Percentage Removal Efficiency Research Articles

Synthesis and characterization of mesoporous caged silica for efficient adsorption of methylene blue from aqueous solution

Addressing the challenge of removing dyes from textile industry wastewater is crucial for wastewater treatment. Adsorption, utilizing suitable materials, emerges as a promising solution. This work introduces caged silica as an effective adsorption material for wastewater treatment in the textile industry. The proposed caged silica was synthesized via the hard template synthesis method, commonly used in various applications such as catalysts and wastewater treatment. Caged silica exhibited an amorphous structure with notable BET surface area (448m2/g), pore volume (0.325cm3/g), and average pore size (2.4nm), confirmed through detailed characterization. Evaluation of its adsorption capacity for methylene blue (MB) revealed an impressive removal efficiency of approximately 95% within the initial 20 min. The adsorption process followed the pseudo-second-order model and adhered more closely to the Freundlich isotherm model than the Langmuir model. Additionally, the study investigates the effects of pH, percent removal efficiency, cyclic stability, and initial MB concentration on the adsorption procedure. Consequently, the synthesized caged silica stands out as a promising mesoporous material for efficiently removing MB from aqueous solutions, offering practical application potential in wastewater treatment.

HSPiP and QbD oriented optimized green nanoemulsion to treat chloramphenicol contaminated water

Nanoemulsion is an isotropic and kinetically stable system used for multiple purposes. Exhaustive flow of chloramphenicol (CAMP) in the water systems raised global thereat to aquatic and human lives. Innate cohesive energy of the material is the basis of predictive HSPiP program. We aimed to prepare biocompatible nanoemulsion employing eugenol oil, lecithin, tween 80, and propylene glycol) for the contaminated water treatment. Furthermore, experimental design oriented robust nanoemulsion (OCEN1) investigated the impact of composition, CTime (exposure time), and nanoemulsion characteristics on percent removal efficiency (%RE). Thermodynamic stability study was conducted at different temperatures. Finally, the presence of CAMP in the treated water was negated by ICP-OES (inductively coupled plasma-optical emission spectroscopy). HSP (Hansen solubility parameters) and experimental solubility data were the basis of excipient selection. A blend of tween-80 and lecithin served as surfactant mixture (Smix) to stabilize nanoemulsion. OCEN1 was associated with high desirability (D = 0.93), low size (43 nm), low PDI (0.19), high %RE (90.72 % over period of 17 min of exposure time), optimal viscosity (1.12 cP), and high zeta potential (−25 mV). Experimental design identified significant impact of composition, exposure time (CTime), and nanoemulsion characteristics on %RE as prime factors to consider before wastewater treatment plant installation. Thus, the approach is simple, rapid, ecofriendly, and scalable to treat CAMP contaminated water with high selectivity and efficiency.

Invasive lignocellulose-based plants bio-sorbents for the elimination of nitrites of emerging concern from water

The regulation of nitrite levels in potable water is primarily motivated by the potential for excessive amounts to induce methemoglobinemia, which is also referred to as blue baby syndrome. Human and industrial activities generate and release nitrite-containing wastewater into water bodies, thereby endangering ecosystem health and contaminating water sources. Biosorption is an alternative and environmentally beneficial method of wastewater treatment. These methods have several advantages over conventional methods, including their cost-effectiveness, accessibility, and reusability. This study investigates the viability of utilizing guava leaf, neem leaf, orange peel, banana peel, and custard apple leaf as bio-sorbents for the removal of nitrite from contaminated water. One hundred percent removal efficiency is the result of this endeavor. Following an examination of all six bio-sorbents, it was observed that the guava leaf bio-sorbents exhibited the most effective performance in the removal of nitrite from water. Additionally, the impacts of various parameters including contact duration, agitation speed, adsorbent dosage, pH, and temperature are also investigated. Additionally, prior to utilization, the biomass may undergo physical and chemical modifications. To enhance the analysis of each bio-sorbent, a range of characterization techniques are utilized, including XRD, SEM-EDX, FTIR, and BET analysis. Economic feasibility can be achieved by regenerating and reprocessing the bio-sorbent subsequent to the nitrites removal process.

