Organic Rankine Cycle System Research Articles

Energy, Exergy, and Economic Performance Comparison and Parametric Optimization of Organic Rankine Cycles Using Isobutane, Isopentane, and Their Mixtures for Waste Heat Recovery

The possibility of applying the organic Rankine cycle (ORC) to further recycle the low-grade waste heat efficiently is studied in the present work. The energy, exergy, and economic models of the ORC system are established, and the isobutane, isopentane, and their mixtures are selected as the organic working mediums (OWMs). Due to the slip characteristics of mixed OWM, four operational conditions of the ORC system are proposed, and then the contrastive analysis of energy, exergy, and economic performances under the four operational conditions are conducted. Finally, the optimal mixture mass fraction and crucial parameters of the ORC system are separately determined through the bi-objective optimization. The results show that the ORC system using the mixed OWM can achieve a larger net power output and exergy efficiency by comparing the pure OWM when the condensing temperature is set as the saturated vapor temperature during the condensation process. The electricity production cost first rises and then decreases with the rising mass fraction of isobutane in mixed OWM, and the ORC system using the isopentane can achieve the smallest electricity production cost. By taking the low-grade flue gas of 433.15 K as the ORC heat source, four operational conditions have the same optimal ORC crucial parameters, namely the evaporating temperature of 393.15 K, condensing temperature of 308.15 K, and superheat degree of 0 K. The pure OWM of isobutane can achieve better overall performance by setting the condensing temperature as the saturated liquid temperature.

Reverse design of molecule‐process‐process networks: A case study from HEN‐ORC system

AbstractThe integrated design of the heat exchanger network (HEN) and organic Rankine cycle (ORC) system with new working fluids is a complex optimization problem. It involves navigating a vast design space across working fluid molecules, ORC processes, and networks. In this article, a new two‐stage reverse strategy is developed. The optimal HEN‐ORC configurations and operating conditions, and the thermodynamic properties of the hypothetical working fluid are identified by an equation of state (EOS) free HEN‐ORC model in the first stage. With two developed group contribution‐artificial neural network thermodynamic property prediction models, working fluid molecules are screened out in the second stage from a database containing more than 430,000 hydrofluoroolefins (HFOs). The presented method is employed in two cases, where new working fluids are found. The total annual cost of Case 1 is 12%–22% lower than the literature, and the power output of Case 2 is 5%–8% higher than the literature.

Waste Heat Utilization in Marine Energy Systems for Enhanced Efficiency

The maritime industry, central to global trade, faces critical challenges related to energy efficiency and environmental sustainability due to significant energy loss from waste heat in marine engines. This review investigates the potential of waste heat recovery (WHR) technologies to enhance operational efficiency and reduce emissions in marine systems. By analyzing major WHR methods, such as heat exchangers, Organic Rankine Cycle (ORC) systems, thermoelectric generators, and combined heat and power (CHP) systems, this work highlights the specific advantages, limitations, and practical considerations of each approach. Unique to this review is an examination of WHR performance in confined marine spaces and compatibility with existing ship components, providing essential insights for practical implementation. Findings emphasize WHR as a viable strategy to reduce fuel consumption and meet environmental regulations, contributing to a more sustainable maritime industry.

Exergetic analysis and multiparametric optimization of a novel three‐fluid‐based organic Rankine cycle evaporative system via Taguchi method

