AbstractThe article presents a solution to a complex problem involving a transient MHD‐free convective chemically reactive flow. The flow involves a viscous incompressible electrically conducting non‐Gray optically thick fluid moving past a semi‐infinite vertical plate that has suddenly started but is temporarily accelerated. The plate has nonlinear parabolic ramped conditions, and the flow is exposed to thermal radiation, heat absorbing sink, and diffusion‐thermo effect. For the current study, the model fluid being used is moist air. The governing equations are obtained using the Laplace transform technique with the help of the Heaviside step function. This study is the first to consider parabolic ramped motion, temperature and concentration simultaneously. Effects of the pertinent parameters on the Sherwood number and Nusselt number are visualized using 3D surface plotting. Findings of the problem manifest that concentration, temperature, and velocity profiles in case of ramped conditions are less than in isothermal conditions. The rate of heat transfer of mercury is less than oxygen, air, water, and ethanol at a room temperature of 22°C–25°C. The ramped plate has the tendency to augment the heat transfer rate. The present study is of great interest in numerous fields of industry and machine‐building applications.