Outstanding Electrical Performance Research Articles

Highly stretchable carbon-based triboelectric nanogenerator textiles woven using coaxial fibres via direct ink writing

In recent years, triboelectric nanogenerators have seen great progress in the Internet of Things, wearable electronics, virtual reality and artificial intelligence technologies. However, current triboelectric nanogenerator devices generally face challenges of complex preparation processes and structures, hindering their application in large-area wearable textiles. In this study, we develop highly stretchable triboelectric fibres using direct ink writing as building blocks for further woven textiles. This consists of a conductive core and insulating sheath, namely composites of multi-wall carbon nanotube and fluorinated ethylene propylene particles, both doped in silicone rubber. The fibre enjoys outstanding electrical performance, as well as excellent mechanical stretchability. Particularly, a single-centimetre-long fibre, upon slight patting, can surprisingly produce an open-circuit voltage of 8 V, a short-circuit current of 110 nA and 2.5 nC short-circuit transferred charges, or equivalent lighting of four to five commercial light-emitting diodes alone, greatly outperforming current wearable devices. These fibres also can endure an extraordinary strain of up to ∼874 %. The fibres are then woven into wearable gloves and socks using traditional weaving techniques, which can realise motion pattern identification and recognition with classification accuracy as high as ∼96 % using convolutional neural networks. This creates application prospects in wearable electronics, providing a scalable and affordable method for weaving daily wearable textiles and favouring large-area, wearable, self-powered sensors and artificial intelligence technologies.

Enhanced Oxidation Resistance and Interface Stability of Atomic-Layer-Deposited MoNx Electrodes via TiN Passivation for DRAM Cell Capacitor Applications.

The continuous miniaturization of dynamic random-access memory (DRAM) capacitors has amplified the demand for electrode materials featuring specific characteristics, such as low resistivity, high work function, chemical stability, excellent interface quality with high-k dielectrics, and superior mechanical properties. In this study, molybdenum nitride (MoNx) films were deposited using a plasma-enhanced atomic layer deposition (PEALD) employing bis(isopropylcyclopentadienyl)molybdenum(IV) dihydride and NH3 plasma for DRAM capacitor electrode applications. Depending on the deposition temperatures of the PEALD MoNx films ranging from 200 to 400 °C, the Mo/N ratio and crystal structure varied, transitioning from the cubic NaCl-B1-type MoN phase with Mo/N ratio of 1.4 to the cubic γ-Mo2N phase with Mo/N ratio of 1.9. Notably, MoNx films grown at 400 °C exhibited low resistivity (435 μΩ·cm), a high work function (5.28 eV), and superior mechanical hardness (11.3 GPa) compared to ALD TiN films. Despite these excellent properties, the PEALD MoNx electrode demonstrated insufficient chemical stability, particularly in terms of oxidation resistance and interface quality with ALD HfxZr1-xO2 (HZO) films. This resulted in poor morphology and the formation of significant oxygen-deficient HZO layers (such as HfO2-x), leading to considerable degradation in the electrical performance of metal-insulator-metal (MIM) capacitors. To mitigate this issue, a thin (2.5-14 nm) ALD TiN layer was introduced as a passivation layer between the MoNx bottom electrode and HZO dielectric. The TiN-passivated MoNx (TiN/MoNx) electrode showed substantially enhanced oxidation resistance and reduced interfacial reactions with the HZO dielectric. Consequently, MIM capacitors with TiN/MoNx bottom electrodes demonstrated outstanding electrical performance, including excellent dielectric properties, low leakage current density, and high mechanical strength. Hence, this study proposes a promising candidates for storage nodes in the next-generation DRAM capacitors.

Orbit symmetry breaking in MXene implements enhanced soft bioelectronic implants.

Bioelectronic implants featuring soft mechanics, excellent biocompatibility, and outstanding electrical performance hold promising potential to revolutionize implantable technology. These biomedical implants can record electrophysiological signals and execute direct therapeutic interventions within internal organs, offering transformative potential in the diagnosis, monitoring, and treatment of various pathological conditions. However, challenges remain in improving excessive impedance at the bioelectronic-tissue interface and thus the efficacy of electrophysiological signaling and intervention. Here, we devise orbit symmetry breaking in MXene (a low-cost scalability, biocompatible, and conductive two dimensionally layered material, which we refer to as OBXene), which exhibits low bioelectronic-tissue impedance, originating from the out-of-plane charge transfer. Furthermore, the Schottky-induced piezoelectricity stemming from the asymmetric orbital configuration of OBXene facilitates interlayered charge transport in the device. We report an OBXene-based cardiac patch applied on the left ventricular epicardium of both rodent and porcine models to enable spatiotemporal epicardium mapping and pacing while coupling the wireless and battery-free operation for long-term real-time recording and closed-loop stimulation.

