Perfect Confinement Research Articles

Perfect confinement of crown ethers in MOF membrane for complete dehydration and fast transport of monovalent ions.

Fast transport of monovalent ions is imperative in selective monovalent ion separation based on membranes. Here, we report the in situ growth of crown ether@UiO-66 membranes at a mild condition, where dibenzo-18-crown-6 (DB18C6) or dibenzo-15-crown-5 is perfectly confined in the UiO-66 cavity. Crown ether@UiO-66 membranes exhibit enhanced monovalent ion transport rates and mono-/divalent ion selectivity, due to the combination of size sieving and interaction screening effects toward the complete monovalent ion dehydration. Specifically, the DB18C6@UiO-66 membrane shows a permeation rate (e.g., K+) of 1.2 mol per square meter per hour and a mono-/divalent ion selectivity (e.g., K+/Mg2+) of 57. Theoretical calculations and simulations illustrate that, presumably, ions are completely dehydrated while transporting through the DB18C6@UiO-66 cavity with a lower energy barrier than that of the UiO-66 cavity. This work provides a strategy to develop efficient ion separation membranes via integrating size sieving and interaction screening and to illuminate the effect of ion dehydration on fast ion transport.

Governance of Friedrich-Wintgen bound states in the continuum by tuning the internal coupling of meta-atoms.

Bound state in the continuum (BIC) is a phenomenon that describes the perfect confinement of electromagnetic waves despite their resonant frequencies lying in the continuous radiative spectrum. BICs can be realized by introducing a destructive interference between distinct modes, referred to as Friedrich-Wintgen BICs (FW-BICs). Herein, we demonstrate that FW-BICs can be derived from coupled modes of individual split-ring resonators (SRR) in the terahertz band. The eigenmode results manifest that FW-BICs are in the center of the far-field polarization vortices. Quasi-BIC-I keeps an ultrahigh quality factor (Q factor) in a broad momentum range along the Γ-X direction, while the Q factor of the quasi-BIC-II drops rapidly. Our results can facilitate the design of devices with high-Q factors with extreme robustness against the incident angle.

An Enhanced High Q-Factor Resonance of Quasi-Bound States in the Continuum With All-Dielectric Metasurface Based on Multilayer Film Structures

Confinement of light is very important to the field of optics, and it is theoretically possible to achieve the perfect confinement for optical modes located in the continuous domain radiation state. Achieving perfect confinement is possible for bound states in the continuum (BIC), which localize waves that lie in the continuous spectrum of the radiative state and remain in a perfect localized state. In this article, we propose a metasurface that consists of arrays of silicon nanoellipsoidal pairs and calculate its transmission spectra and energy bands. Based on an all-dielectric metasurface, a dielectric multilayer film is incorporated to improve the quality factor of the array composed of ellipsoidal table pairs by an order of magnitude. By breaking the symmetry of ellipsoidal table pairs, quasi-BIC resonance modes excited by electric quadrupole (EQ) and magnetic dipoles (MDs) are realized using asymmetric silicon nanoellipsoid surfaces, where the quasi-BIC modes have high <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${Q}$ </tex-math></inline-formula> -factors. In this article, the relationship between the structural asymmetry of Fano resonance controlled by symmetry-protect BICs and the radiation <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${Q}$ </tex-math></inline-formula> -factor is analyzed and demonstrated theoretically. At the same time, we use quasi-BIC resonances in asymmetric silicon nanoellipsoidal pairs of metasurfaces to achieve a huge Goos–Hänchen (GH) shift enhancement, which exceeds the third-order wavelength and a very large group index to achieve excellent slow-light effects. Our work is centered on the design of simulations for the BIC metasurface. Meanwhile, based on the simulation design results, we propose to advance the application of optical communication devices, BIC sensing, optical switches, and optical modulators.