AbstractEvaluations were conducted on the thermal performance of an organic Rankine cycle (ORC) system using three fluids as the evaporative system at a low‐grade heat source. The modified ORC evaporators were replaced with a three‐fluid system, which included hot fluids at the top and bottom and an isopentane working fluid in the middle section. Furthermore, the thermal performance assessment with a hot fluid heat transfer ratio in the outer and inner tubes (Q2/Q1) varying from 25:75 to 75:25 has been investigated. The impact of the hot fluid's (Q2/Q1) heat transfer ratios to saturated steam on the modified ORC's thermal performance assessment was examined, with an evaporative temperature range of 45–65°C and a pinch point temperature difference (PPTD) of 3–10°C. The Taguchi technique solves multiparameter optimization using the L9 orthogonal array. The findings showed that in three‐fluid‐based modified ORC systems, the network output, exergetic efficiency, and irreversibility went down with PPTD for all three Q2/Q1 cases. For Q2/Q1 of 75:25, the ORC's energetic efficiency and overall irreversibility reached their optimum, while a PPTD of 3–10°C reduced the exergetic efficiency by 19.71%. Also, Q2/Q1 of 75:25 showed the highest and 200% higher ORC system work done at PPTD of 3°C than Q2/Q1 of 25:75—the lowest. Modified ORC network generation, energy output, and heat transfer rate showed excellent results at an evaporative temperature of 58.33°C. For optimal network productivity, Q2/Q1 of 75:25 was 160% and 40% greater than 50:50 and 25:75 at 58.33°C, respectively. The three‐fluid‐based modified ORC system performs better with a 75:25 Q2/Q1 ratio. According to Taguchi's analysis, evaporation temperature affects the improved ORC system's thermal, exergy, and network generation. Also, heat transfer ratios (F = Q2/Q1) largely affect system irreversibility.

Comprehensive methodology for the integrating of the organic rankine Cycle-ORC with diesel generators in off-grid areas: Application to a Colombian case study

Efficient fuel management in diesel generator sets for power generation in non-grid areas is a persistent concern. In this context, the use of an Organic Rankine Cycle (ORC) to recover heat from exhaust gases from diesel generator sets represents a promising route for additional power generation. To undertake such projects, it is necessary to understand the critical parameters related to diesel engines, including the specific fuel consumption, mass flow, and exhaust gas temperature. These parameters are fundamental to the sizing process of the ORC heat recovery system. This study introduces an innovative methodology for evaluating the operation of diesel-ORC systems based on the load demand of off-grid communities. The proposed system is a viable solution for the generation of additional power with the objective of improving the overall efficiency and meeting higher energy demands in isolated areas. Four organic fluids were selected for the ORC: R245fa, benzene, cyclopentane, and toluene. This selection was made based on many criteria, including global warming potential (GWP), ozone depletion potential (ODP), and safety classification (ASHRAE 34). In addition, the exergy behaviors of these fluids were reviewed. A comparative analysis was subsequently conducted for a non-interconnected region of Colombia to evaluate the performance of a diesel generator operating independently and in conjunction with the diesel ORC system. The key indicators employed were fuel consumption savings (L/year), energy produced (MWh/year), levelized cost of energy (LCOE, USD/kWh), and payback period (years). The results demonstrated that, over the course of a 1-year simulation period, the benzene ORC system exhibited the highest overall energy efficiency, achieving a value of 41.38%. The exergy analysis indicated that toluene had lower irreversibilities, achieving an exergy efficiency of 44.78%, followed by benzene (43.5%. Furthermore, the diesel-ORC system using benzene demonstrated a notable decrease in the specific fuel consumption from 0.282 to 0.247 L/kWh, signifying a 10.52% reduction in the annual CO2eq emissions. The cost of electricity generation decreased by 4.3%, with investment payback periods not exceeding 14 years.

Performance and economic analysis of various geothermal power plant systems: Case study for the Chingshui geothermal field in Taiwan

