Passive Margin Tectonic Setting Research Articles

Geochemistry of the North Gondwana Paleozoic Araba and Naqus formation siliciclastics, Sinai: implications for provenance, paleoweathering, and tectonic setting

ABSTRACT The Araba and Naqus formations in Ras Milan, Sinai, constitute part of the major continuous Paleozoic clastic belt stretching across northern Gondwana. They are sandstone-dominated successions, resting on Precambrian granitic basement, with lowermost thin basal polymictic conglomerate deposits (1–2 m), marking the unconformity. The Araba Formation section is composed mainly of varicoloured violet to reddish brown, fine to coarse-grained laminated and planner and overturned cross-bedded sandstones, while the overlying Naqus Formation is characterized by chaotically distributed poorly sorted quartz pebbles to cobbles within a moderately-sorted coarse- to medium-grained quartz arenite and by abundance and variety of large-scale tabular and trough cross bedding. Modal QFL classification of Araba and Naqus formation sandstones revealed that they are merely quartzose sandstones (quartz arenites). Geochemistry of the succession shows extremely wide compositional ranges for almost all major elements, but the Araba Formation is relatively enriched in SiO2, TiO2, Fe2O3*, Na2O, P2O5, and depleted in Al2O3, MgO, CaO and K2O relative to Naqus Formation. Only the Araba Formation samples are depleted in the transition elements Ni, Cr and Co and oppositely possess extreme enrichment in the HFSEs (i.e. Zr, Hf, Y, Nb, Ta, Th, U), whereas both formations show variable depletion in the LILE Rb, K and Ba, and excessive REE abundances relative to the PAAS and UCC, and LREE-enriched patterns with marked negative Eu anomalies. The provenance of the Naqus and Araba formations could be an earlier felsic magmatic source, which has undergone extensive sedimentary recycling. They possess high compositional maturity and were subjected to intensive to moderate weathering during humid climatic conditions. Passive margin tectonic setting is implied which denotes the derivation of Araba and Naqus formation siliciclastics from stable continental regions or plate interiors and deposition in intracratonic basins.

Geochemical characterization of Lokoja-Basange Sandstone at Imiegba and Okpekpe areas, Benin flank of Anambra basin, Nigeria: implications for provenance, tectonic setting and source-rock weathering

This study investigates the geochemical attributes of the Lokoja-Basange Sandstone situated in Okpekpe and Imiegba areas of the Benin Flank of Anambra Basin, Nigeria. The aim of this study is to unveil its provenance, tectonic setting, and source rock weathering extent. Using energy dispersive x-ray fluorescence (EDXRF) "Minipal 4" spectrometer analysis, nine outcrop samples were examined for major oxide concentrations. The results show significant average SiO2 (77.09 wt. %), Al2O3 (12.10 wt. %), Fe2O3 (2.72 wt. %), Na2O (1.64 wt. %), K2O (2.41 wt. %), while TiO2, MnO, MgO, CaO, P2O5, LOI had average concentrations of less than 1.00 wt. %. Bivariate plots of log [Fe2O3/K2O] versus log [SiO2/Al2O3] indicate 77.80% litharenites and 22.20% arkose sediments. The [Al2O3]-[CaO+Na2O]-[K2O] ternary plot, the tectonic discriminant diagrams of [SiO2/20]-[K2O+Na2O]-[TiO2+Fe2O3+MgO], log [K2O/Na2O] versus SiO2, [SiO2/Al2O3] versus log [K2O/Na2O] and bivariate discriminant functions plot indicate that the sediments have felsic igneous provenance and quartzose sedimentary origin, within a passive margin tectonic setting and the source-area underwent moderate to near complete chemical weathering in semi-arid to humid climatic conditions with increasing chemical maturity. Conclusively, the chemical alteration index (CIA) ranges from 65.4% to 74.2%, averaging 70.70%; the chemical index of weathering (CIW) averages 82.37%; the plagioclase index of alteration (PIA) averages 78.88%; and the mineralogical index of alteration (MIA) averages 41.43%. These data signify extensive weathering of felsic igneous source rocks, highlighting mineralogical maturity of Lokoja-Basange Sandstone. In essence, this study enriches insights into the sandstone's origins, sedimentary context, and weathering history.

Geochemistry and depositional environment of black shale beds of the Belata Formation, Peninsular Malaysia

Shale deposits from Belata Formation outcrops were examined geochemically and mineralogically to establish their paragenesis and, subsequently, to identify factors that govern their depositional environment. Fifty representative samples were examined through SEM/EDX, XRD and XRF. The findings show the mineralogical composition was abundant in quartz, with pyrite and calcite in trace amount. Zr–TiO2 bivariate diagram showed predominantly felsic and intermediate igneous rocks, suggesting that the shales may be coming from the hidden basement rocks of Peninsular Malaysia. The diagenetic controls on the geochemistry are suggested by the changes in compositional trends. The samples exhibit CIA values ranging from 62.2 to 80.2, and PIA values ranging from 65 to 100. According to the V/Ni, Ni/Co, and V/Cr ratios, these black shales were formed in a suboxic environment. Additionally, the high V/Ni ratios (1.47) point to a marine source for the organic content that gives the shales their dark color. The paleoclimate during deposition was interpreted to be semiarid to warm. The black shale samples are inferred to have originated from a passive margin tectonic setting that followed continental collision and rifting stages of the foreland basin development phase of Peninsular Malaysia based on geochemical proxies and associated diagrams.

