Geological mapping of the Mayombe Chain and Niari Basin of Congo Brazzaville allows for the first time defining the structural architecture and metamorphism of the West Congo Belt. Four different tectono-metamorphic domains, separated by crustal-scale shear zones, are now distinguished (Niari Basin (NB), Eastern (EMC), Central (CMC) and Western (WMC) Mayombe Chain).The NB is marked by only weak regional deformation under middle to upper diagenetic conditions. It is delimited in the west from the EMC by the Mount Belo Shear Zone forming the terminal thrust system of the West Congo orogen.The tectonic style in the EMC is characterized by discrete, widely-spaced low-angle thrusts, reverse faults and strike-slip faults resulting in the formation of duplex and/or positive flower structures. Off these high-strain zones, the rocks are folded into gentle syn- and anticlines. Penetrative schistosity starts in shales in the western part. The metamorphism increases from eastern anchizonal conditions to lower greenschist facies in the west. The EMC is juxtaposed along the Moukondo thrust/back-thrust system with the CMC.The CMC is typified by open to closed upright to NE-verging folds, S1 schistosity with moderate to steep SW dips, onset of regional crenulation cleavage (S2), frequent reverse thrusts and numerous faults. Metamorphic conditions remain in the greenschist facies. The Loukenéné-Mandji Thrust marks the CMC-WMC contact and coincides with a jump in metamorphic grade marked by biotite-in.The WMC consists of Palaeoproterozoic basement stacked with Neoproterozoic rocks. Autochthonous Palaeoproterozoic gneiss and schist record Late Eburnean sedimentation, magmatism and metamorphism between 2110 and 1970 Ma, which are compared with the Eburnean history in Gabon and the Transamazonian orogeny in Brazil. The allochthonous Bikossi Group was thrust during the Pan-African event from the west over Tonian metavolcaniclastic and plutonic rocks before further folding and stacking of both units. The intensity of Pan-African deformation increases from open to closed folds with spaced cleavage in the southeast of the WMC to thrust-dominated tectonics in the northwest, where the Palaeo- and Neoproterozoic rocks are transposed into parallelism with the pronounced schistosity.Geochronology of illite and muscovite documents two Pan-African events at 590-570 Ma (M1) and at 520-500 Ma (M2) that are related to the main collisional and late thermal events in the Araçuai-Ribeira Belt in Brazil. Metamorphic isogrades shifted from M1 to M2 for more than 30 km to the west. Detrital mica and metamorphic illite of the Mpioka Group record M1 and M2, respectively constraining sedimentary deposition between 570 and 520 Ma, which implies the interpretation of the group as molasse of the West Congo Belt.
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