Geothermal power plants are a source of sustainable energy. However, their performance is influenced by various factors, including production temperature and well locations, and few studies have investigated the relationships between these factors. To address this research gap, the present study developed integrated models of a geothermal reservoir and a variety of power plant systems. By using COMSOL and MATLAB, we conducted simulations for the Chingshui geothermal field in Taiwan to investigate the performance and economic feasibility of five common types of geothermal power plant systems over their operational lifetime under different well configurations. The key findings of this investigation are as follows. First, the locations of production wells are a primary factor influencing production temperature. Constructing wells in low-permeability zones results in considerable increases in the pressure differential in the injection pump; thus, wells should not be constructed in such zones. Second, as system flow rate and well depth decrease, production temperature remains relatively stable, net power output decreases, and system efficiency increases. This efficiency increase is caused by decreases in pumping power requirements at lower flow rates and shallower well depths. Finally, among the investigated systems, the organic Rankine cycle system had the lowest electricity production cost and shortest payback period within the enthalpy range of 500–1000 kJ/kg. Double-flash (DF) and DF–binary systems are also viable options when the mass flow rate is 10–20 kg/s and the enthalpy is 700–800 kJ/kg. Overall, the results of this study offer valuable insights for the design of geothermal power plants, thereby contributing to the optimization of renewable energy systems.

Molecular simulations of increased thermal energy storage in metal–organic heat carriers with R1234ze(E)/R32 mixtures combined with IRMOF-1

Metal-organic heat carrier (MOHC) nanofluids offer a promising solution to enhance the efficiency of Organic Rankine Cycle systems. In this study, we developed a computational model to assess the thermal energy storage capacity of MOHC nanofluids using a base fluid mixture of R1234ze(E) and R32 refrigerants. Through Grand Canonical Monte Carlo and molecular dynamics simulations, we examined the adsorption characteristics, desorption heat, and thermodynamic properties of MOHCs. Our findings reveal that R32 molecules are preferentially adsorbed in IRMOF-1 compared to R1234ze(E), with adsorption selectivity of R32 over R1234ze(E) increasing under higher adsorption pressures. When the temperature during the endothermic process surpasses the phase transition point of the base fluid, the latent heat of phase transition can be fully exploited to enhance energy storage. Moreover, the inclusion of IRMOF-1 nanoparticles significantly improves the energy storage properties of both R32 and R1234ze(E), as well as their mixtures. The energy storage enhancement provided by IRMOF-1 is particularly pronounced under high working pressures and low temperature differences. These insights offer valuable guidance for selecting appropriate base fluids in MOHC systems, thereby optimizing the utilization of low-grade energy sources.

Optimization of Organic Rankine Cycle for Hot Dry Rock Power System: A Stackelberg Game Approach

Due to its simple structure and stable operation, the Organic Rankine Cycle (ORC) has gained significant attention as a primary solution for low-grade thermal power generation. However, the economic challenges associated with development difficulties in hot dry rock (HDR) geothermal power systems have necessitated a better balance between performance and cost effectiveness within ORC systems. This paper establishes a game pattern of the Organic Rankine Cycle with performance as the master layer and economy as the slave layer, based on the Stackelberg game theory. The optimal working fluid for the ORC is identified as R600. At the R600 mass flow rate of 50 kg/s, the net system cycle work is 4186 kW, the generation efficiency is 14.52%, and the levelized cost of energy is 0.0176 USD/kWh. The research establishes an optimization method for the Organic Rankine Cycle based on the Stackelberg game framework, where the network of the system is the primary optimization objective, and the heat transfer areas of the evaporator and condenser serve as the secondary optimization objective. An iterative solving method is utilized to achieve equilibrium between the performance and economy of the ORC system. The proposed method is validated through a case study utilizing hot dry rock data from Qinghai Gonghe, allowing for a thorough analysis of the working fluid and system parameters. The findings indicate that the proposed approach effectively balances ORC performance with economic considerations, thereby enhancing the overall revenue of the HDR power system.

Electrical performance of radial turbine driven by low temperature heat source: numerical investigation

High-performance Organic Rankine Cycle (ORC) systems are extensively utilized across various industrial sectors. In some applications, radial flow turbines are crucial for low-temperature heat sources. This study aims to enhance the energy and electrical efficiency of small radial turbines in Organic Rankine Cycle (ORC) ORC systems using n-pentane as the working fluid through numerical analysis. Micro-turbines are proposed to maximize performance for ORC applications. To assess the electrical, hydrodynamic and thermodynamic performance, 3D RANS simulations are conducted for five different mass flow rates with an inlet temperature of 450 K. The findings underscore the potential of radial turbines in ORC systems for utilizing low-temperature heat sources effectively. The results conducted on the entropy resulting from the irreversibility of heat transport and the irreversibility of friction. The following ranges contain the significant parameters for which this work has been completed: mass flow rates (0.1–0.5 kg.s-1), 450 k at the inflow.

