PAH Emission Bands Research Articles

Astronomical observations of the PAH emission bands

The infrared (IR) spectra of many galactic and extragalactic objects are dominated by emission features at 3.3, 6.2, 7.7, 8.6 and 11.2 μm, generally attributed to the IR fluorescence of Polycyclic Aromatic Hydrocarbon molecules (PAHs). These PAH bands have been found in a wide variety of environments throughout theUniverse and contain up to 10% of the total power output of star-forming galaxies.

Spectroscopic observations of ices around embedded young stellar objects in the Large Magellanic Cloud with AKARI

The aim of this study is to understand the chemical conditions of ices around embedded young stellar objects (YSOs) in the metal-poor Large Magellanic Cloud (LMC). We performed near-infrared (2.5-5 micron) spectroscopic observations toward 12 massive embedded YSOs and their candidates in the LMC using the Infrared Camera (IRC) onboard AKARI. We estimated the column densities of the H2O, CO2, and CO ices based on their 3.05, 4.27, and 4.67 micron absorption features, and we investigated the correlation between ice abundances and physical properties of YSOs.The ice absorption features of H2O, CO2, 13CO2, CO, CH3OH, and possibly XCN are detected in the spectra. In addition, hydrogen recombination lines and PAH emission bands are detected toward the majority of the targets. The derived typical CO2/H2O ice ratio of our samples (~0.36 +- 0.09) is greater than that of Galactic massive YSOs (~0.17 +- 0.03), while the CO/H2O ice ratio is comparable. It is shown that the CO2 ice abundance does not correlate with the observed characteristics of YSOs; the strength of hydrogen recombination line and the total luminosity. Likewise, clear no correlation is seen between the CO ice abundance and YSO characteristics, but it is suggested that the CO ice abundance of luminous samples is significantly lower than in other samples.The systematic difference in the CO2 ice abundance around the LMC's massive YSOs, which was suggested by previous studies, is confirmed with the new near-infrared data. We suggest that the strong ultraviolet radiation field and/or the high dust temperature in the LMC are responsible for the observed high abundance of the CO2 ice. It is suggested that the internal stellar radiation does not play an important role in the evolution of the CO2 ice around a massive YSO, while more volatile molecules like CO are susceptible to the effect of the stellar radiation.

The nature of the compact H ii region Sh 2-89 and its stellar content

We present an analysis of the structure and properties of the compact HII region Sh 2-89, and certain of the young stellar objects (YSOs) within this regime, using mid-infrared (MIR) mapping derived from the Spitzer Space Telescope (SST) and visual slit spectroscopy of the inner regions of the source. We show that the region has a bipolar structure, and contains a variety of Class I and II YSOs. Much of the MIR emission appears to be dominated by PAH emission bands, which cause strong increases in flux in the 5.8 and 8.0 microns photometric channels, whilst the variation of H_alpha, [NII] at 6583 A, [SII] at 6716+6731 A, and MIR emission profiles confirms the presence of complex ionisation fronts, and ionisation stratification.

Detection of Extended Hot Water in the Outflow from NGC 2071

We report the results of spectroscopic mapping observations carried out toward a ~1 min x 1 min region within the northern lobe of the outflow from NGC 2071 using the Infrared Spectrograph (IRS) of the Spitzer Space Telescope. These observations covered the 5.2-37 um spectral region and have led to the detection of a number of ionic, atomic, and molecular lines, including fine-structure emission of Si+, Fe+, S++, S, the S(0)-S(7) pure rotational lines of H2, the R(3) and R(4) transitions of HD, and at least 11 transitions of H2O. In addition, the 6.2, 7.4, 7.6, 7.9, 8.6 and 11.3 um PAH emission bands were also observed and several transitions of OH were tentatively detected. Most of the detected line transitions were strong enough to map including, for the first time, three transitions of hot H2O. We find that: (1) the water emission is extended; (2) the extended emission is aligned with the outflow; and, (3) the spatial distribution of the water emission generally follows that observed for H2. Based on the measured line intensities, we derive an HD abundance relative to H2 of 1.1-1.8 10^-5 and an H2O number density of 12-2 cm^3. The H2 density in the water-emitting region is not well constrained by our observations, but is likely between 3 10^4 and 10^6 cm^3, yielding an H2O abundance relative to H2 of between 2 10^-5 and 6 10^-4. Future observations planned for the Herschel Space Observatory should greatly improve the density estimate, and thus our knowledge of the H2O abundance, for the water-emitting regions reported here. Finally, we note a possible departure from the H2O ortho-to-para ratio of 3:1 expected for water formed in hot post-shocked gas, suggesting that a significant fraction of the water vapor we detect may arise from H2O sputtered from cold dust grains.

