Distribution Of Pellets Research Articles

Optimising the feeding system for improving pellet distribution levels in gas-based shaft furnace based on the improved analytic hierarchy process

To improve the gas flow distribution inside the gas-based shaft furnace and ensure the chemical reaction, the discrete element method was used to calculate the effects of revolving chute inclination, particle size mass distribution, particle size distribution width, and hopper angle on the pellet distribution indicators (particle segregation, porosity, gas permeability and feeding time). An improved analytic hierarchy process was presented to fully analyse the nine schemes set up as part of the research. The findings demonstrated that the positive segregation of small particles at the furnace's centre and wall occurred with several feeding systems. The largest influences on porosity were differences in particle size mass distribution and particle size distribution width, and an increase in the proportion of small particles resulted in a significant decrease in porosity. The increase of the mass ratio of large particles made the highest permeability, but also caused uneven distribution of the furnace charge along the radial direction. The simulation results and the ranking of benefits and drawbacks produced by the improved analytic hierarchy process approach agree, demonstrating the applicability of the method to optimise the feeding system as well as its value in identifying the major influences on the feeding system.

Experimental Research on Breakage Characteristics of Feed Pellets under Different Loading Methods

Particle breakage is a common phenomenon during the processes of production, storage, and transportation. Because of the requirements for pellet integrity in poultry farming, research on the breakage characteristics of feed pellets is necessary. In this paper, repeated compression tests under different loading forces and repeated impact tests under different air pressures were carried out with feed pellets as the research object. The breakage behaviors were described, and the particle size distribution of feed pellets was analyzed quantitatively. The results revealed a positive correlation between crack density in feed particle beds and loading force. The compression process was divided into three stages based on force–displacement curves. The size of the feed pellets during repeated impacts decreased continuously and was negatively correlated with air pressure. The Weibull function accurately described the particle size distribution, with R2 values exceeding 0.97 and 0.96. The Weibull parameters showed a steady breakage degree in compression tests and a growing breakage degree in impact tests. The variation in energy and pulverization rate under different loading conditions was examined as the number of loading cycles increased. The relationship between energy and pulverization rates was fitted, showing that both parameters increased with loading cycles in different loading methods. The model of Vogel and Peukert could describe the relationship between energy and pulverization rate well, with R2 values exceeding 0.94. The minimum energy required for pellet breakage was higher in compression than in impact due to the compaction of the feed particle bed during repeated compression. The results can provide basic theory and data support for breakage characteristics and quality evaluation of feed pellets.

Enhancement effects of hydrolysable/soluble Al-type dopants on the efficiency of CaO/CaCO3 thermochemical energy storage

Modification of CaO-based materials using Al-type dopants has been considered a promising method to enhance energy storage performance. The synergistic multi-doping effects of different Al-type dopants (soluble, hydrolysable and insoluble) on the energy storage performances, thermophysical and mechanical properties of CaO-based materials have never been reported. The hydrolysable/soluble Al-type supports co-doped CaO-based pellets were prepared, which exhibited superior energy storage density, multi-cycle stability, reaction rate, thermal conductivity and crushing strength compared to undoped CaO pellets. The regulation mechanisms of hydrolysable/soluble Al-type dopants (AlN/Al(NO3)3) on the reaction kinetics, multi-cycle stability, thermophysical properties and mechanical properties of CaO-based pellets were revealed. The addition of different Al-type dopants results in different dispersions of the formed Ca12Al14O33, which leads to different micro-morphologies and pore structures of CaO-based pellets. Hydrolysable Al-type dopants exhibit a more concentrated distribution in CaO-based pellets and the pellets have smaller crystallite sizes of CaO and predominantly microporous pores, which results in the high CO2 reactivity. Soluble Al-type dopants exhibit a more uniform dispersion in CaO-based pellets and the pellets have larger crystallite sizes of CaO and obvious pore channels, which results in the improved cyclic stability and decomposition kinetics. The optimized CaO-based pellets combine the advantages of the two Al-type dopants and present an increasing trend of energy storage density during the cyclic process. Its energy storage density remains 1571 kJ/kg after 50 cycles, and the value for CaO is only 569 kJ/kg. In addition, the optimal synthesized material has excellent thermal conductivity and crushing strength, which are 1.36 and 9.75 times those of CaO, respectively.

