Organic Matter Content Research Articles

Practical applications of spent mushroom compost in cultivation and disease control of selected vegetables species

AbstractMushroom cultivation is an important branch of the agricultural industry, and global mushrooms production has increased more than sixfold in the last decade. This industry uses large amounts of agricultural, forestry, livestock, and industrial wastes and their by-products. However, it also generates millions of tons of spent mushroom compost (SMC) (approximately 100 million tons per year) which has emerged as a significant issue that hinders the growth of the mushroom business and impacts the environment. Many crop diseases, which cause significant economic losses, are introduced by soil-borne plant pathogens. Spreading spent mushroom compost (SMC) to agricultural soils is a natural way to control plant diseases. Using organic waste material instead of chemicals, which is the most widely used method in agriculture today, is also a more environmentally responsible option. The generated SMC can potentially be used as a soil conditioner, an organic fertilizer, and suitable medium for growing various vegetable crops. The application of SMC has been found to be beneficial in the control of crop diseases by inducing microbiostasis, direct toxicity, or by inducing systemic resistance of the host plant. In the current review, the practical application of SMC in the cultivation of tomato, pepper, lettuce, cucumber, and eggplant was addressed. The application of SMC as a soil amendment showed a significant improvement in soil properties, including soil NPK, organic matter content, and soil beneficial microorganisms. Our review indicated that SMC could be used as a low-cost, alternative growing medium in vegetable production or as a soil amendment to add nutrients and restore soil fertility in agricultural lands. The SMC may be able to replace peat, a non-renewable natural resource, and thereby mitigating the adverse effects of excessive peat extraction in wetlands, bogs, marshes, and peatlands. This review uses unique data on the effective use of SMC in agricultural disease management, reducing the need for chemical pesticides that have adverse effects on both the environment and human health. It also provides a safe method for reusing, recycling, and integrating SMC into a circular economy that reduces its negative environmental effects and carbon footprint impacts. This work also offers a novel application of SMC as a low-cost substitute for peat or other growing media that pose environmental risks. Graphical abstract

Optimization Study of Soil Organic Matter Mapping Model in Complex Terrain Areas: A Case Study of Mingguang City, China

Traditional soil organic matter mapping is mostly polygonal drawing, which is even more difficult to accurately depict in complex terrain areas. The spatial distribution of soil organic matter is closely related to agricultural production, natural resources, environmental governance, and socio-economic development. Efficiently, economically, and accurately obtaining information on changes in soil organic matter in areas with diverse topography is an urgent problem to be solved. Mingguang City has a high research value because of its unique topography and natural landscape. To solve the problem of soil organic matter mapping in this area, this study will construct an excellent organic matter prediction model. Using 173 soil survey samples (123 for training and 50 for testing), the optimal feature variable subsets selected from 31 environmental variables through Pearson correlation, stepwise regression-variance inflation factor, and recursive feature elimination models based on different algorithms were employed. Each selected feature subset was then used to construct organic matter prediction models using multiple advanced machine learning algorithms. By comparing accuracy validation and model performance, the organic matter prediction model suitable for Mingguang City (RFE-RF_SVM) was obtained, that is, the prediction model of organic matter based on support vector machines with the feature variables screened by the feature recursive elimination algorithm of random forest with RMSE = 3.504, VSI = 0.036, and R-squared = 0.730. Furthermore, the analysis focused on assessing the significance of the predictive factors. The mapping results of this study show that the soil organic matter content in the central and northwestern parts of the study area is low, and the reasons for this situation are different. The central part is mainly caused by the change of land use and topography, while the northwestern part is caused by the loose soil structure caused by the parent material. The government can take targeted measures to improve the soil in the areas with poor organic matter.

