Oven-dried Wood Research Articles

The effect of operating conditions on neutral sulphite semi-chemical pulping properties: an industrial pilot plant study

The influence of pulping variables on the pulp and black liquor properties for a neutral sulphite semi-chemical pulping system was investigated in a pilot plant pulping setup situated at an industrial paper mill. Eucalyptus chips were used as raw material and the operating variables were Na2SO3 charge (8–18% w/w on oven-dry wood), Na2CO3 charge (0.5–3.0% w/w on oven-dry wood) and maximum cooking temperature (160–180 °C). Response surface methodology was used to parametrize empirical models to find the optimal conditions for maximizing the short-span compression strength index of the pulp. The derived regression models for the black liquor properties and the pulp hypo number had R2-adjusted values above 0.8 and p-values for overall significance below 0.05. The derived regression models for the handsheet strength properties had R2-adjusted values between 0.3 and 0.45 and p-values for overall significance either below 0.05 or between 0.05 and 0.1. The sulphite charge, followed by the carbonate charge, had the most notable effect on the evaluated properties with the effects of temperature being less significant. Optimization of the pilot plant system showed that the short-span compression strength index of the pulp could be maximized to 26.7 N m/g, using a sulphite charge of 9.4% (w/w on oven-dry wood) and a carbonate charge of 1.94% (w/w on oven-dry wood), similar to short-span compression strength indices typically achieved using other pulping processes.

Influence of Wood Knots of Chinese Weeping Cypress on Selected Physical Properties

The effects of wood knots of Chinese weeping cypress (Cupressus funebris Endl.) wood on selected physical and color properties were investigated. Thirty samples of live knots, dead knots, and clear wood groups were selected for experiments to determine the physical properties of wood density, wood shrinkage, wood swelling, and wood color. The experimental analysis results showed that the wood density values are in the order: dead knots > live knots > clear wood, with a significant difference in wood density between different groups (p < 0.01). In addition, the values of the air-dry volumetric wood shrinkage, air-dry volumetric wood swelling, oven-dry volumetric wood shrinkage, and oven-dry volumetric wood swelling ratios are in the order: dead knots > live knots > clear wood, being consistent with a variation in wood density. Three groups of wood colors were provided: the color of clear wood is light, the color of live knots is reddish, and the color of live knots is blackish, in relative terms. The chromatic aberration between the three groups can be identified, and the wood color difference resulted from the discrepancy in the lightness index.

Influence of Isocyanate Content and Hot-Pressing Temperatures on the Physical–Mechanical Properties of Particleboard Bonded with a Hybrid Urea–Formaldehyde/Isocyanate Adhesive

Particleboard (PB) is mainly produced using urea–formaldehyde (UF) adhesive. However, the low hydrolytic stability of UF leads to poor water resistance by the PB. This research aimed to analyze the effect of hot-pressing temperatures and the addition of methylene diphenyl diisocyanate (MDI) in UF adhesive on the physical and mechanical properties of PB. The first experiment focused on pressing temperature treatments including 130, 140, 150, and 160 °C. The particles were bonded using a combination of UF and MDI resin at a ratio of 70/30 (%w/w). Furthermore, the second experiment focused on UF/MDI ratio treatment, including 100/0, 85/15, 70/30, and 55/45 (%w/w), and the particles were pressed at 140°C. All of the single-layer particleboard in this research were produced in 250 × 250 mm, with a target thickness and density of 10 mm and 750 kg/m3, respectively. This research used 12% resin content based on oven-dry weight wood shaving. The pressing time and pressing pressure were determined to be 10 min and 2.5 N/mm2, respectively. Before the tests, the board was conditioned for 7 days. When studying the effect of treatment temperature, good physical properties (thickness swelling and water absorption) and mechanical properties (MOR and MOE) were obtained at 140 °C. However, no significant difference was observed in the UF/MDI ratio between 85/15 and 55/45 using the same temperature. The increase in the MDI adhesive ratio improves the MOE and MOR values. However, the internal bond was the contrary. This study suggests that a combination of UF/MDI at a ratio of 85/15 and hot-pressing temperature at 140 °C could produce a PB panel that meets a type 8 particleboard according to the JIS A5908-2003 standard and type P2 according to the EN 312-2010 standard.