Monitoring plastic pellet pollution in coastal environments through handheld Raman spectroscopy: Data from the Mediterranean coasts (Southern Italy)

This paper examines the distribution and chemical properties of beached plastic pellets along the Ionian and Tyrrhenian coasts of Southern Italy. Three locations have been sampled: Agnone Bagni (SR) and Paradiso (ME) on the Ionian coast of Sicily, Baia del Tono in Milazzo (ME) on the Sicilian Tyrrhenian coast, and Pizzo Calabro (VV) in Calabria on the Tyrrhenian coast. Variations in shape, size, compactness, color, and other physical features, correlated with residence times and transport, has been highlighted. Raman spectroscopy, used in a portable configuration, enabled rapid identification of polymer types, demonstrating its utility for on-site plastic pollutant monitoring. Polyethylene and polypropylene were the predominant polymers. Principal component analysis of the spectra determined the optimal chemometric classification of pellets by composition, avoiding interference or distortion. In conclusion, the study provided preliminary insights into pellet abundance, composition, weathering extent, and distribution across these shorelines, underscoring the importance of regular beach monitoring.

APPLICATIO STUDY ON KINETICS OF BIOMASS PYROLYSIS IN THE FIXED BED. 1. SIMULATION AND NUMERICAL ANALYSIS OF LIGNIN THERMAL DECOMPOSITION

A non-stationary model of the biomass thermolysis process was built based on three primary independent parallel reactions of the biomass active part conversion into gas, liquid phase and char, taking into account the secondary reactions of tar decomposition into char and light gas. It is shown that the main role in the production of mixed pyrolysis gas (primary gas and light gas) is played by the light gas generation rate due to the secondary reaction of tar decomposition into light gas. This reaction rate significantly exceeds the primary gas production rate due to the fact that the activation energy of the primary gas formation reaction lignin → gas is higher than the activation energy of the lignin → tar reactions. It was found that the rate of generation of the primary reaction lignin → char significantly outweighs the rate of tar → char production, so the latter reaction can be neglected. It is shown that as the temperature of lignin pellets increases, CO and light hydrocarbon C1.16H4 increase and carbon dioxide CO2 and H2О decrease. The consumption of volatile components in the pyrolyzer depends on the temperature distribution of biomass pellets across the pyrolyzer cross-section, which decreases towards the center of the retort, following the consumption of gaseous components decreases as they approach the axis of the pyrolyzer. The amount of mixed pyrolysis gas released and char depends on the radial coordinate r. At r = 0.047 m and time τ = 380 s, the amount of mixed pyrolysis gas is 90 % and char is 10 %, at r = 0.016 m and τ = 380 s = 83 % and = 17 %. Bibl. 13, Fig. 7.

Assessment of Microplastics in Hanumante River of Kathmandu Valley

Plastic debris is one of the most significant organic pollutants in the aquatic environment. Researchers are currently focusing on the impact of micro and nano-scale plastic waste on aquatic systems. In this study, we investigated the distribution of plastic pellets and fragments present in the freshwater ecosystem. The goal was to assess microplastic (MP) abundance in the Hanumante River, a tributary of the Bagmati River, and analyze their properties. Sample collection involved the bottle sampling method. Filtration, wet peroxide oxidation, density separation, gravimetric analysis, and microscopic examination were performed to study the characteristics of microplastics. The study was conducted by following the guidelines of the National Oceanic and Atmospheric Administration (NOAA) protocol. Gravimetric analysis was applied to calculate the reduced mass of the sample after total organic carbon reduction. Results showed that the maximum amount of reduced sample was obtained from the sample taken from sample taken from Madhyapur Thimi area (~3.593g) and the minimum amount of reduced sample was obtained from the sample taken from the Shiva temple Jagati area (~2.130g). Microscopic inspection showed that samples taken from different locations were composed of an average of 14–23 microplastics per liter of sample. FT-IR analysis was performed to analyze the characteristics of microplastics and the type of polymers present in the sample which showed the abundance of polymer materials like polyethylene, polypropylene, and polycarbonates. The findings imply that appropriate plastic waste management measures be implemented in the communities to safeguard the ecosystem benefits derived from the river.