The worthy green heterogeneous Fenton degradation process for removal of E102 in foodstuffs and industrial waste-waters using Cypress arizonica leaves based magnetic nanocomposite (CA-Fe3O4-MNc)

A new, green magnetic nanocomposite (MNc) was synthesized based on framework of Cypress arizonica (CA) leaves and then used as Fenton catalyst for removal of tartrazine (E102) in foodstuffs and industrial waste-waters. Characterization of the synthesized magnetic nanocomposite (CA-Fe3O4-MNc) was performed with IR, EDX, FESEM, XRD and pHpzc analyses. The average particle size and pHpzc of the CA-Fe3O4-MNc were determined to be 24.36 nm and 6.8, respectively. CA-Fe3O4-MNc was composed of C (15.08 %), Fe (51.86 %), O (31.80 %) and Ca (1.26 %) elements. The parameters effecting heterogeneous Fenton dye removal process including pH, catalyst amount, reaction time, H2O2 and initial dye concentrations were investigated to achieve the best removal efficiency for E102. Under optimal conditions, the matrix effect was investigated, the reusability of CA-Fe3O4-MNc was tested, degradation products and mechanism were elucidated, and green analytical procedure index (GAPI) and analytical eco-scale (AES) of the proposed Fenton degradation process were evaluated. E102 removal values were obtained between 93 and 99 % in the applications of some foodstuffs, water samples and artificial model dye solutions. Proposed heterogeneous Fenton removal process with using CA-Fe3O4-MNc catalyst exhibited quantitative removal efficiency for E102. E102 concentrations between 5 and 50 mg/L were removed successfully. It was observed that the synthesized CA-Fe3O4-MNc material could be used at least 5 times to obtain quantitative removal values. The percent removal efficiency value decreased to 93 after five uses. Defined GAPI parameters and calculated AES scores indicated that the proposed CA-Fe3O4-MNc based heterogeneous Fenton degradation process could be considered that a valuable green removal method.

Investigating the improvement of the quality of industrial effluents for reuse with added processes: coagulation, flocculation, multi-layer filter and UV

Reuse of wastewater is one of the ways to develop water resources. In addition to the need for drinking water, many industries also need high-quality water in the production line. Therefore, the purpose of the present study is to investigate the advanced treatment of the wastewater treatment plant of Morche Khort industrial town using the processes of coagulation, flocculation with aeration, multi-layer filter, and disinfection by ultraviolet radiation to increase the quality of wastewater and reuse it in industries. In this study, to investigate the effect of coagulation and flocculation units along with aeration, filtration, and disinfection by ultraviolet rays (UV), on the quality of the secondary effluent from the wastewater treatment plant of Morche Khort industrial town, they were operated on a pilot scale. Polyaluminum chloride (PAC) was used as a coagulant. Layering of three layers of sand filter, from bottom to top including granulated silica at a height of 10 cm, sand at a height of 20 cm, and activated carbon at a height of 70 cm was used. The input and output sampling points of each unit were considered. By repeating twice in five stages of flow rates of 1, 2, 4, 6, and 8 (L/min), the samples were collected to determine COD, TSS, TDS, turbidity, pH, hardness, total coliform, and fecal coliform. Jar test results showed that Alum coagulant works almost the same as PAC in removing turbidity, but the efficiency of removing organic substances by PAC coagulant is higher than that of Alum at lower doses. The results of this study showed that the efficiency of the coagulation and flocculation process in removing turbidity, COD, TSS, TDS, and fat was 56.88%, 46.66%, 38%, 23.19%, and 91.43% respectively. In the current study, the results of the wastewater entering the sand filter showed that the percentage of removal efficiency with a loading rate of 1 (L/min) was turbidity, TSS, COD, TDS, and fat was 16. 93%, 56.84%, 50%, 5.67%, 33.44% respectively. In the UV disinfection unit, the removal efficiency percentage with a loading rate of 1 (L/min) for COD, TSS, turbidity, hardness, total coliform, and fecal coliform is 16%, 3.45%, 3.58%, 5.21%, 99.88%, and 98.37% respectively. Coagulation and flocculation system—multi-layer filter and disinfection can remove chemical–physical and microbial parameters to an acceptable level for using water in advanced purification systems and also for irrigation.