A novel concrete-filled auxetic tube composite structure: Design and compressive characteristic study

Concrete-filled stainless steel tube (CFSST) members take advantage of the high strength and the outstanding corrosion resistance to act as an important role in civil engineering structures. However, the steel tube could not provide the perfect confinement effect for the core concrete during the initial elastic compression stage because Poisson’s ratio of the concrete is smaller than that of the stainless steel tube (SST). In this paper, a novel concrete-filled auxetic stainless steel tube (CFASST) composite structure was designed and manufactured to actively restrain the concrete, making the best use of the desirable deformation characteristics of auxetic tubular structures. The axial compressive performance of these CFASST members and their control factors were investigated experimentally and numerically. Test results were discussed in detail which included failure modes, load versus displacement curves and strain analysis. Finally, parametric analyses were conducted to further study the effects of different parameters (Poisson’s ratio, thickness of the stainless tube) on the CFSST composite structure under axial compression. It was found that CFASST composite structures possess an unusual deformation mode and an improved confinement effect.

Strategies for Perfect Confinement of POM@MOF and Its Applications in Producing Defect-Rich Electrocatalyst.

Polyoxometalate encapsulated by metal-organic framework (POM@MOF) hybrid is an ideal precursor for electrocatalysts because it provides a homogeneous catalyst system with a flexible synergistic effect. However, controlling its fine structures to activate the derived catalyst after pyrolysis remains a challenge. The uniformly distributed carbon-defect tungsten oxides on the 3D carbon matrix were synthesized by using phospho-tungstic acid confined in HKUST-1 (PA@HKUST-1) as the precursor. By choosing ethanol as the solvent, the framework of PA@HKUST-1 was retained integrally and each pore of HKUST-1 kept intact even with holding the PA molecule inside. The well-organized structure of PA@HKUST-1 facilitated to offer a highly distributed metal source, and further transform into defect-rich catalyst. The average size of the resulting WOxCy/C catalysts was 1.5 nm, which was similar to a single molecule of PA. The WOxCy/C catalysts exhibited superior activity in the methanol oxidation reaction after being platinized due to the enhanced resistance to CO poisoning, which is also confirmed by DFT. This finding suggests a new route to design and achieve the defect-rich catalyst with controllable size.

Application of the shear-tensile source model to acoustic emissions in Westerly granite

Traditionally in seismology and in acoustic emission (AE), full moment tensor (MT) is applied as a default model of the mechanism. We present an alternative - an application of shear tensile crack (STC) source model to AEs generated by uniaxial compression loading of Westerly granite. The advantages of STC over the conventional MT are as follows: (i) contrary to the MT, the STC is physical source since it describes straight and simple fracture modes anticipated inside a loaded sample, namely the shear-slip and both of opening and closing tensile cracks; and (ii) the STC is simpler because it is described by fewer parameters (five instead of six required for an unconstrained MT), an essential feature for stabilizing the inverse problem.Better suitability of STC over MT is demonstrated by three exemplary AEs (tensile, shear, and combined). The obtained results were confirmed using a statistical analysis of 1630 reliably determined source mechanisms. The STC, as compared to the MT, provides smaller confidence regions for orientation and even smaller regions for decomposition parameters. Thus, the STC solution appeared to be substantially more useful than the MT, namely for mechanisms with a high content of non-double-couple (non-DC) component, as it allowed better distinction between tensile and shear AEs.Grain scale cracks of tension and combined source type, localized within the middle-height circumferential portion of the specimen, dominated fracturing. Azimuthal distribution of fault planes was found to be approximately uniform for all three source types. The fault dip increased with increasing content of the non-DC component. The average values were 16°, 21°, and 26° for the tensile, combined and shear source types, respectively. The specimen failed by flaking in areas of a high AE activity. AE locations and failure mechanisms indicate a perfect confinement end-boundary conditions between the tested specimen and the loading platens.