An Experimental Study of an Autonomous Heat Removal System Based on an Organic Rankine Cycle for an Advanced Nuclear Power Plant

The present study focuses on the recovery of waste heat in an autonomous safety system designed for advanced nuclear reactors. The system primarily relies on passive safety condensers, which are increasingly integrated into the design of advanced Pressurized Water Reactors (PWRs). These condensers are typically immersed in large water tanks that serve as heat sinks and are placed at sufficient heights to ensure natural circulation. Such a heat removal system can operate for an extended period, depending on the size of the tank. This research is driven by the potential to recover part of the energy stored in the boiling water volume, using it as a heat source for an Organic Rankine Cycle (ORC) system via an immersed heat exchanger. The electricity generated by the ORC engine can be used to power the system components, thereby making it self-sufficient. In particular, a pump replenishes the water tank, ensuring core cooling for a duration no longer limited by the water volume in the tank. An experimental test setup, including a boiling water pool and an ORC engine with an electrical output of approximately several hundred watts, along with an immersed evaporator, was constructed at CEA (Grenoble, France). Several test campaigns were conducted on the experimental test bench, exploring different configurations: two distinct ORC working fluids, cold source temperature variation effects, and relative positioning of the submerged evaporator and heat source within the water tank impact. These tests demonstrated the reliability of the system. The results were also used to validate both the ORC condenser and evaporator models. This article presents this innovative system, which has recently been patented. Moreover, to the best of our knowledge, the investigated configuration of an ORC that includes an immersed evaporator is original.

Thermo-economic investigation and comparative multi-objective optimization of dual-pressure evaporation ORC using binary zeotropic mixtures as working fluids for geothermal energy application

This contribution performs an energy, exergy, and exergoeconomic (3E) analysis of a dual-pressure evaporation organic Rankine cycle system employing twenty different binary zeotropic mixtures as working fluids for power production from a geothermal field. To this end, the designed system is modeled, invoking the mass and energy conservation laws and the exergy and cost balance analyses. Specific Exergy Costing (SPECO) procedure is utilized to provide practical insights into the exergoeconomic aspect of the system. Comparative optimization based on the multi-objective genetic algorithm is accomplished for each mixture in order to simultaneously maximize the exergy efficiency and minimize the total cost rate using the design variables of pressure factor in low-pressure and high-pressure stages, mixture fraction, pinch point temperature differences in low-pressure and high-pressure heat exchangers, and degree of superheat in the high-pressure heat exchanger. In this regard, the Pareto frontiers are drawn for the system with all twenty different binary zeotropic mixtures. The optimal point for each mixture is obtained via the decision-making technique of LINMAP. Subsequently, the LINMAP is re-utilized to find the preferred mixture. The optimization results suggest the R123/C2Butene (96.89/3.11) mixture for this system as the optimum working fluid, considering a trade-off between a low-cost rate of $88.0651 per hr and a high exergy efficiency of 64.07 %. Finally, the exergy flow diagram is plotted to provide the exergy flow rate and the amount of exergy destruction in each segment of the system considering the optimal working fluid. In the proposed system, exergy destruction chiefly occurs within the low-pressure preheater with a value of 1061 kW, followed by the low-pressure turbine and condenser with magnitudes of about 669 kW and 266 kW, respectively.

