Paleo-Asian Oceanic Plate Research Articles

Sedimentary provenance supports a mid-paleozoic tectonic connection between the Junggar and Altai terranes in central Asia

The provenance of Precambrian detritus in the Junggar and Altai terranes provides crucial constraints on the peri-Siberian accretionary tectonic evolution in the middle Paleozoic. The Precambrian detrital zircons have no coeval magmatic equivalents in the Junggar terrane but show U–Pb age spectra and εHf(t) values comparable to those in the Altai terrane. The correlations suggest that the old detrital materials in the Junggar and Altai terranes were most likely derived from the Siberia craton and adjacent Tuva-Mongolian microcontinent. Paleozoic zircons in the Junggar terrane display a εHf(t) pattern from large spread to dominantly positive values at ca. 420–410 Ma. Such an abrupt change points to an accretionary tectonic transition from an advancing to retreating mode during mid-Paleozoic time, synchronous with similar tectonic switch occurring in the Altai terrane. Taking into account the temporal and spatial relations in sedimentation, tectonism and arc magmatism, we propose that the Junggar terrane had once collided onto the peri-Siberian Altai terrane to receive abundant old detritus from the Siberian continent in the Silurian–early Devonian. They were subsequently separated at ca. 420–410 Ma, possibly due to the slab rollback of the subducting Paleo-Asian Ocean (PAO) plate. These results constrain an Early Paleozoic tectono-paleogeographic boundary of the CAOB along the North Tianshan–Solonker suture zone, and also imply a long-lived PAO subduction was responsible for the Neoproterozoic to Paleozoic accretionary orogenesis at the margins of southern Siberia, eastern Kazakhstan, and northern Gondwana.

Paleozoic subduction of the Paleo-Asian Ocean plate: Constraints from Ordovician-Carboniferous volcano-sedimentary rocks in the northern Beishan orogenic collage, NW China

The subduction history of the Hongshishan Ocean within the Beishan orogenic collage is crucial to understand the evolutionary mechanism of the Paleo-Asian Ocean. In this study, we describe the petrography, ages and geochemistry of an Ordovician–Carboniferous volcano-sedimentary succession, which provides a record of the subduction history of the Hongshishan Ocean. We obtained early Ordovician zircon U-Pb ages (482 ± 6 Ma and 472 ± 2 Ma) from the Xianshuihu Formation. The youngest weighted mean detrital zircon age from the Yuanbaoshan Formation is 421.0 ± 8.8 Ma. Most detrital zircons have prominent age peaks at 900–840 Ma and 543–462 Ma, suggesting a main source from the southern Mongolian microcontinent. Volcanic rocks from the Baishan Formation yielded weighted mean ages of 299.3–300.3 Ma. During the Ordovician–Devonian, some volcanic arcs formed on the northern side of Hongshishan-Baiheshan-Erlegen Ula (HBEU) ophiolitic belt, indicating that the Hongshishan Ocean had a northward subduction polarity. During the Carboniferous, continental arcs were well developed on both sides of the HBEU belt, suggesting a bidirectional subduction. An archipelago of multiple arcs of the Hongshishan Ocean resembles that of the West Pacific Ocean. The change in subduction polarity can be attributed to characteristics of multi-oceanic accretion.

The Ordovician Arc–Basin System in the Northern Great Xing’an Range (Northeast China): Constraints from Provenance Analysis of the Luohe Formation

The Northeast China Block is a major component of the Central Asian Orogenic Belt, and its tectonic evolution has attracted much research attention. Ordovician strata are important in reconstructing the tectonic evolution of the Northeast China Block. This paper presents the results of sedimentological, zircon U–Pb, and geochemical analyses of sandstones of the Luohe Formation in the Wunuer area, Northern Great Xing’an Range, Northeast China. Lithological data, sedimentary structures, and grain-size analysis indicate that the Luohe Formation was deposited in a shallow marine environment. Detrital zircon U–Pb dating yields age peaks of 463, 504, 783, 826, 973, and 1882 Ma for sandstones from the Luohe Formation. The youngest zircon grain age of 451 ± 6 Ma represents the maximum depositional age of the Luohe Formation. The peak age at 463 Ma is consistent with the timing of post-collisional magmatism and the formation of the Duobaoshan island arc, while the peak at 504 Ma is consistent with the timing of magmatic activity related to the collision between the Erguna and Xing’an blocks. The peaks at 788, 826, 973, and 1882 Ma correspond to magmatism in the Erguna block, these ages indicate that the sandstones of the Luohe Formation were derived mainly from the Erguna block. Sandstone modal compositional analysis indicates that the provenance of the Luohe Formation was mainly a magmatic arc. The geochemical compositions of the sandstones suggest that the source rocks have continental island arc signatures. Based on the depositional age, sedimentary environment, provenance, and regional geology, it is concluded that the Luohe Formation was deposited in a back-arc basin setting during the formation of the Duobaoshan island arc–basin system in response to subduction of the Paleo-Asian oceanic plate.