Symmetry-protected bound states in the continuum supported by all-dielectric metasurfaces

Symmetry-protected bound states in the continuum (BICs) are nonradiative states with infinite lifetime and perfect confinement of energy even though lying in the radiation continuum due to the symmetry incompatibility. Herein, we study the symmetry-protected BIC supported by metasurfaces composed of silicon nanodisks. Through adding or removing parts of the nanodisks from the edge, a sharp Fano resonance emerges and demonstrates the excitation of quasi-BIC. Their $Q$ factors exhibit the same dependence on the asymmetry degree with these two opposite operations. Furthermore, from both qualitative and quantitative perspectives, analysis on far-field contributions from multipole moments along different directions combining with near-field distributions explains the evolution from BIC to quasi-BIC. The dominant contributor to the quasi-BIC is illustrated to be the electric quadrupole in the $x\ensuremath{-}y$ plane. Finally, the topological charge carried by the BIC is calculated to be $\ensuremath{-}1$, demonstrating the topological characteristics of our design. Such metasurfaces are robust in nanofabrication. Our results may provide a route for resonators with better performance applied in sensing, switching, nonlinear optics, and so on.

Compressing Θ-Chain in Slit Geometry.

When compressed in a slit of width D, a Θ-chain that displays the scaling of size R0 (diameter) with respect to the number of monomers N, R0 ∼ aN1/2, expands in the lateral direction as R|| ∼ aNν(a/D)2ν-1. Provided that the Θ condition is strictly maintained throughout the compression, the well-known scaling exponent of Θ-chain in two dimensions, ν = 4/7, is anticipated in a perfect confinement. However, numerics shows that upon increasing compression from R0/D < 1 to R0/D ≫ 1, ν gradually deviates from ν = 1/2 and plateaus at ν = 3/4, the exponent associated with the self-avoiding walk in two dimensions. Using both theoretical considerations and numerics, we argue that it is highly nontrivial to maintain the Θ condition under confinement because of two major effects. First, as the dimension is reduced from three to two dimensions, the contributions of higher order virial terms, which can be ignored in three dimensions at large N, become significant, making the perturbative expansion used in Flory-type approach inherently problematic. Second and more importantly, the geometrical confinement, which is regarded as an applied external field, alters the second virial coefficient (B2) changes from B2 = 0 (Θ condition) in free space to B2 > 0 (good-solvent condition) in confinement. Our study provides practical insight into how confinement affects the conformation of a single polymer chain.

Sum rules for zeros and intersections of Bessel functions from quantum mechanical perturbation theory

Bessel functions play an important role for quantum states in spherical and cylindrical geometries. In cases of perfect confinement, the energy of Schrödinger and massless Dirac fermions is determined by the zeros and intersections of Bessel functions, respectively. In an external electric field, standard perturbation theory therefore expresses the polarizability as a sum over these zeros or intersections. Both non-relativistic and relativistic polarizabilities can be calculated analytically, however. Hence, by equating analytical expressions to perturbation expansions, several sum rules for the zeros and intersections of Bessel functions emerge.

High-quality graphene sheets decorated with ZIF-8 nanocrystals

Excellent-quality graphene sheets produced via the direct liquid phase exfoliation of highly crystalline graphite (avoiding any oxidative treatment), were employed for the first time as 2D scaffolds for the in-situ synthesis of zeolitic-imidazolate-framework (ZIF-8) material. Our synthetic approach involved the efficient, urea-assisted exfoliation of natural graphite (without using any acids), and the subsequent selective, mild functionalization of the resulting high-quality graphene sheets with benzoic acid functional groups. The graphene derivatives were next decorated via the in-situ development of ultrasmall (approx. 30 nm) ZIF-8 nanocrystals. We discuss the critical role of the functionalized graphene to the selective nucleation and crystal growth of ZIF-8 nanocrystals exclusively at their surface. In-depth gas sorption studies of different gases revealed that the novel ZIF-8@Graph nano-composites exhibited improved porosity (in terms of surface area and pore volume) compared to analogous Graphene Oxide/ZIF-8 hybrids. In addition, the gate effect of the ZIF-8 nanocrystals anchored onto the high-quality graphene, was found very different compared to bulk ZIF-8, a behavior that is attributed mainly to the significantly smaller crystal size and the perfect 2D confinement of ZIF-8 along graphene. Finally, preliminary CO2 adsorption properties of the synthesized novel nano-composites are reported, at near ambient temperature.