Tri‐Layer Heterostructure Channel of a‐IGZO/a‐ITZO/a‐IGZO Toward Enhancement of Transport and Reliability in Amorphous Oxide Semiconductor Thin Film Transistors

AbstractThin film transistors (TFTs) based on amorphous oxide semiconductors (AOS) are promising candidates for panel displays. However, the trade‐off between mobility and reliability in AOS‐TFTs hinders their further applications in next‐generation display techniques and newly developed logic and memory circuits. Here, a structural strategy is proposed for the mobility‐reliability trade‐off, via a triple‐layer channel containing a Ga‐free high‐mobility layer (amorphous InSnZnO, a‐ITZO) sandwiched by two Ga‐rich layers (amorphous InGaZnO, a‐IGZO) with higher reliability. Gate‐induced carrier accumulation is verified mainly being energetically confined within the high mobility a‐ITZO layer, at the newly defined a‐ITZO/a‐IGZO interface. Compared to single layer a‐ITZO‐TFTs, triple‐channel a‐IGZO/a‐ITZO/a‐IGZO TFTs (GTG‐TFTs) exhibit outstanding stability and electrical transport performances, with suppressed positive/negative‐bias‐stress voltage shifts from 1/0.3 to 0.1/0.004 V, enhanced field effect mobility from ≈40 to 56 cm2V−1s−1, and optimized sub‐threshold swing down to 80 mV dec−1. Further numerical simulations and charge transport characterizations, including magnetotransport and gate‐induced Hall effect, indicate that charge transport in tri‐layer structure is less affected by energetic disorders present at gate insulator interfaces.

Antiferroelectric Heterostructures Memristors with Unique Resistive Switching Mechanisms and Properties.

A novel antiferroelectric material, PbSnO3 (PSO), was introduced into a resistive random access memory (RRAM) to reveal its resistive switching (RS) properties. It exhibits outstanding electrical performance with a large memory window (>104), narrow switching voltage distribution (±2 V), and low power consumption. Using high-resolution transmission electron microscopy, we observed the antiferroelectric properties and remanent polarization of the PSO thin films. The in-plane shear strains in the monoclinic PSO layer are attributed to oxygen octahedral tilts, resulting in misfit dislocations and grain boundaries at the PSO/SRO interface. Furthermore, the incoherent grain boundaries between the orthorhombic and monoclinic phases are assumed to be the primary paths of Ag+ filaments. Therefore, the RS behavior is primarily dominated by antiferroelectric polarization and defect mechanisms for the PSO structures. The RS behavior of antiferroelectric heterostructures controlled by switching spontaneous polarization and strain, defects, and surface chemistry reactions can facilitate the development of new antiferroelectric device systems.

Carbon Micro/Nano Machining toward Miniaturized Device: Structural Engineering, Large-Scale Fabrication, and Performance Optimization.

With the rapid development of micro/nano machining, there is an elevated demand for high-performance microdevices withhigh reliability and low cost. Due to their outstanding electrochemical, optical, electrical, and mechanical performance, carbon materials are extensively utilized in constructing microdevices for energy storage, sensing, and optoelectronics. Carbon micro/nano machining is fundamental in carbon-based intelligent microelectronics, multifunctional integrated microsystems, high-reliability portable/wearable consumer electronics, and portable medical diagnostic systems. Despite numerous reviews on carbon materials, a comprehensive overview is lacking that systematically encapsulates the development of high-performance microdevices based on carbon micro/nano structures, from structural design to manufacturing strategies and specific applications. This review focuses on the latest progress in carbon micro/nano machining toward miniaturized device, including structural engineering, large-scale fabrication, and performance optimization. Especially, the review targets an in-depth evaluation of carbon-based micro energy storage devices, microsensors, microactuators, miniaturized photoresponsive and electromagnetic interference shielding devices. Moreover, it highlights the challenges and opportunities in the large-scale manufacturing of carbon-based microdevices, aiming to spark further exciting research directions and application prospectives.

