Random Permutation Set is a newly proposed method for handling uncertainty, which considers the order of the elements in evidence. However, how to fuse RPSs efficiently is still an open issue. To solve this problem, the space composed of order code is defined. Then the mutual mappings between this space and permutation event space are also presented. Finally, the new orthogonal sum is proposed. Compared with the existing left orthogonal sum, the new orthogonal sum can obtain more accurate results with lower entropy and deal with extreme situations. Numerical examples are used to illustrate the superiority of the new orthogonal sum.