Heavy mineral indicators of ridge subduction beneath the Bainaimiao arc in the southeastern Central Asian Orogenic Belt

As one of the major subduction-accretionary systems in the southeastern Central Asian Orogenic Belt, the Bainaimiao arc presents a valuable opportunity for investigating the subduction–accretion process of accretionary orogens. It is located adjacent to the northern margin of the North China Craton and developed arc-related deposits during the Silurian–Devonian period. In this paper, we employed heavy mineral geochemistry and U–Pb ages of zircon and rutile, to determine the provenance of the Silurian–Devonian deposits and reconstruct the paleogeography of the source area. The stratigraphic units involved include the Xuniwusu Formation of Early Silurian and the Xibiehe Formation of Early Devonian.Both the Xuniwusu and Xibiehe formations exhibit heavy mineral assemblages dominated by zircons and tourmalines. Nevertheless, the Xibiehe Formation contains Cr-spinels and garnets which are absent in the Xuniwusu Formation. Geochemical analyses of the detrital Cr-spinels exhibit characteristics of a supra-subduction zone ophiolite. The garnets originated from middle- to high-grade metamorphic rocks, as well as mafic and felsic rocks. The tourmalines in both formations primarily indicate a metasedimentary rock source, with a small percentage of Li-poor granitoid species in the Xuniwusu Formation. The U–Pb age spectra of both detrital zircon and rutile in the Xuniwusu Formation show multiple peaks. The age spectra consist of Precambrian ages, indicative of a recycled origin, as well as Paleozoic ages, suggesting a magmatic origin. In contrast, the U–Pb age spectra of zircon and rutile in the Xibiehe Formation display a unimodal age peak at ca. 455 and 490 Ma, respectively. These differences suggest a provenance shift from the Xuniwusu to Xibiehe formations. The Xuniwusu Formation was sourced from the Bainaimiao arc itself, whereas the Xibiehe Formation has a mixed origin of the Bainaimiao arc and Ondor Sum accretionary complex. The provenance change correlates with the unconformity between the two formations, suggesting a forearc uplift event. In combination with the previous research on the Tulinkai ophiolite, it can be inferred that the forearc uplift was triggered by ridge subduction of the Paleo-Asian Ocean plate at ca. 450–430 Ma. This research provided a new perspective on the ridge subduction of the oceanic slab in fossil orogens.

Age and Tectonic Setting of Layered Lead–Zinc Ore Bodies in the Xiaohongshilazi Deposit: Constraints from Geochronology and Geochemistry of the Volcanic Rocks in Central Jilin Province, NE China

The newly discovered Xiaohongshilazi deposit located in Panshi City, central Jilin Province, NE China, is a medium-scale Pb–Zn–(Ag) deposit. The Pb–Zn–(Ag) orebodies are divided into layered and vein-type orebodies, which have different ore geneses. The layered Pb–Zn orebodies are mainly hosted within and spatially controlled by the volcanic rocks. To constrain the age and tectonic setting of the layered Pb–Zn mineralization, we completed laser-ablation–ICP–MS zircon U–Pb dating and whole-rock major and trace element analyses of the ore-bearing volcanic rocks. The dacite samples were confirmed as belonging to the Daheshen Formation and were the main ore-bearing volcanic rocks for the layered orebodies. They yielded concordia U–Pb ages of 278.1 ± 1.8 Ma and 278.3 ± 1.8 Ma, respectively, indicating that the volcanic rocks from the Daheshen Formation and related layered Pb–Zn mineralization were formed in the early Permian. The andesite and rhyolite located above the layered orebodies yielded concordia U–Pb ages of 225.0 ± 1.1 Ma, 225.3 ± 1.5 Ma, and 224.7 ± 1.2 Ma, respectively; these substances are considered to be of the Sihetun Formation and were first reported in the area. The dacite samples associated with layered Pb–Zn mineralization were high in SiO2 (62.54–65.02 wt.%), enriched in LREEs and LILEs (e.g., Rb, Ba, and K), and showed depletion in HFSEs (e.g., P and Ti). It showed slightly negative Eu anomalies (δEu = 0.60–0.65) and negative Nb anomalies, with Th/Nb (1.12–1.21) and La/Nb (2.8–4.7) ratios, presenting subduction-related arc magma affinity formed in an active continental margin setting. In agreement with previous studies on zircon Hf isotopes (εHf (t) = +0.23~ +10.60) of the volcanic rocks from the Daheshen Formation, we infer that they were derived from the partial melting of the depleted lower crust. In conclusion, mineralization characteristics, geochronological data, geochemical features, and regional tectonic evolution suggest that two Pb–Zn–(Ag) mineralization stages from the Xiaohongshilazi deposit occurred: the layered VMS-type Pb–Zn mineralization associated with the marine volcanic rocks from the early Permian Daheshen Formation, which was induced by the subduction of the Paleo-Asian oceanic plate beneath the northern margin of the North China Craton, and the vein-type Pb–Zn–(Ag) mineralization caused by the subduction of the Paleo-Pacific Plate in the early Jurassic. Considering this, along with the mineralization characteristics of the same-type polymetallic deposits in this region, we propose that the early Permian marine volcanic rocks have great prospecting potential for the VMS-type Pb–Zn polymetallic deposits.

