Peak Mineral Assemblage Research Articles

Archean UHT metamorphism with counterclockwise P–T path: Insights from pelitic granulites from East Hebei, North China Craton

Archean supracrustal rocks that occur as rafts within tonalite–trondhjemite–granodiorite (TTG) gneisses can reach ultra-high temperature (UHT) conditions. Their metamorphic P–T paths and geodynamic regimes are debated. Herein, we present detailed analyses of UHT pelitic migmatites (JD1730 and JD1733) from the East Hebei, North China Craton, using petrology, phase equilibria modelling, and zircon dating, to recover the metamorphic history. Sample JD1730 is a sillimanite–orthopyroxene–cordierite migmatite that contains the sillimanite + orthopyroxene (+cordierite) symplectites, which are interpreted to be the pseudomorphs after sapphirine. JD1733 is a corundum-bearing garnet–cordierite–sillimanite migmatite that contains the corundum + spinel ± ilmenite/rutile aggregates, representing a stable mineral association of low pressures in local Si-unsaturated domains. The two rocks record consistent counterclockwise P–T paths involving pre-peak up-P processes to the UHT peak conditions followed by cooling. The pre-peak up-P processes occurred at 5–7 kbar and > 970 °C constrained from the textural relations involving (i) spinel enveloped by sillimanite and cordierite and mantled by the Sil + Opx symplectites in JD1730, and (ii) the inclusion variation in garnet of JD1733 with the Spl + Crn (±Ilm) aggregates embayed by sillimanite in the core and mantle, and worm-like quartz in the rim. The UHT peak conditions can be constrained to be 7–8 kbar, 980–1060 °C based on the stability of the inferred peak mineral assemblages in P–T pseudosections added with the plots of the re-integrated anorthite contents from perthite. The post-peak cooling processes to 5–8 kbar / 820–850 °C are marked by the growth of biotite in leucosomes of both samples. Zircon dating and geothermometry results suggest that the UHT metamorphism might have persisted for more than 20 Myr from ∼ 2.52 Ga to ∼ 2.50 Ga and the post-UHT cooling continued another 20 Myr or even 40 Myr. Considering the geological features in the terrane, a vertical sagduction regime was preferred for the Neoarchean tectonic evolution of the East Hebei terrane.

Metamorphic evolution of high-pressure and ultrahigh-temperature granulites from the Alxa Block, North China Craton: Implications for the collision and exhumation of Paleoproterozoic orogenic belts

High-pressure (HP) and ultrahigh-temperature (UHT) granulites with a high geothermal gradient (greater than 500 °C/GPa) are prominent features of Paleoproterozoic orogenic belts and may represent paired metamorphic belts present during the early stages of plate tectonics. Understanding their pressure−temperature−time (P-T-t) paths and metamorphic evolutionary relationships could provide valuable constraints on the tectonic processes of Paleoproterozoic orogenic belts. Here, we describe garnet mafic and clinopyroxene-orthopyroxene (Cpx-Opx) granulites from the Diebusige area of the Alxa Block in the western part of the Khondalite Belt, North China Craton. Through detailed petrographic, phase equilibrium modeling, and Ti-in-amphibole thermometric studies, we obtained the preserved peak mineral assemblages of two types of mafic granulites: garnet + clinopyroxene + amphibole + plagioclase + quartz + ilmenite, and clinopyroxene + orthopyroxene + plagioclase + amphibole + garnet (rare) + ilmenite. The preserved peak P-T conditions were determined to be 850−890 °C/11.4−13.2 kbar (HP granulite-facies) and 950−970 °C/8.2−9.2 kbar (UHT conditions), with thermal gradients of ∼70 °C/kbar (moderate differential temperature/differential pressure, dT/dP) and ∼110 °C/kbar (high dT/dP), respectively. Using sensitive high-resolution ion microprobe U-Pb dating and rare earth element analysis of zircons, we found that the garnet mafic granulite recorded an HP granulite-facies metamorphic age of ca. 1.95 Ga and a retrograde cooling age of ca. 1.8 Ga, while the Cpx-Opx granulite recorded a consistent retrograde cooling age of ca. 1.8 Ga. By combining these results with the metamorphic evolution and timing (ca. 1.92−1.91 Ga) of UHT rocks from the Khondalite Belt, we suggest that the garnet (HP) mafic and Cpx-Opx (UHT) granulites may represent different stages of the same metamorphic event, shedding light on the processes involved in the collision and subsequent exhumation of Paleoproterozoic orogenic belts.

Late Neoarchean and Paleoproterozoic tectonothermal and metamorphic evolution recorded in high-pressure granulites: Evidence from the Xuanhua Complex, northern North China Craton

