Palynofacies Data Research Articles

Application of palynomorphs and palynofacies in Early Cretaceous paleoenvironmental reconstruction; Shushan Basin, Egypt

An integration of palynomorph and palynofacies data from the Shushan-1X well is used to infer the paleoenvironmental conditions of the Valanginian to Middle Cenomanian (Cretaceous) section of the western Shushan Basin, northern Egypt. The data obtained contribute significantly to the depositional history of the basin. The low diversity of dinoflagellate cyst assemblages, along with the dominance of land-derived spores and pollen, suggest restricted (marginal) marine environments, in contrast to their coeval representatives from the Tethyan Realm. Open marine (inner shelf) environments developed at a few horizons in the Dahab and Bahariya formations, partly contemporary with the global Aptian and Cenomanian eustatic cycles. These environments were relatively more offshore than those described in the eastern and southeastern parts of the basin. The study of total palynological organic matter (TPOM) has contributed largely to these established environmental settings. It has also allowed the recognition of redox (suboxic to anoxic) conditions and the impact of a large magnitude of terrigenous influence.

Unveiling the petrographical, palynological, palynofacies and geochemical archives of coal and shaly coal deposits in the Mandakini–B block of Talcher Basin: An insight into the paleoecology, depositional environment, kerogen type and source rock potential

Coal and shaly coal beds in the Talcher-Mahanadi Basin, eastern India, belongs to Barakar Formation (Artinskian). A comprehensive analysis was undertaken, including organic petrography, palynology, palynofacies, proximate analysis, Rock-Eval pyrolysis and Field Emission Scanning Electron Microscopy (FE-SEM). The samples consist of the vitrinite group of macerals (avg. 38.2 vol.%), followed by inertinite and liptinite, suggesting peat-forming higher plant vegetation was deposited under prevailing anaerobic conditions. However, the significant presence of inertinite macerals (avg. 29.2 vol.%), including semifusinite and fusinite, along with opaque phytoclasts (avg. 17.3 %), implies occasional shift to oxic conditions. High occurrence of tissue-derived phytoclasts (avg. 64.3 %) indicates that higher plants were the primary contributors to peat formation. Detrovitrinite sub-groups and non-biostructure phytoclasts suggests contributions from herbaceous flora and/or potential tissue degradation due to microbial activity. The palynomorph distribution reveals the dominance of Glossoptriadales, followed by Coniferales and trilete spore groups, comprising 25 genera and 40 species. Non-striate bisaccate pollen, primarily Scheuringipollenites (15–34 %) and sub-dominant striate bisaccate pollen Faunipollenites (11–18 %) prevail in the palynoassemblage. Petrographic indices suggest that the deposition of peat-forming telmatic vegetation has largely occurred in wet forest swamp conditions within the mesotrophic hydrological setting. Palynofacies data, plotted on Tyson’s APP (Amorphous organic matter-Phytoclast-Palynomorph) ternary diagram, suggests suboxic to dysoxic deposition conditions. Low phytoclast preservation index (PPI) indicate proximal deposition of the organic matter. Vitrinite reflectance (VRo%) ranged between 0.42 and 0.68 %, suggesting that the coalification reached up to ‘Medium rank D’ or Bituminous D stage. The substantial total organic contents (TOC: 34.02–61.84 wt.%), hydrogen index (HI) (avg. 154 mg HC/gTOC) and dominance of vitrinite maceral/non-opaque phytoclasts indicate Kerogen Type III and have significant potential for gaseous hydrocarbon generation. FE-SEM images reveal well-developed intergranular and organic pores within the matrix system, serving as both a source and storage in coal beds.

Petrography and geochemistry of siliciclastic sediments in Permo-Triassic transition from the southern Pranhita-Godavari Gondwana basin, India: Implications for paleoclimate

The Kamthi Formation, in the intracratonic Pranhita-Godavari Gondwana rift basin, bore signatures of climate change from a warm humid climate in Late Permian to hot arid during the Early Triassic. Sedimentation took place mainly under fluvial conditions. The Kamthi sediments were unaffected by burial diagenesis and the source remained the same, therefore this provides an excellent opportunity to study the climatic influence on petrogenesis in an intracratonic rift basin. Subsurface palynofacies data of Kamthi Formation from the southern part of the basin established the presence of Upper Permian rock units equivalent to the Raniganj Formation, which are overlain by Lower Triassic sediments equivalent to Panchet Formation of the Damodar valley Gondwana basins, and are separated by a gradational contact. QFL and trace element compositions reveal transitional continental to craton interior provenance with dominantly felsic source areas, along with some meta-sedimentary and mafic components. Dominance of kaolinite, coal, alteration of K-feldspar, and biotite in the Raniganj equivalent sandstones attests to a humid climate. The presence of mostly fresh K-feldspar, ferruginous matrices, Fe-carbonate nodules, cutans, and microcrystalline silica cement in the Panchet equivalent sandstones mark a shift from humid to arid/semi-arid. This climatic shift is not reflected in the uniform feldspatho-quartzose to quartzose sandstone compositions and mudstone major oxide compositions. The mudstones are depleted in mobile elements, have low K2O/Al2O3 (0.11–0.18), low ICV (0.35–0.72), high SiO2/Al2O3 (2.3–3.4), high K2O/Na2O and moderately high CIA (80.12–87.05) that collectively suggest moderately intense weathering. Despite the humid climate, the Raniganj Formation equivalent rock units did not attain the highest mineralogical maturity due to proximity to relatively high-relief source areas in a fluviolacustrine environment. This relationship resulted in a lack of short-term sediment storage that favoured rapid erosion and sedimentation.