Organic Rankine Cycle System Design by Utilizing The Waste Heat of Internal Combustion Engine Based on Numerical Simulation

Abstract Most of the energy supply for today’s human activities still comes from fossil energy. Energy based on fossil fuels can cause an increase in greenhouse gas (GHG) emissions. Therefore, increasing the efficiency of energy conversion systems based on fossil fuels is necessary to mitigate pollutant emissions. The internal combustion engine (ICE) is one energy conversion machine that still consumes fossil energy to work in the transportation sector. Losses during internal combustion engine operation result in reduced engine thermal efficiency. Exhaust gas heat loss is one of the relatively significant losses. It leads to the waste of heat, which could be utilized and converted into valuable energy in the form of electrical energy that the engine can use, resulting in a considerable amount of primary fuel that could be saved. An organic Rankine cycle (ORC) system is considered in this analysis as a heat recovery unit from the Diesel ICE. The Aspen Plus simulation software was chosen to design the system consisting of an ORC unit integrated with a Diesel ICE unit. The working fluid for ORC used in this analysis is R-141B, R-123, and R-245fa. The simulation results show that the heat the ORC unit receives from the ICE via turbocharger is around 366 °C. Thus, the system has a thermal efficiency of 11.11% when using R-141B as the working fluid, 8.41% if R-123 as the working fluid, and 6.63% when using R-245fa as the working fluid. This study also obtained a condenser design as part of the ORC unit. The condenser can be considered a plate heat exchanger, with 53 plates needed to support the process.

Sustainable reuse of oil and gas wells for geothermal energy production: Numerical analysis of deep closed loop solutions in Italy

This study assesses the feasibility of repurposing abandoned oil and gas wells in Italy for geothermal energy production employing a geothermal closed-loop system. A systematic methodology was developed, beginning with raw data collection and progressing to numerical simulations using COMSOL Multiphysics to model a U-shaped deep closed-loop geothermal heat exchanger. The analysis relied on a public database of wells drilled in Italy since the mid-20th century. The Horner plot correction method was applied to measured temperature data to obtain accurate geothermal gradients across Italy, which were then used as input parameters for a numerical sensitivity analysis. The results highlight the critical role of the geothermal gradient and heat carrier fluid flow rate in determining system performance. Regions in Italy with geothermal gradients exceeding 40 °C/km, particularly in the Tyrrhenian area, were identified as having high potential for this technology. A preliminary analysis of a virtual Organic Rankine Cycle (ORC) system estimated power production of 73 kW, with an efficiency of 11.66 % after 25 years of operation under optimal conditions (5 l/s flow rate, 60 °C/km geothermal gradient, and 70 °C evaporation temperature).

Thermodynamic Performance Characterization of a Small-Scale Organic Rankine Cycle with 5 kW Net Power Output

Abstract Indonesia’s current energy landscape predominantly depends on fossil fuels and non-renewable energy sources, thereby exacerbating the issue of global warming. On the other side, geothermal utilization in the country still needs to be expanded to reduce the dependency on fossil fuels, particularly through organic Rankine cycle (ORC) systems. As an example, Ulumbu Geothermal Power Plant in Flores Island currently uses a back pressure turbine, which releases expanded steam directly into the atmosphere at 98.7°C and 0.98 bar. This paper presents a thermodynamic analysis of a small-scale Organic Rankine Cycle with 5kW Net power output based on the waste heat data of the Ulumbu Geothermal Power Plant. The study includes selecting the working fluid based on Ozone Depletion Potential (ODP) and Global Warming Potential (GWP) values, thermal efficiency, refrigerant, and steam mass flow rate calculation. Among 20 refrigerants available in Indonesia, R245fa shows promise, offering a Rankine system efficiency of 10-11%, zero ODP, a GWP of 850, and the lowest refrigerant mass flow rate. These parameters inform useful initial parameters for designing a small-scale ORC system producing 5 kW of net power, promoting cleaner and sustainable energy solutions for communities.

