Original Morphology Research Articles

High-entropy engineering improved the corrosion resistance of rare earth tantalates

High-entropy RETa3O9 ceramics have garnered significant interest in materials science due to their impressive high melting points and lower thermal conductivity. This study focuses on three types of these ceramics: (La0.2Ce0.2Nd0.2Sm0.2Dy0.2)Ta3O9, (La0.2Ce0.2Nd0.2Sm0.2Tm0.2)Ta3O9, and SmTa3O9.The results indicate that the coefficient of thermal expansion (TEC) for RETa3O9 ceramics remains in the range of approximately 5.94×10-6 K-1 to 6.05×10-6 K-1 when subjected to temperatures from room temperature up to 1400°C. This TEC is notably similar to that of silicon carbide ceramic matrix composites (SiC-CMC), which is essential for compatibility in applications where these materials are used together.Moreover, the study highlights an important finding: after 20 hours of exposure to a CMAS (calcium-magnesium-alumino-silicate) environment at 1300°C, the high-entropy tantalates exhibit significantly reduced susceptibility to corrosion compared to traditional single-component tantalate ceramics. While single-component materials, including SmTa3O9, showed greater degradation, the high-entropy RETa3O9 ceramics maintained their original morphology, free from porosity and cracking.This impressive resistance to CMAS corrosion indicates that the high-entropy design is beneficial in enhancing the durability of tantalates in extreme environments. Consequently, these findings suggest that high-entropy RETa3O9 ceramics hold promise for use as thermal/environmental barrier coating (T/EBC) materials in applications involving SiC-CMCs, potentially leading to improved performance and longevity in high-temperature applications.

Photoregulated Supramolecular Polymerization through Halogen Bonding.

Supramolecular polymers are able to change their structure, morphology and function in response to external stimuli. However, controlling the independence of stimuli-responses in these systems is challenging. Herein, we exploit halogen bonding (XB) as a reversible network element to regulate the photoresponsive and adaptive behavior of supramolecular polymers. To this end, we have designed a system comprising an amphiphilic XB acceptor with the ability to self-assemble in aqueous media (OPE-Py) and a molecule with a dual photoresponsive and XB donor function [(E)-Azo-I]. OPE-Py self-assembles in aqueous media into supramolecular polymers, which transform into nanoparticle assemblies upon co-assembly with (E)-Azo-I. Interestingly, a third type of assembly (2D sheets) is obtained if OPE-Py is treated with (E)-Azo-I and exposed to photoirradiation. At ambient conditions, both nanoparticles and 2D sheets remain invariant over time. However, heating dissociates the XB interactions present in both assemblies, resulting in their transformation to the original fiber-like morphology of OPE-Py. Thus, breaking the communication between self-assembly and the stimuli-responses upon heating restores the original state of the system, drawing parallels to feedback loops in programming language. This work broadens the still limited scope of XB in solution assemblies and paves the way for multifunctional adaptive supramolecular systems.

Revealing Anion Exchange in Two-Dimensional Nanocrystals.

Ion exchange is a powerful postsynthesis tool for the design of functional nanomaterials. However, achieving anion exchange while maintaining the original morphology and crystal structure, as well as elucidating the mechanism, remains challenging. Here, we developed an anion-exchange strategy under mild conditions and revealed an unusual ion-exchange mechanism in the semiconductor nanoplatelets. Kinetic studies have demonstrated that the transformation follows first-order kinetics, with the ligand restricting the guest anion from diffusing only in one-dimensional directions. By monitoring the reaction process, we demonstrated that the anion exchange reaction occurs selectively on the polar surface of the NPLs and exhibits asymmetry at the two polar end faces. Theoretical simulations further confirmed that anion exchange began from the chalcogenide-dominated facet. The thermodynamic data suggest that guest ions diffuse into the crystal interior via a direct exchange mechanism. This study provides a pathway for anion exchange and the construction of functional nanocrystals and a platform for studying the optoelectronic behavior of single-sheet heterojunctions.