Palaeoclimatic variability during last eight millennia from a morainal lake in Zanskar, northwest Himalaya, India

Centennial–scale palaeoenvironmental variability has been deduced during past eight millennia using multi–proxy study (textural analysis, environmental magnetic parameters, stable carbon isotopes, palynofacies and elemental concentration), from Khangok–Padam in Zanskar Valley, northwest Himalaya. The multi–proxy record from this morainal lake spanning last ~8200 cal years BP has revealed four hydroclimatic phases. The overall progressively improving hydroclimatic trend is indicated by multi proxy study: sediment size/texture (as a proxy for the energy condition and depositional environment), mineral magnetism (proxy for sediment flux or lithogenic input and lithologic variation), carbon isotope signature (δ13Corg) preserved in organic constituents of sediments (a proxy for palaeovegetation and climate change), elemental geochemistry (proxy for weathering and erosion) and selected samples for palynofacies data (a proxy for changes in biological organic matter). This improving hydroclimatic trend is however punctuated by an abrupt wet spell at ~6200–5200 cal years BP and relatively drier climate during the Little Ice Age between 1400 and 1900 CE. The main driving force implicated for the changes are seen to be the solar output variations. The area lying in a transitional climatic zone of NW Himalaya shows no emphatic record of the events like the 4200 cal. years BP, 2600 cal. years BP and Holocene Climatic Optima. Contrary to the earlier studies in the region (e.g., Tsokar and TsoMorari), our results show an improving hydroclimatic condition in this transition climatic zone between the Indian Summer Monsoon dominated Higher and westerly dominated Trans Himalaya.

Advances in chemical stratigraphy of Pimenteiras Formation, devonian of Parnaíba Basin, Brazil

The oil potential of the Brazilian Paleozoic basins is related to conventional hydrocarbon and unconventional and atypical processes. The Parnaíba Basin fits into the atypical model. Located in Northeast Brazil, it covers approximately 600,000 km2 and includes different sedimentation cycles, from the Precambrian to the Mesozoic. This work seeks to reduce exploratory uncertainties in this basin by using organic geochemistry on samples from shallow wells located on the basin's eastern edge to identify and track key surfaces in the Devonian section. The intervals with total organic carbon (TOC) content above 0.5% were subjected to Rock-Eval pyrolysis analyses, while organic carbon isotope analyses (δ1³C), liquid chromatography, and gas chromatography coupled with mass spectrometry (GC-MS) were performed on the intervals previously identified as being necessary for the generation of oil and gas. Detailed stratigraphic analysis of the Pimenteiras Fm from shallow wells drilled on the basin's eastern edge allowed the identification of two main marine flooding surfaces of Eifelian and Givetian age (surfaces A and B), which limit a third-order genetic sequence (AB). The association of TOC, pyrolysis, δ1³C, biomarkers, and palynofacies data allowed the subdivision of the same section into four chemostratigraphic units, named L-I to L-IV, from the base to the top, and the subdivision of the section on the southwestern edge into three units, named SO–I to SO-III, from the base to the top of outcrop A. The main flooding events in the basin's eastern edge are at the base of unit L-I and unit L-IV and coincide with surfaces A and B, mapped on the gamma-ray logs that limit sequence AB. On the southwestern edge, unit SO-III represents the main flooding event. This new information improves the knowledge regarding the stratigraphy, paleoenvironment, and types of organic matter of the Pimenteiras Fm.

Palaeoenvironmental reconstruction for the Permian (lower Gondwana) succession of the Godavari Valley Coalfield in southern India based on a combined palynofacies, carbon isotope, and biomarker study

