Passive Zone Research Articles

Potential Use of Municipal Solid Waste Pile in Segawe Landfill (Tulungagung Regency, Indonesia) as Raw Material for Refuse Derived Fuel

The Segawe municipal solid waste (SW) landfill in Tulungagung Regency, Indonesia, has currently exceeded its capacity. This study aimed to determine the potential use of dumped SW at the landfill as raw material for the production of refuse derived fuel (RDF). Buried SW samples were collected at a passive zone of the landfill in six locations. The samples were sieved using 10 and 30 mm mesh sieves. A composition analysis was conducted following the ASTM D5231-92 method to sample fractions of greater than 30 mm size. The density was measured according to the weight and volume. The moisture and volatile matter contents were analyzed using the ASTM D2216-10 and D3175-07 methods, respectively. The calorific value was measured using a Parr C3000 bomb calorimeter following the ASTM D5865 method.The buried SW composition was dominated by a fraction size that was greater than 30 mm (79.4%). This fraction was dominantly composed of plastics (71.2%) and had average volatile matter and calorific values which met RDF criteria as a fuel. However, the ash and moisture contents exceeded the standards and, therefore, required appropriate treatments before their applications.

Effect of static magnetic field on corrosion of X70 pipeline steel in dilute sodium bicarbonate solutions

This paper focuses on the effect of a 0.1 T static horizontal magnetic field on the corrosion of X70 pipeline steel in 0–0.05 mol/L sodium bicarbonate solutions. The weight loss data indicate that the magnetic field reduces the average corrosion rate during immersion within 48 h in all the test solutions. The magnetic field tends to increase the average corrosion rates for the immersion time of 72 h and 96 h. The magnetic field increases the proportion of magnetite in corrosion products formed on the specimen of immersion in 0.05 mol/L sodium bicarbonate solution for 168 h. The open-circuit potentials (OCP) are in the active zone of the E-pH diagram within 48 h immersion with 0 T and 0.1 T magnetic field. A 0.1 T magnetic field delays the process for the electrode to enter the passive zone of the E-pH diagram. The linear polarisation resistance (LPR) data shows that the resistance of the active zone with 0.1 T magnetic field is larger than that with 0 T. The electrochemical impedance results also indicate that the electrode is in an active state when the potential is below −700 mVSCE and in a passive state when the potential is above −200 mVSCE.

Effect of Nitrogen on Precipitate Characteristics and Pitting Resistance of Martensitic Stainless Steel.

High-carbon-chromium martensitic stainless steel (MSS) is widely used in many fields due to its excellent mechanical properties, while the coarse eutectic carbide in MSS deteriorates corrosion resistance. In this work, nitrogen was added to the MSS to improve corrosion resistance. The effects of nitrogen on the microstructure and corrosion resistance of MSS were systematically studied. The results showed that the addition of nitrogen promoted the development of Cr2N and reversed austenite, effectively inhibiting the formation of δ-ferrite. Therefore, the durability of the passivation film was improved, the passivation zone was expanded, and the susceptibility to metastable pitting was decreased. As a consequence, nearly two orders of magnitude have been achieved in the pitting potential (Epit) of MSS containing nitrogen, and the polarization resistance value (Rp) has gone up from 4.05 kΩ·cm2 to 1.24 × 102 kΩ·cm2. This means that in a corrosive environment, nitrogen-treated MSS stainless steel is less likely to form pitting pits, which further extends the service life of the material.

A bilateral semi-resolved CFD-DEM approach for cost-effective modelling in a rotary drum

It is of significance to numerically describe particle-flow interphase flow details at a feasible computational cost. Inspired by the semi-resolved Computational Fluid Dynamics-Discrete Element Method (CFD-DEM), an improved bilateral semi-resolved CFD-DEM approach (BSM) approach is developed in this work. Compared with the conventional divided particle volume method (DPVM) and recent semi-resolved CFD-DEM (SM) approach, the BSM approach allows a higher-resolution mesh and achieves higher accuracy as well as applicability when simulating the transient flow with sharp gradients of solid volume fraction and velocity etc. Then the BSM approach is applied to a rotary drum to demonstrate the effectiveness by investigating the internal hydrodynamics details. The typical flow behaviours are detailed; then the effects of the restitution and friction on the internal flow are analysed with details to demonstrate its effectiveness in terms of repose angle, active–passive zone, solid residence time, particle mixing and axial dispersion. The results show a positive correlation of the active depth, mixing degree, and particle dispersion with the friction, while restitution increasing depicts no significant effects on this particulate flow. This work provides an improved numerical tool for understanding the multiphase transient flows involving sharp gradients.