Integrated process for the co-production of bioethanol, furfural, and lignin nanoparticles from birch wood via acid hydrotropic fractionation

This study proposes an efficient biorefining strategy for co-producing of bioethanol, furfural, and lignin nanoparticles (LNPs) from birch wood based on acid hydrotropic fractionation. Birch was fractionated into glucan-rich washed water-insoluble solids (WIS) fraction and xylose-rich spent liquor (SL) fraction with a low p-toluenesulfonic acid (p-TsOH) concentration of 15% (w/v). The obtained WIS was utilized to produce 75.5 g/L ethanol (76.3% ethanol yield based on initial sugars in the enzymatic hydrolysate) through separate hydrolysis and fermentation. Meanwhile, the xylose-rich SL was concentrated and catalyzed by dehydration to produce furfural with tetrahydrofuran (THF) as a co-solvent. The furfural concentration of 27.3 g/L (78.2% theoretical yield) was achieved from the 3-fold concentrated SL (without lignin precipitation) with a 3:1 THF-SL ratio at 160 °C for 7 min. The enzymatic hydrolysis solid residue of WIS was further fractionated by p-TsOH to prepare LNPs with an average particle size of 37.4 nm. The mass balance showed that 6.5 t oven-dry birch wood produced 1.0 t ethanol, 0.61 t furfural and 0.63 t LNPs.

Effect of wood moisture content on the performance of wood burning cook stoves

ABSTRACT Rural Ethiopian communities rely mostly on biomass fuels for subsistence and productive purposes. With an increasing population and dwindling forest resources, wood fuel consumption has exceeded its supply. Besides, people do not know ways of maximising biomass efficiency. The study involves the burning efficiencies of woods with varied moisture contents. Eucalyptus wood of five different moisture contents was used in five identical wood-burning stoves purposefully constructed for this purpose. Tests were conducted over 5 days, thereby giving five replications. In the tests, food temperature, stove body temperature, and stove smoke outlet temperature measurements were conducted along with ambient air temperatures. Wood with 10% moisture content performs better during combustion with respect to low and high moisture content wood. High moisture content delayed the cooking onset and low moisture decreased the duration of effective cooking. The 50% moisture content or greater with respect to oven-dried wood failed to cook. Moisture content of around 30% delayed the time to reach cooking temperature by two and hence elongated the cooking time. There is also the extended smoke time as observed from the smoke outlet temperature.

Intra-species variation in maximum moisture content, cell-wall density and porosity of hardwoods

Abstract Some properties of wood, such as maximum moisture content, cell-wall density and porosity, are not well known, even though they affect the performance of chemical preservatives, glues and coatings on wood. This knowledge gap was addressed in the present study by analysing these physical properties in laurel (Laurus nobilis L.) wood. Laurel is a common hardwood tree in southern Europe. Seventeen laurel trees were felled for the study, and 300 defect-free specimens were obtained from the trees for analysis. The following mean values were obtained: wood maximum moisture content, 114%; cell-wall oven-dry density, 1198 kg m−3; and oven-dry wood porosity, 45%. Significant inter- and intra-tree variations in the three properties were observed. The inter-tree variation was mainly attributed to the tree age, and the trend suggests that wood maximum moisture content and porosity are expected to be lower in older trees than those under study. The values of the three properties were slightly, but statistically significantly, lower at the highest positions in the tree. Harvesting of the basal logs of young trees is therefore advisable only if more porous wood is required, and commercial exploitation of the whole trunk of mature trees is recommended if more compact wood is required. The variation in cell-wall density was not negligible, although this variable is often assumed to be approximately constant for all wood species. Maximum moisture content and wood porosity can be estimated using bulk or apparent density as a predictor variable.