Application of Agro-industrial Solid Waste as Biochar for Iron (II) Removal from Aqueous Solution

In recent years, various industrial activities have introduced a high concentration of iron in the waterbody which causes serious problem to environment. This paper proposed the application of Exhausted Coffee Husk (ECH) as the biosorbent (BS) for removing iron (Fe) (II) in the aqueous solution. The ECH was carbonized into biochar before performing biosorption of the heavy metal ion. The effect of carbonization temperature, time and rate on the performance of the ECH biochar for removing Fe (II) were evaluated. The percentage of removal efficiency (RE) and the capacity of biosorption (mg/g) were considered as the determining parameters. The pyrolysis temperature was varied in a range of 200-600 °C with 50 °C of interval, while the time was in between 1h – 3h with a n interval of 0.5 h, and the temperature gradient of 5 – 25°C/min. The results showed that the temperature had a significant effect on the properties of the ECH biochar as BS for Fe (II). The temperature of 550 °C, at 1.5 h of time and 25 °C/min was chosen as the suggested carbonization temperature of biochar from ECH for biosorption of Fe (II). Keywords: Agro-industrial solid waste, Biosorption, Carbonization, Exhausted coffee husk (ECH), Heavy metal.

Facile green synthesis route for new ecofriendly photo catalyst for degradation acid red 8 dye and nitrogen recovery

This study novelty is that new photo catalyst prepared from sustainability low cost precursors. Dark red color hydrogel composites have been easily prepared from gelatin biopolymer using a simple sol–gel method. Gelatin doped by cobalt chloride, and silver nanoparticles (SNPs) in the presence of traces amount of sodium dodecyl sulfate surfactant and calcium chloride. Water-insoluble Gelatin composites are thermally stable photocatalysts for the degradation of toxic anionic acid red 8 dye. Promising photodynamic activity confirmed by fluorescence emission at λmax 650 nm. Optical absorption in Vis. light enhanced photo catalytic activity. Silver nanoparticles enhanced crystallinity, and improved optical properties and porosity. Dopants by CoCl2 and silver nanoparticles increased band gap of gelatin composites from (1.82 to 1.95) indicating interfacial charge separation. Low band gaps improved photo catalytic activity. Optical band gaps (Eg) lower than 2.0 eV indicates high catalytic activity in the photo degradation acid red 8 dye using Vis. light, wavelength 650 nm. Percent removal efficiency (%Re) of the dye at 500 ppm initial concentration, pH 1, contact time 30 min., and 0.20 g L−1 dose photo catalyst reached 95%. pH not affects removal efficiency. So, gelatin composites removed AR8 dye by photodegradation mechanism rather than adsorption due to photodynamic activity. Kinetics of photodegradation followed pseudo first order kinetic with rate constant k1 5.13 × 10−2 min.−1 Good electrical conductivity and magnetic properties (effective magnetic moment (µeff 4.11 B.M) improved dye degradation into simple inorganic species. Nutrients NH4+, and NO3− degradation products recovered by using alumina silicate clay via a cation exchange mechanism.

Application of aqueous extracts of <i>Alternanthera brasiliana, Chromolaena odorata</i> and <i>Tridax procumbens</i> plants in remediating lead contaminated soils

Soil washing is an effective method of removing lead from contaminated soils. However, great limitations abound in the choice of washing solution that is ecologically sustainable for agricultural soils. In this study, applications of plant soluble extracts in remediating of Pb contaminated soils for ecological sustainability were carried out. Batch laboratory experiments were done using aqueous extracts of Alternanthera brasiliana, Chromolaena odorata, Tridax procumbens and water as control at varying soil-pulp-densities (SPD) of 3, 6, 9, 12, 15%, and washing time of 1, 3, 6, 12 h. For contaminated soil, percentage removal efficiency followed the order: Alternanthera brasiliana (38.1±0.28%) > Chromolaena odorata (21.8±0.12%) > Tridax procumbens (21.3±0.18%). The most appropriate ratio for contaminated soil was 3% SPD at 12 h washing time. Removal efficiency was found to be substantially depended on geochemical phase of Pb (exchangeable-4.04%) in contaminated soil and washing solution pH (5.68). Lead removal efficiency was observed to increased proportionally with increasing washing time, but decreased with increasing SPD. Spike soil with high exchangeable Pb-78.9% recorded significant Pb removal of 63.4±0.24% with Alternanthera brasiliana, 47.8±0.22% with Chromolaena odorata, 38.3±0.38% with Tridax procumbens and 52.0±0.26% with water. Analysis of variance at p=0.05 indicated a significant difference inpercentage Pb removal efficiency across all the four washing solutions. However, the statistical T-test indicated no significant difference at p=0.05 in percentage Pb removal efficiency between both soils. Also, moderately positive correlations were observed between contaminated and spiked soils for Alternanthera brasiliana (0.676), Chromolaena odorata (0.570) and Tridax procumbens (0.517) while negative correlation observed for water (0.485) which served as the control. The three plant extracts exhibited good potential characteristics as washing solutions for the treatment of Pb contaminated soils. Chemical modifications are recommended to enhance and improve their efficiencies when considering the geochemical phase of Pb in soil.

