Hydrocarbon generation in Taranaki Basin, New Zealand, has been proven in several source rocks within the syn- and post-rift basin-fill sedimentary successions. These source rocks are mainly hosted in the marginal and deep marine Upper Cretaceous shales, which generate marine and terrigenous oils. Some of the terrigenous oils could have been linked to the Paleogene coals; however, the capability of these coals to generate and expel liquid hydrocarbons is poorly-investigated. In this study, we present organic geochemistry, kerogen petrography, wireline logging, and basin modelling to evaluate the hydrocarbon generation potential of the Paleogene coals and coal-rich facies of the Kapuni Group sediments in Kapuni Field, Taranaki Basin. A compositional correlation between oil in the Kapuni Group reservoirs and coal extracts was performed to decipher the oil origin and define its parent source rock. Kapuni oils display high pristane/phytane (Pr/Ph) > 5, low dibenzothiophene (DBT)/phenanthrene <0.1 and high relative abundance of C29 regular steranes >60%, typifying their generation from a terrigenous source rock deposited in an oxic, fluvio-deltaic environment. Similar values were also observed in the muddy coal extracts of Farewell Formation, thereby reflecting a positive coal-oil correlation. The maturity-relevant biomarkers (Ts/Tm trisnorhopanes; C29 steranes isomers, and 22S-, 22R C32 homohopanes) are similar in both oils and Farewell coal extracts confirming oil expulsion from Farewell coals during the peak oil window maturity. These results demonstrate the generation and expulsion of coal-oil, thereby shedding light on the prospectively of the Paleogene plays in the Taranaki Basin.