Volcanic Age and Geochemistry of the Permian Linxi Formation in Northeast China: Implications for the Tectonic Evolution of the Paleo-Asian Ocean

Abstract The tectonic evolution of the Paleo-Asian Ocean (PAO) has been well studied, including its gradual narrowing and closure by subduction. However, aspects of the tectonic evolution of the oceanic domain remain unclear, including the exact timing and nature of the closure. The Central Asian Orogenic Belt (CAOB) was formed by the closure of the PAO and, therefore, contains information about the tectonic evolution of the oceanic domain. Here, we report a study of the petrology, geochronology, and geochemistry of the Taohaiyingzi section of the Permian Linxi Formation in Alukhorqin Banner (Northeast China) in the central part of the CAOB. A newly discovered andesitic tuff from the lower part of the Linxi Formation yields a weighted mean 206Pb/238U age of 262.2 ± 1.1 Ma (n = 87), indicating that the lower part of the Linxi Formation of the Taohaiyingzi section was deposited during the late Guadalupian. Provenance weathering indicators show that the sedimentary rocks of the Linxi Formation are of low maturity. Element geochemical characteristics indicate that the Linxi Formation clastic rocks were derived from eroded magmatic rocks that formed in a continental arc setting and were deposited close to the arc in a continental arc basin environment. The active margin setting was generated by the subduction of the paleo-Asian oceanic plate beneath the Xilinhot–Songliao block. The inferred palaeosalinity of the sedimentary environment changed gradually from brackish to fresh water, suggesting the end of oceanic plate subduction during the late Guadalupian, and the closure of the PAO during or after the Lopingian.

Formation of columnar/tabular and vermicular kaolinite in the crystal tonsteins within the Late Carboniferous Coal in the Datong Coalfield, Shanxi Province, North China

The Datong Coalfield, Shanxi Province, North China, is rich in high-grade coal-measure kaolin, primarily occurring as partings within the Late Carboniferous–Early Permian coal seams. There is a type of kaolinite-dominant coarse-grained parting similar to sandstone in appearance, whereas the phanerocrystalline minerals are columnar/tabular and vermicular kaolinite rather than terrigenous detrital minerals. The origins of the coarse-grained partings and the formation mechanism of the columnar/tabular and vermicular kaolinite remain ambiguous. Herein, petrographical, mineralogical, whole-rock geochemical, and zircon U–Pb–Hf isotopic studies of the coarse-grained partings were conducted to explore these issues. The zircons in the coarse-grained partings show typical features of magmatic origin and yield a single age group of very latest Carboniferous at ca. 300 Ma, indicating they were transformed from air-fall volcanic ash. Therefore, the coarse-grained partings are essentially crystal tonsteins. The wide range of negative εHf(t) values and arc-related tectonic affinity of the zircons genetically link the primary volcanic ash to the Late Paleozoic continental arc volcanoes that existed in the Inner Mongolia Paleo-Uplift, related to the southward subduction of the Paleo-Asian oceanic plate beneath the North China Block. Two orthogonal cleavages are generally observed on the columnar/tabular and vermicular kaolinite in the crystal tonsteins, contradicting the crystalline structure of kaolinite that belongs to a 1:1 type phyllosilicate with only one cleavage along its (001) lattice plane. These columnar/tabular and vermicular kaolinite are considered to be pseudomorphic kaolinite after plagioclase in the crystal-rich volcanic ash. When the crystal-rich volcanic ash fell into open and acidic peat-forming environments (mires), the low-pH water containing abundant organic acids and good water circulation conditions facilitate dissolution of plagioclase along the chemically unstable (001) lattice planes and leaching out of Na+, Ca2+, and much of silica. Simultaneously, the Al3+ or hydroxides of aluminum and silica recrystallized along the (001) lattice planes of plagioclase as the substrate, constraining layer-by-layer growth of large kaolinite platelets to eventually form pseudomorphic kaolinite. The cleavages perpendicular to the exclusive (001) cleavage of pseudomorphic kaolinite should be inherited from the twin planes and (010) cleavage cracks (if present) of plagioclase.

Geodynamic controls on the Paleo-Asian oceanic plate evolution: Constraints from Paleozoic intrusive suites along the northern margin of the North China Block

Identifying the spatio-temporal variations of arc-relation magmatism is critical for determining the polarity, geometry, localization, and onset of subduction zones on Earth. When and how the Paleo-Asian oceanic plate subducted beneath the northern margin of the North China Block (NCB) have been widely debated. Here we conducted systematic petrological, geochronological, and geochemical investigations on the Paleozoic magmatic rocks in the northern NCB. The Early Paleozoic magmatic rocks (ca. 490–420 Ma) are only distributed in the Bainaimiao arc and show typical continental arc geochemical characteristics, indicating a south dipping subduction zone. The Devonian alkaline rocks (ca. 400–370 Ma) constitute a ∼ 900 km-long magmatic belt in the northern margin of the NCB. Combined with a striking ca. 370–355 Ma magmatic quiescence and the absence of high-pressure rocks during that period, a flat-slab subduction model is proposed to better account for the tectonic evolution of the northern NCB. Subsequently, the Carboniferous to Permian calc-alkaline arc magmatism (ca. 355–250 Ma) began to emerge and showed northward younging and migration, suggesting slab retreat with roll-back of the subducting Paleo-Asian slab and again opening of mantle wedge along the northern NCB. Our findings therefore suggest that the Paleozoic magmatism in the northern NCB records an entire spatio-temporal evolution of the Paleo-Asian oceanic plate from early subduction angle deepening to flat-slab subduction, then slab rollback and finally normal subduction. This is tentatively interpreted as a combined effect from the Paleo-Asian oceanic plate subduction angle change and a migrating keel in the mantle wedge region.

