Organic Wastewater Treatment Research Articles

A novel cross-flow Ag/wood composite filter for high-concentration organic dye wastewater treatment

A novel cross-flow Ag/wood composite filter for high-concentration organic dye wastewater treatment

Mechanochemical Ball Mill Goethite to Activate Sodium Persulfate for the Treatment of Organic Wastewater Containing Tetracycline Hydrochloride

The contamination of aquatic systems by tetracycline hydrochloride (TC) has emerged as an urgent environmental concern necessitating immediate intervention. Herein, a mechanochemical approach was utilized to synthesize a FeOOH@AC nanocomposite through the co-grinding of goethite (FeOOH), hydroxylamine hydrochloride (NH2OH⋅HCl), and activated carbon (AC). The FeOOH@AC nanocomposite acted as a catalyst for the activation of sodium persulfate (PS), producing strong oxidizing radicals for the removal of TC from water. The results demonstrated that the physicochemical properties and crystal structure of FeOOH were altered via ball-milling treatment. The activation of PS-generated sulfate radicals (SO[Formula: see text] and hydroxyl radicals ([Formula: see text]OH) synergistically degraded TC. Additionally, the degradation rate of TC in a 50[Formula: see text]mg/L solution reached 91.26% after the addition of FeOOH@AC and PS. This work offers a theoretical and technical foundation for the mechanochemical ball milling preparation of FeOOH@AC, facilitating PS activation for the degradation of TC in water.

Microenvironment modulation of Fe single atoms in porous g-C3N4 by introducing −SOx groups for enhanced photo-Fenton reactions

Heterogeneous photo-Fenton reactions based on hydrogen peroxide (H2O2) activation exhibit great potential in the treatment of organic wastewater. For developing efficient photo-Fenton catalysts, a fundamental investigation into the specific catalytic sites and the reaction mechanism is highly desired. Herein, a novel photo-Fenton catalyst (Fe1/CN-SOx) was constructed by synchronously anchoring Fe single atoms (SAs) and oxidized sulfur (−SOx) groups into porous graphitic carbon nitride (g-C3N4). The presence of trace −SOx groups altered the local configuration of g-C3N4 and optimized the coordination microenvironment of Fe SAs, thereby modulating the electronic structures of catalytic sites in favor of H2O2 activation. The cooperation between Fe SAs and the neighboring C atoms bonded with −SOx (C-SOx) enhanced the adsorption and cleavage of H2O2. The photoinduced charge carriers further accelerated Fe2+/Fe3+ redox cycles and hydroxyl radical (•OH) production, achieving an efficient photo-Fenton synergistic catalysis for continuous degradation of organic contaminants. The Fe1/CN-SOx catalyst also exhibited excellent anti-interference performance in diverse aquatic systems and good long-term stability, indicating its great potential for applications in water treatment. This study provides an in-depth insight into the optimal fabrication of single-atom active sites by modulating the local structures of support materials, aiming to enhance photo-Fenton reactions.

Nanoconfined Cu clusters-activated peroxodisulfate for efficient wastewater decontamination via polymerization

In water treatment, the transition from mineralization to polymerization of organic pollutants is an essential step towards carbon and energy recovery. However, achieving efficient polymerization through the construction of heterogeneous catalysts remains a great challenge. In this work, we prepared Cu clusters nanoconfined in ZIF-derived carbon hollow structure to activate peroxodisulfate (PDS), achieving efficient wastewater decontamination via polymerization. The reaction rate is increased by a factor of 62. It shows excellent performance under different conditions (pH, anions, aqueous) as well as stability. Experiments and DFT calculations show that the removal of Bisphenol A was mainly by the direct oxidative transfer process, Cu–N and Cu clusters were involved in the catalytic oxidation. The removal of COD and TOC could reach 80% and 63.50%, respectively. This work provides technical support for the accelerated mechanism of oxidative polymerization during the treatment of toxic organic wastewater.