Geochemistry and clay mineral studies of Jurassic sedimentary rocks from the Spiti region, Himachal Pradesh, North India

An attempt is made in the present study to unravel the provenance, paleoweathering and paleoclimatic conditions of the Jurassic (Spiti Formation) black shales and sandstones from the Spiti region, Tethys Himalaya, using multi proxy approach. The sandstones are subarkose in composition and texturally poorly sorted, subrounded to subangular in shape with moderate spheriocity. The range of the chemical index of alteration (CIA) is 55–90, recorded in the black shales strongly suggests moderate to strong chemical weathering conditions in the source area, which in turn reflect fluctuating climatic conditions prevailing during the deposition of these sediments in Jurassic period in the Spiti region. Geochemical studies reveal that shales are enriched in felsic elements (high SiO2, Al2O3, K2O) and depleted in mafic components (Fe2O3 and MgO).The various geochemical discriminant plots and elemental ratios (SiO2/Al2O3, K2O/Al2O3, Al2O3/TiO2, K2O/Na2O, etc.) indicate the rocks to be the product of weathering of felsic rocks. The paleoclimate in the source area seems to be mostly semi-humid. The plot of the samples on the A-CN-K ternary diagram indicates a granitic weathering trend. The X-ray Diffraction studies show that the prominent clay minerals in the Spiti shales are illite, smectite, chlorite, kaolinite and vermiculite along with quartz, muscovite, alkali feldspar, calcite and phosphatic phase.When plotted on the tectonic discrimination diagram, the samples indicate passive margin tectonic setting.

Source Area Weathering and Tectonic History Inferred from the Geochemistry of the Maastrichtian Sandstone from Patti Formation, Southern Bida Basin, North Central Nigeria

Sandstones sampled from Patti Formation, Southern Bida Basin, were studied geochemically using Inductively Coupled Plasma Atomic Emission Spectrophotometer (ICP-AES) and an Inductively Coupled Plasma Mass Spectrometry (ICP-MS) technique to evaluate their weathering and tectonic setting as well as to deduce the paleo-climatic conditions that existed during their deposition. Geochemically, SiO2 range from 73.9% to 86.2%, Al2O3 (6.7%~17.1%), Fe2O3 (1.1%~1.9%), K2O (0.1%~0.7%) while MgO, CaO, Na2O, P2O5, MnO and TiO2 were <1%. Enriched in Ba (Av. 622.94), Sr (Av. 153.63), Rb (Av. 55.08) and Zr (Av. 51.86) relatively similar in composition to UCC. High SiO2 but low other major oxides signify high mobility during processes of weathering. This was confirmed by high value (>80%) for indices like chemical index of alteration, chemical index of weathering, plagioclase index of alteration, mineralogical index of alteration and relatively lower values for weathering index of parker, recently used alpha indices (αAl E) of sodium (326.17αΑl Na<344.40), magnesium (100.54αΑl mg<398.55), calcium (12.07αΑl Ca<198.99), potassium (4.43αΑl K<64.33), strontium (0.84αΑl E<21.40), barium (0.45 αΑl Ba<10.52) and rubidium (0.0008αΑl Rb<0.06), supported by AI2O3-(CaO*+Na2O)-K2O and CIA vs. SiO2 plots that imply intense weathering in the source area. The obtained high CIA values (>80) indicates a steady-state of weathering under a warm/humid climate as confirmed by the SiO2 vs. Al2O3+ K2O + Na2O plot. High average SiO2 (75.41wt%) with K2O/Na2O ratio >1 (15.63), low Fe2O3 (1.27wt %), Al2O3 (15.82wt%) and TiO2 (0.46) suggest passive margin tectonic setting. This is supported by enriched ΣREE (209.64 ppm), ΣLREE (195.78), LREE/HREE (27.78) and negative Eu/Eu* (0.68), plots of log (K2O/Na2O) vs. SiO2 and SiO2/Al2O3 vs. K2O/Na2O. Major elements discriminant-function multi-dimensional diagram, DF1 (arcrift-col) vs. DF2 (arc-rift-col), for high-silica sediments revealed a continental rift tectonic setting. Thus, the Patti Formation sandstone underwent a high degree of weathering under a humid climatic condition within a continental rift tectonic setting.