Identification of metasomatic components in lithospheric mantle under multiple tectonic regimes: Insights from Early Cretaceous mafic rocks in the northeastern North China Craton

Identification of mantle metasomatic components under multiple tectonic regimes is crucial for reconstructing the subduction history of multiple plates. Representative Early Cretaceous (125–122 Ma) gabbroic diabase from the northeastern North China Craton (NCC), provides a geochemical record to explore the genetic relationship between mantle metasomatic agents and tectonic evolution. Samples from gabbroic diabase exhibit low SiO2 and high MgO contents as well as arc-like trace element patterns, suggesting a sub-continental lithospheric mantle (SCLM) origin. Their inherited zircons and isotope variations indicate the existence of two crustal components with different tectonic affinities that were recycled into the SCLM: Paleo-Asian oceanic crust and Yangtze Craton continental crust. The metasomatic signatures of the two crustal components are previously imprinted on the geochemical compositions of the studied mafic rocks. Subsequently, the melting of the metasomatic SCLM is triggered by the subduction of the Paleo-Pacific Plate. Based on the identification of mantle metasomatic components in this study and previous geological evidence, the spatial extents of the subduction influence of the Paleo-Asian oceanic plate and Yangtze Craton on the SCLM beneath the northeastern NCC are broader than previously considered. These new findings signify a critical role of the mantle metasomatic components that can effectively identify the geological relics of the previous plate subduction. Thus we believe that the former mantle metasomatism and latter mantle melting for mafic rocks suggest two geological implications.

Provenance of multi-stage volcanic ash recorded in the Late Carboniferous coal in the Jungar Coalfield, North China, and their contribution to the enrichment of critical metals in the coal

The origins of partings within the Late Carboniferous No. 6 coal in the Jungar Coalfield, North China, and their relationship to the enrichment of critical metals in the coal, is poorly understood. This study combines UPb ages and LuHf isotope data of zircon, whole-rock geochemistry, LA–ICP–MS elemental mapping, and selective chemical extraction experiments to investigate the provenance of the partings and the occurrence mode of critical metals in the partings collected from the exploration area in the northwest of the Jungar Coalfield. It was found that the zircons in the kaolinite-dominant partings yielded a single age group of ca. 300 Ma at the latest Carboniferous (Gzhelian), indicating that the partings are alteration products of air-fall volcanic ash (tonsteins). The zircons are characterized by negative εHf(t) values and a continental arc tectonic setting, suggesting a genetic connection between the volcanic ash and the Late Paleozoic continental arc that existed in the Inner Mongolia Paleo-Uplift, related to the southward subduction of the Paleo-Asian oceanic plate beneath the northern margin of the North China Block. During the devitrification of volcanic glasses to kaolinite in the mires, the incompatible elements, such as Nb, Ta, Zr, Hf, and rare earth elements (REEs and Y, REY), preserved in the volcanic glasses were leached out as they are incompatible with the crystal lattice of kaolinite. Niobium and Ta, similar to Ti in ionic radii, were preferentially incorporated into fine-grained Ti oxides as reprecipitated products in the alteration process of volcanic ash. The enrichment of Nb, Ta, and Ti in organic matter in the tonsteins suggests that they have some mobility during alteration of volcanic ash and could be, to some extent, transported into the enclosing peats. Zirconium, Hf, and REY were fixed by organic matter admixed with the volcanic ash after their deposition in the mires. Meanwhile, they could also be transported into the enclosing peats, as no secondary minerals formed could substantially retain them. Although Li and Ga were able to be incorporated into the crystal lattice of kaolinite during their crystallization, they could also be transported into the enclosing peats due to their fluid-mobile nature. Both the leaching of a voluminous amount of volcanic ash contacting with the peats and the input of the volcanic ash as an admixture into the peats contributed to the enrichment of critical metals in the Late Carboniferous coal in the Jungar Coalfield.

Triassic volcanism on the North margin of the North China Craton: Insights for lithospheric modification during closure of Paleo-Asian Ocean

As a key tectonic region linking the northern margin of the North China craton (NCC) and eastern Central Asian Orogenic Belt (CAOB), western Liaoning, with extensively distributed magmatic activity, provides natural samples to investigate the evolutionary history of the Paleo-Asian Ocean plate subduction to closure. The Middle Triassic (ca. 241 Ma) trachyandesites and Late Triassic (ca. 223 Ma) basaltic andesites were first identified from the Tiaojishan Formation, western Liaoning. They have variable SiO 2 contents (52.48–60.31 wt%) and alkaline or high-K calc-alkaline to shoshonite compositions, and belong to the metaluminous series. Middle Triassic trachyandesites are enriched in large ion lithophile elements (LILEs), high field strength elements (HFSEs), and light rare earth elements (LREEs) with high Nb/La ratios (0.63–0.76). They have homogeneous whole-rock Sr Nd ( 87 Sr/ 86 Sr i = 0.704684–0.704808, ε Nd (t) = −4.6 to −4.0) and variable zircon Hf isotopic signatures (ε Hf (t) = −10.3 to 8.2), indicating that they probably originated from the partial melting of the subcontinental lithospheric mantle with the addition of asthenosphere materials. In contrast, the Late Triassic basaltic andesites show arc-related geochemical affinities, such as LILEs and LREEs enrichment and HFSEs depletion. They have more enriched whole-rock 87 Sr/ 86 Sr i (0.704895–0.705394), ε Nd (t) (−16.1 to −14.0), and zircon ε Hf (t) (−13.1 to −8.8) than the Middle Triassic trachyandesites, suggesting that they probably represent partial melts of the subduction-related fluids-modified lithospheric mantle. The modification of the northern margin of the NCC lithospheric mantle is closely related to the final subduction of the Palaeo-Asian oceanic plate and the subsequent post-orogenic extension. • Triassic volcanic rocks are founded in Tiaojishan Formation, Western Liaoning. • Study area was in a post-orogenic extensional setting in the Middle-Late Triassic. • Ocean Subduction modified the North China Craton lithosphere in the Triassic.