A Highly Conductive n-Type Conjugated Polymer Synthesized in Water.

Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is a benchmark hole-transporting (p-type) polymer that finds applications in diverse electronic devices. Most of its success is due to its facile synthesis in water, exceptional processability from aqueous solutions, and outstanding electrical performance in ambient. Applications in fields like (opto-)electronics, bioelectronics, and energy harvesting/storage devices often necessitate the complementary use of both p-type and n-type (electron-transporting) materials. However, the availability of n-type materials amenable to water-based polymerization and processing remains limited. Herein, we present a novel synthesis method enabling direct polymerization in water, yielding a highly conductive, water-processable n-type conjugated polymer, namely, poly[(2,2'-(2,5-dihydroxy-1,4-phenylene)diacetic acid)-stat-3,7-dihydrobenzo[1,2-b:4,5-b']difuran-2,6-dione] (PDADF), with remarkable electrical conductivity as high as 66 S cm-1, ranking among the highest for n-type polymers processed using green solvents. The new n-type polymer PDADF also exhibits outstanding stability, maintaining 90% of its initial conductivity after 146 days of storage in air. Our synthetic approach, along with the novel polymer it yields, promises significant advancements for the sustainable development of organic electronic materials and devices.

Zinc oxide bridges the nanofillers to enhance the wear resistance and stability of triboelectric nanogenerators

Triboelectric nanogenerators (TENGs) have received widespread attention as a means of harvesting mechanical energy from the environment and converting it into electricity. As people continue to explore the field of infinite sensors, traditional TENGs have faced persistent challenges in practical application, mainly due to the poor abrasion resistance and stability of the existing polymers commonly used. Herein, the polyphenylene sulfide (PPS) was melt blended with liquid crystal polymer (LCP) to be used as matrix, and the interfacial bonding strength between the matrix and filler was improved by zinc oxide (ZnO) grafted carbon nanotubes/graphene oxide (CNTs/GO). Under friction conditions of 100 N load and 0.5 m/s, the friction coefficient and wear rate of resultant nanocomposites were significantly reduced to 0.2 and 2.09 × 10-5 mm3/N, respectively. The abrasion resistant TENG (AR-TENG) was fabricated based on 0.3ZnO/CNTs/GO/LCP/PPS exhibited outstanding electrical output performance, which was attributed to the high dielectric constant of 5.3, improved surface roughness and interfacial contact area of composites. Consequently, this study reported a novel approach to tailor AR-TENG into a highly abrasion resistant and stable sensor. This customization enabled the AR-TENG to operate reliably in harsh environments (high temperatures and humidity), thereby expanding its potential applications.

Printed Self-Healing Stretchable Electronics for Bio-signal Monitoring and Intelligent Packaging.

Integrating self-healing capabilities into printed stretchable electronic devices is important for improving performance and extending device life. However, achieving printed self-healing stretchable electronic devices with excellent device-level healing ability and stretchability while maintaining outstanding electrical performance remains challenging. Herein, a series of printed device-level self-healing stretchable electronic devices is achieved by depositing liquid metal/silver fractal dendrites/polystyrene-block-polyisoprene-block-polystyrene (LM/Ag FDs/SIS) conductive inks onto a self-healing thermoplastic polyurethane (TPU) film via screen printing method. Owing to the fluidic properties of the LM and the interfacial hydrogen bonding and disulfide bonds of TPU, the as-obtained stretchable electronic devices maintain good electronic properties under strain and exhibit device-level self-healing properties without external stimulation. Printed self-healing stretchable electrodes possess high electrical conductivity (1.6×105Sm-1), excellent electromechanical properties, and dynamic stability, with only a 2.5-fold increase in resistance at 200% strain, even after a complete cut and re-healing treatment. The printed self-healing capacitive stretchable strain sensor shows good linearity (R2 ≈0.9994) in a wide sensing range (0%-200%) and is successfully applied to bio-signal detection. Furthermore, the printed self-healing electronic smart label is designed and can be used for real-time environmental monitoring, which exhibits promising potential for practical application in food preservation packaging.