Depositional conditions of the Upper Cretaceous shales from the Anambra Basin, SE Nigeria: Constraints from mineralogy and geochemistry

Thirty-four core shale samples from the Upper Cretaceous Mamu Formation, southeastern Nigeria, were studied using XRD and geochemical analyses to constrain their provenance, tectonic setting, palaeoweathering and palaeoredox conditions during deposition. X-ray diffraction analysis revealed the presence of clay minerals (kaolinite, illite and illite-smectite mixed layer) and non-clay minerals (quartz and feldspar). The dominance of kaolinite and the high kaolinite/illite (K/I) contents indicate warm and humid climatic conditions during sediment accumulation. The total organic carbon (TOC) content of the shales ranges between 0.31 and 55.34%. The high Chemical Index of Weathering (CIW; mean∼98.8%), Chemical Index of Alteration (CIA; mean∼92%) and Plagioclase Index of Alteration (PIA; mean∼98.7%) for the shales, including a high content of kaolinite, indicate intense chemical weathering in the source area. The positive correlations between V, Cr, Ni, Co, Ga, Cd, Be, Sc, TiO2, MgO with Al2O3 and Ba with K2O suggest that these elements in the shales are mainly held in clay minerals. The elevated contents of Zr and the high Zr/Cr and Zr/Sc ratios imply that the shales were derived from predominantly felsic source rocks. However, TiO2/Zr and Y/Ni ratios suggest a derivation from an admixture of complex felsic and mafic basement rocks. The low average enrichment factor values of Mo (MoEF), V (VEF) and U (UEF), along with low concentrations of redox-sensitive trace element ratios (Mo/U, Ni/Co, V/Cr and Cu/Zn) and high TOC contents infer oxic conditions during deposition. Furthermore, Fe2O3–S-TOC relationships, along with DOPT, V/(V + Ni) and Fe2O3/Al2O3 ratios, suggest dominantly oxic to slightly dysoxic/anoxic conditions during the accumulation of the Mamu Formation shales. Binary plots of K2O/Na2O ratio versus SiO2 indicate a passive margin tectonic setting for the shales.

Provenance, source weathering, and tectonic setting of the lower Cambrian Shuijingtuo Formation in the Middle Yangtze area, China

The organic-rich shale of the Lower Cambrian Shuijingtuo Formation is an important hydrocarbon source rock in South China. The geochemical characteristics of this shale were investigated to determine the provenance, weathering conditions, sedimentary recycling, paleoclimate, and tectonic setting of the Shuijingtuo Formation in Yichang in the Middle Yangtze area. The shale is relatively enriched in CaO, P2O5, Mo, U, V, Cd, and Cu. The rare earth element (REE) patterns of the shale exhibit light rare earth element (LREE) enrichment and heavy rare earth element (HREE) depletion. It has weak negative Eu and Ce anomalies, which are similar to the characteristics of passive margin deposition. The analysis of the carbonate dilution effect conducted in this study reveals that carbonate dilution has a greater effect on the MgO, Ba, Sc, and Zr contents. The provenance discrimination diagrams suggest that the shale is primarily derived from a mixture of intermediate and felsic igneous source rocks, which were similar to Tonalite-trondhjemite-granodiorites (TTGs) in composition. The chemical index of alteration (CIA) values and the A–CN–K ternary diagram indicate that the source area of the shale experienced a low degree of chemical weathering under a cold and arid climate in the early period and a moderate degree of chemical weathering under a warm and humid climate in the later period. The relationship between Zr/Sc and Th/Sc indicates that the shale was deposited by the first cycle of sedimentation rather than via reworking. The discriminant function diagrams, major element ratios, immobile trace element ratios, and ternary relationships between La, Th, Sc, Zr, and Co indicate that the source rocks were deposited in a passive margin tectonic setting. It is suggested that the Ezhong old land, which is predominantly composed of the Huangling granite and the Kongling complex (composed of intermediate and felsic igneous rocks) was the source area.

Characteristics of polymetallic enrichment on oceanic red bed in Matano Formation, Baturubei, Central Sulawesi, Indonesia

The Matano Formation on Sulawesi Island has Cretaceous oceanic red bed (CORB) facies, but there is no further research on the geochemical characteristics of the sedimentary rocks. This study aims to classify the CORB of the Matano Formation and reveal the polymetallic element enrichment in CORB by using the X-ray fluorescence (XRF) analysis method. Matano Formation in the research area consists of two different facies: radiolarites facies and red clay facies. Radiolarites facies grouped as Si-ORB, dominated by siliceous pelagic bioclastic and deposited under oxic environment. The red clay facies grouped as Al-ORB, the components dominated by hemipelagic material with a small amount of silica shelled pelagically and deposited under reduction environment. Red clay facies have higher enrichment elements Mn, V, Ni, Zn and La than radiolarites facies. Oceanic red bed facies of Matano Formation deposited in basin plain environment below carbonate compensation depth in a passive margin tectonic setting.