Petrogenesis and Tectonic Implication of the Hongtaiping High-Mg Diorite in the Wangqing Area, NE China: Constraints from Geochronology, Geochemistry and Hf Isotopes

This study presents new data from zircon U–Pb dating and Hf isotope analysis, as well as whole-rock major- and trace-element compositions of the Hongtaiping high-Mg diorite in the Wangqing area of Yanbian, NE China. Laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) zircon U–Pb dating gives an eruption age of ca. 267 Ma for the high-Mg diorite. These samples have MgO contents of 13.30% to 16.58% and high transition metal element concentrations, classified as sanukite. Their rare earth element (REE) contents range from 45.2 to 68.4 ppm and are characterized by slightly positive Eu anomalies (Eu/Eu* = 1.08–1.17). They show enrichment in light REEs (LREEs) and depletion in heavy REEs (HREEs), with LREE/HREE ratios = 6.54–6.97 and (La/Yb)N values = 7.24–8.08. The Hongtaiping high-Mg diorite is enriched in Rb, U, K, and Sr, but depleted in Th, Nb, and Ta. High MgO contents, Mg# values, and transition metal element concentrations imply that the magma experienced insignificant crystallization fractionation and crustal contamination. Relatively homogenous positive Hf isotopic values indicate that the original magma was generated by the partial melting of a depleted mantle wedge that was metasomatized by subducting slab fluids. The magma was generated by the moderate degree partial melting (20%–30%) of a garnet lherzolite source. Combined with previous studies, this shows that the high-Mg diorite was formed by the northward subduction of the Paleo-Asian oceanic plate during the Middle Permian.

Petrogenesis, tectonic setting, and metallogenic significance of the Middle Permian volcanic rock system of the Miaoling Formation, Yanbian area, NE China: Constraints from geochronology, geochemistry, and Sr–Nd–Hf isotopes

The volcanic rock system of the Miaoling Formation contains the main ore-bearing rocks of two volcanogenic massive sulfide (VMS)-type deposits in the Yanbian area of NE China. Investigation of the VRSMF is needed to better understand the formation of these VMS-type deposits and the tectonic evolution of the Yanbian area. To determine the petrogenesis, material sources, and formation age of the VRSMF, and elucidate its late Paleozoic tectonic evolution and metallogenic significance, this paper presents new petrological, geochronological, geochemical, whole-rock Sr–Nd and in situ zircon Hf isotopic data for the VRSMF. The VRSMF is composed of marine carbonate, intermediate–felsic volcanic rocks (andesite–trachyandesite–dacite) and pyroclastic rocks. Laser-ablation–inductively coupled plasma–mass spectrometry zircon U–Pb dating gives an eruption age of ca. 265 Ma for the pyroclastic rocks in the VRSMF. These rocks are classified as low- to medium-K calc-alkaline series. They are characterized by enrichments in large-ion lithophile elements (e.g., K, Rb, and Ba) and light rare earth elements, and depletions in high field-strength elements (e.g., Nb, Ta, and Ti) and heavy rare earth elements, showing affinity to igneous rocks formed in arc-related tectonic settings. These features, together with homogeneous zircon εHf(t) values of 10.9–15.7 and depleted Sr–Nd isotopic compositions [εNd(t) values of 2.4–5.0], suggest that the parental magma was derived from the partial melting of depleted mantle that had been metasomatized by subduction-related fluids. These results, along with findings of regional geological investigations, suggest that the formation of the VRSMF was related to subduction of the Paleo-Asian oceanic plate during the middle Permian. The VMS-type mineralization in the Hongtaiping and Dongfengnanshan deposits is interpreted to have formed in a bimodal–felsic setting in a back-arc extensional tectonic environment.