Archean cratons usually underwent reworked processes during the late Paleoproterozoic orogeny, which may result in multiple tectonothermal records preserved in some high-grade metamorphic rocks; thus, these rocks provide a key opportunity on understanding the tectonic styles during different periods. In this study, we report new petrological, mineral chemical and geochronological data of a suite of newly discovered mafic and felsic metamorphic rocks in the Xuanhua Complex from the northern North China Craton (NCC), revealing the complex metamorphic thermal history and the transition of tectonic regime from the late Neoarchean to the late Paleoproterozoic. The mafic granulite preserves the prograde quartz and clinopyroxene inclusions within garnets (M1), and the peak stage (M2) is recorded by garnet, clinopyroxene, hornblende, plagioclase, quartz and ilmenite. The first retrograde (M3a) and final cooling stages (M3b) are defined by the appearance of orthopyroxene, and the amphibolite-facies overprinting, respectively. The felsic granulite records the similar peak mineral assemblage (M2), but has higher volumes of feldspar and quartz than the mafic granulite. The retrograde stage (M3) is represented by amphibolite-facies assemblage (hornblende ± biotite ± clinopyroxene) and fine-grained intergrowth of hornblende + plagioclase around garnet. Pseudosection modeling and thermobarometry results suggest that both high-pressure (HP) mafic and felsic granulites record clockwise P–T paths, including isothermal decompression and cooling from the peak stage (M2: 10.4–10.8 kbar/830–860 °C and 9.6–11.2 kbar/850–930 °C, respectively) to the retrograde stages (M3a and M3b: 7.5–8.0 kbar/840–870 °C and 7.8–8.2 kbar/650–700 °C, respectively; M3: 7.2–8.6 kbar/670–800 °C). Zircon U–Pb dating shows that the magmatic precursors of these rocks were emplaced at c. 2.5–2.47 Ga. The metamorphic zircons reveal two groups metamorphic ages of c. 2.51–2.45 Ga and c. 1.90–1.85 Ga. The c. 2.51–2.45 Ga ages indicate a late Neoarchean tectonothermal event, and the c. 1.95–1.85 Ga ages are interpreted to represent the Paleoproterozoic HP granulite-facies metamorphism overprinting. The highest positive εHf(t) value of 7.64 and 2.8–2.6 Ga Hf model ages of c. 2.5 Ga magmatic zircons indicate that the c. 2.5 Ga mantle-derived mafic magma and the c. 2.5 Ga partial melting of 2.8–2.6 Ga basaltic juvenile crust generated the protoliths of mafic and felsic granulites, respectively, revealing 2.8–2.6 Ga and 2.5 Ga crustal growth and c. 2.5 Ga crustal reworking in the northern NCC.To sum up, we consider that the late Neoarchean magmatism and coeval metamorphism recorded in our samples are probably resulted from the amalgamation of micro-blocks. The Paleoproterozoic clockwise P–T–t paths with near-isothermal decompression segments and low geothermal gradients (c. 21–26 °C/km) of HP mafic and felsic granulites indicate a rapid post-collisional exhumation process after the significantly crustal thickening, and this long-term orogeny along the TNCO (c. 1.95–1.85 Ga; > 100 Myr) is related to the incorporation of the NCC into the Columbia supercontinent.

Metamorphic Ages and PT Conditions of Amphibolites in the Diebusige and Bayanwulashan Complexes of the Alxa Block, North China Craton

The metamorphism and geological significance of amphibolites in the Diebusige and Bayanwulashan Complexes of the eastern Alxa Block, North China Craton, were poorly understood until now. This study presents the results of petrology, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb analysis, phase equilibrium modeling and geothermobarometry for these rocks. The peak mineral assemblage of clinopyroxene + hornblende + plagioclase + K-feldspar + ilmenite + quartz + melt is inferred for amphibolite sample ALS2164 in the Diebusige Complex. Correspondingly, the peak mineral assemblage of clinopyroxene + hornblende + plagioclase ± K-feldspar + ilmenite + quartz + melt is identified for amphibolite sample ALS2191 in the Bayanwulshan Complex. Phase equilibrium modelling constrained the peak metamorphic condition of amphibolite sample ALS2164 in the Diebusige Complex to be 825–910 °C/7.2–10.8 kbar, which is similar to that (800–870 °C/7.0–10.7 kbar) of amphibolite sample ALS2191 in the Bayanwulashan Complex. Hbl–pl–qz thermobarometry yielded the metamorphic PT conditions of 732–810 °C/3.0–6.7 kbar for these amphibolites, which are consistent with the average temperatures of 763 °C, 768 °C and 780 °C calculated by Ti-zircon thermometry. As a result, phase equilibrium modelling yielded wide PT condition ranges of 800–910 °C/7.0–10.8 kbar, the lower limit of which is consistent with the upper limit of estimates by the hbl–pl–qz thermobarometer. In addition, LA-ICP-MS U–Pb analysis on metamorphic zircons yielded weighted mean 207Pb/206Pb ages of 1901 ± 22–1817 ± 21 Ma, which represent the timing of amphibolite-facies metamorphism. As a whole, the PT estimates display a high geothermal gradient, which is consistent with coeval ultrahigh-temperature metamorphism and associated mantle-derived mafic-ultramafic rocks in the Diebusige Complex. Combing this information with the previously published data from the Diebusige Complex, an extensional setting after continental collision is inferred for the eastern Alxa Block during the late Paleoproterozoic. The HREE enrichment patterns of metamorphic zircons from the amphibolites in this study are in agreement with that these amphibolites formed at relatively shallower crust than the garnet-bearing mafic granulites in the Diebusige Complex.

High-pressure melting in metapelites of a 2 Ga old subducted oceanic crust (Usagaran belt, Tanzania): implications from melt inclusions, fluid inclusions and thermodynamic modelling

Investigation of polymineralic melt inclusions preserved in garnet of eclogite-facies metapelites of the Usagaran belt, Tanzania, is of particular importance as these metapelites, intercalated in oceanic metabasites, document the rare case of partial melting at high temperatures in a subducted oceanic crust. With an age of 2 Ga the rocks represent one of the oldest oceanic crusts and confirm a subduction process already at Paleoproterozoic times. Partial melting probably was initiated by dehydration melting under the presence of a CO2-rich fluid phase. The melt is preserved in siliceous polymineralic inclusions, while CO2 locally reacted with the garnet host to form dolomite-quartz-kyanite inclusions. During this reaction, the REE spectrum of garnet is adopted by the dolomite. Furthermore, graphite inclusions in garnet must have precipitated from the CO2 fluid by reduction. The highly ordered graphite structure indicates a formation temperature of at least 700 °C. Rehomogenization experiments of the siliceous polymineralic inclusions yield a homogeneous melt of rhyolitic, peraluminous composition. Thermodynamic modelling enables to deduce a P–T path in accordance with high P–T conditions (minimum 2.0 GPa, 900 °C) where a partial melt formed due to phengite breakdown leading to the preserved peak mineral assemblage garnet, alkali feldspar, kyanite, quartz and rutile. A very fast uplift of the oceanic crustal rocks can be deduced from the occurrence of very finely exsolved metastable ternary feldspar and from the preserved prograde zoning in garnet.

