tunnels used as thermal batteries. The study discourages underground thermal energy storage in the presence of convection due to significant heat losses. It shows that thermal energy storage operations via energy tunnels are feasible in site conditions characterized by no groundwater flow, limited temperature differentials between the heat carrier fluid circulating in the pipe heat exchangers and the surroundings, and thermal insulation on the tunnel intrados.

Triplet-Sensitized Switching of High-Energy-Density Norbornadienes for Molecular Solar Thermal Energy Storage with Visible Light.

Norbornadiene-based photoswitches have emerged as promising candidates for harnessing and storing solar energy, holding great promise as a viable solution to meet the growing energy demands. Despite their potential, the effectiveness of their direct photochemical conversion into the resulting quadricyclanes has room for improvement owing to (i) moderate quantum yields, (ii) poor overlap with the solar spectrum and (iii) photochemical back reactions. Herein, we present an approach to enhance the performance of such molecular solar thermal energy storage (MOST) systems through the triplet-sensitized conversion of aryl-substituted norbornadienes. Our study combines deep spectroscopic analyses, irradiation experiments, and quantum mechanical calculations to elucidate the energy transfer mechanism and inherent advantages of the resulting MOST systems. We demonstrate remarkable quantum yields using readily available sensitizers under both LED and solar light irradiation, significantly surpassing those achieved through direct excitation with photons of higher energy. In contrast to the conventional approach, light-induced back reactions of the high-energy products do not play any role, allowing quantitative switching within minutes. These results not only underscore the potential of triplet-sensitized MOST systems to leverage the high energy storage capabilities of multistate photoswitches but they might also stimulate the broader usage of sensitization strategies in photochemical energy conversion.

Triplet‐Sensitized Switching of High‐Energy‐Density Norbornadienes for Molecular Solar Thermal Energy Storage with Visible Light

Norbornadiene‐based photoswitches have emerged as promising candidates for harnessing and storing solar energy, holding great promise as a viable solution to meet the growing energy demands. Despite their potential, the effectiveness of their direct photochemical conversion into the resulting quadricyclanes has room for improvement owing to (i) moderate quantum yields, (ii) poor overlap with the solar spectrum and (iii) photochemical back reactions. Herein, we present an approach to enhance the performance of such molecular solar thermal energy storage (MOST) systems through the triplet‐sensitized conversion of aryl‐substituted norbornadienes. Our study combines deep spectroscopic analyses, irradiation experiments, and quantum mechanical calculations to elucidate the energy transfer mechanism and inherent advantages of the resulting MOST systems. We demonstrate remarkable quantum yields using readily available sensitizers under both LED and solar light irradiation, significantly surpassing those achieved through direct excitation with photons of higher energy. In contrast to the conventional approach, light‐induced back reactions of the high‐energy products do not play any role, allowing quantitative switching within minutes. These results not only underscore the potential of triplet‐sensitized MOST systems to leverage the high energy storage capabilities of multistate photoswitches but they might also stimulate the broader usage of sensitization strategies in photochemical energy conversion.

Numerical analysis of hydrophobic surface effects on cavitation inception and evolution in high-speed centrifugal pumps for thermal energy storage and transfer systems

This study explores the influence of wettability surfaces on cavitation inception and evolution in high-speed centrifugal pumps used for thermal energy storage and transfer systems through numerical simulations. The simulations were conducted using the Kunz mass transfer model implemented in Fluent, combined with the Eulerian multiphase flow approach and the shear stress transport k–ω turbulence model. The cavitation dynamics were analyzed across contact angles ranging from superhydrophilic to superhydrophobic conditions. The results demonstrate that superhydrophobic surfaces delay cavitation onset compared to hydrophilic ones, reducing the critical cavitation coefficient by at least 28%. At flow rates of 1.11 Q0 and 0.89 Q0, cavitation numbers show distinct trends, with superhydrophobic surfaces enhancing cavitation stability and reducing the frequency of cavitation shedding. The reentrant jet dynamics are also affected, with increased hydrophobicity weakening the jets and stabilizing cavitation zones. This research aims to advance the understanding of using surface wettability to manage cavitation in high-speed centrifugal pumps, thereby improving the performance and reliability of thermal energy storage and transfer systems.