Energy spectrum of confined positively charged excitons in single quantum dots

A theoretical model, which relates the binding energy of a positively charged exciton in a quantum dot with the confinement energy is presented. It is shown that the binding energy, defined as the energy difference between the corresponding charged and neutral complexes confined on the same excitonic shell strongly depends on the shell index. Moreover, it is shown that the ratio of the binding energy for positively charged excitons from the $p$- and $s$-shells of a dot depends mainly on the nearly perfect confinement in the dot, which is due to the "hidden symmetry" of the multi-electron-hole system. We applied the theory to the excitons confined to a single GaAlAs/AlAs quantum dots. The relevant binding energy was determined using the micro-photoluminescence and micro-photoluminescence excitation magneto-spectroscopy. We show that within our theory, the confinement energy determined using the ratio of the binding energy corresponds well to the actual confinement energy of the investigated dot.

Steady detonation propagation in a circular arc: a Detonation Shock Dynamics model

We study the physics of steady detonation wave propagation in a two-dimensional circular arc via a Detonation Shock Dynamics (DSD) surface evolution model. The dependence of the surface angular speed and surface spatial structure on the inner arc radius ($R_{i}$), the arc thickness ($R_{e}-R_{i}$, where $R_{e}$ is the outer arc radius) and the degree of confinement on the inner and outer arc is examined. We first analyse the results for a linear $D_{n}$–$\unicode[STIX]{x1D705}$ model, in which the normal surface velocity $D_{n}=D_{CJ}(1-B\unicode[STIX]{x1D705})$, where $D_{CJ}$ is the planar Chapman–Jouguet velocity, $\unicode[STIX]{x1D705}$ is the total surface curvature and $B$ is a length scale representative of a reaction zone thickness. An asymptotic analysis assuming the ratio $B/R_{i}\ll 1$ is conducted for this model and reveals a complex surface structure as a function of the radial variation from the inner to the outer arc. For sufficiently thin arcs, where $(R_{e}-R_{i})/R_{i}=O(B/R_{i})$, the angular speed of the surface depends on the inner arc radius, the arc thickness and the inner and outer arc confinement. For thicker arcs, where $(R_{e}-R_{i})/R_{i}=O(1)$, the angular speed does not depend on the outer arc radius or the outer arc confinement to the order calculated. It is found that the leading-order angular speed depends only on $D_{CJ}$ and $R_{i}$, and corresponds to a Huygens limit (zero curvature) propagation model where $D_{n}=D_{CJ}$, assuming a constant angular speed and perfect confinement on the inner arc surface. Having the normal surface speed depend on curvature requires the insertion of a boundary layer structure near the inner arc surface. This is driven by an increase in the magnitude of the surface wave curvature as the inner arc surface is approached that is needed to meet the confinement condition on the inner arc surface. For weak inner arc confinement, the surface wave spatial variation with the radial coordinate is described by a triple-deck structure. The first-order correction to the angular speed brings in a dependence on the surface curvature through the parameter $B$, while the influence of the inner arc confinement on the angular velocity only appears in the second-order correction. For stronger inner arc confinement, the surface wave structure is described by a two-layer solution, where the effect of the confinement on the angular speed is promoted to the first-order correction. We also compare the steady-state arc solution for a PBX 9502 DSD model to an experimental two-dimensional arc geometry validation test.

Polarized Raman spectroscopy with differing angles of laser incidence on single-layer graphene

Chemical vapor deposition (CVD)-grown single-layer graphene samples, transferred onto a transmission electron microscope (TEM) grid and onto a quartz plate, were studied using polarized Raman spectroscopy with differing angles of laser incidence (θ). Two different polarization configurations are used. In an in-plane configuration, the polarization direction of both incident and scattered light is parallel to the graphene plane. In an out-of-plane configuration, the angle between the polarization vector and the graphene plane is the same as the angle of laser incidence (θ). The normalized Raman intensity of the G-band measured in the out-of-plane configuration, with respect to that in the in-plane configuration, was analyzed as a function of θ. The normalized Raman intensity showed approximately cos2θ-dependence up to θ = 70°, which can be explained by the fact that only the electric field component of the incident and the scattered photon in the out-of-plane configuration projected onto the graphene plane can contribute to the Raman scattering process because of the perfect confinement of the electrons to the graphene plane.