Low-frequency contact-electro-catalysis driven by friction between the PTFE-coated fabric and dye solution

The process of contact electrification occurs when two materials with dissimilar work functions are in contact and charged. Contact-electro-catalysis may occur when electron exchange at the liquid-solid interface initiates a redox reaction. This type of catalysis falls under the mechanically-driven tribocatalysis and has been demonstrated to be able to degrade dye under high-frequency ultrasonic excitation. In this work, a high RhB dye decomposition ratio of 91.5% is achieved by harnessing the ordinary low-frequency solid-liquid friction energy through the design and use of the recyclable fabric with PTFE coating as a solid friction source to agitate the dye solution. In the absence of PTFE coating, the RhB dye decomposition ratio is about 14.8% under the same friction conditions. The enhanced contact-electro-catalysis may be attributed to the high electronegativity of PTFE coating. According to the quenching experiments with active species, it is found that hydroxyl radical (·OH) and superoxide radical (·O2-) are the main active species induced by low-frequency solid-liquid friction. The fabric with PTFE coating after being dried and reused for 5 cycles still possesses 87.9% RhB dye decomposition ratio. With these advantages of high decomposition ratio of organic pollution, low cost, good recyclability, and environmental friendliness, the developed low-frequency contact-electro-catalysis in this work, is potential for organic wastewater treatment application through utilizing waste solid materials to harvest the mechanical friction energy between solid waste fabrics and ordinary waterflow in future.

Perylene diimide configuration to construct g-C3N4 and iron phthalocyanine composite catalyst as PMS activator for contaminant degradation

The photocatalysis-assisted peroxymonosulfate (PMS) activation process has shown great potential for organic wastewater treatment. Herein, the composite photocatalyst (FeTAPc/PDI/CN) was obtained by grafting graphitic carbon nitride (CN) and amino iron phthalocyanine (FeTAPc) onto both ends of perylene tetracarboxylic anhydride (PTCDA) through an imidization process. Under simulated solar irradiation, the catalyst exhibited a remarkable degradation performance toward the target pollutant by activated PMS over a wide pH range from 3 to 11. The degradation efficiency of SMX reached 100 % in 7 min with the reaction kinetic constant of 0.845 min−1, which was 13 times higher than that of pure CN. In addition, the removal rate of FeTAPc/PDI/CN-4 for SMX was more than 80 % after 9 cycles. The introduction of phthalocyanine and PDI improved the separation efficiency of photogenerated electron-hole pairs. Furthermore, the active species involved in the SMX degradation were identified as •OH, SO4•-, •O2– and 1O2. The possible degradation pathways were proposed based on the identified intermediates, in which the oxidation of the amino group on the benzene ring was the main degradation pathway. This study is anticipated to result in a favorable method for designing CN-based photocatalysts with high stability and excellent catalytic activity for environmental remediation.

Insights into mixed dye pollutant degradation by oxygen and air plasma bubbling array

Abstract Synthetic organic dye pollutants pose a serious threat to the aquatic ecological environment due to their difficulty in complete degradation. This study employed a plasma bubble array reactor to degrade individual and mixed dye pollutant solutions of Sunset Yellow (SY), Methyl Orange (MO), and Methyl Violet (MV). The degradation efficiencies and mechanisms of the plasma were investigated under different working gas atmospheres. It was found that oxygen plasma degraded the target dyes and their mixtures more significantly than air plasma. Specifically, compared with air plasma, the removal of single dyes SY, MO and MV by oxygen plasma was increased by 76.6%, 13.8% and 3%, respectively, after 20 min of treatment. As for mixed dyes, after 25 min treatment, oxygen plasma removed 99.1%, which was 31.6% higher than air plasma. However, the degradation kinetic order in oxygen plasma was SY > MO > MV, while that in air plasma was MV > MO > SY. Combined with the detection of reactive oxygen-nitrogen species (RONS), the results showed that the reactive oxygen species (ROS) played an important role in the degradation of SY, and it was also important for the degradation of MO, whereas both the ROS and reactive nitrogen species (RNS) were important for the degradation of MV. Scavenger experiments revealed that hydroxyl (·OH) and superoxide anion (·O2-) played the most important roles in the degradation process. The three dyes were basically completely degraded within 14-20 minutes of treatment, with corresponding yields of 1.94-2.79 g/kWh. Possible degradation pathways for each dye were deduced based on LC-MS and the toxicities of solutions were evaluated by phytotoxicity tests and ion chromatography. The results showed that the biotoxicity of the intermediates was significantly reduced. This study may provide a feasible option for effective application of plasma technology in organic dye wastewater treatment.