Provenance and compositional variations of intra-caldera lake sediments at La Primavera, Jalisco, Western Mexico

The multi-proxy provenance analyses carried out in the Upper Pleistocene sediments of the La Primavera intra-caldera paleolake in western Mexico document the evolution of source areas. This lake formed a few thousand years after the caldera collapse (~95 ka) and lasted until the intra-caldera resurgence process that ended 75 ka ago. Between 93.8 and 71 ka the sedimentary succession that filled the lake was affected by the extrusion of domes at its central part and the constant influx of volcaniclastic debris. Ring-fault domes and extra-caldera activity sourced at San Miguel volcano provided additional volcanic debris into the lake. Based on our multi-proxy studies and recent age determinations of the post-caldera activity is likely that the paleolake was coggled at 78 ka in the central sector of the caldera, synchronously with the caldera resurgence. The resulting deposits (volcaniclastic debris) are tuffaceous sands characterized by lithoarenites rich in neo-volcanic grains, mainly vitrophyric and felsitic volcanic fragments with similar characteristics to the rocks of the Ixtahuantonte, El Nejahuete composite dome, Cerro Alto, Las Pilas, and Dos Coyotes domes. Geochemically, the sediments of the La Primavera caldera exhibit concentrations and elemental relationships of major and trace elements similar to the average of the upper continental crust. However, the high concentrations of some elements, such as La, Th, Ti, and Zr are related to the hyperalkaline nature of the magmatism that originated this volcanic caldera. The concentrations of SiO2/Al2O3, Na2O/K2O, Th, Sc, and Zr/10 indicate a passive margin tectonic setting deposition under low weathering conditions.

Upper Cretaceous-Upper Eocene mud-dominated turbidites of the Belaga Formation, Sarawak (Malaysia): 30Ma of paleogeographic, paleoclimate and tectonic stability in Sundaland

The Upper Cretaceous-Upper Eocene Belaga Formation is characterized by thick deep-water sediments that were accumulated as one of the biggest ancient submarine fans covering a time interval of 30 Ma. Although the Belaga Formation is the extensively investigated formation in the Rajang Group, its source and tectonic setting are still arguable. This study utilizes, for the first time, detailed mineralogical and geochemical investigations on sediments from the Belga Formation to examine its origin. The Belaga Formation is subdivided into five members that are made of seven lithofacies dominated by mudstone. Clay fractions from the mudstones of the five members are composed of illite (40–60 wt %), kaolinite (30–45 wt %) and chlorite (5–15 wt %). Al2O3/TiO2 ratios and calculated SiO2 (wt. %) as well as Zr–TiO2, Al2O3–TiO2, SiO2–Al2O3/TiO2 and Cecn-La/Ybcn plots suggested felsic to intermediate igneous source rocks for all members probably the Lower-Upper Cretaceous granites and tonalities of the Schwaner Mountains situated southwest of the studied area. The abundance of kaolinite, Sr/Cu ratios, C-values, Sr/Cu ratios, Sr/Cu versus Ga/Rb plot and high Chemical Index Alteration (CIA) indicate warm and humid paleoclimate throughout the formation of the Belaga Formation. Geochemical proxies from the major oxides (SiO2–K2O/Na2O, K2O/Na2O–SiO2/Al2O3 binary plots and CaO–Na2O–K2O ternary plot), trace elements (Sc/Cr–La/Y discrimination diagram) and uniform REE patterns with distinct Eu negative anomalies propose a mature passive margin tectonic setting for the five members of the Belaga Formation. Facies analysis indicate typical turbidite sequences in all members. Domination of mudstone and the passive margin tectonic setting suggest a channel-levee complex without lobes submarine fan model (Type III) for these turbidites. Stability in source area composition, paleoclimate, palaeogeography and tectonic setting of Sundaland during the Late Cretaceous-Late Eocene (~30 Ma) indicated from sedimentology and geochemical proxies is consistent with the global paleogeographic and paleoclimatic models for this area during this period. Due to their geological and economic importance as potential hydrocarbon source in the region an all over the world, results of this study provide new insights for the architecture and sedimentology of turbidites.

THE MAJOR ELEMENTAL COMPOSITION OF MIDDLE PALEOCENE SEDIMENTS OF SOUTHERN INDUS BASIN PAKISTAN: IMPLICATION ON PROVENANCE

The current study area is a northeastern part of Karachi arc and located in Lakhi Range and also the Southeastern part of Karachi arc which is Thar Desert. Present study is focused on Bara Formation with specifically source rock study, as it could be understand that from where these detritus were being supplied, either from Indian craton or Asian plate in Middle Paleocene time. These sediments are composed of Sandstone, Shale, Coal, and Siltstone with some traces of fossils. Ninety five samples of Middle Paleocene sediments from three localities (Ranikot, Lakhra and Thar) with five stratigraphic sections have investigated for geochemical elements identification. The studied sediments have been classified as Litharenite, Sublitharenite, arkose, Sub-arkose greywacke, Iron sand, Iron shale. PIA and CIA of studied section of basin had been facing low/low to high weathering conditions in source area. The majority of samples indicate the passive margin tectonic settings. Middle Paleocene sediments of Southern Indus Basin is concluded here as the sediments had been supplied from Indian shield rocks and it can be summarized that the Indian plate was not collided with Asia plate in Middle Paleocene time (61.6-59.2 million years age) at Southern Indus Basin of Pakistan.