Detrital zircon age signatures of the basal Cambrian sandstone unit in North China: implications for drainage divides during global Sauk transgression and separation from Gondwanaland

ABSTRACT The basal Cambrian sandstone unit in the North China craton (NCC) is an example of globally widespread siliciclastic succession that resides on the Great Unconformity and deposited on a hypothesized low-lying peneplain during the Cambrian global eustatic sea-level rise. Detrital zircon age signatures from this distinct sequence enable recognition of the ancient drainage system of the NCC in deep time and track its potential linkage with the Gondwana landmass. LA-ICP-MS U–Pb dating of the fossil-calibrated basal Cambrian (Series 2) detrital zircon samples from seven measured sections reveal marked spatial changes in their age signatures that can be divided into three distinct types. The first is generally characterized by the bimodal age populations with broad peaks at ~1.85 Ga and ~2.5 Ga that correlate with the Archean to Paleoproterozoic basement inboard of the NCC. The second is featured by multimodal distribution with diagnostic Neoproterozoic peaks that correspond to subregional magmatic record. The third also shows multiple-zircon age populations, but yields significant crystallization ages close to the early Cambrian age. Comparing our new data with existing age spectra for the Cambrian strata across the NCC and the northern Gondwana demonstrates that separate drainage systems did exist in the peneplained basement during global Cambrian transgression and the basal Cambrian unit in the NCC was not a part of the far-travelled sand sheet across the northern margin of Gondwana. The most suitable source for Cambrian-aged grains constrained by paleogeographic restoration is the arc terrane developed along the northern margin of the NCC as a result of subduction of the Paleo-Asian oceanic plate. Our new continental-scale detrital zircon provenance signatures in the basal Cambrian unit suggest that the NCC should be considered a discrete continental block separated by the Proto-Tethys Ocean in the Cambrian, rather than an integral part of the northern Gondwana.

Supra-subduction zone ophiolite generated by the initial subduction of an Early Paleozoic island arc system abutting the northern North China Craton: Evidence from meta-igneous rocks

To constrain the evolution of an Early Paleozoic island arc belt abutting the North China Craton (NCC), this study presents new geochronological, geochemical, and Sr–Nd–Hf–O–Pb isotopic data for igneous rocks from the central part of Jilin Province within the southeastern part of the Central Asian Orogenic Belt. The igneous complex in this area hosts both mid-ocean ridge basalt (MORB)- and arc-type rocks that yield zircon 206Pb/238U ages of ca. 492 and 488–459 Ma, respectively. The MORB-type units in this area include metacumulate gabbros, metadiabases, and metabasalts that have normal MORB (N-MORB)-like compositions with (La/Yb)N values of 0.29–0.99, Th/Nb values of 0.07–0.52, whole rock εNd(t) values from +4.32 to +7.29, and initial 208Pb/204Pb values of 38.12–38.20. These compositions are indicative of derivation from the depleted asthenospheric mantle. The arc-type igneous rocks consist of amphibolite, epidiorite, and metagabbro with major- and trace-element and isotopic compositions that are similar to island arc tholeiite to calc-alkaline rocks, with (La/Yb)N values of 1.11–4.26, Th/Nb values of 0.11–2.25, zircon εHf(t) values from +6.03 to +15.30, zircon δ18O values from +4.32 to +5.1, whole-rock εNd(t) values from +2.09 to +7.25, and initial 208Pb/204Pb values of 38.09–38.11. These compositions are indicative of derivation from partial melting of the hydrous depleted mantle wedge material within an intra-oceanic arc setting. The MORB-type rocks formed within a forearc region of the SSZ ophiolite fragment, whereas the arc-type rocks record the evolution of this region from immature to mature island arc tectono-magmatic settings. Combining these new data with the results of previous research suggests that initial subduction of the Paleo-Asian oceanic plate abutting the northern NCC began during the latest Cambrian.

Genesis and Metallogenic Characteristics of the Zhunsujihua Granitic Intrusions in Sonid Left Banner, Inner Mongolia, China

The Zhunsujihua porphyry Mo-Cu deposit is located in the Erenhot–East Ujimqin metallogenic belt in northeastern China. Granodioritic intrusions in the mining area are dominated by granodiorite and granodiorite porphyry, but the Mo mineralization is limited within the granodiorite. Zircon LA-ICP-MS U-Pb dating yields crystallization ages of 301.5 ± 3.0 Ma for granodiorite and 296.0 ± 3.0 Ma for granodiorite porphyry. These ages constrain the magmatic activity at the Zhunsujihua deposit that took place during the subduction of the Paleo-Asian oceanic plate. Whole-rock geochemical data suggest that the granodioritic intrusions belong to calc-alkaline and high-K calc-alkaline series, and are characterized by enrichment in K, Rb, U, Th, and Pb, and depletion in Nb, Ta, Ti, and P. The negative Eu, Ba, and Sr anomalies suggest that they have experienced extensive fractionation of plagioclase. Trace element compositions of zircons from the Zhunsujihua deposit provide constraints on the oxygen fugacity (ƒO2) of the magma, which is shown to high values with ∆FMQ = +0.5 to +5.6. The wide range of zircon εHf (t) (+1.3~+9.4) values, positive whole-rock εNd (t) (+2.5~+3.9) values, and relatively low initial (87Sr/86Sr)i (0.70367~0.70561) ratios indicate that the magmas mainly originated from a juvenile lower crust source derived from depleted mantle, but mixed with pre-existing crustal components. Moreover, the juvenile lower crust represents the main source of Mo for the Zhunsujihua deposit. A high magmatic oxygen fugacity and fractional crystallization played key roles in forming the Zhunsujihua deposit.