Performance of vertical flow wetland in the treatment of medium organic strength synthetic wastewater

Treatment wetlands have been used for decades to treat wastewaters with low organic strength, but little information is available on the treatment of wastewaters with high organic strength. The objective of this study was to evaluate the efficiency of a vertical flow wetland in the primary treatment of synthetic wastewater with medium organic strength (1976 mg COD/L). Alternatives in the reuse of the resulting treated wastewater were also considered. The wetland consisted of several layers of sand and gravel of different granulometry and was planted with the helophyte Eryngium horridum, a species rarely used in treatment wetlands. The wetland was fed with synthetic wastewater by a single feed pulse, with a hydraulic retention time of 24 h. The treatment removed 81% of TSS and 70% of COD. The concentrations of ammonium nitrogen and soluble reactive phosphorus increased due to partial mineralization of organic matter. Total phosphorus and total nitrogen removal were 28% and 5%, respectively. Wastewater suitability for reuse in irrigation increased after treatment. However, a later stage is recommended to further reduce COD and nutrient concentration and disinfect the water.

Preparation and performance of catalyst for organic peroxide wastewater treatment

To improve the oxidation pretreatment efficiency of wastewater from organic peroxides, a catalyst (CeO2-C catalyst) was developed using the calcination method with ceramic particles as the support. The crystalline structure and elemental composition of the CeO2-C catalyst were characterized by Scanning Electron Microscope (SEM), Energy Dispersive Spectrometer (EDS), and X-ray diffraction (XRD). This study explored the effects of CeO2 mass ratio, calcination temperature, and calcination time on the performance of the catalyst. The optimal preparation conditions were established through orthogonal experiments. Additionally, the synergistic effect of the catalyst on the ozone oxidation treatment of peroxide wastewater was investigated. The results indicated that the optimal preparation parameters were a CeO2 mass ratio of 4 %, a calcination temperature of 500 °C, and a duration of 5 h, respectively. After five cycles of reuse, the catalytic activity slightly decreased but remained relatively stable. With an ozone flow rate of 6 L/min, the CeO2-C/ozone catalytic oxidation process achieved a Chemical Oxygen Demand (COD) removal rate of 28.11 % in wastewater, and the B/C (the ratio of BOD concentration to COD concentration) of wastewater improved from 0.093 to 0.152. The calcination method proved effective for preparing the CeO2-C catalyst, which demonstrated significant catalytic performance and held promising application prospects in the oxidation pretreatment of organic peroxide wastewater.

Electrochemical generation of H*-•OH redox pair for rapid removal of refractory nitro-organic micropollutants

This study developed an innovative reduction-oxidation coupling process for treatment of refractory organic wastewater. We constructed a series of N5-coordinated transition metals (TMs) (TMs = Mn, Fe, Co, Ni, Cu) single-atom sites supported on nitrogen-rich carbon nitride (SA-TM-C3N5) for electrochemical generation of the surface-adsorbed hydrogen atom (H*) and hydroxyl radical (•OH). The SA-Co-C3N5 exhibited the highest activity for production of the H*-•OH redox pair, which effectively degraded refractory nitro-organic micropollutants via the parallel reduction-oxidation pathways. The SA-Co-C3N5-mediated electro-Fenton-like system showed high removal efficiency (99 %) and mineralization capacity (78 %) toward metronidazole (MNZ) with low energy consumption (0.019 kWh (g TOC)–1). The trifunctional properties of the H* have contributed to the reduction of nitro compounds, the 2e– ORR for H2O2 production and the Fenton-like catalysis for •OH generation. This work sheds lights on the development of advanced reduction-oxidation coupling process for green and sustainable water purification.

Boosting Fenton-like catalytic performance and environmental stability of nano zero-valent copper (nCu(0)) catalyst by inhibiting the formation of oxide layer: Catalytic performance and mechanistic study