Titanium dioxide/graphene oxide synergetic reinforced composite phase change materials with excellent thermal energy storage and photo-thermal performances

The development of advanced composite solid-solid phase change materials (SSPCMs) is urgent to explore for improving solar energy harvesting and storage. Herein, novel composite SSPCMs with synergetic cross-linking structure were fabricated through polymerization using GO and TiO2 constructed on the polyurethane framework skeleton. GO and TiO2 synergetic enhanced polymer framework played a role as skeletal structure to encapsulate PEG in the molecular chains, and provided as highly thermal conductive pathways for the composite SSPCMs. TiO2 nanoparticles performed as extended surface on the skeletal structure for further improvement in thermal conductivity. The composite SSPCMs exhibited a remarkably improved thermal conductivity as high as 0.7 W/(m‧K) and fast thermal response rate. The good light adsorption property of TiO2 enhanced the light absorbance efficiency of the composite SSPCMs by 94.4%. And the photo-thermal conversion efficiency of the composite SSPCMs highly reached 93.5%. Meanwhile, the composite SSPCMs exhibited excellent anti-leakage performance and shape stability under high temperature. Consequently, the as-prepared composite SSPCMs possessed a potential for applications in thermal energy storage and solar energy utilization systems.

Melting Behavior Effect of MXene Nanoenhanced Phase Change Material on Energy and Exergy Analysis of Double and Triplex Tube Latent Heat Thermal Energy Storage

Abstract The impacts of melting behavior on the thermal performance of triple tube thermal energy storage (TT-TES) and double tube thermal energy storage (DT-TES) systems employing cetyl alcohol and 3% v/v. MXene nano-enhanced PCM (NEPCM) are compared and numerically evaluated in this work. For both the DT-TES and TT-TES systems, the following were investigated in connection to melting time: system efficiency, discharged energy, heat transfer rate, exergy destruction, entropy generation number, exergetic efficiency, melting fraction, and melting temperature contours. In addition, the effect of Stefan, Rayleigh, and Nusselt numbers on Fourier numbers are compared for the DT-TES and TT-TES systems with MXene NEPCM. MXene-based nano-enhanced PCM melting in TT-TES displayed 6.53% more Stefan number than cetyl alcohol. DT-TES with pure cetyl alcohol phase change material (PCM) consumes 0.4% more energy at 7800 s than MXene NEPCM. Pure melting of MXene-based nano-enhanced PCM in a TT-TES had 4.16% higher storage exergy than cetyl alcohol. The entropy generation number of pure melting of MXene-based nano-enhanced PCM in TT-TES is 7.93% lower than that of cetyl alcohol. Pure melting of MXene-based nano-enhanced PCM in TT-TES reduces storage energy by 1.95% over cetyl alcohol. Pure cetyl alcohol has 76.99% optimal system efficiency at 5400 s melting time and MXene NEPCM 77.04% at 4800 s in DT-TES. The charging temperature for pure cetyl alcohol PCM in TT-TES is 0.7% lower than in DT-TES. Furthermore, pure melting of MXene-based nano-enhanced PCM in a TT-TES has 1.95% lower storage energy than cetyl alcohol. For a given volume of MXene-based nano-enhanced cetyl alcohol PCM, melting occurs more rapidly in a TT-TES system.

Prediction of thermo-physical properties and evaluation of thermal energy storage performance of phase change materials based on silicone rubber/graphite (Q/G) composites

ABSTRACT Phase change composite materials (PCCMs) are a type of thermal energy storage system known for their high latent heat of fusion. In this study, PCCM samples based on peroxide-cured silicone rubber (Q) were prepared using a simple soaking procedure in molten Paraffin Wax (PW). At any fixed amount of peroxide, the rubber base samples were filled with varying amounts of graphite powder (G), 4 to 8 Wt.%, to improve the thermo-physical properties. The effect of peroxide and graphite content was then evaluated on the PW loading, PW leakage, and thermal storage performance of the resulting Q/G/PW composites. It was found that the highest ratio of the PW loading to PW leakage occurs at a peroxide content of 6 Wt.%. Moreover, the graphite particles demonstrate a significant role in PW trapping inside the rubber structure and lowering the PW leakage. Finally, the thermal studies showed that the Q/G/PW composite containing 6 wt.% of peroxide and 4 wt.% of graphite has the highest latent heat of 111.5 J/g with a PW loading of 15.2%. This sample also had the lowest thermal diffusivity and the slowest cooling and heating rate.

Multifunctional sandwich composites with optimized phase change material content for simultaneous structural and thermal performance

This work aims at developing novel multifunctional sandwich composites with optimized thermal energy storage and structural load-bearing performance by incorporating microencapsulated phase change materials (PCMs) into polyurethane (PU) foam cores. The optimized foam containing 20 wt% PCM, balancing good latent heat storage (up to 29 J/g) with low thermal conductivity (up to 0.035 W/(m·K) at 50 °C), was used to produce sandwich panels with high-performance epoxy/carbon fiber laminate skins. Microstructural characterization confirmed excellent interfacial adhesion between the core and skins. The multifunctional panels exhibited comparable flexural strengths (150 kPa) and facing stresses (25 MPa) to neat PU sandwich controls. By integrating thermal regulation from PCM phase change with structural reinforcement from the sandwich architecture in a single multifunctional material system, this work contributes to the development of lightweight, energy-efficient composite materials suitable when weight reduction and thermal management are paramount, such as in aeronautics and cold chain logistics.