The study presents integrated palynofacies, organic carbon isotope, and biomarker data to reconstruct palaeoenviromental setting for the Permian sediments (borehole MGK-6) of the Kachinapalli block of the Godavari Valley Coalfield, southern India. The palynofacies data reveal three distinct palynofacies (A–C) as follows. Palynofacies A is dominated by abundant arborescent vegetation (glossopterids and conifers) along with structured organic matter, suggesting freshwater forest swamps in proximal settings. Palynofacies B is dominated by abundant degraded organic matter and amorphous organic matter, suggesting lakeshore/flooded palaeomires in slightly dismal settings. It has a high water level in the hinterland, which enables bacterial degradation of organic matter and establishes low-oxygenation conditions within the water column. These conditions would have provided grounds for the accumulation of either degraded or amorphous organic matter. Palynofacies C is dominated by the abundance of charcoal/opaque phytoclasts, indicating prolonged transportation or post-depositional alteration, suggesting a highly-oxidizing condition in distal settings. The bulk organic δ13C range (−25.1‰ to −20.9‰) in the borehole MGK-6 is in close agreement with the global Permian records. This study also shows a weak but statistically significant correlation with the major forms of palynofacies A and C. The interlinked behaviour of bulk organic δ13C and palynofacies suggests that the changes in palaeobiogeography/palaeodepositional settings were most likely driven by the change in mean annual precipitation. The biomarker study shows the presence of n-alkane from C15 to C31 with unimodal and bimodal distribution patterns, revealing the source materials as vascular plants and microbially-altered organic matter. The combined palynofacies, organic carbon isotope, and biomarker data provide vital clue to salient findings for the development of environmental conditions of Godavari Valley Coalfield during lower Gondwana sedimentation.

Petrographical-geochemical characteristics and floral-faunal compositions of the Valia lignite deposits from Cambay Basin (Gujarat), western India

Lignite-bearing sequence of the Valia mine, associated with the Cambay Shale Formation (early Eocene) in Cambay Basin of western Indian State Gujarat, has been studied. An integrated approach (including organic petrography, palynofacies, palynology, entomology, geochemistry) has been adopted to assess the origin and characters of lignite deposits and their potential for the hydrocarbon generation, besides to understand the evolution and interaction of different biotic (floral-faunal) groups of the geological time. The studied samples (lignites/shales) are characterized by the domination of huminite group (av. 67 vol.%)/phytoclasts (av. 58%) along with the abundance of short-chain n-alkanes (bacterial activity). The frequencies of detrohuminite sub-group, non-biostructured elements, macrophyte-derived amorphous organic matter (AOM, mainly), and high values of proxy aqueous are indicating the elevated bacterial degradation of the OM and/or also suggest the significant contribution of the herbaceous vegetation/aquatic macrophytes/algal input to the palaeo-peat. The relative abundance of hopanes and low values of the steroids/hopanoids ratios further indicate a high bacterial activity. On the other hand, the contents of telohuminite, liptinite group, and cuticle elements together with the high carbon preference index, low proxy wax, and terrigenous/aquatic ratios confirm both terrestrial and macrophyte contributions during the peat accumulation. Fascinatingly, we have found Dipterocarpus-derived amber (fossil resin) within the lignite seam (lower) with remarkably well-preserved arthropod inclusions consisting of arachnids and insects. Generally, insects have an association with flora and provide important ecosystem functions. In the studied amber samples, the insects to arachnids (spiders and pseudoscorpions) ratio is 3:1. Their quantitative analysis indicates the dominance of the Chironomidae (non-biting midges 32%) followed by Araneae, Myrmicinae, Cecidomyiidae, and Mycetophilidae. A rare entity such as pseudoscorpions has also been found during the investigation.The derived petrographic indices indicate that the peat-forming limno-telmatic vegetation was accumulated mainly in back-barrier settings with high groundwater (mesotrophic to rheotrophic) condition. The contents of pyrite (mainly framboidal) mineral and sulphur (0.69–2.24 wt.%) suggesting that peat had experienced the marine influx. Further, the high occurrence of funginite maceral (among inertinite group), and spores of family Microthyriaceae point towards a warm and moist condition. The plotting of palynofacies data on Tyson's APP diagram, and the values of pristane/phytane ratio suggest that the OM was primarily deposited in dysoxic to suboxic settings. The high incidence of family Chironomidae, non-biostructured and low cuticle contents indicate the proximal settings and a low energy environment like lake/pond or marshlands. However, the occurrence of granular-AOM along with high (relatively) opaque phytoclast contents in the upper part indicates that distal settings were formed at the termination of the OM accumulation. The total organic carbon (TOC) contents and hydrogen index values in the studied samples indicate a good to excellent source for the hydrocarbon generation. However, the low gross calorific value (av. 4467 cal/g), values of Tmax (mostly below 435 °C), and H/C and O/C atomic ratios showing that the samples are of immature (early diagenetic stage; huminite reflectance value: av. 0.28%) nature of the OM. Moreover, the different cross plots (hydrogen index (HI) vs. oxygen index (OI), S2vs. TOC, HI vs. Tmax) indicate that the Valia lignite-bearing succession contains admixed type-III/II kerogen, and can generate gaseous and some liquid hydrocarbons upon maturation or with additional heating.