Nano zero-valent copper (nCu(0)) as Fenton-like catalyst has shown great potential in the treatment of organic wastewater. However, nCu(0) is prone to be agglomerated and oxidated, causing to the reduction in catalytic ability. Herein, biochar supported highly dispersed nCu(0) (Cu/C) was synthesized by the carbonization method. And acid-modified strategy was proposed to inhibit the oxidation of nCu(0). Physicochemical properties of Cu/C catalysts modified by different acid (HCl, H2SO4 and HNO3) were analyzed by various characterizations. The results showed that only the introduction of HCl could obviously inhibit the formation of oxide layer on Cu(0), while HNO3 and H2SO4 couldn’t. Furthermore, the content of oxide layers decreased with the increase in HCl addition. Correspondingly, the catalytic performance enhanced gradually. Cu(0) was proved to be the active centers. And the presence of oxide layers was adverse to the catalytic reaction. When the adding amount of HCl reached to 1 mL, the Cu/C-HCl-1.0 catalyst showed the optimal catalytic performance. 97.1 % of p-nitrophenol (PNP) was degraded within 60 min. The reaction rate was 7.6 times that of unmodified Cu/C catalyst. Furthermore, Cu/C-HCl-1.0 catalyst possessed excellent environmental stability. After being directly exposed to air for 4 months, catalytic performance had no obvious decrease. In addition, the catalyst showed efficient degradation ability to phenols, dyes and antibiotics. And it was not sensitive to the initial pH of the organic solution (3.7 ∼ 11.2). OH was confirmed to be the main reactive species for the degradation of organic pollutants, which was formed by the decomposition of PMS by obtaining electrons from Cu(0). This work proposed a novel and efficient method to enhance the catalytic ability and environmental stability of Cu(0) by inhibiting the formation of oxide layer.

Mechanism of o-cresol polymerization and its carbon recovery from aqueous solution by a cathode/Fe2+/H2O2 process

Converting organic pollutants into easily recyclable solid polymers has the advantages of saving oxidants and recovering organic carbon, compared to degrading them into smaller organic molecules. Taking o-cresol as a representative phenolic pollutant, this study realizes the dominant reaction of organic polymerization and the recovery of organic carbon from wastewater via a cathode/Fe2+/H2O2 process. With HO• initiation, 53 % of chemical oxygen demand is removed in the form of suspended solid polymers and equivalent organic carbon is recovered. At the same time, the dissolved organic carbon (DOC) removal reaches 64 %, and the H2O2 consumption is only a quarter of that in an ideal degradation process. The recovered solid polymers are oligomers derived from o-cresol and its derivatives, with the molecular weight ranging from 400 to 2500 Da. The polymerization pathway involves repeated HO• oxidation and coupling of intermediate organic radicals. The energy consumption is 26.7 kWh/kg DOC, significantly lower than that of previous Fenton-like processes in the literature. This study broadens the scope of polymerization-based technologies for organic wastewater treatment, and demonstrates that HO• has the potential to simultaneously reduce organic pollution and recover organic carbon by generating suspended solid organic polymers, which may provide new avenues for H2O2-based Fenton processes toward resource recovery and water purification.

Two-way role of iron-carbon in biochemical reactions: microelectrolysis and enhanced activity of aerobic granular sludge for efficient refractory wastewater treatment

Industrial wastewater contained a large amount of refractory organics, and single treatment processes had limitations. This study investigated the mechanism of refractory organics removal using iron-carbon built-in coupled activated sludge (ICAS) and explored the role and function of iron-carbon (IC) within the ICAS system. The aerobic granular sludge (AGS) cultivated with IC exhibited a loose surface and a tight interior structure. Iron in the AGS concentrated near the outer layer to form a crust, which protected the inner microorganisms. IC promoted EPS secretion and regulated the abundance of positive and negative signaling molecules to maintain AGS stability. Experiments using quinoline as a model refractory organic showed that both physical adsorption by IC and biological adsorption by sludge rapidly fixed a large amount of pollutants, providing a buffer capacity for the system. The iron mineral crust on the AGS surface enhanced quinoline adsorption. Hydroxylation was the first step in quinoline degradation, with IC upregulating the genes iorA/B, qorB, and wrbA involved in this process, and the relative abundances of quinoline-degrading bacteria. Both pyridine ring opening and benzene ring cleavage occurred in the single IC system, and the microelectrolysis process produced •OH and [H], which made degradation pathway for quinoline through IC more complex than microbial degradation. Although the IC-mediated pathway accounted for only a small part of overall quinoline removal in the ICAS system, the ICAS system not only preserved the microelectrolysis process but also enhanced microbial metabolic activity. This work provided insights into the synergistic removal of pollutants and maintenance of AGS stability by the ICAS process, ensuring efficient treatment of refractory organic wastewater.