Multifunctional flame-retardant cotton fabric with hydrophobicity and electrical conductivity for wearable smart textile and self-powered fire-alarm system

The domain of smart textiles represents a widely researched area, showcasing promising prospects. Herein, a multifunctional smart textile (CF@PM-AA) has been designed and fabricated, amalgamating flame retardancy, electrical conductivity, and hydrophobicity into a unified entity. The flame retardant, synthesized through the reaction between amino trimethylene phosphonic acid and allantoin, was impregnated into cotton fabric through a facile impregnation method. Through surface modification with polydimethylsiloxane and multi-walled carbon nanotubes, the obtained CF@PM-AA acquires exceptional hydrophobic and acid-base environment durability. Significantly, the electrical conductivity of CF@PM-AA is greatly enhanced, with a reduced resistance down from 15.9 GΩ to 13 MΩ. Based on their electrical characteristics, the copper sheet and CF@PM-AA function as the electrode and friction layers, respectively, in the construction of the triboelectric nanogenerator. This configuration produces a voltage output of up to 125.6 V at a frequency of 4 Hz. Given its outstanding flame retardancy, hydrophobicity, and electrical performance, CF@PM-AA can be integrated into firefighting suits to establish a fire-alarm system with remote signal transmission function, enhancing personnel safety. Simultaneously, the CF@PM-AA holds promise for diverse applications in wearable flame-retardant and fire-alarm systems, opening new avenues for smart textile utilization in the Internet of Things domain.

Antibiotic-Powered Energy Harvesting: Introducing Benzylpenicillin as an Efficient Tribopositive Material for Triboelectric Nanogenerators

The pursuit of enhancing the performance of triboelectric nanogenerators (TENGs) has led to the exploration of new materials with efficient charge-generating capabilities. Herein, we propose benzylpenicillin sodium salt (b-PEN) as a candidate biomaterial for the tribopositive layer owing to its superior electron-donating capability via the lone pairs of electrons on its sulfur atom, carbonyl, and amino functional groups. The proposed b-PEN TENG device exhibits promising electrical performance with an open-circuit voltage of 185 V, a short-circuit current of 4.52 µA, and a maximum power density of 72 µW/cm2 under force applied by a pneumatic air cylinder at 5 Hz. The biomechanical energy-harvesting capabilities of the b-PEN TENG device are demonstrated by actuating it with finger, hand, and foot movements. Moreover, the proposed TENG device is utilized to charge capacitors and power light-emitting diodes by scavenging the externally applied mechanical energy. This outstanding electrical performance makes b-PEN a promising tribopositive material.

A hBN/B-Si-Al-O-glass composite coating growth on SiCp/Al composite using one-step PEO with nanoparticle addition for outstanding electrical insulation performance

A comprehensive study of the formation of electrical insulation coatings on SiCp/Al composite using plasma electrolytic oxidation (PEO) in an electrolytic system with hBN nanoparticles has been carried out. A complete coating can be formed under a high positive voltage (550–600 V) in a short period of time (3 min), and the coating is mainly composed of the hBN crystal phase as well as some amorphous phases. The high temperature of the local plasma in the PEO process impels these amorphous phases to form an amorphous B-Si-Al-O glass phase. As the treatment time goes on, the cross-sectional porosity of the coating first decreases rapidly and then increases slowly. This is attributed to the fact that the nanoparticles continuously deposit and sinter to repair the larger pores during the coating growth process, hence reducing porosity. Within 6 min, the coating thickness rapidly increases to 133.3 μm, showing excellent electrical insulation performance (with a breakdown voltage of 1460 ± 28 V, volume resistance of 5.52 ± 0.26 G·Ω, electrical resistivity of 4.18 × 1010 Ω∙cm) and high optical band gap value (above 5 eV), which is suitable for electronic packaging or dielectric materials.

Ultra-stretchable, antifreezing, and self-healing ZnO nanofluid-based hydrogels for triboelectric nanogenerators and self-powered biosensors

Flexible, self-healing, and highly sensitive wearable self-powered sensors are essential for promoting the rapid development of wearable electronics. Herein, a hydrogel based on zinc oxide nanofluids (AP-Zn) was synthesized using 2-acrylamido-2-methylpropane sulfonic acid and polyethylene glycol diacrylate. The AP-Zn hydrogel exhibits excellent stretchability (2750 %), high conductivity (1.37 S m−1), antifreezing capabilities (−20 °C), and self-healing abilities. Furthermore, the AP-Zn hydrogel was utilized to construct a triboelectric nanogenerator (AP-Zn-TENG), which demonstrated outstanding electrical output performance, with an open-circuit voltage, short-circuit current, and maximum power density of 135 V, 4.0 μA, and 1.39 W m−2, respectively. As a pressure sensor, the AP-Zn-TENG has a detection limit of 0.025 kPa and can even detect vocal cord vibrations of different pitches. Therefore, the AP-Zn-TENG self-powered sensor can be employed for detecting human behavior. These results suggest that the AP-Zn hydrogel holds great promise in wearable power technology and self-powered biosensors.