Method for calculating the bearing capacities of caisson foundations considering the effects of caisson construction

Theoretical analysis of the effects of caisson on the bearing capacities of large caisson foundations was performed, with the slip line simplified as a polyline. Based on the limit balance of forces in active zone, transition zone and passive zone, a simplified bearing capacity algorithm for caisson shaft wall or partition wall with no buried depth and no excavation is established. The effects of caisson excavation on the caisson foundation bearing capacity were examined, and a theoretical formula for estimating the caisson shaft wall or partition wall bearing capacity considering the effects of the angle and depth of excavation was derived. At the same time, the influence of soil weight and the extension of soil slip line from the bottom of the foundation to the surface on the bearing capacity of the foundation is analyzed when there is a certain buried depth between the shaft wall and the partition wall, and a formula for calculating the bearing capacities of buried caisson foundations was proposed. According to the calculation method of caisson shaft wall or partition wall proposed in this paper under the condition of no buried depth and no excavation, combined with the world’s largest north anchor caisson project of Wufengshan Yangtze River Bridge, the plate loading test and inversion analysis are carried out. The results of the test and the simplified calculation method of foundation bearing capacity are in good agreement, and the error of the inversion value and the theoretical calculation value are within 5%. For the theoretical calculation method of foundation bearing capacity considering foundation excavation and buried depth, experiments, inversion analysis or numerical simulation will be carried out to verify the accuracy of the calculation method.

Effect of rare earth element Y content on microstructure, magnetic properties, and electrochemical properties of the as-annealed FeCoNiAl0.2Yx high-entropy alloys

FeCoNi high-entropy alloy (HEA) is widely used in the aerospace and chemical industry. However, the strength and corrosion resistance of the alloy still need to be improved. In this paper, FeCoNiAl0.2Yx (x = 0, 0.05, 0.1, 0.2, and 0.3 in mole ratio) high entropy alloys with different contents of rare earth (RE) element yttrium (Y) were prepared by the vacuum arc melting method, and then the alloys were subjected to annealing treatment at 800 °C/2h. The microstructure, hardness, magnetism, and corrosion performance of FeCoNiAl0.2Yx HEAs in the annealed state with different contents of element Y were analyzed. The results show that the annealed FeCoNiAl0.2Yx HEAs without the addition of element Y and after the addition of element Y both were composed of a face-centered cubic phase. The alloy showed a dendritic structure inside. The element Y was solidly dissolved in the alloys to refine the microstructure of the alloys, and the dendrites were gradually refined with the addition of Y. The Y element caused the phenomenon of lattice distortion inside the alloys, which led to the increase in the alloys’ hardness. The alloy with x = 0.2 showed the greatest exchange of magnetic atoms and the alloy with x = 0.05 showed the lowest coercivity. The alloy with x = 0.1 showed the lowest self-corrosion current density, the broadest passivation zone, the densest dendrites, the smallest grain spacing, and the weakest tendency for intergranular corrosion. The present study shows that the introduction of element Y improves the microstructural morphology, hardness, magnetism, and corrosion properties of FeCoNiAl0.2Yx HEAs in the annealed state.

Exploration of the polypropylene degrading bacteria candidates from the passive zone of the Supit Urang landfill in Malang city by using the next generation sequencing (NGS) method

Exploration of the polypropylene degrading bacteria candidates from the passive zone of the Supit Urang landfill in Malang city by using the next generation sequencing (NGS) method

Influence and Mechanism of the Excavation Width on Excavation Deformations in Shanghai Soft Clay