SnO2-x/CD-MOF S-Scheme heterostructure photocatalysts synergized by oxygen vacancies and highly porous for rhodamine B and tetracycline degradation: Process, and mechanism analysis

To enhance the performance of environmentally friendly cyclodextrin metal-organic framework (CD-MOF) materials for more effective removal of organic pollutants and wastewater treatment, also the composites underwent optimization, and the adsorption-enhanced photocatalytic mechanism was thoroughly investigated. This study presents the synthesis of novel SnO2-x/CD-MOF (SCM) photocatalysts were prepared by a simple solvothermal method, which were characterized by oxygen vacancies (OVs), high specific surface area and heterojunction. SCM exhibited outstanding photodegradation performance for rhodamine B (RhB) and tetracycline (TC) when exposed to visible light. Specifically, the RhB removal efficiency was an impressive 93.5 %, achieved with a degradation rate constant of 0.0484 min−1, while the removal efficiency of TC was 83.1 %, with a degradation rate constant of 0.0246 min−1. The photodegradation activity of SCM was predominantly influenced by ·O2-, h+, and ·OH. The mechanism of action involves three phases: adsorption, photocatalysis, and desorption-diffusion. The exceptional performance of SCM in terms of photocatalysis can be gave the credit to the synergistic effect of the high specific surface area of γ-CD-MOF and the oxygen vacancy-induced enhancement of SnO2-x catalytic activity. TC degradation intermediates and possible degradation pathways were analyzed and the toxicity of the intermediates was assessed. This study introduces a novel approach to designing CD-MOF-based photocatalysts.

Porous polylactide membranes with high piezo-catalytic efficiency for organic wastewater treatment

Piezo-catalysis has been emerged as a green and promising wastewater treatment technology for efficient removal of persistent organic pollutants (POPs), such as 4-nitrophenol (4-NP). However, it remains challenging to achieve advanced materials with combined advantages of high piezo-catalytic efficiency, good hydrophilicity, and environmental friendliness. In this work, highly crystalline porous polylactide (PLA) membranes possessing such exceptional advantages have been successfully prepared from biodegradable poly(L-lactide)/poly(D-lactide)/polyethylene glycol/polyoxyethylene-polyoxypropylene block copolymer (PLLA/PDLA/PEG/PEO-PPO-PEO) blends by melt processing and subsequent water etching. During the melt-processing, the two PLA enantiomers co-crystallize into stereocomplex (SC) crystals and simultaneously the PEG used as a porogen is expelled from the crystalline regions. The results show that the prepared PLA membranes have not only abundant micro-porous structures but also good hydrophilicity due to the preferential localization of PEO-PPO-PEO copolymer on the pore walls, thus giving rise to an extremely high water flux of 2400 L/m2h. More interestingly, the PLA membranes exhibit remarkable piezoelectric activity and the piezo-catalytic degradation efficiency of 4-NP can reach as high as 96 % under the triggering of water flow involved in vacuum filtration. In addition, the membranes show excellent reusability and the high catalytic efficiency can be well-maintained after five repeated uses. These findings suggest broad application prospects of our porous SC-PLA membranes in organic wastewater treatment.

High-permeance nanocellulose/ZnO hybrid membranes with photo-induced anti-fouling performance for wastewater purification

A hybrid ultrafiltration membrane based on nanocellulose and zinc oxide nanoparticles (ZnO NPs) was prepared by simple layered filtration without any chemical modification. Microscopic morphology analysis showed that the loading ZnO NPs significantly increased the membrane roughness, and wettability test demonstrated that the membrane surface possessed underwater superoleophobicity. Due to the “puncture effect” of the embedded ZnO NPs, abundant nanochannels were formed in the nanocellulose membrane and the highest water permeance of 5439.7 L·m−2·h−1·bar−1 was achieved. The hybrid membranes exhibited high rejection of nanoparticles larger than 20 nm and macromolecules with molecular weights higher than 100 kDa. Furthermore, ZnO NPs significantly improved the wet tensile strength of membrane. The hybrid membranes achieved high separation efficiency of nano-sized emulsions via size exclusion and demulsification effect, as well as the efficient removal of organic dyes and antibiotics via filtration-adsorption. The combination of underwater superoleophobicity and photocatalytic self-cleaning performance effectively solved the problem of a sharp decrease in permeance caused by oil contamination. This type of nanocellulose/ZnO hybrid membrane, which integrates high permeance, high filtration accuracy, and photocatalytic anti-fouling performance in one design, offers an innovative approach to the preparation of nanocellulose membranes for the treatment of organic wastewater.