Application of Panchagavya, a Cow-based Liquid Formulation, as a Lever for Sustainable and Enhanced Vegetable Crop Production: A Review

Panchagavya, a fermented liquid bio-formulation derived from cow-based products such as dung, urine, milk, curd and ghee, has recently gained importance in agricultural practices due to its reported effectiveness in enhancing vegetable crop production. Its formulation involves a fermentation process that harnesses the diverse microbial communities present in cow-derived substances, resulting in a potent nutrient-rich solution that is believed to possess plant growth-promoting properties. One of the primary mechanisms underlying its efficacy lies in the diverse array of microorganisms present in the formulation. These microorganisms, including beneficial bacteria, fungi and actinomycetes, play crucial roles in nutrient cycling, disease suppression and soil conditioning. Additionally, Panchagavya contains plant growth-promoting substances such as hormones, enzymes, vitamins and amino acids, which contribute to enhanced nutrient uptake, root development and overall plant vigour. Furthermore, application of Panchagavya has been shown to improve soil health by enhancing microbial activity, increasing organic matter content and improving soil properties. These soil improvements not only benefit the current crop but also have long-term positive implications for soil fertility and sustainability. This multifaceted approach to crop management offers a holistic solution to enhance crop productivity while reducing reliance on synthetic inputs. This review aims to comprehensively analyse the literature on the effects of Panchagavya on vegetable crops, highlighting its mechanisms of action and potential benefits for increased vegetable crop production.

Ecological Studies on the Soil and Vegetation of Krusadi Group of Islands in the Gulf of Manaar

The account presents the plant ecology with a description of soils and other related features of the Krusadi group of islands situated in the Gulf of Manaar approximately between 9°14'-9°15'N and 79°10.5'-79°14.5' E. Data on pH, organic matter contents, total soluble salts, sodium chloride contents and calcium carbonate contents in the soils of different habitats are presented in tabular form and an attempt made to correlate vegetation with the soil features. A classification of vegetation situations rather than strictly vegetation type has been brought out and comparison made with the main neighbouring island of Rameswaram with similar climate. The paper includes a vegetation map of the area prepared during the field work.

Biofertilization with Liquid Vermicompost-Activated Biochar Enhances Microbial Activity and Soil Properties

Biochar (Bc) and liquid vermicompost extracts (LVEs) are increasingly being used as biofertilizers in agriculture to promote soil-microbe-crop interactions. However, although both these products can potentially act synergistically due to their complementary characteristics, their co-application in different soils has not yet been investigated. Therefore, firstly, an LVE-activated biochar (BLVE) was experimentally formulated and the persistence of LVE bacteria over a 60-day storage period was determined. The total number of LVE bacteria increased by 10-fold after 7 days and was stable throughout the entire biochar storage period. In addition, changes in the composition of the bacterial community were observed after 30 days of storage, indicating that taxa less represented in pure LVE may be advantaged upon biochar colonization. Secondly, a microcosm experiment was performed to evaluate whether the biological fertility and enzyme activities of two soils, differing in organic matter content, could be enhanced by the addition of LVE-activated biochar. In this experiment, three different doses of Bc, LVE, and BLVE against the carbon-related biological fertility index (i.e., biological fertility index, BFI) and three enzyme activities over a 21-day incubation period were tested. The BLVE treatment yielded the best results (i.e., BFI +32%, enzyme activities +38%). This indicates that Bc and LVEs can act synergistically to promote soil fertility, quality, and microbial activity. By integrating LVE-activated biochar into their soil management practices, farmers could achieve higher crop yields and healthier products.

The Impact of 9 Years of Swine Wastewater Application on the Mineral and Organic Quality of Soil in Various Agricultural Crops

This study evaluates the long-term effects of swine wastewater (SWW) on relevant parameters for soil fertility, including calcium (Ca), magnesium (Mg), potassium (K) cations, cation exchange capacity (CEC), and organic matter (OM) in an agricultural area with 9 years of crop cultivation. Three types of SWW (raw, after leaving the biodigester, and after the manure plant) were analyzed with four application rates of SWW (0, 100, 200, and 300 m3.ha−1), associated or not with mineral fertilization, resulting in eight treatments. The study found that the long-term use of SWW had significant effects on soil parameters. Principal component analysis (PCA) was used to summarize the data. The soil’s calcium (Ca), magnesium (Mg), and cation exchange capacity (CEC) levels were higher in soybean compared to other crops and natural soil. Similarly, the treatment with 0 m3.ha−1 of pig manure and without mineral fertilization showed higher levels of these nutrients. In contrast, potassium (K) was found in greater quantities in oats, SWW from the biodigester, higher doses of manure, and with mineral fertilization. The crops had a higher organic matter (OM) content compared to the natural soil, with corn and raw SWW showing the most significant increase.