Carbon and Nitrogen Cycle Dynamic in Continental Late-Carboniferous to Early Permian Basins of Eastern Pangea (Northeastern Massif Central, France)

Late Carboniferous to early Permian organic-rich sedimentary successions of late-orogenic continental basins from the northeastern Massif Central (France) coincide with both the Variscan mountain dismantling and the acme of the long-lasting Late Paleozoic Ice Age. Here, we investigate the carbon and nitrogen cycles in the newly dated sedimentary successions of the Decize–La Machine and Autun basins during these geodynamic and climate upheavals. The sedimentary organic matter has been analyzed through Rock-Eval pyrolysis, palynofacies and elemental and isotope geochemistry along cored-wells and outcropping sections, previously accurately defined in terms of paleo-depositional environments. Rock-Eval and palynofacies data have evidenced two origins of organic matter: a phytoplanktonic/bacterial lacustrine origin (Type I organic matter, organic δ13C values around −23.5‰), and a terrestrial origin (vascular land plants, Type III organic matter, organic δ13C values around −20‰), mixed in the deltaic-lacustrine sediments during background sedimentation (mean organic δ13C values around −22‰). Episodes of high organic matter storage, reflected by black shales and coal-bearing deposits (total organic carbon up to 20 and 70%, respectively) are also recognized in the successions, and are characterized by large negative organic carbon isotope excursions down to −29‰. We suggest that these negative isotope excursions reflect secondary processes, such as organic matter remineralization and/or secondary productivity varying under strict local controls, or possibly larger scale climate controls. At times, these negative δ13C excursions are paired with positive δ15N excursions up to +10‰, reflecting water column denitrification and anammox during lake-water stratification episodes. Together, these isotopic signals (i.e., low sedimentary organic δ13C associated with high bulk δ15N values) indicate periods of high primary productivity of surface waters, where nitrogen and carbon cycles are spatially decoupled. These local processes on the sedimentary isotope archives may partially blur our ability to directly reconstruct paleoclimate variations in such continental settings using only C and N isotopes. At last, we explore an organic δ13C-based mixing model to propose ways to disentangle autochthonous versus allochthonous origin of organic matter in lacustrine continental settings.

Changes in organic matter composition during the Toarcian Oceanic Anoxic Event (T-OAE) in the Posidonia Shale Formation from Dormettingen (SW-Germany)

During the Early Toarcian, deposition of organic carbon-rich-shales occurred throughout the epicontinental sea across Europe. Climate instability and high extinction rates in the marine realm were associated with profound environmental changes. The Toarcian Oceanic Anoxic Event (T-OAE) has been linked to the injection of greenhouse gases (e.g. oceanic methane) into the atmosphere triggered by the emplacement of the Karoo-Ferrar large igneous province (LIP) volcanism. The data presented are obtained from the Posidonia Shale Formation in Dormettingen (southwestern Germany), ~2 km from the well-known Dotternhausen section. Despite the intense palaeontological and geochemical research, studies on the particulate organic matter (POM) across the T-OAE are scarce. Here, we provide a detailed study of POM of the Dormettingen section as a tool to evaluate changes in the depositional environment. Integrated POM (i.e. amorphous organic matter, marine and terrestrial palynomorphs) and geochemical (i.e. carbon isotope δ13C) analyses reveal different episodes of palaeoecological upheavals during the studied time interval. In this study, we will integrate new palynofacies data and combine it with the existing sedimentological and palaeoecological data of Dotternhausen in order to interpret relative sea-level fluctuations and climatic changes at the local palaeogeographic setting.

Late Cretaceous to Early Paleogene global sea level fluctuations and the sedimentary environment in central Alborz (Northern Iran)

The Cretaceous-Paleogene sequence, including K-Pg transition, located 45 km from the South of Sari in the North of Iran was analyzed in regards to lithology, lithofacies, foraminifera, and palynology evaluation. The main aim of this study was the reconstruction of sedimentary environmental condition including relative sea level changes during the K-Pg transition. Seventy rock samples were collected from 133 m of sedimentary rocks, mainly comprising limestone, sandstone, siltstone, and evaporate. Two species of foraminifera, ten species of spore, and seven species of pollen grains have been identified. K/Pg boundary has been determined based on the first occurrence of Tricolpites phillipsii in the 133 m above the base of the studied section. Two palynofacies have been identified based on statistical analysis of palynofacies factors (SOM, MP, Ph). Palynofacies analysis suggests nearshore (inner ramp) as a sedimentary environment for these sequences. Our palynofacies data indicate sea-level regression near K/P which can be correlated to the global sea level trend.

Foraminifera Biostratigraphy, Palynofacies and Paleoenvironment of deposition of the Albian to Santonian sediments in the Southern Benue Trough, Nigeria

