In this paper, a symplectic structure on a Leibniz algebra is defined to be a symmetric nondegenerate bilinear form satisfying certain compatibility condition, and a phase space of a Leibniz algebra is defined to be a symplectic Leibniz algebra satisfying certain conditions. We show that a Leibniz algebra has a phase space if and only if there is a compatible Leibniz-dendriform algebra, and phase spaces of Leibniz algebras are one-to-one corresponds to Manin triples of Leibniz-dendriform algebras. Product (paracomplex) structures and complex structures on Leibniz algebras are studied in terms of decompositions of Leibniz algebras. A para-Kähler structure on a Leibniz algebra is defined to be a symplectic structure and a paracomplex structure satisfying a compatibility condition. We show that a symplectic Leibniz algebra admits a para-Kähler structure if and only if the Leibniz algebra is the direct sum of two Lagrangian subalgebras as vector spaces. A complex product structure on a Leibniz algebra consists of a complex structure and a product structure satisfying a compatibility condition. A pseudo-Kähler structure on a Leibniz algebra is defined to be a symplectic structure and a complex structure satisfying a compatibility condition. Various properties and relations of complex product structures and pseudo-Kähler structures are studied. In particular, Leibniz-dendriform algebras give rise to complex product structures and pseudo-Kähler structures naturally.
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