Highly customisable scanning droplet cell microscopes using 3D-printing

3D printing was applied for the first time to produce highly customised flow type scanning droplet cell microscope heads which combine electrochemical measurements with downstream analytics of the electrolyte. The main advantages are the optimised fluid dynamics, the homogeneous and laminar mass transport along with the simplicity of the production at low costs. An improved design is presented that is hard to be machined in a classical way. This flow-type scanning droplet cell microscope (FT-SDCM) combines features from older versions of the techniques, the classical theta capillary based version and V-shaped microscopes. Different versions are compared and fluid dynamic simulations were performed to reveal their particularities in terms of electrolyte flow and surface wetting. Fabricating of the complex design of the flow cell was realised using a rapid prototyping approach. The newly proposed prototype is tested under various experimental conditions for assessing its stability, wetting and sealing performances. Both chemical and electrochemical dissolution experiments have shown a perfect electrolyte confinement within the cell and a complete wetting of the addressed area together with high throughput experimentation capabilities due to the robust design and ease of use in combination with a gantry robot.

Plasmonics: Hollow Plasmonic U‐Cavities with High‐Aspect‐Ratio Nanofins Sustaining Strong Optical Vortices for Light Trapping and Sensing 6/2014)

Perfect light confinement in hollow, high-aspect-ratio, plasmonic U-shaped cavities is demonstrated by J.-J. Delaunay and co-workers on page 522 through the coupling of the cavity ridge hot spots with scalable mirrored surface plasmon U-cavity resonances. Light is fully trapped in intense optical vortices and confined on the extended cavity surfaces, thus accumulating energy in tunable, strong, and sharp resonances that generate sensitive reflectance dips.

Optical bistability in a single-bus InGaAs micro-ring resonator array

In this paper, we investigate the optical bistability induced by optical nonlinearity in a compact parallel array of micro-ring resonators with radius of 5μm. Due to the nature of perfect light confinement in this structure, resonance and accumulation process in a ring resonator and optical nonlinear effects, are observable even at small optical power (a few milliwatts). Different optical applications such as all-optical switching, optical memory devices, logic gates and modulators are possible, due to optical bistability in a ring resonator. Using alternative semiconductor compounds, instead of silicon that have weak nonlinear optical properties, we improve the performance of ring-resonator based devices. Here we use a polymer cladding layer with negative thermo-optic coefficient. Using this structure we can eliminate the temperature created nonlinearity which is a very slow process. Therefore, the switching speed increases from a few MHz to several tens of GHz. By plotting the transfer function of the resonator, a hysteresis loop is observed in a few milliwatts. Although, using a ring resonator array the bandwidth reduces, however, the width of the hysteresis loop and resolution between both steady state increases.

Creating electromagnetic cavities using transformation optics

We investigate the potential of transformation optics for the design of novel electromagnetic cavities. First, we determine the dispersion relation of bound modes in a device performing an arbitrary radial coordinate transformation and we discuss a number of such cavity structures. Subsequently, we generalize our study to media that implement azimuthal transformations, and show that such transformations can manipulate the azimuthal mode number. Finally, we discuss how the combination of radial and azimuthal coordinate transformations allows for perfect confinement of subwavelength modes inside a cavity consisting of right-handed materials only.