SpitzerSpectral Line Mapping of Supernova Remnants. I. Basic Data and Principal Component Analysis

We report the results of spectroscopic mapping observations carried out toward small (1' × 1') regions within the supernova remnants W44, W28, IC 443, and 3C 391 using the Infrared Spectrograph (IRS) of the Spitzer Space Telescope. These observations, covering the 5.2-37 μm spectral region, have led to the detection of a total of 15 fine-structure transitions of Ne+, Ne++, Si+, P+, S, S++, Cl+, Fe+, and Fe++; the S(0)-S(7) pure rotational lines of molecular hydrogen; and the R(3) and R(4) transitions of hydrogen deuteride. In addition to these 25 spectral lines, the 6.2, 7.7, 8.6, 11.3, and 12.6 μm PAH emission bands were also observed. Most of the detected line transitions have proven strong enough to map in several sources, providing a comprehensive picture of the relative distribution of the various line emissions observable in the Spitzer IRS bandpass. A principal component analysis of the spectral-line maps reveals that the observed emission lines fall into five distinct groups, each of which may exhibit a distinct spatial distribution: (1) lines of S and H2(J > 2); (2) the H2 S(0) line; (3) lines of ions with appearance potentials less than 13.6 eV; (4) lines of ions with appearance potentials greater than 13.6 eV, not including S++; (5) lines of S++. Lines of group 1 likely originate in molecular material subject to a slow, nondissociative shock that is driven by the overpressure within the supernova remnant, and lines in groups 3-5 are associated primarily with dissociative shock fronts with a range of (larger) shock velocities. The H2 S(0) line shows a low-density diffuse emission component and, in some sources, a shock-excited component.

Spatial separation of small and large grains in the transitional disk around the young star IRS 48

Aims. We present spatially resolved mid-infrared images of the disk surrounding the young star IRS 48 in the Ophiuchus cloud complex. The disk exhibits a ring-like structure at 18.7 mu m, and is dominated by very strong emission from polycyclic aromatic hydrocarbons at shorter wavelengths. This allows a detailed study of the relative distributions of small and large dust grains. Methods. Images of IRS 48 in 5 mid-infrared bands from 8.6 to 18.7 mu m as well as a low resolution N-band spectrum are obtained with VLT-VISIR. Optical spectroscopy is used to determine the spectral type of the central star and to measure the strength of the H alpha line. Results. The 18.7 mu m ring peaks at a diameter of 110 AU, with a gap of similar to 60 AU. The shape of the ring is consistent with an inclination of i = 48 degrees +/- 8 degrees. In contrast, the 7.5 - 13 mu m PAH emission bands are centered on the source and appear to fill the gap within the ring. The measured PAH line strengths are 10 - 100 x stronger than those typically measured for young M0 stars and can only be explained with a high PAH abundance and/or strong excess optical/UV emission. The morphology of the images, combined with the absence of a silicate emission feature, imply that the inner disk has been cleared of micron-sized dust but with a significant population of PAHs remaining. We argue that the gap can be due to grain growth and settling or to clearing by an unseen planetary or low-mass companion. IRS 48 may represent a short-lived transitional phase from a classical to a weak-line T Tauri star.

Dust and PAH Emission in the Star‐forming Active Nucleus of NGC 1097

The nucleus of the nearby galaxy, NGC 1097, is known to host a young, compact (r < 9 parsec) nuclear star cluster as well as a low-luminosity active galactic nucleus (AGN). It has been suggested both that the nuclear stellar cluster is associated with a dusty torus, and that low-luminosity AGN like NGC 1097 do not have the torus predicted by the unified model of AGN. To investigate these contradictory possibilities we have acquired Gemini/T-ReCS 11.7 micron and 18.3 micron images of the central few hundred parsecs of this galaxy at < 45 parsec angular resolution, in which the nucleus and spectacular, kiloparsec-scale star-forming ring are detected in both bands. The small-scale mid-infrared (mid-IR) luminosity implies thermal emission from warm dust close to the central engine of this galaxy. Fitting of torus models shows that the observed mid-IR emission cannot be accounted for by dust heated by the central engine. Rather, the principal source heating the dust in this object is the nuclear star cluster itself, suggesting that the dust that we detect is not the torus of AGN unified schemes (although it is also possible that the dusty starburst itself could provide the obscuration invoked by the unified model). Comparison of Spitzer/IRS and Gemini/GNIRS spectra shows that, although polyaromatic hydrocarbon emission (PAH) bands are strong in the immediate circumnuclear region of the galaxy, PAH emission is weak or absent in the central 19 parsecs. The lack of PAH emission can probably be explained largely by destruction/ionization of PAH molecules by hard photons from the nuclear star cluster. If NGC 1097 is typical, PAH emission bands may not be a useful tool with which to find very compact nuclear starbursts even in low-luminosity AGN.