Palm Oil Mill Effluent Disposal and Its Utilization in Agricultural Soil

In the study, soil samples were impacted with 10%, 50% and 100% (v/w) of the palm oil mill effluents. Soil physicochemical properties, soil stress marker enzymes, soil bacteria populations were studied using standard methods. Analysis of the physicochemical properties of the Palm oil mill effluent (POME) showed that POME in the presence of the reference showed the following: pH, conductivity, BOD5, TDS, TSS, TS at 5.67 ±0.014a , 610±0.023c , 4.87±0.025b, 372.1±0.015c , 539.55±0.04a, 911.6±0.032b mg/ml, respectively dissolved mineral such as Magnessium (Mg), potassium (K), calcium (Ca) and phosphate (PO3) were recorded at 9.82±0.05b , 14.52±0.05a, 13.23±0.04c and 8.69±0.01bc mg/ml respectively. Total organic carbon and organic matter contents were recorded at 81.87±0.01a and 100.7±0.02c mg/ml respectively. Organismal proliferation increase as the percentage of the POME per gram of the soil increase from 10-50% (v/w) while a downturn in the organismal counts decreases significantly at 100% (v/w). There was a noticeable decrease in the coliform counts/g of the organisms as the incubation days increases from day 0-14. Enzyme activity relatively decreases as the contaminant concentrations increases from 0-100 v/w. Lipases activity was seen relatively low in all the soil at low concentrations of the effluents (0-50 v/w). At high concentrations of the effluents, there was a significant increase in the enzyme activity. POME can be utilized as sustainable source of organic agro fertilizer when quantified; however poor incentive by peasant farmers may lead to abysmal utilization of the waste water and its negative impact in the soil with aftermath of low soil fertility and poor agricultural productivity.

Improving stormwater infiltration and retention in compacted urban soils at impervious/pervious surface disconnections with biochar

Urban development often results in compacted soils, impairing soil structure and reducing the infiltration and retention of stormwater runoff from impervious features. Biochar is a promising organic soil amendment to improve infiltration and retention of stormwater runoff. Soil at the disconnection between impervious and pervious surfaces represents a critical biochar application point for stormwater management from urban impervious features. This study tested the hypothesis that biochar would significantly improve water retention and transmission at four sites, where varying percentages (0%, 2%, and 4% w/w) of biochar were amended to soils between impervious pavement, and pervious grassed slopes. Field-saturated hydraulic conductivity (Ksat) and easily drainable water storage capacity were monitored at these sites for five months (two sites) and 15 months (two sites). At the end of the monitoring periods, the physical, chemical, and biological properties of each site's soil were assessed to understand the impact of biochar on soil aggregation, which is critical for improved soil structure and water infiltration. Results indicated that the field Ksat, drainable water storage capacity, and plant available water content (AWC) were 7.1 ± 3.6 SE, 2.0 ± 0.3 SE, and 2.1 ± 0.3 SE times higher in soils amended with 4% biochar, respectively, compared to the undisturbed soil. Factor analysis elucidated that biochar amendment increased the organic matter content, aggregate mean weight diameter, organo-mineral content, and fungal hyphal length while decreasing the bulk density. Across the 12 biochar/soil combinations, the multiple linear regression models derived from factor analysis described the changes in Ksat and AWC reasonably well with R2 values of 0.51 and 0.71, respectively. Using soil and biochar properties measured before biochar addition, two recent models, developed from laboratory investigations, were found helpful as screening tools to predict biochar's effect on Ksat and AWC at the four field sites. Overall, the findings illustrate that biochar amendment to compacted urban soils can significantly improve soil structure and hydraulic function at impervious/pervious surface disconnections, and screening models help to predict biochar's effectiveness in this context.

Simulation and parameter determination of the net sorption of phenanthrene by sediment particles