The Albian-Santonian sedimentary sequence in the Ndeaboh-Nenwe area of Enugu, Southern Benue Trough, were analysed for foraminifera and integrated with ostracod and palynofacies analyses to comprehensively appraise the age and depositional environment of the sediments. This is paramount since the studied formations have intermittent series of non-marine sedimentary influences throughout the basin. The results of foraminifera evaluation indicate that the Abakaliki Formation is barren of foraminifera species, whereas the Eze-Aku and Awgu formations have preponderance of planktonic foraminifera assemblages over benthic forms. The Eze-Aku Formation records an abundance of species of Hedbergella and a peak for Heterohelix. The co-occurrence of Whiteinella archeocretacea, Hedbergella planispira, Heterohelix delrieonsis and the ostracod species Ovocytherida symmetrica, suggests a Late Cenomanian to Early Turonian age. Rare species of short-ranging and keeled planktonic taxa are present in Awgu Formation, which has a preponderance of Heterohelix reussi, Heteroheix globulosa, Heterhelix pulchra, Whiteinella baltica, and the ostracods Brachycythere ekpo and Cythereis sp. The Awgu Formation is Middle Turonian to Santonian. The percentage of amorphous organic matter and lithologic characteristics suggest a marine environment for the Abakaliki Formation, although the water depth cannot be ascertained. In the Eze-Aku Formation, the prevalence of Hedbergella and its co-occurrence with Whiteinella and associated palynofacies data (amorphous organic matter, black debris, few structured terrestrial phytoclasts) and dinoflagellate cysts suggest a fairly deep (200–300 m) marine environment with occasional terrestrial input. The low diversity of agglutinated benthic foraminifera assemblage in the Awgu Formation indicates deposition at a minimum paleo-water depth. The paucity of benthic foraminifera, rare occurrence of keeled planktonic species, and the dominance of Hedbergella and Heterohelix; low oxygen tolerant species, in the studied interval are attributed to anaerobic bottom conditions possibly caused by poor bottom water circulation and high organic productivity in the oceans and seas during the Cenomanian-Santonian.

Estudo de palinofácies na sucessão rica em matéria orgânica da Formação Tremembé no poço TMB-3-SP (Oligoceno da Bacia de Taubaté)

In order to show how the upper part of the Tremembé Formation evolved in terms of organic matter and paleoenvironment types, palynofacies of 20 samples from the TMB-3-SP well were analyzed and sedimentological and geochemical data from the same samples were revisited. The association of the palynofacies data with the total organic carbon, hydrogen index and sedimentological data made it possible to group the studied samples in nine sets, named from 1 to 9, from the bottom to the top of the Tremembé Formation. Sets 1, 3, 5, 7, and 9 represent low water depth phases in the lake, while sets 2, 4, 6, and 8 represent high water depth phases in the lake, with Set 6 witnessing the period with thickest and most expanding water depth of the lake. The phases of low water depth in the lake have lower concentrations of fluorescent amorphous organic matter and predominance of Pediastrum algae over Botryococcus algae. In contrast to the phases of high water depth in the lake, with higher concentrations of fluorescent amorphous organic matter and predominance of Botryococcus algae over Pediastrum algae. Parallel to the knowledge of the stratigraphic distribution of the microscopic characteristics of organic matter along the upper part of the Tremembé Formation in the central region of the Taubaté Basin, the new data constitute important paleoenvironmental indicators.

PALYNOLOGY AND CHEMOSTRATIGRAPHY OF MIDDLE TRIASSIC SUCCESSIONS IN NORTHERN SWITZERLAND (WEIACH, BENKEN, LEUGGERN) AND SOUTHERN GERMANY (WEIZEN, FREUDENSTADT)

New Anisian to Ladinian palynology, palynofacies and stable carbon isotope records are reported for the Middle Triassic from deep Swiss wells (Weiach, Benken, Leuggern), well B3/13 (Weizen, S-Germany) and the type area of the Freudenstadt Formation in southern Germany. A wide spectrum of moderately to well-preserved palynomorphs represent a high Middle Triassic plant diversity. Based on the distribution of diverse spore-pollen assemblages five Anisian Palynozones (A–E) and two Ladinian ones (F, G) are differentiated. Throughout these Palynozones the occurrence of spores and pollen, assigned to plant groups so far known only from the Palaeozoic, shed a new light on the evolution of plant assemblages during the Triassic. The comparison of Palynozones A–G with palynostratigraphic schemes from the central part of the Germanic Basin and from the Tethyan realm demonstrate the regional variability of marker species ranges – especially for the Anisian. n agreement with the lithological record, two prominent transgressive events (Lower Muschelkalk, Upper Muschelkalk) are indicated by increased abundances of marine particulate organic matter in palynofacies data. Marginal marine influence is documented at the base of the studied interval, comprising the Buntsandstein and the base of the Lower Muschelkalk. Carbonate carbon isotopes data show a negative shift at the boundary between lower and middle Muschelkalk. Coincidently, a prominent change in relative abundances of climate-sensitive plant groups (e.g. Triadispora spp. vs. Pteridophytes) indicate a change to relatively dryer climatic conditions during the middle Muschelkalk.

