Different from standard indoor testing for photovoltaic (PV) cells, the outdoor working of large PV modules suffers an inevitable issue of nonuniform illumination. Even a 10 % partial area shading results in an 80 % power attenuation. This can be attributed to the endogenous lateral transfer of photogenerated carriers between differently illuminated zones. Herein, we presented an active reallocation strategy for rationalizing lateral carrier transfer inside PV modules, which utilizes triboelectric electro-field to dynamically balance the p-n junction barrier height at interfaces of different illumination states. As demonstrated by a flexible hybrid energy harvester combining triboelectric nanogenerators (TENGs) and solar cells, by managing with rectifier-free circuits or even small chips, a small power sacrifice of TENGs exchanges for remarkable performance improvement of PV modules, leading to a power output gain of up to 87.7 % for half-shaded PV modules of different material and structural configurations. Besides, the reallocation electric field adapts well to a wide range of voltage or even pulsed triboelectric voltage, providing a mutually beneficial energy management technology for multi-source energy harvesting. This strategy of active reallocation by triboelectric effect provides an endogenous PV module promotion approach with prominent structural adaptability for distributed or even portable on-body power generation.
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