Metamorphic evolution of garnet amphibolites from the Fuping Complex: Implications for the Paleoproterozoic subduction–collision history of the Trans‐North China Orogen

The Trans‐North China Orogen (TNCO) is a major Palaeoproterozoic collisional orogen in the North China Craton and has experienced complex tectonic evolution during the assembly of the Eastern and Western Blocks. The vestiges of subducted oceanic crust preserved in this orogen can be used to gain insights into the subduction–collision process associated with the Palaeoproterozoic orogeny. In this study, we investigate garnet amphibolites from the Wanzi Group in the Fuping Complex along the TNCO through integrated petrography, mineral chemistry, phase equilibrium modelling and zircon U–Pb geochronology. Three stages of metamorphic mineral assemblages are identified as follows: (i) the prograde assemblage is preserved as plagioclase, amphibole, biotite and quartz inclusions in garnet porphyroblasts; (ii) the peak mineral assemblage includes coarse‐grained amphibole, garnet, plagioclase, ilmenite, biotite and quartz; and (iii) the retrograde assemblage is mainly represented by the corona of amphibole, plagioclase and biotite in the matrix. Petrological features and phase equilibrium modelling define a clockwise pressure–temperature path involving a prograde stage of 7.2–9.6 kbar and <670°C, peak conditions of 10.0–10.2 kbar and 690–810°C, and a retrograde stage with near‐isothermal decompression to ~7.4 kbar and cooling. Zircon U–Pb dating shows weighted mean ages of 1848 ± 22 Ma and 1836 ± 31 Ma, representing the growth of zircon in the retrograde stage during the uplift and cooling process. In combination with available data from the TNCO, the post‐peak decompression and cooling process is inferred to be long‐lived during 1.90–1.76 Ga, following collision along the TNCO that occurred during 1.97–1.90 Ga, ultimately leading to the final assembly of the North China Craton.

Evolution of Contact Metamorphic Rocks in the Zhoukoudian Area: Evidence from Phase Equilibrium Modelling

The Yanshan intraplate tectonic belt is a tectonic-active area in the central part of the North China Craton that has undergone long-term orogenic evolution. Detailed studies on magmatic activity and metamorphism of this belt are significant for restoring its orogenic thermal evolution process. The Fangshan pluton in the Zhoukoudian area within this tectonic belt is a product of the late Mesozoic Yanshan event. However, there is a lack of detailed research on the metamorphic evolution history of the ancient terrane surrounding the Fangshan pluton subjected to contact thermal metamorphism. To further constrain the metamorphic P–T evolution of contact metamorphism associated with the Fangshan pluton, we collected rock samples in the andalusite–biotite contact metamorphic zone of the Fangshan pluton, and conducted petrographic investigations, geochemical and mineral composition analysis, and phase equilibrium modeling. The phase equilibrium modeling in the MnO–Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O system indicates that the peak mineral assemblages of andalusite–biotite schists are pl + q + mu + bi + and ± kfs + ilm + mt, formed at 550 to 610 °C, 1 to 3.5 kbar, and the peak mineral assemblage of garnet–andalusite–cordierite–biotite schists is gt + pl + q + bi + and + cord + ilm + mt, formed at 580 to 620 °C, 1.5 to 2.1 kbar. Therefore, we believe that the rocks in the andalusite biotite contact metamorphic zone of the Fangshan pluton underwent low pressure and medium temperature metamorphism, with the peak metamorphic conditions of about 550–610 °C, <3.5 kbar. The results show that the rocks in contact with the thermal metamorphic zone were rapidly heated by the heat released by the Fangshan pluton, and after reaching the peak metamorphic temperature, they were cooled down simultaneously with the cooling of the rock mass, defined in a nearly isobaric P–T trajectory.

Fluid migration along deep‐crustal shear zone: A case study of the Rhenosterkoppies Greenstone Belt in the northern Kaapvaal Craton, South Africa

The north‐dipping Hout River Shear Zone (HRSZ), which marks the boundary between the high‐grade Limpopo Complex in its hanging wall and the low‐grade granite‐greenstone terrane of the Kaapvaal Craton in South Africa in its footwall, is a deep‐crustal shear zone that controlled emplacement of hot Limpopo Complex granulites over and against low‐grade granite‐greenstones during exhumation at ~2.72–2.62 Ga. This major shear zone controlled migration of large volumes of hydrous fluids released during devolatilization of underthrusted greenstones that infiltrated into hot overlying granulites, establishing a retrograde anthophyllite‐in isograd and associated zone of retrograde rehydrated granulite that bounds the Limpopo Complex in the south. Here, we report new petrological data based on mineral equilibrium modelling of amphibolites from the Rhenosterkoppies Greenstone Belt (RGB) located in the immediate footwall of the HRSZ and discuss evidence that these rocks also interacted with high‐temperature fluids that infiltrated along the HRSZ. This study provides an important perspective of the interaction of hot granulites with underthrusted relatively cold greenschist‐facies rocks along the steeply north‐dipping section of the HRSZ, and shows that evidence for such interaction is restricted to a relatively narrow zone in the footwall of the HRSZ termed a hot‐iron‐zone. The peak mineral assemblage of a garnet‐free amphibolite from the RGB (magnesio‐hornblende + plagioclase + quartz + clinopyroxene + titanite + ilmenite) yielded the peak P–T condition of 7–8 kbar and 640–680°C with H2O content of 3.5–3.8 mol%. Clinopyroxene is replaced by actinolite + quartz and epidote + quartz symplectites by a post‐peak hydration event at <5 kbar and <590°C caused by elevated H2O content in the rock (>4.0 mol%), possibly related to fluid infiltration along the HRSZ. Mineral equilibria in a garnet‐bearing amphibolite records a prograde path from 5 to 7 kbar and 540–630°C to the peak conditions at 7.6–8.7 kbar and 620–650°C. A clockwise P–T path suggesting rapid compression and decompression has been inferred for the amphibolites from the RGB, possibly because of pressure increase related to overthrusting of the high‐grade terrane (Southern Marginal Zone of the Limpopo Complex) onto the low‐grade granite‐greenstone terrane, followed by rapid exhumation. The quantity of H2O associated with the amphibolite‐facies metamorphism in the RGB was elevated from the peak stage (M(H2O) = 3.5–3.8 mol%) to the retrograde stage (M(H2O) = 4.0–4.5 mol%) of metamorphism in the RGB, possibly suggesting fluid infiltration not only from internal sources but also from external sources. The results of this study indicate that a H2O‐bearing fluid, which infiltrated along the HRSZ, affected both the footwall and the hanging wall sections of the shear zone, although the effect on the footwall section was limited.