Extreme Conditions for Plasma-Facing Components in Tokamak Fusion Devices

Safe and reliable operation is still one of the major challenges in the development of fusion energy. In magnetic fusion devices, perfect plasma confinement is difficult to achieve. During transient loss of plasma confinement, high plasma power and particle beams (power densities up to hundreds of gigawatts per square meter in time duration on the order of milliseconds) strike the reactor walls, particularly the divertor plate, and can significantly damage the exposed surfaces and also indirectly damage nearby components. To predict the resulting damage of the direct plasma impact on the divertor plate, comprehensive multiphysics multiphase models are developed, integrated, and implemented in the High Energy Interaction with General Heterogeneous Target Systems computer simulation package. The evolution of the divertor material, resulting vaporization, heating and ionization of vapor plasma to higher temperatures, and, consequently, the resulting photon radiation, transport, and deposition around the divertor area are calculated for typical instability parameters of the edge-localized modes and disruption for an ITER-like geometry.

Efficient Terahertz Emission from InGaN/GaN Heterostructure

Pulsed terahertz (THz) radiation from semiconductors excited by femtosecond laser has been studied extensively in the recent years. The two main methods [1] are used to generate the broadband THz radiation. The methods are based on THz emission from the biased photoconductive switches and on THz emission from the surface of freestanding semiconductors. Multiple mechanisms are responsible for the THz emission from the freestanding semiconductor surface including nonlinear optical rectification, photocurrent induced by the surface-field, photocurrent induced by the built-in field in p–i–n structures, and by photocurrent induced photo-Dember effect. However, the intensity of THz emission from the surface of freestanding semiconductors still is very low. The analysis [2] of the transient dynamics of photoexcited carriers shows that the surface and contactless p–i–n THz emitters have serious deficiencies that significantly reduce the intensity of THz radiation. First, only a minor part of the excited carriers contributes to the transient current if the inverse absorption coefficient exceeds the surface depletion width or the i-layer thickness of the p–i–n structure. In this case, the major part of carriers is created in the region where the built-in electric field is screened by the extrinsic carriers. Second, the plasma frequency of photocarriers is position-dependent due to the exponential decay of the created carrier density. As a result, the transient response of the created carriers is incoherent in different regions of the structure because the frequency of current oscillations is position-dependent. Therefore, the amplitude of oscillations of the resulting current is significantly reduced by the interference effects. To overcome such deficiencies of THz emitters, the novel δ-doped GaAs/AlGaAs heterostructure is suggested in [2]. It is shown in [2] that THz energy radiated from the freestanding semiconductors is significantly enhanced when the above noted deficiencies are eliminated. It is obtained from Monte Carlo simulations that the efficiency of THz emission from the δ-doped GaAs/AlGaAs heterostructure exceeds the efficiency of THz emission from the homogeneous GaAs by two orders of magnitude. In the present work, the basic ideas suggested in [2] are used to design THz emitters based on InGaN/GaN heterostructures. The pulsed THz emission from the InGaN/GaN heterostructures is studied using Monte Carlo simulations [2, 3] of the transient dynamics of photoexcited electron–hole plasma. The InGaN/GaN heterostructures appear to be very suitable for the development of highly efficient THz emitters. High electron mobility in the optically active InGaN layers provides a large amplitude of the transient current. The offsets of the conduction and valence bands at the InGaN/GaN heterointerfaces are sufficiently high to ensure the perfect confinement of the excited carriers inside the InGaN layers. In addition to the basic ideas of [2], the polarization charges at the InGaN/GaN interfaces are employed in the design of the appropriate potential profile in the InGaN/ GaN heterostructures for the efficient THz emission.

Polarization-maintaining photonic bandgap Bragg fiber

The possibility of fabricating a polarization-maintaining Bragg fiber has been studied. It is shown that violation of the cylindrical symmetry of a Bragg mirror in most cases results in a sharp increase in optical loss, which is caused by resonance transmission through the Bragg mirror at wavelengths near the cutoffs of the modes of the high-index rings with a nonzero azimuthal index. It is shown that placing stress-applied parts or air holes inside the Bragg fiber core allows one to avoid this effect. A polarization-maintaining Bragg fiber with perfect light confinement in the core is demonstrated for the first time to our knowledge.