Simultaneous improvements in energy density and thermal conductivity of PAN polymer nanocomposites enabled by core-shell structure BZCT@BNNS nanofibers

If the heat generated by electronic devices in high-power applications cannot be dissipated in a timely manner, it will not only affect the use of the equipment but also reduce its service life. Therefore, there is an urgent need to develop thin films of dielectric nanocomposites with high thermal conductivity, high energy storage, and excellent flexibility and electrical insulation performance. In this study, we reported the successful preparation of BZCT nanofibers (BZCT NFs) and core-shell structures BZCT@BNNS nanofibers using electrospinning and coaxial electrospinning techniques, respectively, and there were used to composite with polyacrylonitrile (PAN) polymer matrix to prepare BZCT NFs/PAN and BZCT@BNNS/PAN dielectric nanocomposites thin film. Research has found that when the shell thickness of BNNS is 15 nm and BZCT@BNNS (15 nm) volume fraction is 20 vol%, the comprehensive performance of the dielectric nanocomposites is the best, with thermal conductivity and energy storage performance of 3.36 W m−1K−1 and 12.23 J/cm3, respectively. Therefore, the nanocomposites thin film can be used as a potential high-performance dielectric material for thermal management applications in high-power density electronic devices.

Thermal energy storage performance of liquid polyethylene glycol in core–shell polycarbonate and reduced graphene oxide fibers

Thermal energy storage is a promising, sustainable solution for challenging energy management issues. We deploy the fabrication of the reduced graphene oxide (rGO)–polycarbonate (PC) as shell and polyethylene glycol (PEG) as core to obtain hydrophobic phase change electrospun core–shell fiber system for low-temperature thermal management application. The encapsulation ratio of PEG is controlled by controlling the core flow rate, and ~ 93% heat energy storage efficacy is apparent for 1.5 mlh−1 of core flow rate. Moreover, the prepared fiber possesses maximum latent melting and freezing enthalpy of 30.1 ± 3.7 and 25.6 ± 4.0 Jg−1, respectively. The transient dynamic temperature vs. time curve of the rGO-loaded phase change fiber demonstrates the delay of fiber surface temperature change compared to pristine fiber. We indeed show that the tunable heat transfer and thermal energy storage efficacy of phase change fiber is achieved via controlled liquid PEG delivery and the addition of rGO in shell architecture. Notably, the effectiveness of unique phase change material (PCM)–based core–shell fibers is concluded from advanced scanning thermal microscopy (SThM) and self-thermoregulation tests.

High temperature polyimide nanocomposites containing two-dimensional nanofillers for improved thermal stability and capacitive energy storage performance

High temperature polyimide nanocomposites containing two-dimensional nanofillers for improved thermal stability and capacitive energy storage performance

Numerical and Experimental Investigation on Performance of Thermal Energy Storage Integrated Micro-Cold Storage Unit

Numerical and Experimental Investigation on Performance of Thermal Energy Storage Integrated Micro-Cold Storage Unit

Experimental and Numerical Investigation of Macroencapsulated Phase Change Materials for Thermal Energy Storage.

Among the different types of phase change materials, paraffin is known to be the most widely used type due to its advantages. However, paraffin's low thermal conductivity, its limited operating temperature range, and leakage and stabilization problems are the main barriers to its use in applications. In this research, a thermal energy storage unit (TESU) was designed using a cylindrical macroencapsulation technique to minimize these problems. Experimental and numerical analyses of the storage unit using a tubular heat exchanger were carried out. The Ansys 18.2-Fluent software was used for the numerical analysis. Two types of paraffins with different thermophysical properties were used in the TESU, including both encapsulated and non-encapsulated forms, and their thermal energy storage performances were compared. The influence of the heat transfer fluid (HTF) inlet conditions on the charging performance (melting) was investigated. The findings demonstrated that the heat transfer rate is highly influenced by the HTF intake temperature. When the effect of paraffin encapsulation on heat transfer was examined, a significant decrease in the total melting time was observed as the heat transfer surface and thermal conductivity increased. Therefore, the energy stored simultaneously increased by 60.5% with the encapsulation of paraffin-1 (melting temperature range of 52.9-60.4 °C) and by 50.7% with the encapsulation of paraffin-2 (melting temperature range of 32.2-46.1 °C), thus increasing the charging rate.

