Optical excitation induces a transition in NO2 from a ground state |a> to an excited state |b>. The state |b> is not stable. The molecule evolves irreversibly from |b> to a state |c> in a time τ0≈3μs. We investigate the transition from |b> to |c> by analysing results of molecular beam and static gas experiments, and we conclude that the irreversible evolution is either an intramolecular radiationless transition of a symmetric to an asymmetric configuration of the isolated NO2 or the effect of a background cosmic field inducing a parity nonconserving transition from |b> to |c>.