Resonant Particles Research Articles

Improving the thermochromic performance of VO2 films by embedding Cu-Al nanoparticles as heterogeneous nucleation cores in the VO2/VO2 bilayer structure

VO2-based films show great potential applications in thermochromic smart windows. However, enhancing luminous transmittance (Tlum) while maintaining high solar modulation ability (ΔTsol) remains a formidable challenge. Here, we present a novel VO2/Cu-Al nanoparticles (NPs)/VO2 composite film structure, seamlessly integrating Cu-Al bimetallic NPs within VO2 films by pulsed laser deposition on alkali-free glass substrates. The content of Cu-Al NPs in the composite films is controlled by the pulse number (Np) applied to the Cu-Al alloy target. X-ray diffraction results indicate that the crystallinity of VO2 films is significantly enhanced by the incorporation of an appropriate amount of Cu-Al NPs. The SEM characterization results revealed that the particle size of VO2 composite films initially increases to approximately 131 nm and subsequently decreases to around 120 nm as Np increases, with a concurrent transition in particle shape from quasi-circular to elongated. The Tlum and ΔTsol of the resulting composite films were dramatically improved to 71.6 % and 9.5 %, respectively, when Np was 300. These enhanced thermochromic properties are attributed to the localized surface plasmon resonance (LSPR) of the VO2 particles. This research opens up a promising avenue for the convenient production of customized high-quality VO2 films tailored for smart window applications.

Flexible Hair‐Like Piezoelectric Acoustic Particle Velocity Sensor with Enhanced Sensitivity for Speaker Recognition

AbstractFlexible resonant acoustic sensors exhibit enhanced sensitivity near their resonant frequencies and have attracted increasing interest as essential components for next‐generation human‐machine speech interactions. However, membrane‐based resonant acoustic sensors are bulky owing to the inherently high bending stiffness of the sensing membrane. Inspired by the tiny hair‐based sensitive acoustic receptors of spiders, this study reports a hair‐like piezoelectric resonant acoustic particle velocity sensor (HP‐APVS) that enables highly sensitive sound sensing with a significantly reduced size. The HP‐APVS device is essentially a polyimide cantilever array fabricated using Nb0.02‐Pb(Zr0.6Ti0.4)O3 (PZT) on polyimide and self‐bending processes. The experimental results demonstrate that the HP‐APVS shows a linear response to acoustic particle velocity instead of acoustic pressure, with enhanced sensitivity in the resonance mode. Additionally, the proposed HP‐APVS exhibits an outstanding speaker recognition rate of 95.3% with an error rate reduction of 75% compared with that of a reference commercial microphone, indicating many potential applications in the realms of biometric authentication, voice user interfaces, and other intelligent acoustic electronics.

Trajectory error compensation method for grinding robots based on kinematic calibration and joint variable prediction

Trajectory accuracy, a crucial metric in assessing the dynamic performance of grinding robots, is influenced by the uncertain movement of the tool center point, directly impacting the surface quality of processed workpieces. This article introduces an innovative method for compensating trajectory errors. Initially, a strategy for error compensation is derived using differential kinematics theory. Subsequently, a robot kinematic calibration method utilizing ring particle swarm optimization (RPSO) is proposed to address static errors in the grinding robot. Simultaneously, a method for predicting robot joint variables based on a dual-channel feedforward neural network (DCFNN) is designed to mitigate dynamic errors. Finally, a simulation platform is developed to validate the proposed method. Simulation analysis using extensive data demonstrates an 89.3% improvement in absolute position accuracy and a 74.2% reduction in error fluctuation range, outperforming sparrow search algorithm (SSA), improved mayfly algorithm (IMA), multi-representation integrated predictive neural network (MRIPNN), etc. Algorithmic comparison reveals that kinematic calibration significantly reduces the average trajectory error, while joint variable prediction notably minimizes error fluctuation. Validation through trajectory straightness testing and a 3D printing propeller grinding experiment achieves a trajectory straightness of 0.2425 mm. Implementing this method enables achieving 86.1% surface machining allowance within tolerance, making it an optimal solution for grinding robots.