The metabasites from the Texel Unit (Austroalpine nappe stack): markers of Cretaceous intracontinental subduction and subsequent collision

Abstract Eclogites in the Texel Unit (Austroalpine nappe stack; Eastern Alps, South Tyrol, Italy) represent the westernmost out-crops of the E-W striking Eoalpine High-Pressure Belt (EHB). East of the Tauern Window, the EHB forms part of a Cretaceous intracontinental south-dipping subduction/collision zone. The impetus of this contribution is to extend the geothermo-barometric data of the eclogites from the EHB using conventional geothermobarometry and multi-equilibrium calculations as well as Zr-in-rutile/titanite geothermometry and to put the P-T results of eclogites and amphibolites from the Texel Unit into the geodynamic framework. The investigated samples of this study are from the Spronser- and the Saltaus valleys (S-Tyrol) in the Austroalpine Texel Unit. The Texel Unit is composed mainly of paragneisses with minor intercalations of micaschists, orthogneisses, amphibolites and subordinately eclogites. The amphibolites from the Spronser valley contain the mineral assemblage amphibole + plagioclase + garnet + clinozoisite/epidote + quartz + titanite ± ilmenite ± rutile ± apatite ± calcite. Chemical zoning in plagioclase and amphibole shows two main growth stages: an older P-dominated stage (e.g. albite and barroisite cores) and a younger amphibolite-facies stage. The core of the amphiboles shows barroisite composition, the rim can be chemically classified as hornblende, edenite, tschermakite and pargasite. Geothermobarometric calculations with multi-equilibrium geothermobarometry (THERMOCALC v.3.21) yield temperatures of 600–654°C and pressures of 0.98–1.17 GPa for the same samples. The eclogites from the Saltaus valley contain the peak mineral assemblage omphacite + amphibole + garnet + clinozoisite/epidote + muscovite + quartz + titanite ± ilmenite ± rutile. Thermobarometric calculations, were performed in the system CaO-FeO-MgO-Na2O-Al2O3-FeO-SiO2-H2O with the assemblage clinopyroxene + garnet + amphibole + clinozoisite/epidote + muscovite + quartz ± H2O. The calculations involved an H2O-absent invariant point (mode-1 calculation) as well as two types of average P-T mode-2 calculations. The obtained average P-T H2O-absent mode 1 P-T conditions are 1.89 ± 0.18 GPa and 578 ± 60°C. Using the average P-T mode-2 two types of calculations were done: (1) calculations without amphiboles but with H2O present, which yield mean P-T conditions of 1.95 ± 0.28 GPa and 601 ± 55°C and (2) calculations with amphiboles but without H2O, which yield mean P-T conditions of 1.95 ± 0.26 GPa and 666 ± 77°C. Calculations using THERMOCALC v.3.33 yield similar results with slightly higher pressures of 0.3 GPa. Based on the present geothermobarometric data in conjunction with available mineral ages the eclogites represent the Eoalpine intracontinental subduction stage whereas the amphibolites reflect the subsequent, P-accentuated stage of decompression associated with the subsequent Eoalpine collisional stage.

Metamorphic Evolution and Orogenic Process Related to the Eastern Paleo-Tethyan Warm Subduction and Indochina–South China Collision

Abstract The eastern Paleo-Tethyan Jinshajiang–Ailaoshan–Song Ma orogenic belt in the Southeast Tibetan Plateau represents the tectonic boundary between the Indochina and South China blocks. Regional Cenozoic lithospheric strike-slip movements caused by the India–Asia collision have modified many of the pristine geological records associated with the Indosinian orogeny. The lack of reliable petrological evidences, particularly of high-pressure (HP) metamorphism, has hindered the tracing of the evolutionary history of the Paleo-Tethyan orogenic belt. We report the mineralogy, geochemistry, geochronology and thermodynamic modelling of eclogite lenses/blocks and their host garnet–phengite schists from the Song Ma Suture Zone of Northwest Vietnam and reveal their protolith origins and metamorphic evolution. The eclogites are geochemically similar to mid-ocean ridge basalt, showing weak depletions in high field-strength elements, positive to slightly negative whole-rock ɛNd(t) ratios (−1.69 to +5.15) and slightly high 87Sr/86Sr(t) ratios (0.70466–0.70834). The igneous protolith of the eclogites formed in the late Silurian (425.4 ± 3.6 Ma; igneous zircon dating, 638–459 Ma TDM dating), which makes them the oldest known mid-ocean ridge mafic rocks in an ancient Paleo-Tethyan Ocean. Various eclogites preserve similar peak mineral assemblages (garnet + omphacite + phengite + rutile + quartz ± epidote/clinozoisite ± kyanite ± winchite) under indistinguishable peak conditions. Their prograde P–T trajectories show a uniform pattern of progressive heating and weak compression along a geothermal gradient of 8°C–10°C/km, indicating a warm subduction setting at a low angle that contrasts with the cold oceanic subduction recorded in the adjacent Paleo-Tethyan suture zones. Combined with detrital U–Pb ages from previous studies, our geochronological data indicate that the host schists originated from continental crust within the South China Block and underwent a pervasive Triassic HP metamorphism related to the Indosinian orogeny. The eclogites and host schists yielded HP metamorphic ages of 239–234 Ma and retrogressive amphibolite-facies metamorphic ages of 231–229 Ma, suggesting rapid cooling (14.0°C–21.6°C/Myr) and exhumation (6.4 km/Myr) from the mantle to the crust. The Song Ma eclogites and their host schists formed when the final ocean closure transitioned to the initial Indochina–South China collision. The Song Ma eclogites and their host schists provide essential information on the opening and closure of the eastern Paleo-Tethys and the subsequent amalgamation of Southeast Asian continental fragments.