Palynofacies analysis for interpreting paleoenvironment and hydrocarbon potential of Triassic–Jurassic strata in the Sichuan Basin, China

The Sichuan Basin is one of the largest petroliferous basins in China. The continental fluvial‒lacustrine sediments of the Upper Triassic Xujiahe Formation and the Lower Jurassic Zhenzhuchong Formation yield diverse fossil organisms and host one of the most important gas reservoirs in the basin. However, paleontological implication for the paleoenvironment and hydrocarbon source is less documented. Here, we report, for the first time for this basin, results from palynofacies analyses combined with thermal alteration data in the Early Mesozoic deposit of the Qilixia section, northeastern Sichuan Basin. The results show that, organic matters in sediments are dominated by phytoclasts, with less abundant palynomorphs and a few amorphous organic matters (AOMs). Four palynofacies assemblages were identified, reflecting depositional settings in a general proximal and oxic fluvial‒deltaic environment, with two distal–proximal sedimentary cycles. The prominent dominance of opaque phytoclasts within the lower Zhenzhuchong Formation may be related to frequent wildfires across the Triassic–Jurassic transition. Palynofacies data (especially the relative abundance of opaque phytoclasts) may reflect 405 kyr eccentricity cyclicity pattern. The palynofacies and thermal alteration index (TAI), combined with geochemical data indicate the presence of type III kerogen in mature to post-mature phases, suggesting gas potential of the Xujiahe and Zhenzhuchong formations in the northeastern Sichuan Basin. This study provides significant implications for better understanding the paleoenvironment variations during the Triassic–Jurassic transition and the future gas exploration in this area.

Re-Os geochronology and isotope systematics, and organic and sulfur geochemistry of the middle–late Paleocene Waipawa Formation, New Zealand: Insights into early Paleogene seawater Os isotope composition

In the middle–late Paleocene, a marine, organic-rich sedimentary unit (Waipawa Formation [Fm]) in which the organic matter was derived mainly from terrestrial plants was deposited in many of New Zealand's sedimentary basins. The unique organofacies of this formation has not been identified in any other time interval within the geological history of the Southwest Pacific, indicating that unusual climatic and oceanographic conditions likely prevailed during this time. It has, therefore, attracted wide scientific interest due to its significance for regional and global reconstruction of the early Paleogene transitional climate as well as potential for oil and gas production. Scarcity of age-diagnostic fossils, presence of unconformities and lack of volcanic interbeds have, however, hindered precise dating and correlations of all the known occurrences of the formation. Here, rhenium‑osmium (Re-Os) geochronology has yielded the first radiometric age for the formation (57.5 ± 3.5 Ma), which is consistent with available biostratigraphic age determinations (59.4–58.7 Ma). Further, a comparison of Re-Os, bulk pyrolysis, sulfur and palynofacies data for the Waipawa Fm with those of more typical marine sediments such as the underlying Whangai Fm supports the interpretation that the chelating precursors or fundamental binding sites responsible for uptake of Re and Os are present in all types of organic matter, and that these elements have a greater affinity for organic chelating sites than for sulfides. The results also indicate that sedimentation rate may not play a dominant role in enhanced uptake of Re and Os by organic-rich sedimentary rocks.The initial 187Os/188Os values for the Waipawa (~0.28) and Whangai (~0.36) formations are broadly similar to those reported for coeval pelagic sediments from the central Pacific Ocean, further constraining the low-resolution marine 187Os/188Os record of the Paleocene. We present a compilation of 187Os/188Os values from organic-rich sedimentary rocks spanning the period between 70 and 50 Ma which shows that seawater Os gradually became less radiogenic from the latest Cretaceous, reaching a minimum value in the earliest late Paleocene (~59 Ma) during the deposition of Waipawa Fm, and then increased through the later Paleocene and into the early Eocene. The composite Os isotope record broadly correlates with global temperature (δ18O and TEX86) and carbon isotope (δ13C) records from the middle Paleocene to early Eocene, which is inferred to reflect climate-modulated changes in continental weathering patterns.

Organo-petrographic and geochemical characteristics of Gurha lignite deposits, Rajasthan, India: Insights into the palaeovegetation, palaeoenvironment and hydrocarbon source rock potential

The sedimentary sequence containing lignite deposits in Gurha quarry of the Bikaner-Nagaur Basin (Rajasthan) has been investigated. The samples from lignite and allied shale horizons were evaluated for petrographical, palynological, palynofacies and organic geochemical inferences, to depict the source flora and to reconstruct the palaeodepositional conditions prevailed during the sedimentation. An assessment for the hydrocarbon generation potential of these deposits has also been made. The results revealed the dominance of huminite macerals and phytoclasts organic matter (OM) indicating the existence of forested vegetation in the vicinity of the depositional site. A relatively high terrigenous/aquatic ratio (TAR) and the carbon preference index (CPI) are also suggesting the contribution of higher plants in the peat formation. However, the n-alkane distributions, maximizing at n-C17 and n-C29, showed inputs from the algal communities along with the higher plant derived organic matters. Recovered palynomorphs of the families Onagraceae, Meliaceae, Arecaceae, Rhizophoraceae, Rubiaceae, Ctenolophonaceae, etc. together with oleanene and ursane types of triterpenoids suggest the contribution from angiosperms source vegetation. Interestingly, the presence of Araucareaceae and Podocarpaceae pollen grains shows the existence of gymnosperms vegetation. Further, the presence of tetracyclic diterpanes; demethylated ent-beyerane, sandaracopimarane, pimarane, and Kaurane type of compounds confirms the contribution of conifers. The variation in the values of the coefficient of non-equality (H: 0.68%–7.56%), the standard deviation (δ: 0.04%–0.16%) and the coefficient of variability (V: 16.10%–46.47%), also shows the heterogeneity in the source organic matter.The various petrographical indices, palynological entities, and geochemical parameters indicate that the peat-forming vegetation was accumulated under a mixed environment and fluctuating hydrological settings. The interpretation of palynofacies data on APP (Amorphous organic matter-Phytoclast-Palynomorphs) diagram suggests that the accumulation of organic matter occurred in a dysoxic-suboxic condition in a proximal (to land) setting with the shift to an anoxic condition in distal setting towards the termination of sedimentation. The huminite (ulminite) reflectance (Rr) values (av. 0.28%) showed a good relationship with average Tmax value (414 ​°C), suggesting the immaturity. The TOC content ranges of 13–59 ​wt.%, and HI values vary between 101 and 546 ​mg HC/g TOC in the studied samples. Collectively, the studied lignite and shale samples have the admixed kerogens (Type III–II) and exhibit the ability to generate the gaseous to oil hydrocarbons upon maturation.