Effects of pellet ratio on the burden movement and distribution characteristics in the BF throat

In order to solve the urgent problem of energy conservation and emission reduction in the iron and steel industry, the use of high proportion pellets in blast furnace smelting will be the trend of ironmaking development in recent years. In the present work, a geometric model of a serial-hopper bell-less type charging system based on the discrete element method was built, which was used to investigate the distribution behavior of burden under the condition of multi-ring charging and different pellet ratios. The results show: (1) the overall velocity and particle flow width of the burden at the chute outlet become larger which results the average radius of falling point increases. (2) The pellet ratio has a significant effect on the distribution characteristics and the burden profiles at the furnace throat. When the pellet ratio increases from 0% to 100%, the relative radius of peak position of the burden layer increases from 0.491 R to 0.639 R, while the peak height decreases from 0.860 m to 0.543 m. (3) The burden segregation occurs at both the radial and longitudinal positions of the layer. In the radial position, the distribution of pellets near the center is relatively concentrated compared with sinter and there is no burden segregation occurs near the relative radius of 0.590 R. In the longitudinal position, the pellets are mainly distributed at the bottom of the burden layer, while the upper part is relatively less distributed. The research content and results may give a reference for the charging operation of BF under the condition of large pellet ratio, and consequently reduce CO2 emission in ironmaking process.

An unexpected explosion while fumigating a grain silo: It wasn't the dust

AbstractLarge‐scale fumigation of grain silos is a strategy to mitigate infestation of the bulk material. A common fumigant precursor for grain processes is aluminum phosphide, which exothermically decomposes in the presence of moisture (from the grain or air) to the toxic fumigant: phosphine gas. To overcome the hazards of exothermic decomposition and phosphine exposure, aluminum phosphide pellets can be metered into the silo's grain feed to distribute them throughout the grain more evenly. This approach decreases the decomposition rate of aluminum phosphide, better distributes heat generation to avoid igniting grain, and sustains a phosphine gas concentration well below the pyrophoric concentration—all while achieving the fumigation objectives. During a fumigation activity, a large explosion occurred within a group of silos at a grain elevator complex. Dust explosions are a common hazard for grain handling facilities, but this incident was caused by the autoignition of a phosphine gas cloud inside the conveyor tunnels. It was only through post‐incident evaluations of the grain flow dynamics and pellet addition activities that a gap between the desired pellet distribution and the incident conditions was identified. As a result, a new insight into bulk grain handling and safe fumigation was developed.

Evolution of biomass particles during pelletization process

Pulverizing is an essential unit operation in co-firing biomass with coal. Pulverizers are only compatible with pellet forms of fibrous biomass materials and crush them down to their original forming particle sizes. That is why the data on the size distribution of the particles forming a biomass pellet is crucial to achieving optimum combustion conditions. The current study determines the internal particle size distribution of pellets after wet disintegration, following ISO 17830 standard, and aims to suggest improvements to the mentioned standard based on new measured evidence. Experiments were carried out on white wood pellets (no bark) and brown wood pellets containing bark at four water temperatures: 20, 40, 60, and 95 °C, with or without stirring. The particle size distribution of the pre-pelletizer wood particles was also measured and compared with particles in the formed pellets. Ambient water temperature of 20 °C was found to be adequate for the complete disintegration of pellets, and no mechanical stirring was required. About 30% of particles in the disintegrated pellets were 0.5–1.0 mm. Pelletization changes the particle size distribution to smaller particles. The disintegrated bark pellets contained more fines than white pellets.

Seasonal variation and spatial distribution of microplastic pellets and their associated contaminants along the central east coast of India.