Multifunctional phase change film with high recyclability, adjustable thermal responsiveness, and intrinsic self-healing ability for thermal energy storage

Phase change materials (PCMs) present promising potential for guaranteeing safety in thermal management systems. However, most reported PCMs have a single application in energy storage for thermal management systems, which does not meet the growing demand for multi-functional materials. In this paper, the flexible material and hydrogen-bonding function are innovatively combined to design and prepare a novel multi-functional flexible phase change film (PPL). The 0.2PPL-2 film exhibits solid-solid phase change behavior with energy storage density of 131.8 J/g at the transition temperature of 42.1 °C, thermal cycling stability (500 cycles), wide-temperature range flexibility (0–60 °C) and self-healing property. Notably, the PPL film can be recycled up to 98.5% by intrinsic remodeling. Moreover, the PPL film can be tailored to the desired colors and configurations and can be cleverly assembled on several thermal management systems at ambient temperature through its flexibility combined with shape-memory properties. More interestingly, the transmittance of PPL will be altered when the ambient temperature changes (60 °C), conveying a clear thermal signal. Finally, the thermal energy storage performance of the PPL film is successfully tested by human thermotherapy and electronic device temperature control experiments. The proposed functional integration strategy provides innovative ideas to design PCMs for multifunctionality, and makes significant contributions in green chemistry, high-efficiency thermal management, and energy sustainability.

Enhanced heat transfer and thermal storage performance of molten K2CO3 by ZnO nanoparticles: A molecular dynamics study

Molten salt serves as a popular medium for thermal storage and transfer in concentrated solar power (CSP) systems. The existing experimental studies have found the capacity of enhancing the heat storage property of the molten carbonate by doping ZnO nanoparticles. However, it has been rarely reported to conduct simulations of ZnO/molten carbonate nanofluids, and the underlying mechanism of how ZnO nanoparticles enhance the heat transfer and storage capacity has less been explored. In this study, molecular dynamics (MD) simulation has been used to investigate the heat transfer and storage properties of a molten K2CO3 nanofluid containing ZnO nanoparticles. It was found that as the nanoparticle mass ratio in molten salt based nanofluids rises, their specific heat capacity initially increases but subsequently diminishes. The specific heat capacity peaks when the ZnO mass ratio is at 1 wt%, resulting in an increase of 17.83 % compared with the base salt. The thermal conductivity in nanofluids based on molten salt increases with the increasing of ZnO mass ratio. Multi-perspective analysis of the mechanism how ZnO nanoparticles enhance the thermal energy storage performance of molten salt, including the microstructural analysis, number density, vibrational density of state, and heat flow decomposition, is conducted. In addition, results of the number density illustrates that a compressed layer of K+ is formed surrounding the ZnO nanoparticles, and the change in the potential energy leads to an increasing heat capacity. Analysis of the heat flow decomposition suggests that the enhanced nonbonded interaction is the main reason for the improvement of thermal conductive performance in the nanofluids based on molten salt. The findings in the present study provide a new perspective of how ZnO nanoparticles enhance the thermophysical properties of molten salts.

A comparative analysis on charging performance of triplex-tube heat exchanger under various configurations of composite phase change material

In present work, the melting performance of triplex-tube latent heat thermal energy storage (LHTES) unit was numerically studied using equal volumes of PCM and metal foam composite PCM (CPCM) in various arrangements. For the n-eicosane (as PCM), the study was conducted at the fixed Rayleigh number (Ra) = 4.08x107, Prandtl number (Pr) = 62.9, and Stefan number (Ste) = 0.14. The results showed that positioning the metal foam on the bottom side and distributing segmented CPCM with alternating PCM zones effectively improved the system performance. Moreover, this also prevents the overheating of thermal layers in the LHTES unit. While the model labelled M2 exhibited the highest economic efficiency among all isotropic models, its low dimensionless thermal energy storage (TES) density (i.e., q’ ∼ 0.6) led this study to focus on models falling under the category having a TES density of ∼ 0.8. Compared to a pure PCM model, the configurations under equal volume ratio category demonstrated up to ∼ four times higher TES rate (p’) and the significant reduction of ∼ 75 % in melting time. The optimized isotropic model achieved the highest TES rate per unit cost with peak value of ∼ 3 at a price ratio (N) of 1. Lastly, the testing of metal foam anisotropy on the chosen design showed a substantial increase in melting/heat storage rates. The largest drop of ∼ 33 % in the total melting time was noticed for model M2 as compared to isotropic case.