A hybrid adhesive system composed of phenol-formaldehyde (PF) resin and polymeric methylene diphenyl diisocyanate (pMDI), modified with two types of alkaline catalysts, namely NaOH and CaCO3 at 20% (w/v), was used for manufacturing the oriented strand board (OSB) from sengon (Paraserianthes falcataria L. Nielsen) wood. The catalyst was added at a concentration of 1% of the solids content of PF adhesive, and pMDI was added at 2.5% and 5.0% of the PF adhesive solids content. Adding catalysts and cross-linking agents increased the solids content and viscosity of the adhesive and accelerated the gelation time. The water absorption of OSB increased with the addition of catalysts and crosslinking agents compared to the control PF. Still, the CaCO3 catalyst worked optimally in reducing the thickness swelling of OSB. The mechanical properties of the laboratory-fabricated OSB panels increased with the addition of catalyst and cross-linker, except for the modulus of elasticity parallel to the grain. The optimal performance of OSB was obtained by adding 1% CaCO3 and 2.5% pMDI based on the PF’s solids content.
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