Investigating the Optimization of Magnetic Biochar Production from Rubber Seed Shells for Enhanced Cr(VI) Removal Efficiency

This study aimed to utilize agricultural and produce low-cost magnetic biochar from rubber-seed shells using ferric chloride (FeCl3) as a transition metal. The study employs Response Surface Methodology (RSM) based on the Box-Behnken Design (BBD) to determine optimal production conditions for removing chromium (Cr(VI)). The effect of preparation conditions such as pyrolysis temperature (500-700 °C), duration (90-180 min), and impregnation (1-3 M) on the produced magnetic biochar was examined. The optimal condition was demonstrated based on yield percentage and Cr(VI) removal efficiencies. The study revealed that the optimal conditions for producing magnetic biochar from rubber seed shells were a pyrolysis temperature of 580 °C, a pyrolysis time of 130 min, and a FeCl3 concentration of 3 M. Under these conditions, a yield of 48.63% was achieved, and the removal efficiencies for Cr(VI) were 41.29%. This research suggests that utilizing agricultural waste products from rubber seed shells may be a viable and economical method for producing magnetic biochar, which can serve as an efficient adsorption agent.

In silico approaches for the prediction of the breakthrough of organic contaminants in wastewater treatment plants.

The removal efficiency (RE) of organic contaminants in wastewater treatment plants (WWTPs) is a major determinant of the environmental impact of chemicals which are discharged to wastewater. In a recent study, non-target screening analysis was applied to quantify the percentage removal efficiency (RE%) of more than 300 polar contaminants, by analyzing influent and effluent samples from a Swedish WWTP with direct injection UHPLC-Orbitrap-MS/MS. Based on subsets extracted from these data, we developed quantitative structure-property relationships (QSPRs) for the prediction of WWTP breakthrough (BT) to the effluent water. QSPRs were developed by means of multiple linear regression (MLR) and were selected after checking for overfitting and chance relationships by means of bootstrap and randomization procedures. A first model provided good fitting performance, showing that the proposed approach for the development of QSPRs for the prediction of BT is reasonable. By further populating the dataset with similar chemicals using a Tanimoto index approach based on substructure count fingerprints, a second QSPR indicated that the prediction of BT is also applicable to new chemicals sufficiently similar to the training set. Finally, a class-specific QSPR for PEGs and PPGs showed BT prediction trends consistent with known degradation pathways.

Study and Verify the Performance Evaluation and Percentage Removal Efficiency of the Plant

Domestic, commercial, and industrial wastewater all belong to the category of urban wastewater. There are various treatment technologies available to treat the waste water from simple oxidation ponds to advanced MBBR systems. The present study is to verify the performance evaluation and percentage removal efficiency of the plant. The various water quality parameters like COD, BOD, TSS, TDS, Oil & Grease , Nitrates, pH, EC, DO, Turbidity and Phosphates of the waste water were being analyzed for the which were collected. Water samples were collected at different stages of treatment plant such as (raw water inlet, Aeration tank, Clarisettler and Treated water outlet) in the weekly basis for a period of 6 weeks before disposal into water body streams. After treatment, the average percentage removal efficiency for the parameters COD, BOD, TSS, TDS, Oil & Grease, and Phosphates was found to be 89%, 88%, 85%, 68%, 69% and 75%. After the analysis the result were finalized by comparing data with CPCB and IS standard values and ultimately, the performance and removal efficiency of the waste water treatment facility was found to be under good condition and the treated water are being used for flush-outs and gardening.