Xylanase pretreatment of mechanically destructured chips of Eucalyptus tereticornis and its effect on kraft pulping

Mechanical pulping of raw wood material is a highly energy intensive and pollution generating step in the papermaking process. This study focused on combined mechanical and xylanase treatment prior to the kraft pulping of E. tereticornis. A screened pulp yield of 49.1% (on oven-dry wood basis) with a Kappa number of 24.9 was obtained at the optimum cooking temperature of 160 °C without any pretreatment of the wood chips. After mechanical treatment (destructuring), a slightly higher screened pulp yield (49.4%) was obtained with a Kappa number of 24.2 at the cooking temperature of 145 °C with the same active alkali charge (15%). The optimum cooking temperature was further reduced to 140 °C for the destructured xylanase-treated wood chips. The xylanase treatment resulted in a 2% reduction in screened pulp yield due to hydrolysis of xylan. However, the Kappa number was reduced to 18.2 after xylanase pretreatment of the mechanically destructured wood chips. The combined pretreatment (destructured and xylanase treatment) of wood chips resulted in a reduction in cooking temperature by 20°C compared to untreated wood chips. Such a reduction in cooking temperature can effectively reduce steam consumption. The combined pretreatment improved the pulp brightness by 2.0 (ISO points) and physical strength properties, which included the tensile index, tear index, and burst index by 11.06%, 21.72%, and 21.79%, respectively, compared to the control.

Effect of calcite addition on technical properties and reduction of formaldehyde emissions of medium density fiberboard

Physical, mechanical, and formaldehyde emission properties were studied for medium density fiberboard (MDF) produced with oak (75%) and pine (25%) fibers that had been mechanically refined in the presence of calcite particles. The calcite slurry was prepared at two levels of solids, 1.5% and 3% (10 and 20 kg·m-³). Chips were cooked for 4 min at 185 °C, under 8 bar vapor pressure in an Andritz defibrillator. 1.8% liquid paraffin, 0.72% ammonium sulphate solution, and 11% urea-formaldehyde were added by percentage based on oven-dried wood fibers in the blowline at the exit of the defibrator. The fibers were dried to 11% moisture content. MDF boards (2100 mm × 2800 mm × 18 mm) were created using a continuous hot-press process. The addition of calcite in the course of MDF production resulted in improved physical properties, such as thickness swelling (ThS 24 hours) and water absorption (WA 24 hours). MDF boards prepared with calcite exhibited higher internal bond (IB), modulus of rupture (MOR), and modulus of elasticity (MOE). Resistance to axial withdrawal of screw also was increased by addition of 3% calcite. In addition, the lowest levels of formaldehyde emission were observed for MDF prepared with calcite at the 3% level.

The use of borax pentahydrate of inorganic filler in medium density fiberboard production

The aim of the study was the use of the inorganic borax pentahydrate mineral in medium density fiberboard production instead of biomass fiber and to specify the performance which physical, mechanical, combustion of produced boards. Chips used in manufacture were subjected to cooking for 4,5 minutes in Asplund defibrator at the vapor pressure of 7,6 kg/cm2 pressure and 190 oC temperature. 1,6 % paraffin according to based on oven-dried wood fibers was added to cooked chips before the fiber processing in segments of defibrillator section. 1 % ammonium sulphate according to based on oven-dried wood fibers were added to fiber in the bowline. Borax pentahydrate was prepared in a separate tank in order to use the production of medium density fiberboard medium density fiberboard. Borax pentahydrate inorganic mineral was mixed with urea-formaldehyde resin. Urea-formaldehyde glue was prepared as three different solutions including the borax pentahydrate as 3 % (20 kg), 6 % (40 kg) and 9 % (60 kg) respectively. Borax pentahydrate mixed fibers were dried to 12 % moisture. Mat was formed before prepress. Daily multi-press was manufactured 188 °C temperature and 32 kg/cm² pressure and 270 second pressing time. Manufactured boards size were 2100x4900x18 (mm). According to this work result, 3 % and 6 % rate borax pentahydrate added medium density fiberboard boards were measured more good physical and mechanical test results compare to control boards. 9 % borax pentahydrate added medium density fiberboard boards were shown incredibly superior performance at fire resistance

Effects of cryogenic temperature on some mechanical properties of beech (Fagus orientalis Lipsky) wood