Investigation of dependent scattering criterion for dispersed particulate medium: Effects of metal particle plasmon resonances and host medium absorption

Spectral radiative transfer between particles within dispersed particulate medium is prevalent across various fields, which may be influenced by the microscopic dependent scattering effect (DSE). However, independent scattering assumption (ISA) is only employed in the radiative transfer of most studies, which can lead to significant errors. Consequently, there is an urgent need to establish the more accurate and widely applicable dependent scattering criterion for determining whether the radiative transfer is independent or dependent scattering. However, the most existing criteria are only applicable under the assumption of optically soft particles with weak absorption. This limitation results in the criteria being valid only for certain types of particles, excluding nonmetal particles with highly complex refractive indices and metal particles with strongly absorption. Furthermore, the existing criteria also fail to consider the impact of host medium absorption (HMA) on the localized surface plasmon resonance (LSPR) of metal particles and the DSE between particles. It would represent another significant limitation. To address these above limitations, this paper develops a comprehensive and systematic dependent scattering criterion with considering the plasmon resonances for metal particle and host medium absorption. The multiple sphere T-matrix (MSTM) method, generalized Mie scattering, and Monte Carlo ray tracing (MCRT) method are further employed to calculate and compare the radiative properties across different scales. The extinction cross section is the most suitable contrast parameter in the dependent scattering criterion with the consideration of host medium absorption. Clearance-to-wavelength ratio c/λ is used to characterize dependent scattering criterion. Consequently, the dependent scattering criterion c/λ for nonmetal particles is 6. While the dependent scattering criterion c/λ for metal particles is 5.5.

Nonlinear simulations of GAEs in NSTX-U

A set of nonlinear simulations has been performed in order to study the nonlinear evolution of unstable global Alfvén eigenmodes in the National Spherical Torus Experiment-Upgrade (NSTX-U). Results of the single toroidal mode number, n, simulations are compared with a full nonlinear simulation (all toroidal harmonics included). In single-n simulations, the conservation of two integrals of motion of a particle in a cyclotron resonance with a monochromatic wave is demonstrated, resulting in a one-dimensional evolution of the particle distribution in (E,μ,pϕ) phase-space. Nonlinear simulations (both single-n and full nonlinear) show a significant redistribution of the resonant fast ions, especially in the pitch parameter. Thus, the changes in the resonant particle's parallel and perpendicular energies can be several times larger than the total particle energy change, with only a small fraction transferring into the excitation of the mode itself. This implies that even a relatively small amplitude mode can significantly modify the beam distribution in the resonant region. For the NSTX-U case considered, the single-n simulation results are close to full nonlinear simulation only for the most unstable mode, in which case the saturation amplitudes and changes in the fast ion distribution are comparable. In contrast, peak amplitudes of subdominant modes in all-n simulations are smaller by a factor of 3–10 compared to single-n runs due to the flattening of the beam ion distribution by the fastest growing mode.

Optical manipulations without light forces: deep superlattice for trapping and rotation of impurity particles in a buffer gas

We propose a scheme to obtain a deep optical superlattice (OSL) for resonant impurity particles in a buffer gas. In contrast to the well-known traditional methods of forming optical lattices (supelattices) that are based on the gradient force of radiation pressure, the presented scheme is based on the effect of a light induced drift (LID) in interfering light waves. The principle of its operation is based on the conception of so-called rectified forces induced by interfering bichromatic optical fields, which was developed earlier in the theory of resonant radiation-pressure forces. In the scheme under consideration, a deep OSL (with a period much larger than the optical wavelength) is formed due to the action of the effective rectified force on atomic particles which is proportional to the difference between the frequencies of transport collisions of excited and unexcited particles with buffer gas atoms.

Electron microscopy of stable electrophoretic fractions of natural humic acids – the key to the understanding of their structural organization