USE OF COCONUT HUSKS TO FACILITATE THE REMOVAL OF H2S FROM BIOGAS

The study investigates the potential of coconut husks in purifying biogas, a common issue in the use of biogas due to the high costs and environmental impact of expensive purification technologies. The study used an experimental setup generating biogas from kitchen waste and analysed its composition using an industry-standard biogas analyser. Coconut husks could remove hydrogen sulphide (H2S), with a high percentage removal efficiency of 54% at a column length of 0.5 m from the inlet. Based on the results, 2 kg of coconut husk could purify 837 L of biogas, with a removal efficiency of approximately 62%, before exhaustion. This suggests that coconut husks can be used in biogas purification to remove H2S, which is the most challenging component as it can corrode metal parts when used at high concentrations above 750 ppm. Further research is needed on large-scale purification using coconut husks at high pressure to allow more gas adsorption by the purification media.

Identification, removal of microplastics and surfactants from laundry wastewater using electrocoagulation method

Microplastics (MPs) and surfactants are generally recognized as emerging contaminants with complicated ecotoxicological impacts. The majority of study data refers to laundry wastewater as a substantial source of MPs and surfactants in the aquatic system, which reaches aquatic environments through sewer discharges even when wastewater treatment facilities retain them. This study focused on releasing and removing contaminants from laundry wastewater, particularly MPs and surfactants. The electrocoagulation method was used to remove the pollutants from laundry wastewater. According to the results, a reference load of 2 kg of synthetic materials releases 92,700 to 1,14,300 synthetic microfibers (MFs). MFs, surfactants, and chemical oxygen demand (COD) removal efficiency are higher at neutral pH. The percentage removal efficiency of MFs, surfactants, and COD was 97.9%, 91.2%, and 86.3%, respectively, at an operating time of 25 min, a current density of 300 A/m2 with optimum power consumption. The total operation cost of laundry wastewater treatment by electrocoagulation was US$0.53 /m3. The readers will gain a complete understanding of the removal of MFs and surfactants from laundry wastewater using the electrocoagulation technique.

Phytoremediation Process of Textile Industry Effluent by Eichhornia Crassipes and Pistia Stratiotes

In the world, a large part of the wastewater is not previously treated, resulting in the contamination of water resources. Textile wastewater contains large volume of pollution load. In the present study, the removal of pH, COD, TS, TDS, TSS, Sulphate and Chloride has been studied by using Eichhornia crassipes and Pistia stratiotes. A lab scale study was conducted to test the feasibility of Eichhornia crassipes and Pistia stratiotes for treating textile wastewater. pH was reduced from alkaline to nearly neutral in all dilution. The maximum percentage reduction was observed after treatment with Eichhornia crassipes and it was 25.62% for pH, 69% for COD, 25.71% for TS, 34.61% for TDS, 68% and 45% for Sulphate and Chloride respectively. Aftrer treatment with Pistia stratiotes percentage removal efficiency was pH 23%, COD 45%, TS 20%, TDS 17.53%, Sulphate 64% and Chloride 39.51%. Hence, the efficiency for removal of pollutants of textile wastewater by Eichhornia Crassipes is more than Pistia stratiotes.

Optimization of effecting parameters for flue gas desulfurization in a self‐priming venturi scrubber using response surface methodology

AbstractHydrogen sulfide (H2S), a highly poisonous and corrosive gas, is regarded as a hazardous air pollutant with significant effects on human health. Hence, reduction of hydrogen sulfide (H2S) gas from the atmosphere is very essential. In the present work, self‐priming venturi scrubber is employed to extract H2S gas from the air. Response surface methodology (RSM) with a central composite design (CCD) has been selected to investigate maximizing the H2S removal efficiency by optimizing the process variables. Experiments were carried out by altering the throat gas velocity, outer cylinder liquid level and inlet concentration of H2S. The analysis of variance (ANOVA) test showed that the parameters had a significant effect on the efficiency of H2S removal. A quadratic equation has been developed that accurately predicts the percentage of removal efficiency. The appropriateness of the generated model has been verified by the value of higher R2 resulting from the regression analysis. According to the observations, the velocity of throat gas has the highest effect on the H2S removal efficiency, whereas inlet H2S concentration has the least effect.