It is important to know the changes in the mechanical properties of wood during freezing for engineering calculations of the wood material to be used in cold environments. Although this is important, the mechanical properties of wood at temperatures below − 100 °C have rarely been studied. In this study, the effects of cryogenic temperature (− 196 °C) on the bending strength, modulus of elasticity in bending and compression strength parallel to the grain of oven-dried and air-dried beech wood was investigated. As a result of the experiment, the mechanical strength properties of the wood increased during freezing. The increase in bending strength and modulus of elasticity values were higher in air-dried wood than those in oven-dried wood. However, the increase in compression strength values was determined at the same rates as 61% for air-dried and oven-dried wood. This increase in mechanical strength properties of wood during freezing could be explained by freezing of water in the wood, hardening of wood cell walls, decreasing intermolecular distance, increasing intermolecular force and stabilization of crystalline structure.

Mechanical and formaldehyde-related properties of medium density fiberboard with zeolite additive

Zeolite was investigated as a potential component in the production of medium-density fiberboard (MDF). A mixture of beech (40%), oak (30%), and pine (30%) wood chips was used for fiber production. Chips were cooked for 4 min in an Asplund defibrator with a vapor pressure of 8 bar, and a temperature of 180 °C. Chemicals were added on fibers in the blow line. The resins were added at 11 wt% based on oven-dried wood fibers. Ammonium sulphate was added at 0.72 wt% based on resins. Paraffin wax was added as 1.8 wt% based on resin. Zeolite was prepared in a separate tank for its use instead of lignocellulosic fibers in the production of 1 m³ MDF. The fibers were dried to 12% moisture. A temperature of approximately 190 °C and a pressure of approximately 32 kg.m-² were applied to the mixture for 280 s to make MDF panels (500 x 490 x 14 mm). Mechanical properties of MDF boards were significantly increased for bending (MOE) and elastic modulus (MOR), but a little negatively affected on internal bond (IB), physical properties were negatively increased thickness swelling (ThS) and water absorption (WA). Consequently, increasing zeolite minerals in MDF boards showed best results of formaldehyde emission properties of MDF.

Acoustic Properties of Resonant Spruce Wood Modified Using Oil-Heat Treatment (OHT).

Wedge-shaped boards of spruce wood (Picea abies Karst.) are used to make violin fronts, also known as soundboards. Oil-heat treatment (OHT) can influence the acoustic properties of resonant wood, such as spruce. In this study, the effect of OHT on spruce wood was evaluated, using palm oil as a heating medium, at four different temperatures: 140, 160, 180 and 200 °C. Physical, mechanical and acoustic properties of spruce wood were evaluated before and after OHT and included the following: density, modulus of elasticity in the static bending test, and wood sound velocity. The acoustic parameters after OHT improved; however, the samples bent after modification had a higher modulus of elasticity, with a simultaneous deterioration of the acoustic parameters. The dynamic modulus of elasticity increased by 11%, and the musical constant by 5%. The static modulus increased by more than 3.5%, but the acoustic parameters calculated on the basis of these results indicated a deterioration of the acoustic properties of completely oven-dried wood. The increase in moisture content to air-dried condition contributed to a slight increase in the mean musical constant at the highest modification temperature.

Effect of Boron and Phosphorus Compounds on Fire and Technological Properties of Oriented Strandboard

Effects of various fire retardant chemicals on fire and technological properties of laboratory made oriented strandboards (OSBs) were investigated. Aspen chips were used in the production of OSB panels. An exterior liquid phenol formaldehyde resin with 47 percent solid content was used as adhesive. There was no addition of any hardener and filling materials into resin in the OSB manufacturing. Boron compounds such as borax and boric acid, and phospate compounds such as monoammonium phosphate and diammonium phospahate were used as fire retardant chemicals in the OSB panels. An exterior liquid phenol formaldehyde resin was used as adhesive. The chemicals in powder form were added into the resin blender at contents of 2%, 4%, and 6% based on oven-dry wood weight. The OSB panels containing borax had the highest thickness swelling, followed by the panels containing boric acid, monoammonium phospahate, and diammonium phosphate, respectively. Increasing the content of these chemicals in the OSB resulted in greater thickness swelling. For the mechanical properties, the chemicals can be used up to oven dry particle weight of 6% in the panels at humid and dry conditions because of the fact that they met the standard values of mechanical properties given in TS EN 300 for types of OSB/3 (exterior type. Fire resistance of the panels was improved with increased chemical content in the panels.