Transmission electron microscopy (TEM) with contrast staining by uranyl acetate solution was used to study morphological differences between soil humic acids (HAs) and their A, B and C + D fractions obtained using coupling preparative low-pressure size exclusion chromatography and analytical polyacrylamide gel electrophoresis. The electrophoretic mobility of fractions varied in order C + D B A. The distribution of various morphological elements between fractions showed that large structures such as vesicle-like formations 70–150 nm long and 30–80 nm wide with clear edges were found exclusively in fraction A and occupied ~55% of the TEM image area. On the other hand, long fibrils with a length of 60–100 nm, a width of 4–6 nm and a thickness of 2–3 nm, as well as their bundles with a length of 150 nm and a diameter of 30–70 nm were identified only in the C + D fraction and occupied ~59 % area of TEM images. Smaller morphological elements such as point particles with a diameter of 2–3 nm, ring particles with a diameter of 4–6 nm, worm-shaped short particles with a length of 20–30 nm, and spheroids with a diameter of 10– 30 nm were observed in all samples, but in varying quantities. Significant morphological differences between the fractions can be explained by their composition, previously established by using a few physico-chemical methods. The ratio Car(165–108 ppm)/Calk(108–0 ppm), or aromaticity index, calculated from 13C-NMR, could be one of the indicators of the various morphological structures formation. The obtained TEM results clearly confirm the supramolecular organization of soil HAs.

The velocity-space signature of transit-time damping

Transit-time damping (TTD) is a process in which the magnetic mirror force – induced by the parallel gradient of magnetic field strength – interacts with resonant plasma particles in a time-varying magnetic field, leading to the collisionless damping of electromagnetic waves and the resulting energization of those particles through the perpendicular component of the electric field, $E_\perp$ . In this study, we utilize the recently developed field–particle correlation technique to analyse gyrokinetic simulation data. This method enables the identification of the velocity-space structure of the TTD energy transfer rate between waves and particles during the damping of plasma turbulence. Our analysis reveals a unique bipolar pattern of energy transfer in the velocity-space characteristic of TTD. By identifying this pattern, we provide clear evidence of TTD's significant role in the damping of strong plasma turbulence. Additionally, we compare the TTD signature with that of Landau damping (LD). Although they both produce a bipolar pattern of phase-space energy density loss and gain about the parallel resonant velocity of the Alfvénic waves, they are mediated by different forces and exhibit different behaviours as the perpendicular velocity $v_\perp \to 0$ . We also explore how the dominant damping mechanism varies with ion plasma beta $\beta _i$ , showing that TTD dominates over LD for $\beta _i > 1$ . This work deepens our understanding of the role of TTD in the damping of weakly collisional plasma turbulence and paves the way to seek the signature of TTD using in situ spacecraft observations of turbulence in space plasmas.

Analysis and design of compact dual-mode bandpass filter based on modified CSRR with wide stopband for 5G sub-6 GHz mobile communications

In this paper, a dual-mode bandpass filter with a wide stopband based on modified complementary split-ring resonators for 5G sub-6 GHz mobile communications is presented. The non-magnetic resonant particle known as a complimentary split ring resonator is used with a host microstrip line with a series gap in order to obtain a bandpass response. Since a complementary split-ring resonator provides a narrow passband, a T-slot has been introduced in the middle of this resonator to obtain dual-mode behavior with controllable bandwidth. Moreover, a pair of stubs are added to the host microstrip line in order to achieve a wide stopband with good out-of-band rejection. The proposed resonator is analyzed, and a bandpass filter is designed to operate at 3.6 GHz to cover the 5G band from 3.4 to 3.8 GHz. The results show that the filter has a low insertion loss, good return loss, and a wide stopband up to 9 GHz with a compact size since its resonator offers a size of 0.1 λ g × 0.14 λ g where λ g is the guided wavelength at 3.6 GHz.

Identification of Coupled Landau and Anomalous Resonances in Space Plasmas.

Wave-particle resonance, a ubiquitous process in the plasma universe, occurs when resonant particles observe a constant wave phase to enable sustained energy transfer. Here, we present spacecraft observations of simultaneous Landau and anomalous resonances between oblique whistler waves and the same group of protons, which are evidenced, respectively, by phase-space rings in parallel-velocity spectra and phase-bunched distributions in gyrophase spectra. Our results indicate the coupling between Landau and anomalous resonances via the overlapping of the resonance islands.