SIW Triplets Including Meander-Line and CRLH Resonators and Their Applications to Quasi-Elliptic Filters

This article presents a design technique of quasi-elliptic filters by applying two novel planar triplets, which eliminates the need for negative couplings. A composite right-/left-handed (CRLH) resonator, together with a meander-line resonator, is investigated first in this article. These two resonators demonstrate a significant difference with respect to their phase shift characteristics that are completely opposite below and above their resonant frequencies. With such a feature, two meander-line and CRLH-loaded substrate integrated waveguide (SIW) triplets are proposed, which can produce a transmission zero (TZ) above and below the passbands if an inductive cross coupling is applied. Therefore, all couplings would be positive regardless of the location of TZs. The applications of the two triplets to quasi-elliptic filters, which are realized by parallel and cascaded triplet topologies, are then illustrated. Two filter prototypes operating at the <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$X$</tex-math> </inline-formula> -band are designed and fabricated for validation. They show outstanding electrical performance in terms of high selectivity, low loss, and compactness. It indicates that a joint application of conventional shunt <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">LC</i> resonant nodes and a CRLH node is a viable option in filter design.

Effect of Sb-induced oxygen octahedral distortion on piezoelectric performance and thermal stability of Pb(In,Nb)O3-Pb(Hf,Ti)O3 ceramics

The combination of excellent thermal stability and outstanding electrical performance is of great significance for piezoelectric ceramics. Herein, we have prepared 0.11Pb(In0.5Nb0.5)O3-0.89Pb(Hf0.47Ti0.53)O3-Sb2O5 (PIN-PHT-xSb) ceramics by solid-phase method and investigated the effect of oxygen octahedral lattice distortion on microstructure and macroscopic electrical properties. The distortion index of oxygen octahedra is studied by Rietveld refinement, showing that optimal octahedral distortion can soften B-O repulsion, disrupt long-range ordered ferroelectric domains, and enhance local heterogeneities, significantly increasing piezoelectric properties. Moreover, outstanding thermal stability and ultrahigh piezoelectric response of PIN-PHT-1.2Sb ceramics are realized under the synergistic influence of octahedral distortion, excellent density, and large grain size. Compared with PIN-PHT ceramics, PIN-PHT-1.2Sb ceramics exhibit ultrahigh piezoelectric responses (d33 = 706 pC/N, kp = 0.68, εr = 3244), a high Curie temperature (TC) of 300 °C, excellent thermal stability, and anti-fatigue properties.

Graphene-Based Electrochemical Biosensors for Breast Cancer Detection

Breast cancer (BC) is the most common cancer in women, which is also the second most public cancer worldwide. When detected early, BC can be treated more easily and prevented from spreading beyond the breast. In recent years, various BC biosensor strategies have been studied, including optical, electrical, electrochemical, and mechanical biosensors. In particular, the high sensitivity and short detection time of electrochemical biosensors make them suitable for the recognition of BC biomarkers. Moreover, the sensitivity of the electrochemical biosensor can be increased by incorporating nanomaterials. In this respect, the outstanding mechanical and electrical performances of graphene have led to an increasingly intense study of graphene-based materials for BC electrochemical biosensors. Hence, the present review examines the latest advances in graphene-based electrochemical biosensors for BC biosensing. For each biosensor, the detection limit (LOD), linear range (LR), and diagnosis technique are analyzed. This is followed by a discussion of the prospects and current challenges, along with potential strategies for enhancing the performance of electrochemical biosensors.