Spitzer Observations of Deeply Obscured Galactic Nuclei

We report on our first results from a mid-infrared spectroscopic study of ISM features in a sample of deeply obscured ULIRG nuclei using the InfraRed Spectrograph (IRS) on the Spitzer Space Telescope. The spectra are extremely rich and complex, revealing absorption features of both amorphous and crystalline silicates, aliphatic hydrocarbons, water ice and gas-phase bands of hot CO and warm C2H2, HCN and CO2. PAH emission bands were found to be generally weak and in some cases absent. The features probe a dense and warm environment, in which crystalline silicates and water ice are able to survive but volatile ices, commonly detected in Galactic dense molecular clouds, cannot. If powered largely by star formation, the stellar density and conditions of the gas and dust have to be extreme not to give rise to the commonly detected emission features associated with starbursts.

Shock-induced PDR in the Herbig-Haro object HH 2

We report mid-infrared ($5-17\mu m$) and SO, CO, $^{13}$CO millimeter line observations of the protostellar jet HH~2 and the parental molecular cloud. We have detected for the first time mid-infrared emission along a protostellar jet. We find that the outflowing gas extends much further away than the Herbig-Haro object HH~2, showing direct evidence that downstream gas has been accelerated by previous outflow events. These gas layers appear to have been detached from the parental cloud, as they are distributed around a cavity, probably dug by protostellar outflow(s). SO emission is detected in shocked gas regions associated with outflows. The UV field produced in the strong shock region HH~2H-A has produced a low-excitation Photon-Dominated Region at the walls of the cavity, which is detected in the PAH emission bands and in the continuum between 5 and $17\mu m$. This continuum arises from very small grains transiently heated by a FUV field G $\simeq 20G_0$, which probably formed from evaporation of dust grain mantles in shocks.

Polycyclic Aromatic Hydrocarbons and Infrared Astrophysics. The State of the PAH Model and a Possible Tracer of Nitrogen in Carbon‐Rich Dust

AbstractFor Abstract see ChemInform Abstract in Full Text.

The [ITAL]ISO[/ITAL]–SWS 2.4–45.2 Micron Spectrum toward Orion IR[CLC]c[/CLC

The complete infrared spectrum from 2.4 to 45.2 μm toward the prototypical massive star-forming region Orion IRc2 is presented, obtained with the Short Wavelength Spectrometer (SWS) on board the Infrared Space Observatory (ISO) at a resolving power λ/Δλ ≈ 1300-2500. A wealth of emission and absorption features is found, including H2 vibration-rotation lines, the full set of H2 pure rotational lines (0,0) S(1)-S(17), H recombination lines, ionic fine-structure lines, PAH emission features, and absorption and emission bands by interstellar ices and gas-phase molecules, including CO2, CH4, and SO2. Particularly interesting is the detection of strong emission and absorption lines in the H2O ν2 bending mode at 6.2 μm and the observation of highly excited pure rotational lines of H2O in absorption at 25-45 μm. The origin of these lines in each of the physical components included in the ISO-SWS beam (H II region, PDR, quiescent ridge, shocked low-velocity plateau) is briefly discussed.

IRAS low-resolution spectra of galaxies

The spectra of external galaxies are selected and extracted from the IRAS LRS database. Twenty-one objects present viable spectra. One is a peculiar star-forming E-S0 galaxy. The remainder are all starburst or H II region galaxies. Their average spectrum demonstrates the importance of the PAH emission bands in the 8-23-micron region and reinforces the conclusion reached from ground-based spectra, that there is a strong correlation between the PAH bands and the starburst or H II region character of a galaxy.