Adiabatic theory of resonant particle dynamics with frequency chirping chorus waves in magnetospheric plasmas

We present the adiabatic regime for the particles interacting with the frequency chirping waves in the inhomogeneous magnetic field. Despite the rapid change of the parameters during the interaction, we can construct an adiabatic invariant with new canonical coordinates, which is shown to be conserved as long as the particles stay trapped in the reference frame moving with the resonance. Assuming the trapped particle distribution as a function of the adiabatic invariant and the water-bag approximation, we derive an analytic form of the nonlinear current as a function of the inhomogeneous parameter that describes the frequency chirping and inhomogeneities in the background magnetic field. The nonlinear current expression is also examined in the Vlasov hybrid simulations, and the simulation results show that the nonlinear current can be well described by the adiabatic water-bag approximation, except for the chirping onset stage and the source region where the adiabatic approximation is invalid.

Tuning Multipolar Mie Scattering of Particles on a Dielectric-Covered Mirror.

Optically resonant particles are key building blocks of many nanophotonic devices such as optical antennas and metasurfaces. Because the functionalities of such devices are largely determined by the optical properties of individual resonators, extending the attainable responses from a given particle is highly desirable. Practically, this is usually achieved by introducing an asymmetric dielectric environment. However, commonly used simple substrates have limited influences on the optical properties of the particles atop. Here, we show that the multipolar scattering of silicon microspheres can be effectively modified by placing the particles on a dielectric-covered mirror, which tunes the coupling between the Mie resonances of microspheres and the standing waves and waveguide modes in the dielectric spacer. This tunability allows selective excitation, enhancement, suppression, and even elimination of the multipolar resonances and enables scattering at extended wavelengths, providing transformative opportunities in controlling light-matter interactions for various applications. We further demonstrate with experiments the detection of molecular fingerprints by single-particle mid-infrared spectroscopy and with simulations strong optical repulsive forces that could elevate the particles from a substrate.

Uranus’s Influence on Neptune’s Exterior Mean-motion Resonances

Neptune’s external mean-motion resonances play an important role in sculpting the observed population of trans-Neptunian objects (TNOs). The population of scattering TNOs is known to “stick” to Neptune's resonances while evolving in semimajor axis (a), though simulations show that resonance sticking is less prevalent at a ≳ 200–250 au. Here we present an extensive numerical exploration of the strengths of Neptune's resonances for scattering TNOs with perihelion distances q = 33 au. We show that the drop-off in resonance sticking for the large a scattering TNOs is not a generic feature of scattering dynamics but can instead be attributed to the specific configuration of Neptune and Uranus in our solar system. In simulations with just Uranus removed from the giant planet system, Neptune's resonances are strong in the scattering population out to at least ∼300 au. Uranus and Neptune are near a 2:1 period ratio, and the variations in Neptune's orbit resulting from this near-resonance are responsible for destabilizing Neptune's resonances for high-e TNO orbits beyond the ∼20:1 resonance at a ≈ 220 au. Direct interactions between Uranus and the scattering population are responsible for slightly weakening Neptune's closer-in resonances. In simulations where Neptune and Uranus are placed in their mutual 2:1 resonance, we see almost no stable libration of scattering particles in Neptune's external resonances. Our results have important implications for how the strengths of Neptune's distant resonances varied during the epoch of planet migration when the Neptune–Uranus period ratio was evolving. These strength variations likely affected the distant scattering, resonant, and detached TNO populations.

Gravitational disturbance on asteroidal ring systems by close encounter with a small object

To date, rings are found around a Centaur (10199) Chariklo, trans-neptunian objects (TNOs) (136108) Haumea, and (50000) Quaoar. These discoveries suggest that asteroidal ring systems may be common, particularly in the outer solar system. Since collisions are a ubiquitous and fundamental evolutionary process throughout the solar system, we conjecture that asteroidal ring systems must have experienced close encounters with small objects as part of their evolutionary process. Here, we investigate the response of ring systems when they experience gravitational disturbance by a close encounter with another small object, by calculating the change in eccentricity and the fraction of lost ring particles. We find that a perturber needs to be as massive as or more massive than the ringed object, and needs to pass in the immediate vicinity of the ring in order to cause significant disruption. The change in eccentricity expected for Chariklo's inner ring and Quaoar's outer ring agrees with the analytical expression derived from the impulse approximation, while that for Haumea's ring agrees with the analytical expression called “exponential regime”. If we define a lifetime of a ring as the mean time to experience disruptive close encounters that can raise the eccentricity of ring particles >0.1, the lifetime for ring systems around Chariklo, Haumea, and Quaoar are >104 Gyr. We conclude that ring systems around Chariklo, Haumea, and Quaoar are highly unlikely to suffer from close encounters with another small object even if those systems are as old as 4 Gyr. Close encounter with a small object may not be responsible for the finite eccentricity observed for Chariklo's ring system, although eccentricity of ring particles could be increased to ∼10−4 in 4 Gyr. We also find that the lifetime is shorter for smaller ringed objects, and it still exceeds 4 Gyr for km-sized ringed objects in the outer solar system. Therefore, regardless of the size of ringed objects, asteroidal ring systems in the outer solar system are unlikely to suffer severe damage by close encounter with a small object. On the other hand, the lifetime is estimated to be on the order of 100 Myr for km-sized asteroids and 10 Myr for 100 m-sized asteroids in the near-Earth region and the main belt. This finding offers a dynamical explanation why ring systems have not been found in the inner solar system.