Microplastic pellets (MPPs) are one of the significant sources of plastic pollution on shorelines worldwide. In this study, for the first time, we have examined the occurrence of MPPs and their spatial and seasonal distributions, adsorbed contaminants, polymer composition, and ecological risks at eight renowned beaches of Andhra Pradesh, central east coast of India. A total of 3950 MPPs were collected from eight beaches along the central east coast of India during October 2020, representing pre-northeast monsoon (pNEM), and during January 2021, representing the northeast monsoon (NEM). The abundance of MPPs was higher during the NEM than those found in the pNEM. ATR-FTIR and SEM analyses were conducted to characterize the polymer types and weathering patterns of MPPs. Energy-Dispersive X-ray spectrometer (EDS) results show the MPP adsorbance of heavy metals such as Ni, Cr, Cu, Pb, and Zn. The degree of contamination and polymer hazard risks of MPPs were assessed using the pollution load index (PLI) and polymer hazard index (PHI). The conducive wind and currents during the NEM lead to higher MPP abundance than during the pNEM. However, the spatial variations of MPPs showed significant differences among the beaches. This study revealed that the presence of MPPs on the beaches along the central east coast of India might pose a considerable polymer hazard risk to the ecosystem. The substantial surface weathering features of MPPs would lead to more toxic nanoplastics in the future.

Appendicularians and marine snowin situvertical distribution in Argentinean Patagonia

AbstractDetailed in situ vertical and temporal distribution of appendicularians, marine snow, fecal pellets, nano- and microplankton were recorded simultaneously with environmental data in the San Jorge Gulf, Argentinean Patagonia (45°–47°S). Data were taken at a fixed station over 36 h in February 2014 with an autonomous Video Plankton Recorder and a FlowCAM®. The water column was thermally stratified with a pycnocline at ~ 40 m. Appendicularians dominated in the upper 65 m with a condensed pattern above the pycnocline at high chlorophyll a concentrations, matching the subsurface chlorophyll maximum layer at ~ 20 m. Our results suggest the absence of vertical migration of appendicularians. Marine snow, strongly correlated with appendicularians, showed high concentrations above the pycnocline, whereas fecal pellets from krill were distributed throughout the water column. Discarded houses of appendicularians or their mucus fragments were the main components of marine snow aggregates, with phytoplankton, detritus and krill pellets also contributing. Nanoplankton dominated over microplankton, with vertical distribution patterns that might depend on local grazing pressure and advective processes. Our study, the first one in the region using underwater imagery, emphasizes the leading contribution of appendicularians to marine snow aggregates in the San Jorge Gulf and their potential implications in the bentho-pelagic coupling.

Evaluation of the packed state of catalyst pellets in the gas phase reactor (Effect of catalyst pellet shape on its packed state)

In this paper, we propose a simulation method to evaluate the packed state of catalyst pellets in a pipe reactor for gas phase reaction. This simulation method is based on dynamic explicit FEM (finite element method) and consists of three steps. Specifically, first, the catalyst pellets freely fall under gravity and flow into a packing hose with a hopper-like inlet. Then, after the catalyst pellets reach the bottom of the pipe reactor, the packing hose is pulled up to create a random packing of the catalyst pellets in the pipe reactor. Finally, the bulk density and stress distribution of the catalyst pellets randomly packed in the pipe reactor are calculated, and the packed state of the catalyst pellets is evaluated. Using this simulation method, we simulated the packing of cylindrical catalyst pellets into the pipe reactor and evaluated the packed state of the catalyst pellets in the pipe reactor. As a result, it is clarified that the maximum equivalent stress generated at the bottom of the catalyst pellets packed in the pipe reactor approaches a constant value as the ratio of the packed height of the catalyst pellets to the diameter of the pipe reactor increases. In addition, the effects of the shape of the catalyst pellets on the bulk density and average equivalent stress of the catalyst pellets in the pipe reactor are elucidated, and the optimal shape of the catalyst pellets that can increase the bulk density and reduces the stress is found. The optimally shaped catalyst pellets are expected to improve their packed state in the pipe reactor, extend the durability of the catalyst pellets and increase the efficiency of production. In this paper, it is assumed that the packed state and durability of the catalyst pellets are evaluated based on the bulk density and stress distribution of the catalyst pellets in the pipe reactor.