Leaf‐Like TENGs for Harvesting Gentle Wind Energy at An Air Velocity as Low as 0.2 m s−1

AbstractExisting technologies for harvesting electrical energy from gentle wind face an enormous challenge due to the limitations of cut‐in and rated wind speed. Here, a leaf‐like triboelectric nanogenerator (LL‐TENG) is proposed that uses contact electrification caused by the damped forced vibration of topology‐optimized structure consisting of flexible leaf, vein bearing plate, and counterweight piece. The effectiveness of the topology‐optimized leaf‐like structure is studied, which solves the problem of reduced output due to electrostatic adsorption between the leaf surfaces while reducing the cut‐in (0.2 m s−1) and rated wind speed (2.5 m s−1). The LL‐TENG unit having small dimensions of 40 cm−2 (mass of 9.7 g) at a gentle wind of 2.5 m s−1 exhibits outstanding electrical performances, which produces an open‐circuit voltage of 338 V, a short‐circuit current of 7.9 µA and the transferred charge density of 62.5 µC m−2 with a low resonant frequency of 4 Hz, giving an instantaneous peak power of 2 mW. A distributed power source consists of the five LL‐TENGs in parallel is developed by designed self‐adaptive structure, for which the peak power output reaches 3.98 mW, and its practicability and durability are successfully demonstrated. This study is a promising distributed power source technology to drive electronics in gentle wind outdoor environments.

Printable Coffee‐Ring Structures for Highly Uniform All‐Oxide Optoelectronic Synaptic Transistors

AbstractPrintable oxide transistors have emerged as important optoelectronic synaptic devices to emulate the human visual cognitive system by integrating both photo‐sensing and visual perception functions. However, the inferior electrical performance and low pixel density of printed oxide synaptic transistors impede their implementation of complex neuromorphic computing. Herein, a printable all‐oxide optoelectronic synaptic transistor array based on a modified coffee‐ring structure of indium tin oxide (ITO) is reported. The extraordinary structural design endows the printed ITO transistors with high device uniformity, outstanding electrical performance, and superior process efficiency. Furthermore, a 10 × 12 coffee‐ring structure optoelectronic synaptic transistor array with a high spatial resolution (142 dpi) exhibits durable visual detection and memory behaviors. Meanwhile, an artificial neural network based on the coffee‐ring structure synaptic transistors exhibits high accuracy in the recognition rate. These results promise the efficiency of the exceptional printing strategy in developing advanced optoelectronic synaptic transistors for artificial visual systems.

Facile Synthesis of Biobased Polyamide Derived from Epoxidized Soybean Oil as a High-Efficiency Triboelectric Nanogenerator

A biobased thermosetting polyamide has been synthesized through the crosslinking of epoxidized soybean oil (ESO) with hexamethylenediamine (HMDA) for application in sustainable energy harvesting devices, triboelectric nanogenerators (TENGs). A simple synthetic method requiring neither a solvent nor catalysts was employed. Amide formation was confirmed by FTIR signals corresponding to C═O stretching at ∼1650 cm–1, N–H bending vibration at ∼1540 cm–1, and C–N stretching at 1168 cm–1. Polyamides of ESO/HMDA demonstrated excellent thermal stability (displaying a DTG peak at around 460 °C), high hydrophobicity with a water uptake of lower than 1.5%, and contact angles in the range of 86–120°. Importantly, the ESO/HMDA TENG exhibited outstanding electrical performance compared to other biobased devices, with the highest output voltage and current of 150 V and 14 μA, respectively. The high efficiency of the TENG was attributed to the significant nitrogen content within the polyamide structure, where enhanced electrical performance correlated with greater ratios of HMDA. ESO/HMDA biobased polyamides offer an exciting new opportunity for utilization in the fabrication of sustainable energy harvesting devices, such as TENGs.

Polyaniline/carbon nanotube composites in sensor applications

Polyaniline (PA) has outstanding electronic, electrical and chemical properties. The incorporation of carbon nanotubes (CNT) into PA matrix could result in PA/CNT nanocomposites that possess enhanced properties. This review outlines the preparation methods of PA/CNT nanocomposites where they could be prepared by in situ polymerization and solution mixing. In addition, the fabrication methods of electrodes based on PA/CNT nanocomposites to be used in sensors will be investigated. In this regard, such electrodes can be fabricated through in situ synthesis of PA/CNT on electrode surface, electro-polymerization of Ani on carbon nanotube-modified electrode or casting of the prepared PA/CNT on the electrode surface. Also, the use of PA/CNT nanocomposites as sensing materials in biosensors, gas sensors, metal ion sensors, environmental pollutants sensors and pH sensors will be highlighted. The use of such nanocomposites in various types of sensors could be attributed to their remarkable chemical properties, large surface area and outstanding electrical performance.