Geochemical evaluation of Campanian-Maastritchian clay-shale sediments of Patti formation, Southern Bida and Mamu Formation, northern Anambra basins

Two basins (Southern Bida and Northern Anambra Basins) were investigated to deduce weathering, paleooxygenation, provenance, depositional environment and tectonic setting, as well as to establish a relationship between the two basins. The obtained high values of calculated weathering indices such as Chemical index of alteration (CIA > 90), Chemical Index of Weathering (CIW > 90), Plagioclase Index of Alteration (PIA > 90) and the Al2O3-(CaO + Na2O)-K2O ternary relationship for the clay – shale sediments from both basins indicate intense weathering in the source area. Important geochemical ratios such as V/Cr, Cu/Zn, Ni/Co, (Cu+Mo)/Zn, revealed predominantly oxic conditions for the clay – shale sediments from both basins, although, a more reducing or an anoxic condition cannot be ruled out for the clay – shale sediments from the Southern Bida basin due to high ratios of U/Th (1.93-5.67) and Cu/Zn (0.19-5.00). In addition, the Sr/Ba ratios (0.16–3.50) for the clay-shales from the Southern Bida basin indicated an alternated marine and continental paleo-depositional settings and only continental setting (Sr/Ba ratios = 0.22 – 0.50) for the Northern Anambra basin. The Th/Sc, La/Sc, Th/Co and the LREE/HREE ratios showed a derivation of the shale and clay deposits from similar felsic-rich source rock while the log of (K2O/Na2O) vs SiO2, revealed a Passive Margin tectonic setting for the two Basins. There is insignificant differences between the geochemical classifications, weathering, source rock/provenance and tectonic settings of clay-shale sediments of both sedimentary basins, however, there exist slight disparity in their salinity conditions and redox settings.
 Keywords: Geochemistry, Clay-shale, Provenance, Tectonic Setting, Northern Anambra and Southern Bida Basins

Palaeo-weathering Characteristics and Nature of Source Lithology of a Carbonaceous Metasedimentary Unit in the Dalma Volcano-sedimentary Belt, North Singhbhum Mobile Belt, Eastern India

The Palaeo to Mesoproterozoic Dalma volcano-sedimentary basin (DVSB) is a typical greenstone belt sequence within the North Singhbhum Mobile Belt (NSMB) of Singhbhum Crustal Province (SCP), eastern India. The volcano-sedimentary belt is situated in the central portion of NSMB and separates the Chaibasa and Dhalbhum formation lying at its south from the Chandil Formation at its north. The metasedimentary unit comprises carbonaceous phyllite, carbonaceous cherty quartzite, quartz mica schist and quartzite. In the present work, the Au-rich carbonaceous metasedimentary rocks were studied to understand the source rocks characteristic, paleoweathering history and possible tectonic set-up. Geochemical classification diagrams based on the major oxide data indicates that these units belong to arkose to wacke field and the protolith underwent moderate to high degree of chemical weathering. Based on critical elemental ratios, it is inferred that the sediments were subjected to moderate degree of physical weathering, associated with sediment sorting and recycling. A fractionated REE pattern coupled with prominent negative Eu anomaly and elevated Th/Sc ratios indicate a felsic provenance for these metasedimentary units. The data further suggests that the sediments were deposited in a passive margin tectonic setting, during a prolonged period of upliftment and erosion of the Archean Singhbhum granite complex.

Tectonic discrimination of siliciclastic sedimentary record of the northern Tethyan margin at the end of the Triassic

Tectonic setting of both the uppermost Triassic Tomanova and the lowermost Jurassic Dudziniec formations can be characterized by a series of diagnostic discrimination diagrams. High-silica and low-silica multi-dimensional diagrams indicate that the sediments could have been deposited in the continental collision/rift setting. Diagrams of K 2 O/Na 2 O versus SiO 2 , SiO 2 /Al 2 O 3 versus K 2 O/Na 2 O and Th-Co-Zr/10 as well as Th-Sc-Zr/10 determine an origin from the tectonically active and/or passive continental margin setting. REE parameters indicate predominantly a passive margin tectonic setting of the sediments. The most probable source of clastic admixture in the Scythian to Domerian sediments in the Tatric Unit was situated in a remnant of the Variscan collisional orogen – the Vindelician Highlands. Occasional monsoonal rains occurring in orbitally controlled cycles transported weathered material from the source area down river valleys on the seaward slopes of the Variscan Vindelician Mountains towards the Tethyan Sea. The input of this material influenced also the marginal parts of the Fatricum (e.g., Vysoka or Havran units).