Metamorphic Evolution of the Archean Supracrustal Rocks from the Qingyuan Area of the Northern Liaoning Terrane, North China Craton: Constrained Using Phase Equilibrium Modeling and Monazite Dating

Archean supracrustal rocks from the Qingyuan area of the northern Liaoning terrane, the North China Craton, occur as enclaves or rafts of various scales within tonalite–trondhjemite–granodiorite (TTG) domes. They were normally subjected to metamorphism at amphibolite facies with locally granulite facies. We collected biotite two-feldspar gneiss from the Hongtoushan of the Qingyuan area and conducted petrography, mineral chemistry, phase equilibrium modeling and monazite dating to reveal its metamorphic evolution. The peak condition was constrained to be 750–775 °C at ~7 kbar based on the stability of the inferred peak mineral assemblage and mineral compositions including the pyrite and grossular contents in the garnet core, and XMg in biotite. The final condition was constrained to be ~700 °C at ~6 kbar on the solidus based on the presence of muscovite in the final assemblage. The post-peak near-isobaric cooling process was consistent with the core→rim decreasing pyrite content in garnet. Monazite dating yielded a metamorphic age of ~2.50 Ga for the sample, coeval with the final magmatism of TTGs in the terrane. By combining other geological features, we suggest a vertical sagduction process to be responsible for the metamorphic evolution of the Qingyuan area. This process may be correlated with Archean mantle plume.

Geochemistry and Phase Equilibrium Modelling of Garnet-Biotite Gneiss from Mauranipur, Bundelkhand Craton, Northern India: Implication for Tectonic Setting and Metamorphism

The Mauranipur region is situated along the central part of the Bundelkhand Craton (BuC) in the northern Indian shield, which consists of garnet- biotite gneisses with various deformational structures in the form of folding, faulting, augen and tail structures. These deformation structures are tectonic imprints that reveal the tectonic nature of the garnet-biotite gneisses. The groundmass of Grt-Bt gneisses is characterized by presence of garnet, biotite, plagioclase, K-feldspar, quartz, and ilmenite. The phase equilibrium modelling and geochemical attributes depict the tectonic activity and metamorphic evolution of the studied rocks. The P-T pseudosection has been calculated in the NCKFMASHT system, which revealed that the peak mineral assemblage stabilized in the P-T range of 6.35–6.75 kbar and 755–780ºC, and it further goes to retrograde metamorphism under P-T condition ranging from 4.80–5.28 kbar and 718–735ºC. These gneisses represent a calc-alkaline to high-K calc-alkaline series of protolithic origin. The negative anomaly of Nb and Ti for all samples indicates that a subduction tectonic setting has occurred in the BuC. The (La/Lu)N ratio and differences in the trace elements indicate heterogeneous sources and large variation in the degree of partial melting. The Y vs Nb and (Y+Nb) vs Rb tectonic discrimination diagrams indicate that the Grt-Bt gneisses have an affinity towards the volcanic arc granite and developed during subduction setting. The geochemical interpretation provides significant evidence that protoliths of Grt-Bt gneisses were further metamorphosed by the continent-continent collision. Keywords: Garnet-biotite gneiss, Pseudosection, P-T condition, Geochemistry, Bundelkhand

Petrology and geochronology of sapphirine‐bearing granulites from the Limpopo Complex in eastern Botswana: Implications for Palaeoproterozoic long‐lived high‐pressure/ultrahigh‐temperature metamorphism and rapid exhumation

The Limpopo Complex in southern Africa is a classic example of Neoarchean collisional orogens with a Palaeoproterozoic thermal overprint. We report new petrological, pressure–temperature (P–T), and geochronological data of sapphirine‐bearing Mg–Al‐rich and pelitic granulites from a metasupracrustal unit (the Beit Bridge Complex [BBC]) in the eastern part of Botswana to constrain its P–T–time evolution. Textural observations and phase equilibria modelling of the peak mineral assemblage of Mg–Al‐rich granulites (K‐feldspar + orthopyroxene [Opx2; Al2O3 up to 8.8 wt.%] + sillimanite [Sil2] + quartz + rutile + biotite [Bt2] + inferred melt) in the NCKFMASHTO system recorded a peak metamorphic condition of >930°C and > 10.3 kbar. A pelitic granulite recorded consistent P–T conditions of 960–980°C and > 10.3 kbar, indicating high‐pressure (HP) and ultrahigh‐temperature (UHT) metamorphism for the BBC in Botswana. Post‐peak retrograde conditions were obtained based on the stability of sapphirine + cordierite symplectite assemblage in the Mg–Al‐rich rocks (820–860°C and 6.4–7.0 kbar) and orthopyroxene [Opx3] + cordierite symplectite assemblage in the pelitic granulite (830–930°C and 4.3–5.8 kbar), indicating near‐isothermal decompression after the peak HP–UHT metamorphism along a clockwise P–T path. Similar HP–UHT metamorphism followed by a near‐isothermal decompression along a clockwise P–T path was reported from different regions of the BBC in South Africa and Zimbabwe (P > 14 kbar and ~1,000°C based on the stability fields of magnesian staurolite and sapphirine + quartz assemblage), although the peak P–T condition is slightly lower in Botswana. Monazite grains with patchy zoning show isochron ages of 2,115 ± 77 Ma for Th‐poor domains, and 2,058 ± 40 Ma and 2,033 ± 34 Ma for Th‐rich domains. Similar ages were obtained from zircon U–Pb geochronology as 2,232–2,135 Ma and 2,010 ± 19 Ma (Th/U = 0.05–0.26). The younger ages (2.0 Ga) probably indicate the timing of near‐peak high‐grade event, while the older ages might indicate a thermal event during the prograde heating stage. The P–T conditions and zircon/monazite ages suggest Palaeoproterozoic long‐lived metamorphism associated with intracontinental transpressional tectonics related to Palaeoproterozoic orogenic events around the united Zimbabwe–Kaapvaal Craton.

