The Stuttgart S-Bahn network comprises six subway lines and is used by approximately 425,000 people on a daily basis. In previous studies in other cities, it was found that subways can be a source and collection point of particulate matter (PM), which is detrimental to human health. This study focused on making an initial assessment of the pollution situation inside the trains and on the underground platforms. Real-time measurements were performed with high time-resolution instruments inside the S-Bahn trains, two underground stations, and two outdoor stations in the Stuttgart subway network in November 2019. Firstly, the variation in concentration inside the train as it traveled through the tunnel was investigated, and it was recurrently observed that the pollutant concentration in the train increased while traveling through the tunnel and then decreased when nearing the tunnel exit. Secondly, the measurement location with the highest particulate matter concentrations was determined. The particulate matter concentrations on underground platforms were higher than those on the train and on the outdoor platforms. In addition, the dominant fraction of the particulate matter measured was in the range of ultrafine particles (UFP). Finally, the wind speed and wind direction data were analyzed in conjunction with specific locations along the platforms. From the wind measurement results, it was assumed that the combined airflows led to higher particle resuspension and particulate matter concentrations in these areas. In conclusion, it was determined that subway users were exposed to higher particle concentrations, particularly UFP (10–116 nm), while standing on underground platforms and when traveling through underground tunnels. It was found that the PNCs inside the train wagons as well as PM and BC mass concentrations increase when passing through the tunnel. Additionally, the average number concentration of UFPs on underground platforms was significantly higher than in other locations by factors of around 1.7 to 1.9 for UFPs and 1.6 to 2 for coarse and fine particles.
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