Acoustic-Based Prediction of End-Product-Based Fibre Determinates within Standing Jack Pine Trees

The objective of this study was to specify, parameterize, and evaluate an acoustic-based inferential framework for estimating commercially-relevant wood attributes within standing jack pine (Pinus banksiana Lamb) trees. The analytical framework consisted of a suite of models for predicting the dynamic modulus of elasticity (me), microfibril angle (ma), oven-dried wood density (wd), tracheid wall thickness (wt), radial and tangential tracheid diameters (dr and dt, respectively), fibre coarseness (co), and specific surface area (sa), from dilatational stress wave velocity (vd). Data acquisition consisted of (1) in-forest collection of acoustic velocity measurements on 61 sample trees situated within 10 variable-sized plots that were established in four mature jack pine stands situated in boreal Canada followed by the removal of breast-height cross-sectional disk samples, and (2) given (1), in-laboratory extraction of radial-based transverse xylem samples from the 61 disks and subsequent attribute determination via Silviscan-3. Statistically, attribute-specific acoustic prediction models were specified, parameterized, and, subsequently, evaluated on their goodness-of-fit, lack-of-fit, and predictive ability. The results indicated that significant (p ≤ 0.05) and unbiased relationships could be established for all attributes but dt. The models explained 71%, 66%, 61%, 42%, 30%, 19%, and 13% of the variation in me, wt, sa, co, wd, ma, and dr, respectively. Simulated model performance when deploying an acoustic-based wood density estimate indicated that the expected magnitude of the error arising from predicting dt, co, sa, wt, me, and ma prediction would be in the order of ±8%, ±12%, ±12%, ±13%, ±20%, and ±39% of their true values, respectively. Assessment of the utility of predicting the prerequisite wd estimate using micro-drill resistance measures revealed that the amplitude-based wd estimate was inconsequentially more precise than that obtained from vd (≈ <2%). A discourse regarding the potential utility and limitations of the acoustic-based computational suite for forecasting jack pine end-product potential was also articulated.

Multi-Stage Hydrothermal Processing of Eucalyptus Globulus Wood: An Experimental Assessment

Eucalyptus globulus wood samples were subjected to hydrothermal processing according to a three-stage, crossflow scheme with intercalated washing stages. The operational conditions for each hydrothermal stage were selected based on previous experiments, as the kinetics and yields depended on the composition of the reaction media. The solid recovery yields as well as the compositions of the various solids and liquids involved in each stage were measured, in order to allow the formulation of material balances. Under the conditions selected, the various stages enabled solid recovery yields in the range 70.8–74.4 g/100 g oven-dry wood, with extensive hemicellulose removal and almost quantitative recovery of both cellulose and lignin in solid phase. The production of valuable polysaccharide-derived products (including saccharides and furans) along the process decreased owing to the different initial composition of the various reaction media. In turn, the generation of monosaccharides from soluble saccharides of oligomeric or polymeric nature was promoted in the second and third stages. The experimental data provided in this study allow a quantitative assessment on the considered process, a basic information for simulation and economic evaluation.

From wood chips to pellets to milled pellets: The mechanical processing pathway of Austrian pine and European beech

This study assesses the changes in physical properties (particle size, shape, density) of Austrian pine (softwood) and European beech (hardwood), as they are mechanically processed from wood chips to pellets and then to milled pellets. A series of semi-industrial hammer mills and a semi-industrial pellet mill were used. The specific pelletizing and grinding energy, as well as the pellet mill and hammer mill capacity, were determined. Size, shape, and bulk density of the wood particles obtained at each processing step were studied. The pellet quality was analyzed according to international standards. Results show that the pelletization modifies the internal pellet particle shape and length due to the breakage of particles across their longest dimension, leading to more circular and less elongated particles. However, the particle width was nearly unaffected, indicating a directional fracture behavior for wood particles during pelletization. The particle breaking effect was more dominant for beech particles. Beech contained a lower amount of extractives than pine that led to higher specific pelletizing energy. In addition, beech pellets had a lower quality concerning durability and density. Relationships between specific grinding energies and characteristic product particle sizes were also determined. E.g., the specific energy for grinding pine pellets was about 10 kWh/t oven-dry wood for a characteristic product size of 0.8 mm, while grinding beech pellets required about 7 kWh/t oven-dry wood for a characteristic product size of 0.6 mm. The study concludes that less energy is needed to pelletize pine than beech under the same processing conditions, but more energy is needed to mill pine than beech.