Nonlinear excitation of energetic particle driven geodesic acoustic mode by Alfvén instability in ASDEX-Upgrade Tokamak

Recently, the coexistence of multiple energetic particle driven instabilities was observed in experiments on the ASDEX-Upgrade tokamak (Lauber et al 2018 27th IAEA Fusion Energy Conf.). A hybrid simulation using the MEGA code was performed to investigate the properties of those instabilities. The basic mode properties obtained in the simulations, such as mode frequencies, mode numbers, and inward energetic particle (EP) redistribution, are in good agreement with the experiments. It is found that the energetic particle driven geodesic acoustic mode (EGAM) is initially stable, then zonal flow gradually occurs with the growth of the Alfvén instability, and finally, the EGAM is nonlinearly excited and the amplitude exceeds the Alfvén instability. The dependence of EGAM properties on EP pressure and pitch angle distribution is analyzed. The EGAM amplitude increases with EP pressure. The nonlinearly excited EGAM is a high-frequency branch that appears even under the condition of a slowing-down EP distribution. The resonant particles are also analyzed, but the dominant resonant particles of the EGAM in the linear growth phase are not found because the EGAM does not grow in the linear regime. In the phase space of pitch angle variable Λ and energy E, it is found that initially the Alfvén instability is excited by EPs with poloidal frequency 70 kHz, then, after the saturation of the Alfvén instability, the resonance region moves towards lower energy and touches the EGAM resonance line, and finally, EGAM is excited by the particles with poloidal frequency 50 kHz . This process is a kind of resonance overlap.

Entropic stochastic resonance of finite-size particles in confined Brownian transport.

We demonstrate the existence of entropic stochastic resonance (ESR) of passive Brownian particles with finite size in a double- or triple-circular confined cavity, and compare the similarities and differences of ESR in the double-circular cavity and triple-circular cavity. When the diffusion of Brownian particles is constrained to the double- or triple-circular cavity, the presence of irregular boundaries leads to entropic barriers. The interplay between the entropic barriers, a periodic input signal, the gravity of particles, and intrinsic thermal noise may give rise to a peak in the spectral amplification factor and therefore to the appearance of the ESR phenomenon. It is shown that ESR can occur in both a double-circular cavity and a triple-circular cavity, and by adjusting some parameters of the system, the response of the system can be optimized. The differences are that the spectral amplification factor in a triple-circular cavity is significantly larger than that in a double-circular cavity, and compared with the ESR in a double-circular cavity, the ESR effect in a triple-circular cavity occurs within a wider range of external force parameters. In addition, the strength of ESR also depends on the particle radius, and smaller particles can induce more obvious ESR, indicating that the size effect cannot be safely neglected. The ESR phenomenon usually occurs in small-scale systems where confinement and noise play an important role. Therefore, the mechanism that is found could be used to manipulate and control nanodevices and biomolecules.

Acceleration of solar wind particles due to inertial Alfvén waves

Gaining an understanding of the effects and dynamics of the solar wind is crucial for the study of space weather, Earth's magnetosphere, spacecraft protection, the dynamics of the Solar System, and various other subjects. Observations show that Alfvén waves effectively transfer energy to resonant particles. This study demonstrates how inertial Alfvén waves deliver their energy to resonant plasma particles in different solar environments under certain conditions. The analysis shows that inertial Alfvén waves experience more rapid damping with increasing parallel wavenumber, ambient magnetic field strength, and particle number density, coupled with a decrease in temperature. The rate of energy transfer to resonant particles intensifies with higher temperatures and reduced parallel wavenumber and particle number density. Particles with higher initial velocities actively participate in Landau damping, especially in regions with a stronger ambient magnetic field.