Mechanism of crustal thickening and exhumation of southern Lhasa terrane during the Late Cretaceous: Evidence from high-pressure metamorphic rocks of the Eastern Himalayan Syntaxis

AbstractThe mechanism of Late Cretaceous crustal thickening and exhumation of the southern Lhasa terrane is critical for understanding the tectonic evolution of the Tibetan Plateau. High-pressure metamorphic rocks from the lower crust are good candidates for addressing this issue. In this study, we focus on Late Cretaceous, high-pressure, garnet-bearing amphibolites from the Nyingchi Complex of the Eastern Himalayan Syntaxis and present an integrated study of geochronology, petrography, mineral chemistry, and thermodynamic modeling. Petrographic data determine three metamorphic stages (M1–M3). The M1 stage is characterized by a peak mineral assemblage of garnet + hornblende + albite + rutile + muscovite + quartz, which is followed by a post-peak (M2) assemblage of garnet + hornblende + plagioclase + epidote + biotite + rutile + quartz. The late retrograde stage (M3) is defined by hornblende + plagioclase symplectites surrounding garnet porphyroblasts. Mineral chemistry, with thermodynamic modeling, constrains the P-T conditions of the M1–M3 stages to 14–19 kbar/660–720 °C, 8–10 kbar/650–660 °C, and <7 kbar/<600 °C, respectively. Metamorphic zircons yield a concordant age at 90 Ma, which indicates the formation of garnet-bearing amphibolites. These results indicate a P-T-t path involving near-isothermal decompression for garnetbearing amphibolites, which suggests that the Nyingchi Complex underwent peak-pressure metamorphism (M1) at 90 Ma, followed by rapid exhumation to the depth of 32–26 km along the subduction channel. Moreover, the garnet-bearing amphibolites are considered to be the product of high-pressure metamorphism of mafic crust at the base of the Gangdese belt. Hence, the crust of the Gangdese belt experienced significant crustal thickening of up to 60 km at 90 Ma.

Latest Mesoproterozoic (ca. 1.2–1.1 Ga) amphibolite-facies metamorphism from the Dete-Kamativi Inlier, NW Zimbabwe: Implications for a Rodinia-related intracratonic orogen in Southern Africa

The Magondi Belt has been regarded as a Paleoproterozoic orogen formed by the collision of the Zimbabwe Craton and an unknown continental block. The Dete-Kamativi Inlier (DKI) located approximately 200 km west-southwest of the main Magondi Belt has been regarded as an extension of the belt. Here, we report new geochronological data for pelitic schists and a felsic orthogneiss from the DKI using monazites (CHIME method) and zircons (LA-ICP-MS analysis), and discuss the tectonic evolution of the region. Zircons from a felsic orthogneiss in the Kamativi area yielded magmatic and metamorphic ages of 2279 ± 25 Ma and 2020 ± 28 Ma, respectively. Similar Paleoproterozoic ages of ca. 2.1–1.8 Ga were also obtained from subhedral and rounded monazite grains in the pelitic schists. In contrast, irregular-shaped monazite intergrown with biotite in a different pelitic schist gave three latest Mesoproterozoic isochron ages of 1196 ± 37 Ma, 1143 ± 32 Ma, and 1070 ± 25 Ma, suggesting a long-lived (>120 million years) thermal event with several monazite-growing stages. Consistent isochron ages of 1062 ± 41 Ma and 1061 ± 26 Ma were obtained from monazites in the felsic orthogneiss and metapelite samples from an adjacent region. The application of phase equilibrium modeling for the peak mineral assemblage in the garnet-andalusite-biotite-cordierite-bearing pelitic schist with 1196–1070 Ma metamorphic ages indicated a peak P–T condition of 520–600 °C and 1.5–2.5 kbar, suggesting low-pressure amphibolite-facies metamorphism. The condition is lower than that obtained from the hornblende-plagioclase geothermometry of amphibolites (>700 °C) from the southwest part of the DKI, which probably corresponds to an earlier (ca. 2.0 Ga) high-grade metamorphic condition. The youngest thermal event, 994–982 Ma, from monazite rim in a mylonitic orthogneiss might correspond to the timing of later deformation. The latest Mesoproterozoic (1.2–1.1 Ga) amphibolite-facies metamorphism was likely associated with an intracratonic orogeny related to the activity of broadly coeval orogenic events, such as the Namaqua-Natal orogenic belt related to the amalgamation of the Rodinia supercontinent. Regional magmatic activity of the Umkondo large igneous province at 1112–1108 Ma could have also been an additional heat source.

Two Phases of Metamorphism in the High-Pressure Schists in Central Inner Mongolia, China: Implications for the Tectonic Transition From Terminal Subduction of the Paleo-Asian Ocean to Continental Collision

High-pressure (HP) rocks exhumed from subduction zones usually record much warmer geotherms than numerical modelling results, as their peak mineral assemblages are always modified during the exhumation process. The decompressional metamorphic evolution of HP rocks should be considered carefully if using their P–T records to constrain the thermal structure of a subduction zone. The Ondor Sum Group, known as mélanges containing various high P/T metamorphic rocks in central Inner Mongolia, represents a fragment of subducted oceanic crust in the Early Paleozoic, However, the thermal structure of the subduction zone is unavailable due to an absence of exhumed HP rocks with P–T estimates. In this study, the HP schists were newly discovered in the Ondor Sum Group at Airgin Sum in the central Inner Mongolia. The HP schists include a garnet–phengite schist (sample EL01) and a garnet–amphibole schist (sample EL08). The petrography of these rocks and phase equilibrium modelling using THERMOCALC suggest two phases of metamorphism, both of which are characterized by clockwise P–T evolutions involving pre-peak prograde stage, peak-stage, and post-peak decompression stage. The peak P–T conditions of the early-phase metamorphism are constrained by P–T pseudosections to be ∼18 kbar/∼535°C for sample EL01 and 18 kbar/∼500°C for sample EL08. The peak P–T conditions of the late-phase metamorphism are constrained by P–T pseudosections to be ∼8 kbar/532°C in EL01 and ∼7.0 kbar/495°C in EL08. Available U–Pb data of zircons from the HP schists and a granodiorite vein using LA–ICP–MS constrain the timing of early-phase HP metamorphism in the early Paleozoic and the late-phase metamorphism supposed to be in the Devonian based on the previous reported ages. The peak P–T conditions for the early-phase metamorphism were high-P/T conditions with a thermal gradient of ∼8°C/km, pointing to a warm oceanic subduction. The overprinting late-phase metamorphism represents medium-P/T conditions with a geothermal gradient of 22–25°C/km, which we attribute to a collisional thickening process. As a result, we suggest that the HP schists in the Ondor Sum Group represent the terminal stage of subduction of the Paleo-Asian oceanic plate, and that the schists were involved in the continental collision after the closure of the Paleo-Asian Ocean in the Devonian.