This study investigated the influence and mechanism of the excavation width on excavation deformations in Shanghai soft clay. Based on three excavations that had different final excavation depths, dissimilar retaining structures and diverse geological conditions, 40 sets of two-dimensional numerical models with different excavation widths were employed to analyze the deformation rules affected by the excavation width. Moreover, a series of simplified models with different excavation widths were employed to analyze the effect of the excavation width on excavation deformations. The results show that under the same excavation depth, both the horizontal displacements of the retaining walls and ground surface settlements increase as the excavation width increases, but the increasing rate gradually decreases. Factors such as the unloading influence depth, the overlap degree of the passive zones, the stress state of the basal soils and the development of the relative shear stress have a significant influence on excavation deformations. With increasing excavation width, the unloading influence depth gradually deepens, the overlap area of the passive zones gradually decreases, the direction of the rotation of the major principal stress gradually reduces and the relative shear stress of the distant and deep soils gradually expands. Therefore, the constraint ability of the passive zones on excavation deformation gradually reduces and excavation deformations gradually increase.

Experimental study on stress and deformation characteristics of foundation pit considering excavation width using 3D printing technology

A sophisticated model of the foundation pit support structure was developed via a model test that incorporated 3D printing technology. A meticulously scaled-down simulation of foundation pit excavation was conducted, utilizing the excavation width of the foundation pit as the sole variable, to evaluate and compare the impact of various foundation pit widths on the force and deformation characteristics of the foundation pit following layer-by-layer excavation. The findings indicate that the stress and deformation characteristics of the retaining structure shift from the “cantilever” mode to a composite mode of “internally convex” or “concave-convex” as the pit is excavated and internal support is installed. The change in pit width has minimal influence on the mechanical response law of the support structure during excavation. Nonetheless, the alteration in the pit width had a direct effect on both the internal force and deformation of the support structure, as well as the change in surface settlement value. In the experiment, wider pits had monitoring values that increased multiple times compared to narrower pits. The width of the foundation pit has a considerable impact on the mechanical response and stability of the pit, which is evident in the relatively lower lateral earth pressure on the outside of the retaining structure in narrower pits. This results in less stress and deformation of the pit structure. Moreover, the decrease in the passive zone of the pit contributes to better stability, indicating that the lower lateral earth pressure on the outside of the retaining structure is an innate reason for the excellent stability of narrower pits.

Corrosion Behavior of Carbon Steel in LiCl/H2O Mixtures

The corrosion behavior of 1018 carbon steel in LiCl/H2O mixtures has been evaluated by using potentiodynamic polarization curves, electrochemical noise and electrochemical impedance spectroscopy techniques. Two different concentrations of LiCl were employed, namely 35 and 40 wt. %, and the testing temperatures included 25, 35 and 70 °C. It was found that the steel showed a passive zone; the corrosion current density value increased with an increase in the solution temperature and concentration. The pitting potential value decreased with an increase in the testing temperature and the solution concentration. The corrosion process was under charge transfer control. This mechanism was unaltered either by the solution temperature or concentration. The charge transfer resistance value decreased with an increase in both the solution temperature and concentration. A localized, pitting type of corrosion dominated the corrosion morphology at 25 and 35 °C, whereas at 70 °C, the main type of attack was a mixed type of corrosion.

Effect of ultrasonic vibration-assisted laser cladding frequency on the microstructure and properties of Fe-0.5C-15Cr alloy cladding layers

In this paper, Fe-0.5C-15Cr wear and corrosion resistant alloy coating was prepared on 3Cr13 stainless steel surface by ultrasonic vibration assisted laser cladding technology. The effects of ultrasonic vibration frequency on the microstructure, microhardness and corrosion resistance of the coating were studied. The results show that the length of the dendrites of the cladding layer decreased significantly after ultrasonic vibration is applied, the grains size is refined significantly, and the morphology of the grain boundary carbides changed from fishbone-like to short rods, when the vibration frequency is 20.2 kHz, the grain refinement is the most significant, and the orientation of the dendrites is obviously weakened. The hardness of the applied ultrasonic vibration specimens increased by 10–20 HV0.2 relative to the non-ultrasonic specimens, with the increase of vibration frequency, the hardness of the cladding layer firstly increased and then slightly decreased, and the peak appeared at 20.2 kHz. The coefficient of friction of the specimens when the ultrasonic frequency of 20.2 kHz is applied is lower than that of the specimens with non-ultrasonic frequency by 12.8 %, and the abrasive wear rate is reduced by 14.3 %. After ultrasonic vibration, the pitting potential of the cladding layer increases, the dimensional passivation current density decreased, the width of the passivation zone becomes wider, and the intergranular corrosion reactivation rate decreased, When the ultrasonic frequency is 20.2 kHz and 20.4 kHz, the pitting corrosion resistance and intergranular corrosion resistance of the cladding layer are significantly improved. This is because the cavitation effect, resonance effect and acoustic flow effect of ultrasonic vibration promote the non-uniform nucleation, refine the dendrites and intergranular carbides, and promote the redistribution of the corrosion-resistant element Cr in the in-grain martensite and grain boundary carbides, increasing the content of Cr in the matrix, and thus improving the wear resistance and corrosion resistance of the cladding layer.