Influence of green solvents on the recovery of cathode active materials from electrode scraps: A comparative study

Direct recycling of cathode materials from spent Li-ion batteries (LIBs) or electrode scraps necessitates the efficient recovery of active materials from the aluminum foil. The variability in electrode types and recovery processes across previous studies complicates the comparative assessment of the recovery performance of green solvents. In this study, we evaluated the performance of three green solvents—triethyl phosphate (TEP), dihydrolevoglucosenone (Cyrene), and propylene carbonate (PC)—in recovering valuable active materials from industrial-grade cathode scraps. Using ultrasonication, we developed a standardized, energy-efficient recovery process that eliminated the need for conventional stirring and achieved complete cathode delamination from the aluminum foil. Furthermore, we successfully recovered the used green solvents after the process, ensuring their reuse and supporting a circular economy. The recovered materials retained their original morphology, chemical composition, and crystalline structure; however, the presence of surface impurities varied significantly depending on the green solvent used. These impurities had a considerable impact on the electrochemical performance of the recovered materials. TEP and PC yielded high-purity active materials and aluminum foils suitable for reuse or direct recycling, while Cyrene resulted in substantial residues of PVDF/solvent, requiring additional post-processing. Additionally, the recyclability of these green solvents was influenced by their solubility power for PVDF. This study provides valuable insights into the green solvent-based recycling process, laying the groundwork for future sustainable practices in LIB recycling.

Parallel evolution of unusual ‘harpiform’ morphologies in distantly related trilobites

Abstract Harpetid and trinucleid trilobites share a similar and unusual morphology, the most striking feature of which is a wide, flattened cephalic brim with many pits or holes. This similarity was once interpreted as a sign that these two groups of trilobites were closely related, but in recent years it has instead been assumed that the ‘harpiform’ brim arose in both groups independently. However, relatedness and similarity can be difficult to disentangle in fossil taxa without close living relatives, and this assumption about the harpiform brim has never been explicitly tested. Our study re-evaluates the relationship between Harpetida and Trinucleioidea in order to test a longstanding assumption about trilobite relationships and as a case study in evaluating different kinds of morphological similarity in extinct groups. We inferred a new phylogenetic tree using parsimony methods and discrete morphological character data from a broad sampling of harpetids, trinucleids, and their relatives. Despite their gross morphological similarities, we found that harpetids and trinucleids were readily distinguished in our analyses, a result consistent with a hypothesis of multiple origins for the harpiform brim. By mapping brim-related characters across our new phylogeny, we identified a sequence of morphological innovations that arose in parallel in both groups and led ultimately in each case to the evolution of the harpiform brim. These results indicate that harpiform brims are a prime example of parallel evolution—the similar development of a morphological trait in distantly related taxa that nevertheless share a similar original morphology. In addition, our phylogeny supports the idea that trinucleids are specialized, harpiform asaphids, rather than an independent order of trilobites. We also provide new information on the relationships of the putative ‘basal-most’ members of Trinucleioidea, the Liostracinidae, and confirm recent assessments that this family is more distantly related to trinucleids.

Research on the evolution mechanism of surface morphology and solidification crystallization simulation of molten pool in electron beam polishing

Clarifying the flow and solidification process rules of a molten pool in scanning electron beam polishing remains challenging. This paper establishes a geometric model that closely resembles the original milling morphology, investigates the morphology evolution process, the flow law of the molten pool, and the change in driving force under the action of the electron beam, and solves the solidification and crystallization parameters of the solid-liquid interface. Results demonstrate that thermocapillary force is the dominant driving factor for horizontal motion inside the molten pool, which immediately leads to the emergence of velocity conversion sites on the surface of the molten pool, thus effecting surface fluctuation variations. Combined with polishing inspection, the average surface roughness error is controlled within ±7 %. Solid-liquid interface deflection significantly affects grain growth, and solidification and crystallization parameters follow similar patterns at different workpiece speeds. The grain structure of the melt zone can be predicted with the crystallization parameters at various depths of the melt layer.