ZnO/carbon quantum dots nanocomposites derived from Moringa oleifera gum: An improved catalytic vitiation of methylene blue dye

The present study reports on the enhanced photocatalytic and chemocatalytic performance of ZnO/carbon dots (CDs) nanocomposites for the degradation of methylene blue (MB) dye. Carbon quantum dots were prepared by employing Moringa oleifera gum powder as a carbon source through the hydrothermal process. ZnO/CQDs nanocomposites were synthesized by dispersing ZnO nanoparticles into carbon quantum dot solution. The obtained samples were characterized by using techniques like FTIR, UV, and SEM with EDX analysis. When the methylene blue (MB) dye was exposed to visible light at room temperature, the ZnO/CQDs nanocomposites photocatalyst exhibited more photocatalytic and chemocatalytic activity than the pure ZnO nanoparticle photocatalyst. Antibacterial activity and cytotoxic assay of ZnO/CQDs nanocomposites were also investigated. In addition to protecting the environment, the purpose of this research is to create a new visible-light photocatalyst for the effective treatment of organic wastewater.

Performance of Bioenergy Production from Durian Shell Wastes Coupled with Dye Wastewater Treatment

Adsorption using biochar is a high-efficient method for removing dyes from wastewater, and it has become a hot research topic in recent years. Biochar produced from organic wastes through pyrolysis is a promising way to combine bioenergy recovery and dye removal. In this study, durian shell (DS) was used as a feedstock for biochar and bio-oil production under different pyrolysis temperatures (400, 500, and 600 °C) for bioenergy recovery. Then, the biochar was applied as the absorbent for methylene blue (MB) removal from wastewater under batch and continuous experiments. It was found that the bio-oil production was slightly affected by temperature, while the productivity of biochar decreased from 42.05% to 30.65% with the increase in pyrolysis temperature from 400 to 600 °C. Compared with the biochar produced at 500 °C (DS-500) and 600 °C (DS-600), the biochar obtained at 400 °C (DS-400) exhibited higher MB removal efficiency and adsorption capacity under various pH conditions due to the superior microstructure. A high pH condition was beneficial for the adsorption process with DS-400. Additionally, the MB removal efficiencies increased with the increase in biochar dosage by providing more activated sites. A high MB content can promote the adsorption process, but a too high MB content negatively affects the removal efficiency due to the sorption saturation. Adsorption processes are more likely to match a pseudo-second-order model by chemical reactions. In the long-term continuous experiment, MB can be effectively removed to match the discharge standard by DS-400. This study provided a sustainable pathway for organic waste disposal and dye wastewater treatment.

Research Progress on Catalytic Ceramic Membrane Degradation of Phenol Containing Wastewater

In recent years, ceramic membrane supported catalysts for catalytic ozonation have made certain progress in the treatment of organic wastewater. This process has the advantages of simple operation, high oxidation efficiency, high catalyst utilization, ceramic membrane resistance to pollution, and no secondary pollution. However, the large-scale promotion and use of this process still rely on the development of highly active and stable heterogeneous catalysts. Therefore, it is crucial to summarize the development status of ceramic membrane supported ozone catalysts at home and abroad in recent years. This article first summarizes the recent research on catalytic membranes; Secondly, the production method of catalytic ceramic membrane is elaborated; Finally, the research significance of catalytic ceramic membranes is discussed.

The preparation and characterization of WS2 nanomaterials with different morphologies and the mechanistic study of peroxymonosulfate activation for phenol degradation

Transitional metal chalcogenides like WS2 play a significant role as cocatalysts in activating PMS (peroxymonosulfate) due to their high reductivity. Three WS2 samples with different morphologies, specific surface areas, and 1 T phase contents were prepared in this study. Characterizations by SEM, TEM, BET, XRD, Raman, XPS, and catalytic degradation experiments confirmed that the a-WS2 sample exhibited the richest morphology, the largest specific surface area, the highest 1 T phase content, and the best cocatalytic performance. The a-WS2/Fe(II)/PMS system efficiently degraded 20 mg/L phenol within 15 minutes and was also effective in degrading pollutants like RhB (Rhodamine B) and OFX (Ofloxacin). Characterization predicted the degradation pathway of phenol and revealed 10 intermediate products. The degradation mechanism indicated that the presence of WS2 accelerated the conversion of Fe(III) to Fe(II), thereby further promoting the activation of PMS. ·SO4−, ·OH, and ·O2− were identified as the main active radicals in this system. a-WS2 exhibits characteristics such as high catalytic performance, good stability, high recyclability, and a low ion leaching rate, and it generates sulfur vacancies during use. This system shows promising prospects in the treatment of high-concentration organic wastewater.