Effect of superheat degree on the performance of an organic Rankine cycle system that utilizes a wet working fluid

AbstractLimited experimental research has been conducted on organic Rankine cycle (ORC) systems that use wet working fluids. Therefore, the present study examined how the performance of an ORC system that uses a wet working fluid (R134a) was affected by the superheat degree ratio (SDR) under various scroll rotation speeds. The SDR is the dimensionless ratio between superheat degree and evaporation temperature at a given heat source temperature. Experimental results indicated that at scroll rotation speeds of 900, 1350, and 1800 rpm, the maximum output power of the aforementioned system was 1103, 1464, and 1537 W, respectively, with SDRs of 0.49, 0.49, and 0.54, respectively. The maximum net efficiencies at these speeds were 5.87%, 5.91%, and 5.32%, respectively, which occurred at SDRs of 0.61, 0.49, and 0.48, respectively. This level of system performance was attributable to the high enthalpy at the expander inlet and the high mass flow rate at the high evaporation pressure under an SDR of approximately 0.5. Although increasing the SDR did not enhance the scroll expander's isentropic efficiency, this efficiency decreased considerably when the SDR fell below 0.2. These findings emphasize the importance of optimizing the SDR of ORC systems to improve their performance.

Zeotropic mixture as a working fluid for cascade Rankine cycle-based reverse osmosis: Energy, exergy, and economic analysis

This study investigates the cascade Rankine cycle coupled with a reverse osmosis system for brackish groundwater treatment. The proposed system integrates a steam Rankine cycle (SRC) and an organic Rankine cycle (ORC) in a looped configuration, utilizing solar energy as a heat source. Each Rankine cycle is coupled with reverse osmosis (RO) to produce approximately 1 m3/h of permeate from each RO system. The system is investigated with working fluid combinations from R1233zd(E), R1234ze(Z), and R1336mzz(Z). Through comprehensive energy, exergy, and economic analyses, the system's performance is evaluated with zeotropic mixtures compared to pure R1233zd(E). The results demonstrate reliable performance with zeotropic mixtures, particularly R1233zd(E)/R1234ze(Z) with a mass composition of 0.6/0.4, demonstrating the maximum ORC expander work output of 1.15 kW. Parametric analysis reveals remarkable performance under different ORC system parameters. Variations in SRC condensation pressure show a trade-off performance between SRC and ORC turbine work output. Exergy analysis reveals an increase in exergy destruction by evaporation-based ORC components and a reduction in exergy destruction by condensation-based components, emphasizing improved irreversibility during the condensation process. Economic analysis indicates a marginal impact on the overall system cost, with the treated water cost ranging from 0.891 to 0.919 $/m3.

Dynamic performance analysis and optimization research on solar dual-stage evaporation multigeneration system

A novel solar dual-stage evaporation multigeneration system is proposed, with analysis on the impact of the parabolic trough collector area (APTC) and the volume of the heat storage tank (VHST) on performance under dynamic conditions. The particle swarm optimization- genetic algorithm and the minimum path method optimized the system’s overall performance. Results show that reducing APTC and increasing VHST can enhance energy performance within a certain range, but beyond specific thresholds, changes in APTC and VHST no longer affect it. As APTC and VHST increase, economic performance initially improves but then declines. The particle swarm optimization- genetic algorithm increased optimization efficiency and avoided local optima. When using the minimum path method, the dimensionless cumulative error was 0.63, balancing thermal and economic performance. Using toluene as the working fluid, the optimized system achieved thermal and exergy efficiencies of 56.06 % and 9.15 %, respectively, with a net present value of 58.12 M$, a payback period of 5.23 years, and an equivalent CO2 reduction of 24.8 kt, outperforming the solar organic Rankine cycle system in energy efficiency, economic performance, and carbon reduction potential. The solar dual-stage evaporation multigeneration system achieved the best performance with toluene as the working fluid, while heptane provided longer running time and greater carbon reduction potential. At low rated power generation, performance differences between toluene and heptane were minimal, while as the rated power generation increased, toluene showed significant advantages in thermal and economic performance.