Low Temperature Interface Modification: Electrochemical Dissolution Mechanism of Typical Iron and Nickel Base Alloys

<p>Due to its unique advantages, electrochemical machining (ECM) is playing an increasingly significant role in the manufacture of difficult-to-machine materials. Most of the current ECM research is conducted at room temperature, with studies on ECM in a cryogenic environment not having been reported to date. This study is focused on the electrochemical dissolution characteristics of typical iron and nickel base alloys in NaNO<sub>3</sub> solution at low temperature (−10°C). The polarization behaviors and passive film properties were studied by various electrochemical test methods. The results indicated that a higher voltage is required for decomposition and more pronounced pitting of their structures occurs in the passive zone in a cryogenic environment. A more in-depth study of the composition and structure of the passive films by X-ray photoelectron spectroscopy and electrochemical impedance spectroscopy showed that the passive films of the alloys are modified at low temperature, and their capacitance characteristics are more prominent, which makes corrosion of the alloys more likely to occur uniformly. These modified passive films have a huge impact on the surface morphologies of the alloys, with non-uniform corrosion suppressed and an improvement in their surface finish, indicating that lowering the temperature improves the localization of ECM. Together with the cryogenic impact of electron energy state compression, the accuracy of ECM can be further improved.</p>

Assessment of soil constitutive models for predicting seismic response of sheet pile walls: A LEAP-2022 project study

This paper outlines the findings derived from a study conducted within the LEAP-2022 project, focusing on analyzing the seismic response of a sheet-pile retaining structure that supports liquefiable soils. The primary objective is to assess the efficacy of two distinct constitutive models–Manzari-Dafalias (MD) and PM4Sand–following their calibration utilizing element tests conducted on Ottawa-F65 sand. By employing these calibrated models, finite element models are generated to emulate centrifuge experiments. The results indicate that both the MD and PM4Sand models adequately capture the behavior of liquefiable soils and consequent wall displacements. Furthermore, the study emphasizes the significance of accurately calibrating for cyclic stress demands at the wall’s toe and the passive zone to precisely predict wall behavior. It also highlights that number of cycles has a significant effect on simulation results.

Corrosion behavior and oxide layer of selective-laser-melted Al-Mg-Sc-Zr alloy in marine atmospheric environment with different Cl−concentration

In this study, the corrosion response of the Al-Mg-Sc-Zr alloy produced by selective laser-melting in marine atmospheric environments with different Cl− concentrations was studied by electrochemical and immersion. Microstructural observations showed the microstructural of Al-Mg- Sc -Zr alloy featured a double grain microstructure, making up a coarse and fine grain area. TEM showed that some white precipitates enriched with Zr and Sc were dispersed in the samples. The potentiodynamic polarization test indicated increasing the Cl− concentration led to a negative shift of corrosion potential and narrowed the potential range of the passive zone, which also caused the increase of corrosion current density value. The electrochemical impedance spectroscopy showed that higher Cl− concentration was greatly detrimental to generating a compact and dense oxide film on the Al-Mg-Sc-Zr alloys, as indicated by decreasing the resistance of the corrosion product layer and charge transfer resistance. The immersion test demonstrated that the samples suffered serious pit corrosion when the Cl− content increased to 1.5 and 3.5 wt%, showing a larger size and more depth of corrosion pits. This study is expected to provide data to determine the reliability of the SLM-manufactured Al-Mg-Sc-Zr alloy in marine atmospheric conditions.