Geochemistry of Maastrichtian Clastic Sedimentary Rocks from Western Flank of Anambra Basin, Nigeria: Implications for Provenance, Tectonic Setting, Paleoclimate and Depositional Paleoenvironment

The geochemistry, provenance, tectonic setting, paleoclimate and depositional paleoenvironment of Maastrichtian clastic sedimentary rocks from the western flank of Cretaceous-Tertiary intracratonic Anambra Basin, Nigeria have been studied through major and trace element geochemical analysis. Ten (10) representatives outcrop samples collected from two stratigraphic sections in the study area were analyzed chemically using Inductively Coupled Plasma Atomic Emission Spectroscopy, ICP-AES (Lithium Borate Fusion). The geochemical data shows that the sediments are enriched in major oxides including SiO2, Al2O3, Fe2O3 and TiO2 but depleted in other major element oxides. Also, the sandstones have higher concentrations in SiO2, CaO and Na2O compared to the associated mudrocks whereas the mudrocks are more enriched in Al2O3, Fe2O3, MgO, K2O, TiO2 and P2O5 compared to the sandstones. The mudrock samples have higher concentration of Ba, Ni, Sr, Y, Nb, Sc in comparison to sandstones. However, sandstone samples have higher concentration in Zr (1098.50 ppm) than the mudrocks (1038 ppm). The sandstones are classified as litharenites, sublitharenites, Fe-rich sandstones, while the mudrocks are labeled as shale and Fe-rich shale based on chemical composition. Analysis of the data shows a dominantly felsic igneous to intermediate igneous and quartzose sedimentary provenances of mixed granite and granodiorite composition as indicated by various discriminant plots. The inferred provenance is corroborated by the low concentrations of Cr, Ni and Sc in the samples and other proxies. On the basis of various tectonic setting discriminant function diagrams, the Maastrichtian sediments from the study area were deposited on passive margin tectonic setting that developed consequent to the breakup of Gwandana supercontinent but was later affected by tectonism in Santonian times. The alteration feldspars to smectite and kaolinite as depicted by the A-CN-K ternary diagram alongside the high values of chemical index of alteration (CIA, 87.38 - 98.09) and chemical index of weathering (CIW, 89.22 - 99.90) indicates paleogeographic setting characterized by warm and humid/tropical paleoclimatic condition where there was prevalence of intense chemical weathering. The low values of Sr/Ba ratio (0.31 - 0.70) suggest sediment deposition in continental to deltaic paleoenvironment.

Geochemical characterisation of the

The geochemistry of the <2 μm fractions of Cretaceous-Tertiary Kaolins from Eastern Dahomey and Niger Delta Basins, Nigeria was investigated to infer their paleoenvironment, provenance, and tectonic settings using major, trace, and rare earth elements (REE). Twenty-eight (28) samples comprising of fifteen (15) Cretaceous and thirteen (13) Tertiary kaolins, respectively, were collected. Geochemical compositions of the <2 μm fractions were obtained using X-ray fluorescence (XRF) Spectrometry and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICPMS) analytical methods. Weathering indices such as chemical index of alteration (CIA, 96.98–99.39) and chemical index of weathering (CIW, 98.95–99.89) suggested intense chemical weathering under a wet tropical climatic condition. Ni/Co, V/Ni ratios and bivariate plot of V versus Ni indicated that they were deposited under marine oxygen-poor environment which is consistent with the horst and graben structural framework model of the Eastern Dahomey and Niger Delta Basins. The major, trace and REE data suggest that these deposits were derived from predominantly felsic source rocks with contributions from intermediate source rocks. The geochemical discrimination plots showed that the Cretaceous and Tertiary kaolins have been deposited in passive margin tectonic settings.

Geochemistry of Sandstone Type Uranium Deposit in Tarat Formation from Tim-Mersoi Basin in Northern Niger (West Africa): Implication on Provenance, Paleo-Redox and Tectonic Setting