The Impact of Anatomical Characteristics on the Structural Integrity of Wood

The structural integrity of wood is closely related to its brittleness and thus to its suitability for numerous applications where dynamic loads, wear and abrasion occur. The structural integrity of wood is only vaguely correlated with its density, but affected by different chemical, physico-structural and anatomical characteristics, which are difficult to encompass as a whole. This study aimed to analyze the results from High-Energy Multiple Impact (HEMI) tests of a wide range of softwood and hardwood species with an average oven-dry wood density in a range between 0.25 and 0.99 g/cm³ and multifaceted anatomical features. Therefore, small clear specimens from a total of 40 different soft- and hardwood species were crushed in a heavy vibratory ball mill. The obtained particles were fractionated and used to calculate the ‘Resistance to Impact Milling (RIM)’ as a measure of the wood structural integrity. The differences in structural integrity and thus in brittleness were predominantly affected by anatomical characteristics. The size, density and distribution of vessels as well as the ray density of wood were found to have a significant impact on the structural integrity of hardwoods. The structural integrity of softwood was rather affected by the number of growth ring borders and the occurrence of resin canals. The density affected the Resistance to Impact Milling (RIM) of neither the softwoods nor the hardwoods.

Effect of mineral materials content as filler in medium density fiberboard

The use of different mineral material types and contents in medium density fiberboard (MDF) production was investigated. Three different minerals (sepiolite, dolomite, and perlite) and five different ratios (3%, 6%, 9%, 12%, and 15%) were used according to the oven-dry wood fiber weight. These minerals were homogeneously added as powder between the wood fibers. Some physical, mechanical, limit oxygen index (LOI), and thermogravimetric analysis (TGA) tests of the boards were conducted. The mineral fillers negatively affected the physical properties such as water absorption (WA), thickness swelling (ThS), and mechanical properties such as modulus of rupture (MOR), modulus of elasticity (MOE), and internal bond (IB). However, LOI and TGA test results showed a positive effect on combustion resistance depending on the type and rate of mineral fillers.

MULTIVARIATE ANALYSIS OF THE VARIABILITY IN THE DENSITY OF OVEN-DRY WOOD OF SILVER BIRCH (BETULA PENDULA ROTH.) IN POLAND

MULTIVARIATE ANALYSIS OF THE VARIABILITY IN THE DENSITY OF OVEN-DRY WOOD OF SILVER BIRCH (BETULA PENDULA ROTH.) IN POLAND

Determination of physical and chemical properties and degradation of archeological Japanese cypress wood from the Tohyamago area using near-infrared spectroscopy

Here, we evaluated the application of near-infrared (NIR) spectroscopy for estimating the degradation level of archeological wood samples from the Tohyamago area, the dendrochronological ages of which were also determined. The wood samples were radially cut from three logs obtained from the Tohyamago area. NIR reflectance spectra were measured from the tangential faces of air- and oven-dried wood samples using a Fourier transform NIR spectrophotometer. The second derivative spectra within the wavenumber range of 6400–5200 cm−1, in which the effect of moisture content in wood is suspected to be insignificant, showed a characteristic behavior with age. By comparing the second derivative spectral change in our wood samples with that in wood degraded by aging, thermal treatment, fungal attack, and lightning reported in the literature, we found that the second derivative spectra of wood samples from one log was similar to those of wood degraded by hygro-thermal treatment, whereas those of wood samples from another log was similar to those of wood degraded by brown-rot fungi. The physical and chemical properties of archeological wood were well predicted using a combination of partial least square regression analysis and NIR spectroscopy.