Initial Experimental Results on Ion Cyclotron Resonance Heating Selectively Mixed Low Z Ions to Enhance Production Efficiency of Multicharged Ions on Electron Cyclotron Resonance Ion Source

According to the accessibility conditions of wave propagation in the magnetized plasma of an electron cyclotron resonance (ECR) ion source (ECRIS), it is speculated that the essential factor that determines the limitations in the multiply charged ion currents is the left-hand polarization wave cutoff (L-cutoff). It is necessary to overcome this limitation, we proposed the introduction of ion cyclotron resonance (ICR) or lower hybrid resonance (LHR) by lower frequency waves. We conduct heating low-mass ions selectively in enhanced producing multiply charged ion by mixing low-mass element gas, which has been conventionally performed in ECRIS, or relaxation of the potential well based on the existence of resonant electron particles by ECR. This paper will describe the initial experimental results of ICR application by introducing low-frequency RF electromagnetic waves in the ECRIS.

Particle sizes in Saturn’s rings from UVIS stellar occultations 2. Outlier Populations in the C ring and Cassini Division

The Cassini Ultraviolet Imaging Spectrograph (UVIS) included a High-Speed Photometer (HSP), which observed hundreds of stellar occultations by Saturn’s ring system across a range of viewing geometries (Colwell et al. 2010). The unocculted time series data from the HSP follow Poisson counting statistics, such that the second and third central moments of the unocculted data should be equal to the mean photon rate of the star. When the star is occulted by the rings, the presence of ring particles introduces a correlation in the previously uncorrelated photons. This causes each of the central moments to deviate from their expected value. In particular, the second central moment, μ2, commonly known as the variance, becomes greater than the mean (Colwell et al. 2018). The third central moment, μ3, also deviates from this expectation upon occultation, but the nature of the deviation varies with optical depth. In particular, μ3 is less than its Poisson expectation for τ<0.33 and greater than this expectation for τ>0.33. The introduction of outlier features, namely small gaps (‘ghosts’, Baillié et al. (2013)) and clumps produce variable effects on the behavior of both μ2 and μ3, which is also dependent on optical depth.We compare the higher-order moments from Monte Carlo Simulations of a simplified ring system to those from the UVIS data to gain insight into the nature of such outliers in the C ring and Cassini Division. The behavior of the data in the C ring plateaus indicates that a small population of ∼ 10-m ghosts exists in this region, with a frequency of about 1 ghost per km of radial extent. In the background C ring, we find that particle sizes are positively correlated with optical depth and the data cannot be explained with a simple power-law size distribution. Instead, we are able to describe the behavior of the higher-order moments using a bent-power law size distribution of particles. We find similar behavior in the C ring ramp and Cassini Division ramp. However, we cannot rule out nor confirm the presence of either ghosts or clumps in the background Cassini Division. In the Triple Band, the local ∼ 10-m ghost frequency oscillates between about 1 and 4 ghosts per km.

Insights into reaction–diffusion behaviors of acetylene selective hydrogenation on pellet catalysts

AbstractIn this work, a particle‐resolved computational fluid dynamics model of the acetylene hydrogenation process is developed to investigate the effects of catalyst particle structures on the reaction–diffusion behaviors aiming to improve selectivity toward target ethylene. The effects of packing structures on mass and heat transfer are explored by employing particles with varying shapes, wall thicknesses, and external diameters. The simulation results reveal that decreasing diffusion paths and elevating reactor bed temperature will enhance ethylene selectivity, and cylinder and Raschig ring packing structures exhibit the lowest and highest ethylene selectivity of 35.6% and 48.9% at 70% of acetylene conversion, respectively. Reducing wall thicknesses of Raschig ring particles facilitates the diffusion of generated ethylene from the interior zone of catalysts but concurrently inhibits the conversion of acetylene to ethylene. The Raschig ring catalyst particle with 1.9 mm of wall thickness and 3.5 mm of external diameter is finally revealed to exhibit the highest ethylene selectivity.