The impermeable area and the peak discharge volume have been consistently increasing due to widening of city development and renewal. Thus, distortion of water cycle has been serious problem compared to the past. When it comes to NPS pollution, lack of information on the load and characteristics of pollutants led to the insufficient reduction measures. Because the particles with size over 100 in road runoffs can go through gravitational sedimentation, they are controllable in grit chamber according to the structure of NPS pollution reduction facilities. In this section, using CFD model, the behavior of fluid and particle distribution according to structure characteristics of reduction facilities will be simulated and the optical condition for successful treatment in grit chamber will be calculated. As a result of study, numerical analysis about treatment of particulate pollutants with size greater than 100 for which gravitational sedimentation is possible showed that by controlling the inflow velocity the sedimentation efficiency could be improved and it is determined that maintenance will become facilitated through the installment of facilities such as baffles at grit chamber.