Designing ternary Co-Ni-Fe layered double hydroxides within a novel 3D cross-flower framework for efficient catalytic performance in oxygen evolution reaction

In this study, we synthesized novel three-dimensional (3D) cross-flowered Co-Ni metal–organic framework (Co-Ni-MOF) precursors using the chemical precipitation method. Subsequently, we obtained Co-Ni-Fe layered double hydroxides (Co-Ni-Fe-LDHs) through an ion exchange strategy, which preserved their original morphology while consisting of ultrathin layered hydroxide nanosheets. The interlayer spacing of the LDH lamellar structure was finely tuned by varying the ratios of Co to Ni. The results demonstrated that Co-Ni-Fe LDHs, characterized by a unique three-dimensional cross-shaped structure and an optimal composition ratio of Co2+:Ni2+ = 2:1, exhibited increased interlayer spacing. This structural characteristic contributed to their excellent electrochemical performance, positioning them as optimal electrode materials for catalytic oxygen evolution reactions (OER). Our observations revealed that Co-Ni-Fe-LDHs exhibited remarkable OER activity, characterized by a low Tafel slope of 41.82 mV dec−1, a low overpotential of 322 mV at a current density of 10 mA cm−2, and outstanding stability over a 48-hour period. In-situ Raman spectroscopy results indicated that the active site of the composite was γ-CoOOH. Additionally, the room temperature stirring and standing strategy employed in this study is easier to scale up and yields a higher quantity of reaction products compared to traditional high-temperature and high-pressure conditions. This investigation provides novel insights into the design and fabrication of Co-Ni-Fe-LDHs catalyst with 3D cross-flower structures, demonstrating enhanced electrocatalytic activity and commendable stability. These findings suggest promising applications in the field of electrolyzed water.

Effect of Powder Reuse on Powder Characteristics and Properties of DED Laser Beam Metal Additive Manufacturing Process with Stellite® 21 and UNS S32750

In this work, the influence of powder reuse up to three times on directed energy deposition (DED) with laser processing has been studied. The work was carried out on two different gas atomized powders: a cobalt-based alloy type Stellite® 21, and a super duplex stainless steel type UNS S32750. One of the main findings is the influence of oxygen content of the reused powder particles on the final quality and densification of the deposited material and the powder catch efficiency of the laser deposition process. There is a direct relationship between a higher surface oxidation of the particles and the presence of oxygen content in the particles and in the as-built materials, as well as oxides, balance of phases (in the case of the super duplex alloy), pores and defects at the micro level in the laser-deposited material, as well as a decrease in the amount of material that actually melts, reducing powder catch efficiency (more than 12% in the worst case scenario) and the initial bead geometry (height and width) that was obtained for the same process parameters when the virgin powder was used (without oxidation and with original morphology of the powder particles). This causes some melting faults, oxides and formation of undesired oxide compounds in the microstructure, and un-balance of phases particularly in the super duplex stainless steel material, reducing the amount of ferrite from 50.1% to 37.4%, affecting in turn material soundness and its mechanical properties, particularly the hardness. However, the Stellite® 21 alloy type can be reused up to three times, while the super duplex can be reused only once without any major influence of the particles’ surface oxidation on the deposited material quality and hardness.

Selective Cleavage and Structural Stability of Double Crosslinked Aromatic Polyamide Porous Materials

AbstractA porous, crosslinked aromatic polyamide having COCl and COOH groups (referred to as PA herein) prepared had a mesoporous structure and comprised agglomerates of particles with average diameters of approximately 30 nm. The PA was found to swell with significant deformation in response to water vapor, but was almost unchanged after exposure to toluene vapor. The polymeric structure returned to its original porous morphology after removal of the solvents, demonstrating that the PA possessed affinity for specific solvents and shape memory. The chemical composition and porous structure of the PA were also not affected by heating to 330 °C. The COCl groups in the PA could be modified by reaction with 2,4,6‐triaminopyrimidine (TAP), resulting in a doubly crosslinked structure based on the reaction with the TAP as well as the existing amide moieties in the polymer. The degree of modification was highly dependent on the reaction solvent used. The porous structure of the PA was essentially unchanged after this modification. The TAP‐based crosslinks in the modified PA could be selectively cleaved along with vaporization of the TAP by heating at 330 °C, which no change to the porous structure. Thus, the PA showed excellent heat resistance and structural stability.

