We identify a novel leading-power contribution to the pure weak annihilation non-leptonic B-meson decay amplitudes, which arises from the hard-collinear gluon exchange between the light quark of the bottom meson and the final-state active partons. This interesting observation is naturally expected to shed new light on deciphering rapidity divergences in the convolution integrals of the soft-collinear factorization formulae. Subsequently we explore an intriguing enhancement mechanism due to the penguin contractions of the current-current operators from the weak effective Hamiltonian, which yields the significant impacts on the CP violating observables.