A Flexible Robust Possibilistic Programming Approach toward Wood Pellets Supply Chain Network Design

Increasing energy demand and the detrimental environmental impacts of fossil fuels have led to the development of renewable energy sources. Rapid demand growth for wood pellets over the last decade has established wood pellets as a potential renewable energy source in a globally competitive energy market. Integrated decision making including all stakeholders in the wood pellet supply chain (WPSC) is essential for a smooth transition to commercially viable wood pellet production. In this aspect, this study aims to suggest a decision support system for optimizing biomass-based wood pellet production supply chain network design (WPP-SCND). The WPP-SCND decision system minimizes the total supply chain (SC) cost of the system while also reducing carbon emissions associated with wood pellet SC activities. All objective parameters, including biomass availability at the supply terminals, market demand, and biomass production, are considered fuzzy to account for epistemic uncertainty. A fuzzy flexible robust possibilistic programming (fuzzy-FRPP) technique is developed for solving the suggested uncertain WPP-SCND model. The case findings show that the imprecise nature of the parameters has a significant impact on the strategic and tactical decisions in the wood pellet SC. By investing almost 10% of the total cost, robust decisions within the wood pellet SC can be obtained. It is established that the fuzzy-FRPP technique successfully provides robust decisions and achieves a balance between transportation costs, emissions costs, and economies of scale when making capacity decisions. Although the suggested decision support system is used to manage the production and distribution of wood pellets, the insights and solution methodology may be extended to the production of other biofuels. The proposed research may be valuable to authorities involved in planning large-scale wood pellet-related production-distribution projects.

Mixing evolution behavior of raw and gasified biomass pellets in a fluidized bed reactor

Due to a large particle size and a small specific surface, a homogeneous mixing of biomass pellets with bed materials during gasification plays a critical role in the devolatilization and carbon conversion. In this work, the mixing evolution behavior of biomass pellets at different gasification stages is investigated for the first time. Two bubbling fluidized beds are established to perform the preparation of biomass samples undergoing different gasification times and visualized mixing experiments, respectively. An image processing technique is introduced for the determination of the real-time distribution of biomass pellets. The vertical and lateral migration paths of biomass pellets at different gasification stages are revealed. The improvement of binary mixing by adjusting the operating conditions as well as the adaptability to different biomass loadings are discussed. A convolutional neural network is developed to validate the influence of fluidization velocity on the resulting flow and classify the fluidization behavior.

Effect of Natural Ilmenite on the Solid Biomass Conversion of Inhomogeneous Fuels in Small-Scale Bubbling Fluidized Beds

The application of oxygen carriers as alternative bed material in fluidized bed combustion originates from chemical lopping processes. They serve as oxygen transport agents undergoing consecutive redox cycles. Thereby, oxygen carriers can provide surplus oxygen in oxygen-lean areas of fluidized bed combustion processes. In turn, re-oxidation takes place in oxygen-rich reactor parts. A more homogeneous combustion and reduced CO emissions follow during steady-state operation. However, especially regarding solid biomass conversion, inhomogeneous fuel qualities result in transient combustion conditions. Therefore, this research deals with the influence of the oxygen carrier ilmenite on solid biomass conversion. Separated batch experiments with methane (volatile), char and wood pellets took place in a laboratory bubbling fluidized bed reactor. They reveal that ilmenite enhances the in-bed CO2 yield by up to 63% during methane combustion. Batch char experiments confirm that solid–solid reactions with ilmenite are negligible. However, heterogeneous gas–solid reactions reduce the O2 partial pressure and limit the char conversion rate. The batch wood pellet experiments show that the ilmenite oxygen buffering effect is mitigated due to high local oxygen demand around the pellets and limited pellet distribution in the bed. Finally, the continuous operation in a 100 kWth BFB with inhomogeneous fuel input indicates a higher in-bed fuel conversion and confirms lower CO emissions and less fluctuation in the flue gas during inhomogeneous fuel supply.

The structural diversity of ibuprofen sustained-release pellets on the same goal of bioequivalence consistency

The consistency evaluation, which is largely unexplored is crucial in regulating the quality and efficacy of generic drugs. In this report, after generic ibuprofen (IBU) sustained-release pellets were developed and validated as bioequivalent to the reference list drug (RLD) in 48 healthy human volunteers (p < 0.001***), three-dimensional (3D) structures of generic IBU pellets from bioequivalence tests, along with RLD were investigated and compared for architecture using Micro-computed tomography (Micro-CT). The surface and internal architectures of the pellets, sphericity, pellet volume, core volume and gray value have been evaluated in both static and dynamic conditions. The material distribution and composition of IBU pellets were characterized using synchrotron radiation-FTIR mapping. Although the structures of RLD and the generic products were not similar dynamically, identical release profiles and bioequivalence were obtained. Overall, micro-CT could be very useful for characterization of internal structure, material design and development of new dosage form.