Eco-friendly thiol-functionalized magnetic oxygenous carbon nitride nanocomposites for effective elimination of heavy metals

The increased pollution of water resources by toxic heavy metals poses a huge threat to the aqueous ecosystem. Since the low concentrations of heavy metals are often highly toxic but difficult to remove, novel efficient adsorbents still need to be explored. Herein, the superparamagnetic thiol-functionalized oxygenous carbon nitride nanocomposite (CNO/Fe3O4-SH) with multifunctional groups such as –NH2, –OH, –SH, and –COOH was fabricated by a simple and eco-friendly method. The maximum adsorption capacities of Pb2+, As3+, and Cd2+ ions on CNO/Fe3O4-SH at pH = 6 were 80.79, 71.78 and 66.19 mg/g, respectively, when their equilibrium concentrations were 20 mg/L. Under the equilibrium concentration below 0.01 mg/L, the adsorption capacities of these heavy metals over CNO/Fe3O4-SH were much higher than those of other adsorbents. The competitive adsorption investigations showed that the adsorption order in polymetallic solutions was Pb2+ > As3+ > Cd2+. Adsorption kinetics and isotherms studies indicated that the adsorption of Pb2+, As3+ and Cd2+ by CNO/Fe3O4-SH was attributed to monolayer adsorption and the adsorption process was controlled by chemical adsorption. The thermodynamic experiments showed that the adsorption processes were spontaneous and endothermic. After six adsorption/desorption cycles, CNO/Fe3O4-SH maintained its original morphology and adsorption ability, indicating its excellent regeneration performance, which had significant potential application in the decontamination of trace heavy metal ions in water.

Three-dimensional reconstruction of Late Miocene Trapa from eastern Zhejiang Province, China: Insights into its phytogeography and evolution

Abundant plant fossils were found in the Upper Miocene Shengxian Formation, eastern Zhejiang Province, China, among which Trapa belongs to a dominant population. The fossil fruits of Trapa were well preserved with abundant details. However, due to compaction during fossilization, Trapa fruits were often flattened, leading to the loss of some characteristic features. Thereby, a bias in taxonomic and phylogenetic studies would occur when such studies were based on these fruit fossils. In this study, we present the first quantitative three-dimensional reconstruction of compressed Trapa fruit fossils to restore their original morphology prior to burial. This approach provides a novel perspective for the identification and classification of compressed fruit fossils. The three-dimensional reconstruction of Trapa fruit fossils enabled accurate comparisons with extant species. We subsequently identified it as a new species, named Traparadiatiformis L. Xiao sp. nov., revealing differences from previously known taxa of Trapa. Importantly, our comparison suggests that the long lower horns and residual stalk may represent inherent characteristics of early Trapa fruits. However, these traits gradually degenerated during fruit evolution, resulting in morphological simplification during geological time. T. radiatiformis with primitive features exhibits good resemblance to Trapanatans fruit characteristics, which means it may be an ancestor of T. natans. We summarize the palaeogeographic distribution of fossil Trapa using previously published literature and demonstrate that the genus was most prosperous in the Miocene and exhibited the same distribution as that at present. Additionally, through detailed morphological comparisons between Trapa and Hemitrapa fruits, along with phylogenetic analysis within the Primotrapa genus itself, we propose a homology between Trapa and Hemitrapa, suggesting that they could have a common ancestor.

Hybrid-feature based spherical quasi-conformal registration for AD-induced hippocampal surface morphological changes