Montmorillonite modified Ni/Mg/Al ternary layered double hydroxide nanoflowers with enhanced adsorption features

A hydrothermal technique was employed to synthesize Ni/Mg/Al ternary L.D.H.s modified with montmorillonite (NMA-MMT-LDHs). Many characterization methods, including X-ray diffraction (XRD), scanning electron microscopy (S.E.M.), Fourier transform infrared (FTIR), and Brunauer, Emmett, and Teller (B.E.T.), were used to assess the physiochemical properties of the produced analytes. Congo red and methylene blue were utilized as model dyes to treat textile waste with the synthesized analytes. The batch adsorption model was utilized to conduct the adsorption experiments under varying contact time, adsorbent dosage, and solution pH conditions. A pseudo-second-order kinetics and the Langmuir adsorption model control the adsorption process. The maximum monolayer adsorption capacities of C.R. and M.B. were determined to be 344 and 200 mg/g, respectively. As the quantity of dosage increased from the 0.01–0.04 g, the percent removal efficiency (%) increased from 75 to 87 % for S2-LDH, 84–88 % for S2-MMT, 86–93 % for S3-MMT, and 95–97% for S4-MMT for C.R. dye and 82–85 % for S2-LDH, 83–89 % for S2-MMT, 83–91 % for S3-MMT, and 84–92 % for S4-MMT for M.B. dye. The removal percentage of C.R. dye for adsorbents S2-LDH, S2-MMT, S3-MMT, and S4-MMT were 75 %, 84 %, 86 %, and 95 %, respectively and 82 %, 83 %, 83 %, and 85 %, respectively for the M.B. dye removal. The presence of MMT significantly increases the affinity of Ni/Mg/Al-LDHs (NMA-LDHs), and the designed production technique can be used to produce a variety of compositionally distinct adsorbent materials.

The utilization of cost-effective natural sorbents for the eradication of heavy metal contaminants from the real world-based adsorbate system

In India, Industrial growth has resulted towards the release of numerous contaminated heavy metals into the environment, Various industries directly discharged the effluents containing harmful pollutants such as toxic heavy metals into the aqueous medium. There are numbers of treatment methods available to remove toxic elements from effluents before disposal. Several research investigations have been conducted to determine the capacity of unconventional absorbents to remove various wastewater impurities. Bio-sorption technique uses agricultural and natural left-over materials as adsorbents since they remain considerably less expensive, supportable, and available than traditional effluent treatment technologies. This study concentrates removal efficiency of orange peels (OP), rice husk (RH) and sugarcane bagasse (SCB) from the industrial effluents. Adsorption studies have been conducted for OP, RH and SCB with differing dose, pH, and contact duration, determined to be appropriate and leading to the highest levels of removal effectiveness. At 1.00 gm dosage, the maximum % removal efficiency of Cu, Cr, Ni, Cd and Zn removal for OP, RH and SCB were 84.90%, 90.45%, 86.21%, 98.00% and 74.11% respectively by using OP, RH and SCB the max. percentage removal efficiency of Cu, Cr, Ni, Cd and Zn for OP, RH were 82.81%, 76.80%, 76.16%, 78.46%, 78.59% at a pH value of 5, 6, 5, 7 and 7 respectively. The max. percentage removal efficiency of Cu, Cr, Ni, Cd and Zn using OP, RH and SCB were 93.45%, 93.05%,77.66%, 94.62%, 85.10% at the contact time of 120, 60, 120, 60 and 80 minutes respectively.

Soil Washing to Eliminate Polycyclic Aromatic Hydrocarbons from Petroleum Contaminated Soil - Temperature Effect

This study’s goals were to identify the components of polycyclic aromatic hydrocarbons (PAHs) in soil samples polluted with petroleum and to ascertain how temperature affected the removal of PAHs pollutants from petroleum-contaminated soil. The concentration of contaminants in the soil samples decreased from 46.22-12.07 ppm to 77.01-30.06 ppm at a temperature increase of 20–160°C, as shown by the results of this study, which are also supported by the percentage removal efficiencies of 22.22–79.69% and 32.90–73.81% for samples M and S, respectively. It was further discovered that 160℃ was the ideal temperature range for soil washing to eliminate the pollutants. High removal efficiency values demonstrated the efficacy of the soil washing approach in removing pollutants with high PAH concentrations. This information can help in the creation of more successful and affordable soil remediation techniques.