Two Phases of Metamorphism in the High-Pressure Schists in Central Inner Mongolia, China: Implications for the Tectonic Transition From Terminal Subduction of the Paleo-Asian Ocean to Continental Collision

High-pressure (HP) rocks exhumed from subduction zones usually record much warmer geotherms than numerical modelling results, as their peak mineral assemblages are always modified during the exhumation process. The decompressional metamorphic evolution of HP rocks should be considered carefully if using their P–T records to constrain the thermal structure of a subduction zone. The Ondor Sum Group, known as mélanges containing various high P/T metamorphic rocks in central Inner Mongolia, represents a fragment of subducted oceanic crust in the Early Paleozoic, However, the thermal structure of the subduction zone is unavailable due to an absence of exhumed HP rocks with P–T estimates. In this study, the HP schists were newly discovered in the Ondor Sum Group at Airgin Sum in the central Inner Mongolia. The HP schists include a garnet–phengite schist (sample EL01) and a garnet–amphibole schist (sample EL08). The petrography of these rocks and phase equilibrium modelling using THERMOCALC suggest two phases of metamorphism, both of which are characterized by clockwise P–T evolutions involving pre-peak prograde stage, peak-stage, and post-peak decompression stage. The peak P–T conditions of the early-phase metamorphism are constrained by P–T pseudosections to be ∼18 kbar/∼535°C for sample EL01 and 18 kbar/∼500°C for sample EL08. The peak P–T conditions of the late-phase metamorphism are constrained by P–T pseudosections to be ∼8 kbar/532°C in EL01 and ∼7.0 kbar/495°C in EL08. Available U–Pb data of zircons from the HP schists and a granodiorite vein using LA–ICP–MS constrain the timing of early-phase HP metamorphism in the early Paleozoic and the late-phase metamorphism supposed to be in the Devonian based on the previous reported ages. The peak P–T conditions for the early-phase metamorphism were high-P/T conditions with a thermal gradient of ∼8°C/km, pointing to a warm oceanic subduction. The overprinting late-phase metamorphism represents medium-P/T conditions with a geothermal gradient of 22–25°C/km, which we attribute to a collisional thickening process. As a result, we suggest that the HP schists in the Ondor Sum Group represent the terminal stage of subduction of the Paleo-Asian oceanic plate, and that the schists were involved in the continental collision after the closure of the Paleo-Asian Ocean in the Devonian.

Provenance of the early Cretaceous sediments in the southern Alxa Area: Implications for tectonic evolution of the south Central Asian Orogenic Belt

The Central Asian orogenic belt is an accretionary orogenic belt that lies between the Siberian block and the Tarim and North China blocks. Since the central south of the Central Asian Orogenic Belt has been covered by desert and the Meso-Cenozoic Bayingobi Basin, its spatial configuration, evolution, closure time, and the Paleo-Asian ocean location have not been well described. Through zircon UPb dating, in-situ Hf isotope and rock geochemistry of the Lower Cretaceous Bayingobi Formation sandstones, the provenance of the Bayingobi Formation, and the central south boundary of the Central Asian orogenic belt were determined, the tectonic evolution process was discussed, and the tectonic evolution models were established. The provenance of the Bayingobi Formation mainly originated from Permian to Early Triassic granodiorite, diorite and potassium feldspar granite that cover a large area of the Zongnaishan-Shalazhashan tectonic belt. In the early Permian, this tectonic belt was mainly a continental island arc but gradually transitioned to a continental active margin, accompanied by intense tectonic magmatic activity. With the boundary as the Quagan Qulu ophiolite belt, the north is the Central Asian Orogenic Belt that mainly exhibits juvenile crustal materials, while the south is the Alxa block, which has an affinity with the North China block, and mainly exhibits older crustal materials. From the late Carboniferous to the early Permian, the Paleo-Asian Ocean plate was compressed, subducted along the Enger Us suture, and magmatic distributed along the Nuru-Langshan tectonic belt; from the late early Permian to late Permian, the Paleo-Asian Ocean plate rolled back, changing the subduction zone stress state from compression to extension. During this period, there were large-scale developments of magmatic rocks in the Zongnaishan-Shalazhashan tectonic belt. From early Early Triassic to Middle Triassic period, the Siberian active margin collided with the Alxa block, the Paleo-Asian Ocean was closed, and the overlying Alxa plate experienced lithospheric extension and thinning, accompanied by asthenospheric upwelling, partial melting and the addition of new crustal material. The Meso-Cenozoic basin sediments along the original suture belt are characterized by an enrichment of large ion lithosphere elements, a loss of high field strength elements, LREE enrichment and loss of HREE.

Ophiolites and ocean plate stratigraphy (OPS) preserved across the Central Mongolian Microcontinent: A new mega-archive of data for the tectonic evolution of the Paleo-Asian Ocean