Background and objectiveEstablishing accurate one-to-one morphological correspondence between different hippocampal surfaces is a solid foundation for the analysis of AD-induced hippocampal morphological changes. However, owing to the large variations between hippocampal surfaces, exiting registration work either fails to obtain the accurate matching of local and overall morphological features or does not preserve the bijectivity during parametric mapping. For this reason, this study proposes a hybrid-feature based spherical quasi-conformal registration (HSQR) method that can effectively maintain the diffeomorphic property while meeting the hybrid-feature matching constraints in the spherical parameter domain. MethodsThe HSQR algorithm is primarily achieved through hippocampal surface hybrid feature extraction and spherical quasi-conformal registration. First, hybrid features for a comprehensive morphological description of the hippocampal surface were established, which included essential anatomical features (landmarks) and mean curvature (intensity) features to ensure the accuracy of surface morphology alignment. Second, spherical parameterization was applied to genus-0 closed surfaces, such as the hippocampus, which maximized the preservation of the original local surface morphology through area-preserving properties. Third, a novel spherical quasi-conformal registration algorithm that can handle large deformations is established. It transforms a 3D spherical parameter domain into a 2D plane parameter domain using iterative local stereo projection to improve the efficiency of the registration algorithm. Subsequently, by controlling the Beltramin coefficient, the hybrid morphological features could be aligned while ensuring bijection before and after registration. ResultsUsing a cohort including 161 patients with amyloid-β (Aβ) positive Alzheimer disease (AD), 234 Aβ positive mild cognitive impairment (MCI) and 266 Aβ negative cognitively unimpaired (CU) individuals from the Alzheimer's Disease Neuroimaging Initiative (ADNI) database, we set up the experiment which indicated that the HSQR-based whole bilateral hippocampal atrophy features demonstrated the stronger statistical power for group morphological differences of CU vs. MCI with q-value: 0.0453 for left hippocampus and 0.0401 for right hippocampus and group morphological differences of AD vs. MCI with q-value: 0.0282 for left hippocampus and 0.0421 for right hippocampus. ConclusionsOur registration algorithm may provide a solid foundation for the accurate quantification of hippocampal surface morphological changes for the differential diagnosis and tracking of AD.

Strong binding between nanoplastic and bacterial proteins facilitates protein corona formation and reduces nanoplastics toxicity

The interaction and combination of nanoplastics with microorganisms, enzymes, plant proteins, and other substances have garnered considerable attention in current research. This study specifically examined the interaction and biological effects of NPs and proteins. The findings indicated that the presence of externally wrapped proteins alters the original morphology and surface roughness of nanoplastics, leading to the formation of unevenly distributed coronas on the surface. This confirms that nanoplastics can interact with proteins to form protein coronas. The study characterized the adsorption behavior of bacterial proteins on unmodified, amino-modified, and carboxyl-modified nanoplastics using Langmuir and Freundlich isotherm models, showing that the adsorption process of the three nanoplastics on bacterial proteins was mainly controlled by chemisorption. Fluorescence spectroscopy revealed a higher binding affinity of unmodified nanoplastics. Nearly 40 % of the proteins in the protein corona of unmodified NPs are involved in metabolite production and electron transport processes. Nearly 50 % of the proteins in the protein corona of amino-modified NPs are involved in cellular metabolic processes, followed by enzymes that carry out redox reactions. The protein corona of carboxyl-modified NPs has the highest number of proteins involved in metabolic pathways, followed by proteins involved in energy-electron transfer. The formation of protein coronas on NPs with different surface modifications can reduce the toxicity of nanoplastics to bacteria to a certain extent compared to pure nanoplastics, especially amino-modified NPs, which show a significant increase in bacterial survival. The formation of protein coronas on NPs leads to varying degrees of decrease in bacterial ROS and MDA generation, with amino-modified NPs showing the most reduction; SOD and CAT exhibit varying degrees of increase and decrease. These findings not only advance our understanding of the biological impacts of NPs but also provide a basis for future in-depth investigations into the pathways of NP contamination in real environments.

Topographic variation and fluid flow characteristics in rough contact interface

Understanding flow characteristics of fluid near rough contact is important for the design of fluid-based lubrication and basic of tribology physics. In this study, the spreading and seepage processes of anhydrous ethanol in the interface between glass and rough PDMS are observed by a homemade optical in-situ tester. Digital image processing technology and numerical simulation software are adapted to identify and extract the topological properties of interface and thin fluid flow characteristics. Particular attention is paid to the dynamic evolution of the contact interface morphology under different stresses, the distribution of microchannels in the interface, the spreading characteristics of the fluid in contact interface, as well as the mechanical driving mechanism. Original surface morphology and the contact stress have a significant impact on the interface topography and the distribution of interfacial microchannels, which shows that the feature lengths of the microchannels, the spreading area and the spreading rate of the fluid are inversely proportional to the load. And the flow path of the fluid in the interface is mainly divided into three stages: along the wall of the island, generating liquid bridges, and moving from the tip side to the root side in the wedge-shaped channel. The main mechanical mechanism of liquid flow in the interface is the equilibrium between the capillary force that drives the liquid spreading and viscous resistance of solid wall to liquid. In addition, the phenomenon of “trapped air” occurs during the flow process due to the irregular characteristics of the microchannel. This study lays a certain theoretical foundation for the research of microscopic flow behavior of the liquid in the rough contact interface, the friction and lubrication of the mechanical system, and the sealing mechanism.