Enhanced Adsorption of Azoxystrobin from Water by As-Prepared Silica Nanoparticles

Nanoparticles are of great interest for water treatment as they remove a significant portion of water contaminants. In analogy to these emerging practices, the present work investigated the feasibility of using silica nanoparticles (SiO2-NPs) to remove azoxystrobin from an aqueous solution. We investigated the effects of experimental parameters, such as solution temperature, adsorbent dosage, contact time, and initial azoxystrobin concentration, on the removal efficiency of azoxystrobin. Structural and chemical analysis of the synthesized nanoparticles was performing using X-ray diffraction patterns (XRD), scanning electron microscopy (SEM), dynamic light scattering (DLS), and surface studies. The percentage of azoxystrobin removal efficiency was 92.8 at an initial azoxystrobin concentration of 10 mg/L. The result showed that by increasing the adsorbent dosage from 0.005 to 0.1 mg, the percentage removal efficiency of azoxystrobin from aqueous solution increased significantly from 59.72% to 95.21%. At the same time, the adsorption amount of azoxystrobin in equilibrium decreased with increasing temperature. It was found that the optimum temperature for removing azoxystrobin was 20 °C. Although the study was conducted under well-controlled laboratory conditions, the silica nanoparticle system showed excellent performance in removing a significant amount of azoxystrobin, making it a potential alternative/cooperator in water treatment for removing pesticides from aqueous solutions.

Spectroscopic, kinetics and molecular structure investigations of acriflavine hydrochloride dye onto thiobarbituric acid nanoblend TD-DFT calculations: Removal of dyes from wastewater applications

The goal of this study is to use an ultraviolet–visible spectroscopic method at maximum absorption λmax = 450 nm to explore the elimination of poisonous acriflavine hydrochloride (ACF) utilizing antibacterial thiobarbituric acid (TBA) as an adsorbent. We looked at the effects of a number of variables, including [dye], adsorbent quantity, time, and temperature on the adsorption process. At 450 nm, thiobarbituric acid had a maximum percentage removal of ACF is 62 % at 20 °C and the adsorbent dose increased from 0.01 to 0.1 g/10 ml, so, the percentage removal efficiency of acriflavine dye increases steadily but the adsorption capacity of acriflavine dye suddenly decreases. The nanoblend (ACF + TBA)NB thin film is studied using various methods, including FT-IR, kientic, isotherms of liquid-phase adsorption and SEM methods. In FT-IR spectra the changes appears in the absorption peak suggested that the ACF molecules were interacting with the functional groups of the bio-sorbent. Again, the surface of TBA morphology and textural characteristics was carried out using SEM technique. TBA absorbed a substantial amount of ACF and developed an ACF material covering their surface. The physicochemical interactions between TBA and adsorbate molecules change the microstructure of TBA somewhat. (TBA)TF and (ACF + TBA)NB thin films with a thickness of 200 ± 5 nm are manufactured by PVD technique at a low deposition rate with basic pressure of the chamber was 5 × 10−5 mbar. Time dependent Density Functional theory (TD-DFT) was also utilised tooptimizeisolated molecule nanoblend (ACF + TBA)NB/Iso employing TD-DFTD/Mol3 and Cambridge Serial Total Energy Bundle (TD-FDT/CASTEP). Using the DFT-B3LYP method with a 6-31G(d,p) basis, the optimised geometries, vibrational wavenumbers, intensity of vibrational bands, and numerous atomic charges of 9VC have been studied. The adsorption equilibrium were evaluated using Langmuir and Freundlich isotherms, and a suitable reaction mechanism was proposed and argued. From the experimental results obtained, the temperature rises from 293 to 323 oK, and the dye's capacity of adsorption and percentage of removal decrease with rising temperature. The exothermic nature of the adsorption of ACF on TBA is demonstrated by the obtained value of ΔH° as −15.3809 kJ mol−1. The assumed ΔG° value (−13.672 kJmol−1) establishes the spontaneous type of the adsorption model. Additionally, the value of ΔS° (−5.83 J mol K−1) provides information about TBA's lack of affinity for ACF.