Arctic vegetation, temperature, and hydrology during Early Eocene transient global warming events

Early Eocene global climate was warmer than much of the Cenozoic and was punctuated by a series of transient warming events or ‘hyperthermals’ associated with carbon isotope excursions when temperature increased by 4–8 °C. The Paleocene-Eocene Thermal Maximum (PETM, ~55 Ma) and Eocene Thermal Maximum 2 (ETM2, 53.5 Ma) hyperthermals were of short duration (<200 kyr) and dramatically restructured terrestrial vegetation and mammalian faunas at mid-latitudes. Data on the character and magnitude of change in terrestrial vegetation and climate during and after the PETM and ETM2 at high northern latitudes, however, are limited to a small number of stratigraphically restricted records. The Arctic Coring Expedition (ACEX) marine sediment core from the Lomonosov Ridge in the Arctic Basin provides a stratigraphically expanded early Eocene record of Arctic terrestrial vegetation and climates. Using pollen/spore assemblages, palynofacies data, bioclimatic analyses (Nearest Living Relative, or NLR), and lipid biomarker paleothermometry, we present evidence for expansion of mesothermal (Mean Annual Temperatures 13–20 °C) forests to the Arctic during the PETM and ETM2. Our data indicate that PETM mean annual temperatures were ~2° to 3.5 °C warmer than those of the Late Paleocene. Mean winter temperatures in the PETM reached ≥5 °C (~2 °C warmer than the late Paleocene), based on pollen-based bioclimatic reconstructions and the presence of palm and Bombacoideae pollen. Increased runoff of water and nutrients to the ocean during both hyperthermals resulted in greater salinity stratification and hypoxia/anoxia, based on marked increases in concentration of massive Amorphous Organic Matter (AOM) and dominance of low-salinity dinocysts. During the PETM recovery, taxodioid Cupressaceae-dominated swamp forests were important elements of the landscape, representing intermediate climate conditions between the early Eocene hyperthermals and background conditions of the late Paleocene. • Arctic vegetation in the PETM and ETM2 included broadleaf forests, palms, and subtropical taxa. • Taxodioid swamp forests dominated Arctic landmasses during the PETM recovery. • Mixed conifer-broadleaf forests occupied Arctic sites during non-hyperthermals. • Proxy data indicate increased runoff and hypoxia during Eocene hyperthermals. • Bioclimatic and brGDGT indicators show ~2–3.5 °C warming during hyperthermals.

Palaeoenvironmental changes recorded in the palynology and palynofacies of a Late Permian Marker Mudstone (Galilee Basin, Australia)

