This research examines the optimal feasibility of incorporating siliceous additives as an adjunct material for cement in the formulation of environmentally sustainable high-performance concrete (Eco-HPC). Siliceous materials, including Nano silica (NS), Rice Husk Ash (RHA), and Fly Ash (FA), were fine-tuned within the cementitious system in order to achieve the amplified performance of Eco-HPC by reducing the required cement content from 370 kg/m3 to 273 kg/m3. This is achieved by employing the Modified Andreasen and Andreasen (MA&A) particle packing model, with ‘q’ (distribution factor) as ‘0.3’. The Levenberg Marquardt algorithm (curve fitting) was utilized to validate the packing density of each concrete blends. Initially, the dry NS agglomerates are synthesized into stabilized aqueous dispersion through High shear mixing (10 min/1750 rpm) followed by probe sonication (15 min/(1/3) s/s) with anionic surfactant dosage of 0.1 g/10 g. Incorporating secondary siliceous binders into the cement matrix led to an enhancement in the packing density, increasing from 0.94 (nullary) to 0.96 (quaternary) which in turn alters the reactivity and cohesiveness of the matrix. Compressive strength values for Binary (NS2), Ternary (RN15, FN20), and quaternary mix (FRN25) were observed as 57.42 MPa, 56.83 MPa, 55.34 MPa, and 52.58 MPa, respectively, for primary binder contents of 362 kg/m3, 314 kg/m3, 296 kg/m3, and 273 kg/m3 without compromising durability parameters. An assessment on reduced carbon dioxide emissions indicated that increasing the cement replacement percentages in Eco-HPC by up to 30% for binder contents of 358 kg/m3, 296 kg/m3, 259 kg/m3, and 273 kg/m3 resulted in a reduction of CO2 emissions by 2.98%, 18%, 27%, and 23.33%, respectively. Among the twelve formulated mixes, FRN25, FRN20, FRN15 and FN30 are identified as Eco-HPC mix through a computational framework which integrates the packing density, carbon emission, strength and diffusion coefficient.
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