The study aimed at investigating the geochemistry of a sandstone-type uranium deposit in Tarat formation for provenance, paleo-redox, tectonic setting in order to propose a geological model of uranium. X-Ray Fluorescence (XRF) and Induced Coupled Plasma Mass Spectrometry (ICP-MS) analyses were used to determine the sandstone composition. Major, trace and rare earth element compositions of the sandstones have been investigated to determine their provenance, tectonic setting and the influence of weathering conditions. Field studies of Tarat formation revealed that a major accident N30° that can be interpreted as an extension of the Austriche accident ensures the controls of Tarat sedimentation and mineralization deposits and the presence oxidized zone and reduced zone indicate the direction of circulation of the mineralized fluids from West to East. The uranium mineralization is disseminated as pitchblende that gives a yellow color to the sandstone while, molybdenum mineralization gives a blue color to the sandstone. Results of the Geochemical analysis indicate that the sandstone-type uranium deposit of Taratis classified into Protoquarzite (i.e. lithearenite and sublitharenite), arkose, subarkose, wacke and quartz arenite and varied in their maturity. Their Rare Earth Elements (REE) pattern displays high light REE over heavy REE, flat HREE and a significant negative Eu and Ce anomalies and in general correlated well with the NASC and PAAS average composition. The source area may have contained quartzose sedimentary rocks. The geochemical data support deposition in reducing environment of arid to humid climatic conditions rich in organic matter affected by passive margin (PM) tectonic setting and the sediments are derived from felsic and mafic source rocks. Trace and REE data as well as the high values of the weathering indices: Chemical Index of Alteration (CIA), Plagioclase Index of Alteration (PIA) and Chemical Index of Weathering (CIW) suggest intermediate to extreme weathering conditions in the source area or during transportation. The studied sandstones are inferred as highly mature sediments evidenced from their high SiO2/Al2O3 > 1 and the presence of the ultra-stable clay minerals, smectite, kaolinite, chlorite and illite. Also the Th/U < 3 ratio suggests high uranium enrichment of Tarat sandstones over crust average composition. From the factor analysis of the analyzed sandstone, there is no direct relationship between organic carbon and uranium, indicating the absence of organo-uraniferous composite and a major source derived from felsic to the mafic rock of Air Massif. The mineralized fluids of circulating from west to east are usually capped and underlain by impermeable mudstone or clay-rich units and uranium mineralization occurs in the association U-Mo-Pb or U-Zn-Ni-Pb structurally controlled by the major fault in Azaoua lineament fault NS of Arlit in the West, the N70° Tin Adrar “faisceau” in the North, the N30° Mouron accident in the Southeast, N30 Autriche accident in the West and precipitated in areas of suitable reducing environment of arid to humid climatic conditions rich in organic matter affected by passive margin (PM) tectonic setting. The negative correlation of U-Th and U-Na in our samples indicates intense remobilization of uranium in Tarat formation.

The giant Upper Yangtze Pb–Zn province in SW China: Reviews, new advances and a new genetic model

In the western margin of the Yangtze Block, SW China, the Emeishan large igneous province (ELIP) is spatially associated with >400 carbonate-hosted epigenetic Pb–Zn deposits. These deposits form the giant Upper Yangtze Pb–Zn metallogenic province with >20 Mt base metals. In the southeastern part of this province, the important Pb–Zn deposits include those of the Yinchangpo, Yunluhe, Maozhachang, Tianqiao, Banbanqiao, Mangdong, Shaojiwan, Liangyan, Qingshan, Shanshulin, Nayongzhi and Guanziyao deposits. Sulfide ore bodies in these deposits are (i) hosted in late Ediacaran to middle Permian limestone, dolomitic limestone and dolostone; (ii) structurally controlled by reverse fault-anticline tectonic systems; and (iii) spatially associated with the ELIP flood basalts and mafic dikes, and early Permian, early Carboniferous and early Cambrian organic matter-rich black shales. C–O isotopic compositions suggest that dolostone and limestone, mantle-derived rocks of the ELIP, and sedimentary organic matters supplied C–O to the hydrothermal systems through water/rock (W/R) interaction. New and existing S isotopic compositions of sulfides imply multiple sources of S and the reduction of sulfate through both abiotic thermochemical (TSR) and bacterially mediated (BSR) processes. Zn isotopes indicate that the sources of Zn were most likely related to the ELIP with various contributions from sediments and basements locally. Pb isotope signatures are suggestive of derivation of Pb from basements and sedimentary rocks with variable influences from the ELIP. Sr isotopes support that mantle-derived rocks, sediments and basements were involved in Pb–Zn mineralization, and they have various contributions in different deposits. We consider that the Pb–Zn deposits in the Upper Yangtze province are the mixed products of multiple S species-bearing solutions and metal-rich fluids, both of which were derived from, flowed through or interacted with multiple lithostratigraphic units in the western Yangtze Block. The change of tectonic regimes from extension to compression after eruption of basalts of the ELIP, and then to extension during Early Mesozoic, facilitated extraction, migration, and excretion of ore-forming metals and associated fluids. Mixing of fluids and reduction geochemical barrier activated TSR, causing cyclical carbonate dissolution, CO2 degassing and recrystallization (namely carbonate buffer). All these processes triggered continuous precipitation of huge amounts of hydrothermal minerals. Underplating and eruption of ELIP basalts provided heat flow, fluids and volatiles, whereas the basalts acted as an impermeable and protective layer, and even as ore-hosting rocks. These Pb–Zn deposits have spatial and genetic association with igneous activities of the ELIP, and are characterized by high ore grades (>10 wt% Pb + Zn), high concentrations of associated metals (e.g. Cu, Ag, Ge, and Cd), and medium-low temperatures (usually < 300 °C) and salinities (commonly < 20 wt% NaCl equiv.), all of which are significantly different from those of typical Mississippi Valley-type (MVT) deposits. Hence, the carbonate-hosted epigenetic Pb–Zn deposits in the Upper Yangtze metallogenic province representing to a new type of Pb–Zn deposits that are hosted in platform carbonate sequences and formed within compressional zones of passive margin tectonic settings.