Paleoproterozoic ultrahigh‐temperature metamorphism in the Alxa Block, the Khondalite Belt, North China Craton: Petrology and phase equilibria of quartz‐absent corundum‐bearing pelitic granulites

AbstractAn Al‐rich, quartz‐absent corundum‐bearing pelitic granulite is reported for the first time at the Diebusige complex in the Alxa Block in the western part of the Khondalite Belt (KB), North China Craton (NCC). A detailed petrographic study shows that a quartz‐present domain occurs in porphyroblastic garnet cores from the corundum‐bearing pelitic granulite, with a prograde metamorphic mineral assemblage (M1) of garnet + plagioclase + quartz + biotite + spinel + rutile ± melt, and a quartz‐absent domain occurs in the matrix of this rock, with a preserved peak mineral assemblage (M2) of garnet + corundum + spinel + biotite + plagioclase + K‐feldspar + rutile + melt and a retrograde metamorphic mineral assemblage (M3) of garnet + sillimanite + corundum + biotite + plagioclase + K‐feldspar ± rutile. Phase equilibrium modelling and Zr‐in‐rutile and ternary feldspar thermometry all reveal similar peak conditions of 890–940°C at 7.5–9.8 kbar, which indicate a high geothermal gradient of ~110°C/kbar and ultrahigh‐temperature (UHT) conditions. Combining this information with the detailed analysis of metamorphic zircons, we obtain the metamorphic evolution of the corundum‐bearing pelitic granulite. Specifically, the corundum‐bearing pelitic granulite experienced granulite‐facies metamorphism at ~1950 Ma. Then, this rock was slowly uplifted with heating and partial melting until it achieved UHT conditions. Finally, it cooled to the solidus at ~1830 Ma. Thus, we propose that the UHT metamorphic conditions of a corundum‐bearing pelitic granulite from the Diebusige complex of the Alxa Block may be the result of long‐term slow uplift with heating under a high geothermal gradient.

Ultrahigh temperature metamorphism and isobaric cooling of Neoarchean ultramafic‐mafic granulites in the southern granulite terrain, India: Phase equilibrium modelling and SHRIMP zircon U–Pb dating

AbstractThis study presents the results of petrology, SHRIMP zircon U–Pb analysis, conventional Fe–Mg geothermobarometry, REE (rare earth element)‐based geothermobarometry, and phase equilibrium modelling, for newly discovered ultramafic‐mafic granulites (garnet pyroxenite with minor plagioclase and garnet‐bearing granulite) in the Namakkal Block of the southern granulite terrain (SGT), India. Results from this study shed light on the growth, evolution, and thermal state of lower continental crust during the Neoarchean, as a cross‐section of the Archean lower continental crust is well‐exposed in the SGT. SHRIMP zircon U–Pb dating of a garnet pyroxenite sample (18ID‐41) yielded a weighted mean 207Pb/206Pb age of 2531 ± 6 Ma, which is the same within uncertainty as one weighted mean SHRIMP metamorphic zircon 207Pb/206Pb age of 2519 ± 9 Ma from mafic granulite sample (18ID‐43). In addition, zircon U–Pb analyses also yielded an apparent 207Pb/206Pb age of 2474 ± 3 Ma (1σ) for the garnet pyroxenite, and a weighted mean 207Pb/206Pb age of 2489 ± 8 Ma for the mafic granulite. Thus, the timing of metamorphism of the ultramafic‐mafic granulites was constrained to be ca. 2530–2470 Ma. The peak metamorphic phase assemblage of the garnet pyroxenite is grt–cpx–pl–ilm–liq, which was modelled to be stable at 1058–1172°C/7.8–11.6 kbar, whereas the retrograde mineral assemblage of grt–cpx–hbl–pl–qz–ilm–liq occurred at 877–888°C/9.9–11 kbar. The mafic granulite was demonstrated to record similar peak and retrograde metamorphic P–T conditions to those of the garnet pyroxenite but have a relatively small P–T range of the peak mineral assemblage. The ultrahigh temperature metamorphism of these ultramafic‐mafic granulites was further confirmed by the temperature results (1057–1087°C) from the REE‐in‐two‐pyroxene thermometer. As a result, a retrograde metamorphic P–T path characterized by near‐isobaric cooling from ~1080°C at ~10 kbar to ~900°C at ~10 kbar was constructed for these rocks, which is consistent with an extremely high thermal state that persisted for ca. 60 Ma in the lower crust.