Improving maternal welfare during gestation has positive outcomes on neonatal survival and modulates offspring immune response in pigs

Improving the housing of pregnant sows by giving them more space and access to deep straw had positive effects on their welfare, influenced their maternal behavior and improved the survival of their offspring. The present study aimed at determining whether these effects were actually due to environmental enrichment and whether the provision of straw pellets and wood can partly mimic the effects of straw bedding during gestation. Three graded levels of enrichment were used, that were, collective conventional pens on slatted floor (C, n = 26), the same pens with manipulable wood materials and distribution of straw pellets after the meals (CE, n = 30), and larger pens on deep straw litter (E, n = 27). Sows were then housed in identical farrowing crates from 105 days of gestation until weaning. Decreased stereotypies, blood neutrophils, and salivary cortisol, and increased behavioral investigation indicated that health and welfare of sows during gestation were improved in the E environment compared with the C environment. The CE sows responded as C or E sows depending on the trait. Piglet mortality rate in the first 12 h after birth was lower in E and CE litters than in C litters, but enrichment level during gestation had only small effects on lactating sow behavior and milk composition postpartum. On days 2 and 3 of lactation, E sows interrupted less often their nursing sequences than C and CE sows. On day 2, milk from both E and CE sows contained more minerals than that from C sows. In one-day-old piglets, the expression levels of genes encoding toll-like receptors (TLR2, TLR4) and cytokines (interleukin-1, -6 and -10) in whole blood after 20-h culture, were greater in E piglets than in CE or C piglets. In conclusion, housing sows in an enriched environment during gestation improved early neonatal survival, probably via moderate and cumulative positive effects on sow behavior, milk composition, and offspring innate immune response. The gradation in the effects observed in C, CE and E housing environment reinforced the hypothesis of a causal relationship between maternal environmental enrichment, sow welfare and postnatal piglet traits.

Study on the distribution of poultry manure pellets

Study on the distribution of poultry manure pellets

Theoretical Substantiation of the Movement of Mineral Fertilizer Pellets After Leaving the Spreading Disc

The processes of movement of pellets of solid mineral fertilizers after their leaving the spreading disc of the solid mineral fertilizer centrifugal distributor are described. The dependences of the change in the pellet distribution plume on the change in the design parameters of the spreading disc, the speed of its rotation, as well as the location of the outlet window of the accelerating chamber are obtained.

Determination of Length of Individual Pellets and Pellets’ Lengths Distribution

A form and dimensions of fuel particles influence the intensity of their burning and approaches to the mathematic description of the process. Known methods do not allow correctly measuring all pellets’ lengths and describing pellets’ lengths distribution. The purpose of the study is to substantiate method for determining the individual pellet length and to specify statistical characteristics of pellets’ lengths distribution. The purpose was achieved by applying the proposed method of indirect determination of the length of each pellet by weighing it, followed by calculation of the equivalent length and modal cluster analysis of the distribution of pellets by length, based on the probability density distribution. The most noteworthy results are that the experimental calculation of the equivalent length gives results that coincide with direct measurements for pellets of the correct shape, but in contrast to direct measurements can also be used to determine the equivalent lengths of irregularly shaped pellets and their fragments. Clustering allowed grouping pellets around objectively existing local maxima in the probability density distribution, which can be identified at intervals of pellet lengths not exceeding 2 mm. The importance of the obtained results is that the indirect method of determining the length of pellets allows replacing the measurement of pellet lengths by their weighing, which eliminates subjective factors when measuring the length of irregularly shaped pellets and their fragments. Clustering characterised the granulometric composition of pellets with histograms of probability, mass fraction, and average length by clusters. Upon using proposed approaches, granulometric composition of industrially produced pellets was specified and increased probabilities were noted for 8 mm pellets in clusters of smaller lengths, compared to 6 mm pellets; while straw pellets are characterised by a higher probability in clusters with shorter lengths compared to wood pellets