Innovative valorization of spent liquors from hydrothermal carbonization for light-induced nanoparticle synthesis

To develop the biorefinery concept around the hydrothermal carbonization (HTC) process, it is essential to take advantage of the spent liquor (SL) produced. In general, SLs were reported to be treated by anaerobic digestion; however, some molecules present in SL are considered biological inhibitors. Nonetheless, this might be advantageous as these molecules exhibit antioxidant activity, opening a new valorization alternative as green reducing and capping agents for particle synthesis. Among the hydrothermally treated biomasses, the SL from Jatropha fruit husk (JFH) presented the highest antioxidant activity (TEAC ∼ 1597 µM g−1), increasing its capability to form metal nanoparticles due to their reducing effect. Still, nanoparticle aggregation was observed, evidencing its lack of capping effect. In this sense, the present study provides a novel approach to recovering the organic compounds from HTC spent liquor (OC-HTCSL) in viscous concentrates by evaporating the remaining water. Surprisingly, the JFH sample showed the lowest antioxidant activity and phenolic content after concentration. Nevertheless, this concentrate reflected a capping effect for the LED-assisted synthesis of silver nanoparticles. Stable silver colloids containing nanoparticles with an average diameter of 17 nm were successfully obtained. These silver nanoparticles retained their original morphology after being stored for six months. This research suggests that a lower antioxidant activity and phenolic content of the OC-HTCSL concentrate might be more effective in forming silver nanoparticles.

DENTAL REHABILITATION BY THE OCCLUSAL MATRIX TECHNIQUE USING PROVISIONAL RESTORATOR: Case report of a pediatric patient from the city of Mato Verde - MG

The occlusal matrix technique allows the recording of anatomical details of the remaining tooth structure before starting cavity preparation, enabling the reestablishment of the original tooth morphology by means of an occlusal matrix. The objective of this study was to report a clinical case of dental rehabilitation by the occlusal matrix technique using a temporary restorative in pediatric dentistry. This research is an observational descriptive study (committee, nº 6.906.292). The work was conducted in the city of Mato Verde, Minas Gerais, at Faculdade Verde Norte (FAVENORTE). A 7-year-old female patient, together with her guardian, attended the FAVENORTE Dentistry clinic for dental care, complaining that her tooth had some “dark spots”. During the clinical examination, it was observed that tooth 46 had an active carious lesion on the occlusal surface in a region of pits and fissures with shadowing in the underlying dentin (ICDAS – Score 4), but with relatively intact occlusal anatomy. Interproximal radiographic examination showed that the carious lesion was in the dentin, but not close to the pulp. Due to the preservation of the occlusal anatomy of the tooth, the proposed treatment for the patient was the use of the occlusal matrix technique, selective removal of carious tissue, and restoration with composite resin, aiming to restore form and function. The occlusal matrix technique has proven to be an effective and efficient approach in the rehabilitation of carious lesions on occlusal surfaces, especially in pediatric patients. The technique allowed the faithful reproduction of the original anatomy of the tooth, which is essential for the maintenance of masticatory function, esthetics and occlusal integrity.

Architecture and dynamics of Precambrian linear megadunes: Galho do Miguel Formation, Mesoproterozoic, South-East Brazil