Early Paleozoic metamorphic evolution of the East Kunlun Orogen recorded in Langmuri garnet-amphibolite

东昆仑造山带近年来被厘定为早古生代高压-超高压变质带。带内广泛出露早古生代的中-高级变质基性岩，这些岩石记录了不同的变质温压和多期的变质年龄，是反演和制约东昆仑早古生代变质演化的重要样品。本文选取东昆仑浪木日地区的石榴斜长角闪岩为研究对象，开展了变质岩石学及锆石年代学研究。石榴斜长角闪岩呈团块状出露在黑云二长片麻岩中，主要组成矿物为石榴子石、角闪石、斜长石、透辉石和石英，含少量黑云母、绿泥石、金红石、钛铁矿和榍石。石榴子石变斑晶的核部含有绿帘石、角闪石、斜长石、金红石和石英包裹体，其成分从核部到边部，锰铝榴石逐渐降低、钙铝榴石和Mg/（Mg+Fe²⁺）比值逐渐升高，为进变质作用形成的环带。岩石中的矿物结构关系和成分特征显示其经历了进变质、峰期变质和退变质三个阶段的变质演化，变质温压分别为：T≈610℃和P≈6.5kbar、T≈700℃和P≈10.5kbar以及T≈650℃和P≈4.5kbar。这三阶段的变质作用构成顺时针的变质P-T轨迹，指示岩石经历进变质升温升压至峰期阶段，随后经历近等温降压的退变质阶段。同时该P-T轨迹特征表明岩石形成于俯冲-碰撞的构造背景。对石榴斜长角闪岩中的锆石进行SIMS U-Pb定年，得到492.8±5.1Ma的谐和年龄。锆石的形态特征与典型的变质锆石一致，其内包裹的石榴子石、角闪石和斜长石组合与岩石的峰期矿物组合一致。因此，锆石在峰期变质阶段结晶，所测年龄~493Ma为角闪岩相峰期变质年龄。本文研究的石榴斜长角闪岩与该区高压-超高压榴辉岩在野外产状、P-T轨迹和变质年龄等方面密切相关，暗示ca.490Ma是该区高压-超高压变质作用的一个重要时间节点。石榴斜长角闪岩和榴辉岩之间的变质差异，表明东昆仑早古生代经历了多阶段的变质作用，不同岩石记录了原特提斯洋俯冲-碰撞过程的不同阶段。本文获得的变质P-T轨迹和变质年龄可为进一步探究东昆仑早古生代高压-超高压变质作用提供限定。;The East Kunlun Orogen (EKO) was recently considered an Early Paleozoic HP-UHP metamorphic belt. Many Early Paleozoic intermediate- to high-grade meta-basic rocks exposed in the belt record different metamorphic conditions and ages, and as a result, they are important samples for studying Early Paleozoic metamorphic evolution of the EKO. This paper presents metamorphic petrological and zircon geochronological studies of a garnet-amphibolite in Langmuri area in the eastern section of the EKO. The garnet-amphibolite mainly consists of garnet, plagioclase, amphibole, diopside and quartz, with a small amount of biotite, chlorite, rutile, ilmenite and titanite. The porphyroblastic garnet grains include epidote, amphibole, plagioclase, rutile and quartz in their cores. A compositional profile of the garnet shows a decrease in spessartine and grossular and an increase in Mg/(Mg+Fe²⁺) from its core to rim. These compositional features suggest that the garnet crystallized in a process of prograde metamorphism. Textural relationship and mineral compositions reveal that the rock experienced three stages of metamorphism, with their metamorphic conditions of T≈610℃ and P≈6.0kbar (prograde stage), T≈700℃ and P≈10.5kbar (peak stage), and T≈650℃ and P≈4.5kbar (retrograde stage), respectively. These metamorphic conditions form a clockwise P-T path, with a nearly isothermal decomposition process from the peak stage to the retrograde stage. The characteristics of the P-T path indicate the garnet-amphibolite was formed in the subduction-collision tectonic process. Zircon SIMS U-Pb analysis yield a concordant age of 492.8±5.1Ma. The morphological characteristics of the measured zircons are consistent with those of typical metamorphic zircon. The mineral inclusions (garnet, amphibole and plagioclase) of the zircons are consistent with the peak mineral assemblage of the rock, which suggests that the zircons should crystallize at the peak stage of amphibolite facies. Therefore, the age of~493Ma is the peak metamorphic age of the garnet-amphibolite. The garnet-amphibolite studied in this paper show close relationship with the HP-UHP eclogites of the same area in the aspects of field occurrence, P-T path, and metamorphic age. The relationship between the two rock types indicates ca. 490Ma should be an important stage of the HP-UHP metamorphism of this area. Meanwhile, the differential metamorphism between the two rock types implies the EKO experienced multi-stage metamorphism in the Early Paleozoic, thus different rocks recorded different stages of the subduction-collision process of Proto-Tethys Ocean. The P-T path and metamorphic age presented in this paper can provide constraints into the further study of the Early Paleozoic metamorphic evolution of the EKO.

Exhumation of deeply subducted continental crust along contrasting pathways: Examples from the North Qaidam ultrahigh pressure metamorphic terrane, North Tibet

Deeply buried continental terranes now exposed in the core of mountain belts are characterized by dominant felsic gneisses enclosing eclogite and garnet peridotite. Some medium–low temperature eclogites can preserve peak mineral assemblages. In contrast, some eclogites and their country rocks have been turned to granulite-facies assemblages. The apparent discrepancy between the two types of eclogites may reflect different exhumation pathways and mechanisms. Based on detailed field investigation and geological mapping, two ultrahigh pressure (UHP) metamorphic units are recognized in the western North Qaidam Mountains. The Yuka-Luofengpo UHP metamorphic unit (YKU) is characterized by medium–low temperature eclogites and metapelites, whereas the Luliangshan UHP metamorphic unit (LLU) primarily consists of granulitized eclogites and pelitic granulites. The two units are separated by an early Paleozoic arc magmatic-metamorphic unit.The disparate metamorphic evolutions of the UHP metamorphic rocks from the YKU and LLU indicate that the two adjacent metamorphic units underwent different exhumation pathways. We combine our data with published geodynamic numerical modeling to infer that the YKU UHP metamorphic rocks detached from the subducted slab at different depths and exhumed within a cold continental subduction channel. In contrast, the granulitized eclogites and pelitic granulites of the LLU were vertically exhumed from the subduction channel through the hot mantle wedge into the overriding crustal plate by diapirism (relamination) and experienced a prolonged granulite facies overprint prior to exhumation to the shallow crust.