Following the breakup of Rodinia and the opening of the Paleo-Asian ocean the relative positions of geological units (now in Mongolia) remain uncertain, and in consequence relevant paleogeographic reconstructions are poorly construed. In this paper, we apply an integrated approach to the reconstruction of the Paleo-Asian ocean using preserved ophiolites and ocean plate stratigraphy (OPS) in the Mongolian Lake and Altay zones in western Mongolia, which surround the Precambrian Central Mongolian Microcontinent (CMM) in the center of Central Asia.The Lake Zone of Mongolia contains many sediments of Ocean Plate Stratigraphy (OPS) and their underlying basalt-dominated ophiolites, which occur in three main zones along the western margin of the Precambrian crystalline basement of the CMM. The ophiolites in all zones have similar isotopic ages of ca. 570 Ma. The sections of OPS, together with serpentinite mélanges and other volcanogenic-sedimentary assemblages, have been thrust in nappe sheets over the Zavkhan block of the CMM.In the Neoproterozoic microcontinents derived from Rodinia drifted towards Siberia, and a passive margin developed on the Zavkhan block on the eastern margin of the Paleo-Asian ocean. In mid-upper Neoproterozoic times the eastern side of the Paleo-Asian oceanic plate was thrust over the CMM, and in the early Cambrian the Khasagt and Tas Khairkhan ophiolites were obducted and a mid-ocean ridge (?) reached the CMM, preventing further obduction. In the Neoproterozoic the western margin of the Paleo-Asian ocean was subducted under the Rodinia-derived microcontinent and evolved into an active continental margin. In mid-Cambrian–early Ordovician times thick turbidites were deposited in the Altay. Marine sediments, which had accumulated in the Devonian to Carboniferous in the Paleo-Asian ocean are preserved in a remnant ocean in the Lake Zone. Locally in the Devonian, terrigenous – volcanogenic sequences were deposited in the Ulgey extensional superimposed basin, and later in Meso-Cenozoic time (?) some ophiolitic and OPS fragments (Tsagaan Nuur, Ulaankhus and Bodonch) were exposed along fault escarpments that were possibly re-activated during transpression related to the India-Eurasia collision.Our analysis of the Neoproterozoic–Middle Paleozoic tectonic development of western Mongolia leads to a new holistic model for the evolution of the western Altaids, according to which the ophiolites and OPS formed in the Mongolian Lake and Altay zones between two microcontinents within a new tectonic framework of the western Altaids.

Late Paleozoic subduction-related magmatism in NE China and its implication: Insights from intrusions in the Handagai Fe[sbnd]Cu deposit

North East (NE) China forms the easternmost part of the Central Asian Orogenic Belt. However, its Paleozoic geological evolution process remains controversial, especially the complex subduction-accretion-orogeny processes of the Paleo-Asian Ocean plate, as well as the linking magmatism-metallogenic with tectonic evolution during that time. This paper reports the results of geochemical, geochronological, and isotopic analyses of igneous rocks at the Handagai skarn Fe–Cu deposit to elucidate the late Paleozoic tectonic framework and evolution of NE China and the setting of ore formation. New zircon LA–ICP–MS U–Pb data for monzogranite, quartz diorite, and quartz monzodiorite record Carboniferous ages of 350 ± 2 Ma, 321 ± 3 Ma, and 319 ± 2 Ma, respectively. The monzogranites have high SiO2 (69.57–71.97 wt%) and total-alkali (6.68–7.56 wt%) contents and relatively low MgO contents (0.60–1.03 wt%) and Mg numbers (33–41). They have arc-type trace-element signatures, with enrichment in large-ion lithophile elements and light rare earth elements, together with depletion in Nb, Ta, P, and Ti. Their whole-rock Sr–Nd–Pb and zircon in-situ LuHf isotopic compositions ((87Sr/86Sr)i = 0.7008–0.7062; εNd(t) = −1.9 to +1.9; (206Pb/204Pb)t = 17.900–19.006; εHf(t) = 5.04–15.28) and young two–stage Nd–Hf model ages (TDM2 = 1105–749 Ma and 899–574 Ma, respectively) indicate that their precursor magma was derived from partial melting of Mesoproterozoic to Neoproterozoic juvenile lower crust that had been metasomatized by fluids/melts from an enriched mantle wedge. The quartz diorites and quartz monzodiorites are characterized by intermediate SiO2 (58.21–61.47 wt%), high MgO (3.62–5.42 wt%), and low CaO (3.15–4.96 wt%) contents, and high Cr (151–222 ppm) and Ni (97–131 ppm) contents, as well as elevated Sr and Ba. They have strong Nb and Ta depletion and highly fractionated rare earth elements, indicating a geochemical affinity to typical high-Mg andesites. These rocks exhibit mid-ocean ridge basalt (MORB)-like whole-rock Nd–Sr–Pb–Hf isotopic characteristics, with high εNd (t) and εHf (t) values of +1.60 to +3.20 and + 10.21 to +13.61, respectively, and relatively low (87Sr/86Sr)i and (206Pb/204Pb)i ratios of 0.7028–0.7045 and 16.768–17.856, respectively. They also have low Sr/Y (30–59), Ba/Th (75–213), and Ba/La (26.05–38.24), but elevated Th/Yb (4.51–7.36), Th/Nb (0.78–1.17), and Rb/Y (2.79–6.29) ratios. We conclude that they were generated by partial melting of depleted lithospheric mantle previously metasomatized by subduction-related fluids and sediment melts. These results, integrated with regional geological, geochronological, and geochemical data, constrain the tectonic evolution of NE China during the late Paleozoic. This involved normal subduction at 400–335 Ma, ridge subduction at 333–319 Ma, and slab break–off at 315–272 Ma. The high-Mg andesitic/dioritic magmas had high oxygen fugacities and high water and volatile (e.g., Cl, S) contents, and sufficient ore resources (e.g., Cu, Au, Fe) from the mantle wedge to be favorable for Cu (–Au–Fe) mineralization.