Depositional environments, provenance and paleoclimatic implications of Ordovician siliciclastic rocks of the Thango Formation, Spiti Valley, Tethys Himalaya, northern India

Recently published findings indicate that the Ordovician period has been much more dynamic than previously anticipated thus making this period significant in geological time. The Ordovician of India can best be studied in the Spiti region because the Spiti basin records the complete uninterrupted history of excellent marine sedimentary rocks starting from Cambrian to Paleogene which were deposited along the northern margin of India. Due to these reasons the geochemical data on the Ordovician rocks from the Spiti region is uncommon. The present geochemical study on the Ordovician Thango Formation (Sanugba Group) is mainly aimed to understand the provenance and the paleoclimatic conditions. The sandstones are the dominant lithology of the Thango Formation with intercalations of minor amount of shales. Detailed petrographic and sedimentological analysis of these rocks suggest that three major depositional environments, viz., fluvial, transitional and marine prevailed in the basin representing transgressive and regressive phases. The major and trace element ratios such as SiO2/Al2O3, K2O/Na2O and La-Th- Sc discrimination diagram suggest that these rocks were deposited in passive margin tectonic settings. Various geochemical discriminants and elemental ratios such as K2O/Na2O, Al2O3/TiO2, La/Sc, Th/Sc, Cr/Th, Zr/Sc, (Gd/Yb)N and pronounced negative Eu anomalies indicate the rocks to be the product of weathering of post-Archean granites. The striking similarities of the multi-elemental spider diagrams of the studied sediments and the Himalayan granitoids indicate that sediments are sourced from the Proterozoic orogenic belts of the Himalayan region. Chemical index of alteration (CIA) values of the studied sediments (55–72) suggest that the source rocks underwent low to moderate degree of chemical weathering. The span of the CIA values (55–72) recorded in the sediments from the Spiti region may have resulted from varying degrees of weathering conditions in the source area. This, in turn, reflects variable climatic conditions prevailing during the Ordovician period, which is consistent with the global studies. The high CIA values observed by numerous studies on siliciclastic sediments may imply warm paleoclimate attributed to an increase in atmospheric carbon dioxide and/or methane levels inducing an acidic weathering environment and enhanced silicate weathering. While the low CIA values indicates prevalence of arid-glacial conditions where negligible chemical alteration is possible. This study documents the noteworthy events like fluctuating (rise and fall) atmospheric CO2 and sea levels during the Ordovician period, a conclusion which is consistent with the other such studies on the Phanerozoic glaciation (or mass extinction) events on Gondwana supercontinent.

Geochemistry of Archean Radioactive Quartz Pebble Conglomerates and Quartzites from western margin of Singhbhum-Orissa Craton, eastern India: Implications on Paleo-weathering, provenance and tectonic setting

Lenses of radioactive Quartz Pebble Conglomerates (QPC) and associated quartzites are exposed along western margin of Archean Bonai Granite in Singhbhum-Orissa Craton, eastern India intermittently spreading over a strike length of 8–10km. QPCs are radioactive while quartzites are mostly non-radioactive in nature. The purpose of the research is to investigate and characterize the radioactive QPC and quartzites geochemically to decipher their paleo-weathering conditions, provenance characteristics and possible tectonic setting of deposition. Geochemical data suggest moderate to high chemical weathering conditions in the provenance areas of QPC and quartzites. Major, trace and REE data indicate predominantly felsic to partly mafic-ultramafic sources for the deposition of radioactive Quartz Pebble Conglomerates from the surrounding Archean terrain.Elevated values of Th, U, Pb, La, Ce, Y and low Sc with high critical trace elemental ratios of Th/Sc, La/Sc, Th/Cr and Zr/Sc in radioactive QPC indicate their derivation from felsic igneous source. Low concentration of Th and Sc in quartzites compared to QPC and their variable Th/Sc ratios indicate both felsic and mafic sources for quartzites, albeit their preferential felsic affiliation. Higher Cr/Th ratios in quartzites (18.4), moderate Cr/Th in QPC (5.42), low to moderate Y/Ni in QPC (0.36–12.4) and quartzite (0.29–1.88), along with Au ranging from 30 to 1527ppb, Pt up to 188ppb and 682ppb in QPC and quartzites respectively point towards some contribution from mafic-ultramafic source as well. REE patterns and in particular negative Eu anomalies for both QPC and quartzites further support their derivation from felsic rocks and could possibly linked to some of the phases of Archean Singhbhum Granite and Bonai Granite. Granitic to pegmatitic source for QPC is also revealed by the presence of rounded to sub-rounded monazite, zircon and thorian-uraninite grains in their matrix. Study indicates that QPC and quartzites were deposited in a passive margin tectonic setting developed during Archean between a span of 3.3 and 3.16Ga along the western margin of Bonai Granite when the reducing condition was prevalent as indicated by their low Th/U ratios (<4.0) and presence of detrital grains of uraninite and pyrite in QPC. Radioactive QPC from western margin of Archean Singhbhum-Orissa Craton bears broad resemblance with QPC from Witwatersrand basin of South Africa and Elliot Lake, Canada and thus appears to be ideal sites for exploring QPC hosted U (+Au-PGE) mineralization in the analogous areas.