Mechanically Stabilized Earth (MSE) retaining wall at hotel in Bariloche City

In the city of Bariloche, Argentina after heavy rains, among other things, a slope failure occurred. At the top of it there were gabions, which, due to the loss of stability, together with a large mass of soil and trees, collided tragically against the facilities of the Hotel. This article describes the use of geosynthetics for the construction of a 20m high MSE (Mechanically Stabilized Earth) retaining wall in order to contain the slope soil. At the same time, the consequent drainages for water runoff and the release of hydrostatic pressures needed to be considered. Instead of gabions, a wall made of prefabricated concrete blocks was proposed, along with PVA geogrids for slope stabilization and soil reinforcement. Due to the large size of the slope, a stepped wall with six terraces was proposed, which would later be naturally vegetated. Each wall was locally dimensioned for a specified height, and then a global stability verification of the structure was carried out.The inclusion of geosynthetic reinforcements in the soil for the construction of a reinforced wall results in a material with better mechanical characteristics. This solution offers significant technical and economic advantages, increasing the shear strength of the system (ensuring stability), reducing the deformability of the structure (both in static and seismic conditions), and saving construction time and material. Thanks to their excellent interaction properties, reinforcement geosynthetics (flexible elements with stiffness and tensile strength) work together with the soil, connecting the potentially "unstable" region (active zone) with the "stable" region (passive zone) for a given failure surface. Furthermore, the system flexibility and adaptability allowed the structure to be adapted in an aesthetic way, respecting the site architecture and environment.

Case Analysis of Water Gushing in a Deep Foundation Pit Caused by Local Defects.

Water gushing is a common engineering geological disaster in the process of foundation pit construction. Its successful judgment directly affects the safety of engineering construction. Taking the case of water gushing at the bottom of the foundation pitas as a research object, the mechanism and treatment of water gushing in foundation pits, the stability against water gushing, and its influencing factors are analyzed with a field investigation, field testing, and theoretical calculation. The calculation formula for the safety factor and critical thickness of the foundation pit against surges, considering the influence of multiple factors, is deduced. The influence of the height of the confined water level, the thickness of the water-resisting layer, the shear strength of the soil mass, the reinforcement depth of the soil mass in the pit, and the diameter of the bearing pile in the pit on the safety factor of the foundation pit surge are expounded. In addition, measures such as the reinforcement of the soil mass in the passive area in the pit, the increase in the thickness of the water-resisting layer, and the reduction in the confined water level are proposed to improve the anti-surge stability of the foundation pit. A new monitoring method is proposed for characterizing uplift deformation at the bottom of the pit without affecting normal construction. The research results show that: (1) the minimum safety factor against surges, considering multiple factors, is 1.455, and the critical thickness is 5.87 m, which is in line with specifications. (2) Measures such as reinforcing the soil in the passive zone of the pit, increasing the thickness of the water-insulating layer, and lowering the bearing pressure level are used to improve the stability of the pit against surges. (3) The pit, obtained by the pit bottom counter-pressure, pumping water out of the pit, and the timely construction of the pit bottom bedding to block the program, exhibits a measured maximum bottom plate pressure of 115.189 kPa, and the deformation corresponding to the method proposed in this paper is 1.406 mm, which is better disposed in the field. The research results provide a reference basis for the judgment of anti-surge stability of foundation pits and similar engineering applications.

Tailoring the amorphous-nanocrystalline structures of TiNbZrNx films towards improving the anti-corrosion and mechanical properties by controlling nitrogen flow ratio

Multi-principal element alloy (MPEA) films demonstrate superior corrosion resistance and tribological properties, which have substantial potential for applications in marine engineering equipment. In this study, the TiNbZrNx MPEA nitride films were successfully deposited on 316 L austenitic stainless steel by direct current (DC) magnetron sputtering at various nitrogen flow ratio (RN2). The phase, composition, microstructure, corrosion and mechanical behaviors were investigated in detail. The results showed that the phase transitioned from amorphous to amorphous/nanocrystalline as RN2 increased. The TiNbZrNx films deposited at RN2 = 0.15–0.4 exhibited better corrosion performance in the electrochemical and salt spray tests. The RN2 = 0.4 film presented the optimal corrosion resistance, with the lowest self-corrosion current density (0.249 μA/cm2) and the largest passivation zone (from OCP to >1.2 VSCE). The amorphous/nanocrystalline film deposited at RN2 = 0.2 showed a remarkable nanohardness of 7.03 GPa and adhesion strength of 18.86 N. The strengthening effect can be attributed to the interstitial dissolution of nitrogen atoms among the metal atoms. The formation of nitride nanocrystalline phases and the existence of interfaces can effectively improve the plastic deformation ability of amorphous alloy films. This work provides theoretical guidance for the development of MPEA nitride films with tunable properties for key moving parts in marine equipment.