Recognizing the deposits of linear megadunes in ancient aeolian successions is challenging when the original bedform topography is not preserved. The present study provides a detailed analysis of the depositional architecture of an ∼ 80 m-thick interval of the Mesoproterozoic Galho do Miguel Formation (SE Brazil) to reconstruct the original morphologies of linear megadunes and to understand their dynamics. The depositional architecture reveals compound cross-bedded sets, which transition laterally into thick low-angle cross-stratified sets and planar-parallel sandstone beds. The depositional features indicate the presence of complex megadunes separated by adjoining wide dry inter-megadune areas, which were themselves flooded seasonally by a water table that rose above the depositional surface. Linear megadunes experienced two phases of development: vertical accretion and subsequent episode of lateral migration. During the vertical accretion phase, high sediment supply, typical of Precambrian aeolian systems, and the convergence of winds from two distinct directions promoted high rates of megadune growth, bedform elongation, and the formation of superimposed dunes. The lateral migration phase was characterised by a component of lateral bedform shift relative to the main along-crest sediment transport direction; this prevented preservation of a bimodal pattern of dune cross-strata azimuths. The accumulation of these deposits occurred via a combination of megadune climbing that occurred with progressive rise of the water-table level. The water-table rise hindered cannibalization of the lower parts of the migrating megadunes, allowing the accumulation and subsequent preservation of megadune sandstone packages. The rise of the water table was also responsible for the accumulation of thick dry inter-megadune strata. The unusual thickness of linear megadune and inter-megadune deposits of the Galho do Miguel Formation, as compared with Phanerozoic examples, are attributed to the interplay between the barren conditions of the early Earth, the morphodynamics of the linear megadunes, and the seasonal impact of the water table at the accumulation surface. Without a water-table control, opportunities for megadune accumulation and preservation were likely limited in Precambrian ergs.

Reappraisal and refined diagnosis of ultrasonography and histological findings for hydatidiform moles: a multicentre retrospective study of 821 patients

AimsSpecific identification of a hydatidiform mole (HM) and subclassification of a complete hydatidiform mole (CHM) or partial hydatidiform mole (PHM) are critical. This study aimed to reappraise the diagnostic performance...

The isomerization of glucose to fructose in ethanol over ZrO2 on mesoporous silica prepared through in-situ and post-impregnation methods

Fructose is a vital ketose in the production of 5-hydroxymethylfurfural platform molecules. Herein, Zr-doped hexagonal mesoporous silica was prepared over in situ co-assembly (Zr-x-HMS, x is the mole ratio of Si to Zr, x = 20, 50) and post-impregnation (Zr-Imx-HMS, x = 20, 50, 100) processes to regulate its catalytic performance against the isomerization of glucose to fructose in ethanol. The post-impregnation process did not significantly change the original pore structure and morphology of HMS, Zr-Im50-HMS with medium Zr loading possessed the most Lewis acid sites with medium strength among Zr-Imx-HMS catalysts. The in situ process changed the physical properties of HMS and enhanced the interaction of Zr sites and silica framework, facilitating the formation of Lewis acid sites with medium strength. Zr-Im50-HMS possessed the most suitable acidity for fructose production, and an optimal yield of 31.2% was achieved at 160 °C and 20 min. Moreover, the recyclability of Zr-Im50-HMS was acceptable.

Arbitrary Construction of Versatile NIR-Driven Microrobots.

Emerging light-driven micro/nanorobots (LMNRs) showcase profound potential for sophisticated manipulation and various applications. However, the realization of a versatile and straightforward fabrication technique remains a challenging pursuit. This study introduces an innovative bulk heterojunction organic semiconductor solar cell (OSC)-based spin-coating approach, aiming to facilitate the arbitrary construction of LMNRs. Leveraging the distinctive properties of a near-infrared (NIR)-responsive organic semiconductor heterojunction solution, this technique enables uniform coating across various dimensional structures (0D, 1D, 2D, 3D) to be LMNRs, denoted as "motorization." The film, with a slender profile measuring ≈140nm in thickness, effectively preserves the original morphology of objects while imparting actuation capabilities exceeding hundreds of times their own weight. The propelled motion of these microrobots is realized through NIR-driven photoelectrochemical reaction-induced self-diffusiophoresis, showcasing a versatile array of controllable motion profiles. The strategic customization of arbitrary microrobot construction addresses specific applications, ranging from 0D microrobots inducing living crystal formation to intricate, multidimensional structures designed for tasks such as microplastic extraction, cargo delivery, and phototactic precise maneuvers. This study advances user-friendly and versatile LMNR technologies, unlocking new possibilities for various applications, signaling a transformative era in multifunctional micro/nanorobot technologies.