Reconstructing the terrestrial palaeoenvironment during the end-Permian is made challenging by widespread erosion and ecosystem destruction. High-resolution sampling for palynofacies and palynology in sections that preserve the boundary interval allows for detailed examination of the drastic environmental changes that characterize the Permian–Triassic mass extinction. In the Bowen and Galilee basins in eastern Australia, this environmental perturbation is recorded within a Marker Mudstone that occurs above the uppermost Permian coal seams. The Marker Mudstone is used as a stratigraphic reference level at many localities, but has previously only been studied at a single locality in the Bowen Basin. In the present study, borehole Tambo 1-1A drilled in the Galilee Basin was selected to clarify whether this black, organic-rich mudstone marks a marine transgression, and to examine potential indicators of the end-Permian mass extinction. A total of 22 samples were taken from the mudstone unit, and from the over- and underlying strata and processed for palynology, palynofacies, and carbon isotope analysis.Biostratigraphic data indicate that the Marker Mudstone itself covers the uppermost part of unit APP5, with the first index taxa of unit APP6 floras occurring in samples less than 80cm above this interval. This can be correlated with several other localities in the Bowen and Sydney basins where this shift occurs just above the uppermost Permian coal seam. Palynofacies data agree with previous interpretations of a southwards prograding delta that subsides as base level rises to form an extensive waterbody in which the Marker Mudstone was deposited. A change from translucent phytoclast-dominated to opaque phytoclast-dominated palynofacies within the Marker Mudstone suggests a shift to more oxic conditions in the water column, while base level begins to fluctuate, or increased terrestrial input from fluvial systems as the hinterland rises. Algal bodies resembling Botryococcus are found in the strata above the Marker Mudstone, but differ in morphology from the algal bodies found in the deltaic facies below. The presence of acanthomorph acritarchs in the Marker Mudstone and in the overlying Rewan Formation may indicate marine influence. Forms resembling fungal spores are present, but they do not show a “spike” as seen in other P–T boundary localities.The relative position of unit APP6 to the P–T boundary itself remains unclear. APP6 assemblages are dominated by simple acavate trilete and cavate trilete spores, which suggests stressed environment dominated by ferns and lycopods. The presence of degraded phytoclasts towards the top of the Marker Mudstone may also be used to suggest a mass-extinction interval. They may also be indicative of shifting local palaeoenvironmental changes, an interpretation that is supported by the low magnitude negative excursion of the δ13C isotope values within the Marker Mudstone. More datasets from the Bowen and Galilee basins will be essential to decoupling these signals.

Source rock evaluation and thermal maturity modeling of Jake oil fields, Fula sub-basin, Muglad Basin, Sudan

Comprehensive source rock evaluation, burial history modeling, and thermal maturity of oil generation have been investigated in petroleum system of Jake oil fields. The consideration of geological, geochemical, and palynofacies data was used for source rock and thermal maturity. Basin Mod® software was applied to construct the burial and thermal histories and to determine the timing of hydrocarbon generation and expulsion. The modeling was achieved through transient heat flow and collaborated with measured %Ro. The Lower Cretaceous Abu Gabra Formation was believed to be organic-rich shale and characterized by source rock of excellent abundance and potential that possesses total organic carbon (TOC) ranging from 0.37 to 6.27 wt% and production yield 1.31–49.23 mg HC/g rock. Kerogens can be classified as oil-prone types I–II. Vitrinite reflectance (Ro) and Tmax values suggested that most samples were of early maturation for oil generation. Palynofacies and geochemical combination indicated that amorphous phytoclasts of plant debris were dominated by high TOC and hydrogen index (HI), whereas assemblage kerogens confirmed the presence of oil source rock. Geohistory models showed the highest rapid subsidence rates during the Early-Late Cretaceous. The results demonstrated that petroleum could be generated in the upper (1950–2500 m) and the lower intervals (2550 total depth) of Jake South field. Maturity and hydrocarbon generation modeling indicated that the source rocks reached the early maturation stage in the Early Cretaceous (127 Ma) at a temperature of 90 °C. The middle maturation stage began in the Late Cretaceous (64 Ma) with a temperature of 110 °C. Essential oil generation started approximately 63 Ma ago and continues to the present day.

A palynofacies study of past fluvio-deltaic and shelf environments, the Oligocene-Miocene succession, North Sea Basin: A reference data set for similar Cenozoic systems

Abstract Correct interpretations of depositional environments are fundamental for evaluating the geological history of a sedimentary basin. Palynofacies analyses are a valuable supplement to sedimentological and seismic studies. In order to develop a palynofacies reference dataset for fluvio-deltaic and shelfal successions, a study of the assemblages of sedimentary organic particles from seven different well-defined depositional environments within the uppermost Oligocene – lower Miocene succession onshore Denmark (eastern North Sea Basin) has been performed. The study deals with the following environments; floodplain, lagoon, washover-fan flat, prodelta, shoreface, offshore transition and shelf. The sedimentary organic particles were grouped into four major categories; 1) Structured wood particles, 2) Amorphous organic matter (AOM, in the present study mainly consisting of partly degraded vitrinite), 3) Cuticle and membranes and 4) Palynomorphs. The palynomorphs were grouped into eight subcategories; 1) Microspores, 2) Non-saccate pollen, 3) Bisaccate pollen, 4) Botryococcus, 5) Other freshwater algae, 6) Fungal hyphae and –spores, 7) Acritarchs and 8) Organic-walled dinoflagellate cysts. A combination of a univariate box plots and a multivariate Principal Component Analysis (PCA) of the palynofacies data clear revealed the quantitative characteristics and variations within each discrete environment as well as their principal similarities and differences. In spite of some natural overlaps, for example between the lagoon and offshore transition environments, the data revealed distinct characteristics, e.g. a strong dominance of wood particles in the shoreface environment, a strong dominance of bisaccate pollen in the washover-fan flat environment and a near absence of dinocysts in the floodplain environment. An overall increase in relative abundances of dinocysts and a decrease in abundances of non-saccate pollen in the proximal-distal trend were also outlined. This study outlines a palynofacies reference dataset that can be used as a tool for interpreting depositional environments in equivalent settings, preferentially combined with other information such as seismic data, well logs, and/or lithology.