Soil deformation under cyclic horizontal load in sand: Insights from experiments

In addition to making a significant contribution to the reduction of carbon emissions, the offshore wind industry has played a significant role in the production of green energy. However, the foundation of offshore wind turbines is threatened by extreme wave loads in the long-term during normal service. Such loads alter the strength and stiffness of surrounding sand affecting the ultimate capacity and serviceability of the pile foundation. To explore the interaction mechanism between pile and soil, this study combines a model test system with Particle Image Velocimetry (PIV) to study the deformation and stiffness degradation characteristics of the soil around piles under wave loading. The results indicated that the behaviors of the horizontal displacement at the pile top remain consistent regardless of the different triggers, and their general performance can be divided into three stages: linear, sluggish-growth, and stable-deformed stage. Furthermore, the deformation fields of passive zone soil mass exhibit a wedge-shaped distribution, while active zone soil shows significant differences under different loading conditions. In this study, the stiffness degradation model of the soil around the pile was optimized, and the calculated results are in good agreement with the experimental results. The model can be used to evaluate the stiffness degradation of soil under wave loading, and the research results can provide references for designing monopile foundations for offshore wind turbines.

Effect of pH on corrosion behaviour of CoCrNi MEA imposed by alternating current in Na2CO3/NaHCO3 solution

ABSTRACT The corrosion behaviour and mechanism of CoCrNi medium-entropy alloy (MEA) imposed by alternating current (AC) in HCO3 −/CO3 2− solution with various pH were systematically investigated via a series of corrosion tests. The results showed that with the augment of pH value, the polarisation resistance of the MEA decreased significantly, Ep shifted negatively, and ipI value increased, as well as corrosion rate was enhanced, revealing that the corrosion resistance was weakened. As solution pH increased, the formation of secondary passivation zone became easier, which may be attributed to the reaction conversion process of Cr(III) to Cr(VI) species. Moreover, the increase in pH led to an increase in defect density and a thinning of passivation film, facilitating the corrosion of the MEA. AC interference accelerated the ion exchange process and promoted the formation possibility of stable pitting. Higher iAC and pH inhibited the repassivation of metastable pitting, and increased the pitting susceptibility. Highlights The effect of pH on the corrosion behaviour of CoCrNi MEA with imposed AC was clarified. High pH and iAC accelerated the nucleation and growth of metastable pits. With increased pH and iAC, the stability and protective ability of passive film were weakened. The secondary passivation of the MEA was mainly due to the conversion of Cr(III) to Cr(VI) species.

Electrophoretic Deposition of Chitosan–Hydroxyapatite Films and Their Electrochemical Behavior in Artificial Plasma

The electrochemical behavior of chitosan–hydroxyapatite films deposited on Ti CP was evaluated. Hydroxyapatite was synthesized from eggshell at different precipitation pH conditions. The films were deposited on the Ti CP surface from chitosan–hydroxyapatite solutions by means of electrophoretic deposition. The hydroxyapatite content of the solutions varied from 0 to 20 g/L. The different films obtained were evaluated by means of electrochemical measurements such as polarization curves, open circuit potential measurements, polarization resistance, and electrochemical impedance. The results obtained showed that regardless of the precipitation pH, it is possible to obtain pure hydroxyapatite from a waste such as eggshell. The incorporation of hydroxyapatite within the chitosan structure allows for improvement of the electrochemical performance of the bare Ti CP surface. It was observed that the passive zone was achieved at lower current densities, and that the stability zone of the passive layer increased. Electrochemical impedance analyzes showed that there is an improvement in corrosion resistance due to a more controlled growth of the passive layer that allows for the formation of a dense and compact film.