General integration method for system configuration of organic Rankine cycle based on stage-wise concept

Organic Rankine Cycle (ORC) integrated systems with heat sources consist of heat exchange processes and thermodynamic power conversion processes. Fully exploring feasible system configuration while considering fluid selection is crucial for enhancing ORC power generation and balancing economic costs. This study innovatively proposes a theoretical framework that decomposes the Rankine cycle into basic thermodynamic processes. The design of system configuration is regarded as the adjustment of the series-parallel relationships of these basic processes, aiming to achieve simultaneous optimization of the cycle structure and the HEN structure, thereby greatly expanded the search space for feasible ORC system configurations. The optimization problem is solved using a bi-level strategy, The outer layer determines the number of thermal power conversion components, operating parameters, and working fluid selection, then provides the associated stream information to the inner layer for optimizing the heat exchange scheme. Applying this method to two different case studies from the literature validated its effectiveness in optimizing scenarios with single and complex heat sources. The Pareto frontier obtained under the conditions of Case I indicates that the investment cost can be reduced by $33.04 k/yr while maintaining the same net power output. In exchange for an increase of $1.51 k/yr in investment cost, the maximum net power output can be improved by 124.74 kW. Under the conditions of Case II, the maximum net output power can increase by 9.71 %–52.5 %, and the Pareto frontier featuring outputs exceeding 50 kW is provided. By analyzing the relative positions of literature schemes and Pareto front within the solution space, the impact of system configuration improvements on the objective functions is explained. These results confirm the effectiveness of the proposed approach for designing optimal ORC energy recovery systems for heat sources. This contribution advances optimization methods for similar closed cycle configurations, which is significant for advancing the utilization of waste heat and addressing sustainability challenges.

Thermodynamic analysis of a cascade organic Rankine cycle power generation system driven by hybrid geothermal energy and liquefied natural gas

The combination of renewable energy and liquefied natural gas (LNG) cold energy can effectively improve energy utilization efficiency and achieve the goal of energy conservation and emission reduction, which is one of the important directions of future development. This work proposed a cascade organic Rankine cycle (ORC) driven by a geothermal heat source and an LNG heat sink. Seven organic fluids are chosen as candidates to form different working fluid pairs. The effects of the main design parameters on system performance are carried out through the thermodynamic analysis. Then, the optimal design conditions and fluid selection schemes are searched based on the single-objective optimization results. Finally, the exergy destruction study is conducted under the optimal design conditions and working fluid pair. Results showed that the cascade ORC system using the working fluid pair of R601/R290 had the highest exergy efficiency, which could reach 20.02%. At the same time, under the optimal design conditions, the secondary cycle condenser and LNG direct expansion brought high exergy destruction, which was respectively 29.3% and 25.8%, and followed by the two turbines in the cascade ORC system, which were 16.1%, 11.2% and 7.7%.

Thermal stability of MDM and oxidative decomposition mechanism under the condition of air infiltration: A combined experimental, ReaxFF-MD and DFT study

When siloxanes are used as the working fluids of organic Rankine cycle systems, there is a possibility of air infiltration due to the large vacuum present in the condenser. To address this issue, experimental and simulation studies were conducted on the thermal stability and pyrolysis product characteristics of octamethyltrisiloxane (MDM) in the presence of air. The results indicated that air significantly promotes the decomposition of MDM at the temperatures above 250 °C. Air was helpful in increasing the formation of CH2O, CO, and CO2, and also enhanced polymerization of decomposition product of siloxane, leading to higher yields of MD2M, MD3M, MD4M, D3, D4, and D5. By combining reactive force field molecular dynamics (ReaxFF-MD) simulations with density functional theory (DFT) calculations, the microscopic mechanisms of MDM's oxidative decomposition by O2 in air and H2O under humid conditions were elucidated. O2 can easily combine with unsaturated Si atoms to form Si-O bonds, combine with CH3 radicals to form C-O bonds, and undergoes hydrogen extraction reactions to initiate decomposition. H2O mainly undergoes initial decomposition through CH3 radical hydrogenation and binding with unsaturated Si atoms. The generated O2H, O, and OH radicals tend to bind with Si atoms in molecules and radicals, facilitating polymerization reactions.