The traditional Satcom-on-the-Move (SOTM) mechanical structure consists of a dual-axis configuration with an azimuth axis and a pitch axis. In this structure, when the pitch angle is 90 degrees, the rotation of the azimuth axis cannot change the antenna’s direction. To solve this issue, a three-axis SOTM mechanical structure has been developed. The traditional three-axis SOTM servo control system adopts a closed-loop control scheme. In this scheme, due to the difficulty in directly obtaining the antenna’s rotation angle, the angles of rotation for each axis are typically selected to represent the antenna’s rotation angle. The closed-loop feedback includes the angles and angular velocities of the axes, which cannot completely capture the antenna’s motion state, essentially constituting an indirect closed-loop control. Addressing the shortcomings of this indirect closed-loop control, this paper first establishes the kinematic relations between the axes of the three-axis SOTM antenna using the Denavit–Hartenberg (DH) method. Subsequently, the relationship between antenna pointing and the rotational states of the three axes was derived using the Jacobian operator. Building upon this foundation, a direct closed-loop control structure for a three-axis SOTM antenna was designed. To enable the control system to achieve rapid convergence with minimal overshoot, an Active Disturbance Rejection Control (ADRC) algorithm based on smooth continuous functions is introduced as the inner and outer loop controller algorithms within the direct closed-loop control structure. To address the nonlinearity in the design scheme, a piecewise linearization method is proposed to reduce the demands on the microprocessor’s performance and enhance the engineering feasibility of the solution. Finally, the effectiveness of the proposed approach is validated through experiments. The experimental results demonstrate that compared to traditional indirect closed-loop control methods, utilizing the direct closed-loop control method for the three-axis SOTM antenna presented in this paper can lead to higher precision in pointing the antenna towards satellites and enhance communication effectiveness.