The distribution of polycyclic aromatic hydrocarbons (PAHs) in the ocean is affected by the sorption-desorption process of sediment particles. This process is determined by the concentration of PAHs in seawater, water temperature, and organic matter content of sediment particles. Quantitative relationships between the net sorption rates (=the difference of sorption and desorption rates) and these factors have not been established yet and used in PAH transport models. In this study, phenanthrene was chosen as the representative of PAHs. Three groups of experimental data were collected to address the dependence of the net sorption processes on the initial concentration, water temperature, and organic carbon content representing organic matter content. One-site and two-compartment mass-transfer models were tested to represent the experimental data using various parameters. The results showed that the two-compartment mass-transfer model performed better than the one-site mass-transfer model. The parameters of the two-compartment mass-transfer model include the sorption rate coefficients kafand kas (L g−1 min−1), and the desorption rate coefficients kdf and kds (min−1). The parameters at different temperatures and organic carbon contents were obtained by numerical simulations. Linear relationships were obtained between the parameters and water temperature, as well as organic carbon content. kaf, kas and kdf decreased linearly, while kds increased linearly with temperature. kaf, kas and kdf increased linearly, while kds decreased linearly with organic carbon content. The r2 values between the simulation results based on the relationships and the experimental results reached 0.96–0.99, which supports the application of the model to simulate sorption-desorption processes at different water temperatures and organic carbon contents in a realistic ocean.

Interrelationship Among Soil Parameters and their Alteration with Seasonal Changes in the Soil of Bawal Town, Haryana

Soil is the backbone of agriculture and original source of nutrient that are needed by plants and crops to grow and survival. It is governed by various factors like anthropogenic and natural factors. In this study we aim to interpret the effect of climatic changes mainly seasonal variations on the soil health of Bawal industrial area. Samples were collected at the depth of 15 cm, from three different sites in three different seasons; summer, winter and monsoon. Samples were analyzed for pH, Electrical conductivity (EC), Organic matter (OM), Available nitrogen (N), potassium (K), phosphorus (P) Magnesium (Mg) and Sodium (Na). Results revealed that the OM, K, P, and Na concentration of the soil were found to follow the order; winter>rainy>summer. In contrast to this, Soil pH and Mg content were reported their highest concentration in summer followed by winter and least in monsoon season. EC and N content were found to follow the order; rainy season > winter > summer. Statistical analysis concluded the significant variation in physiochemical parameters of soil with variation in seasons except pH and EC (in summer and winter season). Interdependency of soil parameters was interpreted using multiple linear regression and results highlight that, Soil pH and Mg content were showing a significant linear regression with R2 (0.890). Na showed a significant R2 with K (0.855), P (0.827) and OM (0.803). Nitrogen content had found to show good regression with EC and soil pH. Organic matter and Potassium were also reporting significant R2 values (0.931). Soil fertility was found to get affected by climatic change but the variations could be utilized by cultivating the suitable crops according to soil parameter contents in a particular season.

EFFECT OF PROBIOTIC TREATMENT ON THE MICROBIOLOGICAL ACTIVITY OF UKRAINIAN TYPICAL BLACK SOIL

The search for novel substances that promote the establishment of a microbial community and facilitate optimal humification processes while increasing soil organic matter content offers an opportunity for land restoration. The objective of study was to determine the abundance of ecological and trophic groups of soil microorganisms and the intensity of microbiological processes when subjected to probiotic treatment at various concentrations and doses in typical black soil. The eco-trophic groups of soil microorganisms were identified by inoculating dilutions of soil suspensions onto selective nutrient media. The direction and intensity of soil microbiological processes were assessed using the mineralization-immobilization, oligotrophy, and pedotrophy indexes. The results demonstrate that probiotics has a positive impact on the microbiological activity of the soil, leading to an increase in the number of ecological and trophic groups of soil microorganisms during both spring and autumn seasons. Notably, a significant effect on the soil microorganism conditions was observed after 30 days of probiotic treatment. Probiotics exhibit a favorable influence on microbiological processes within the soil, fostering conducive conditions for the development of soil microorganisms and the formation of humus. The most effective concentration of probiotics for promoting the functionality of microbial communities in black soils is determined to be 10%, accompanied by a dose of 100 l ha-1. Consequently, the application of probiotic treatment at a concentration of 10% and a dose of 100 l/ha-1 holds the potential to enhance the biological state of the soil, restore soil microbial diversity, and serve as an environmentally safe fertilizer.

Hyperspectral estimation model of soil organic matter content based on principal gradient grey information

PurposeIn order to explore a new estimation approach of hyperspectral estimation, this paper aims to establish a hyperspectral estimation model of soil organic matter content with the principal gradient grey information based on the grey information theory.Design/methodology/approachFirstly, the estimation factors are selected by transforming the spectral data. The eigenvalue matrix of the modelling samples is converted into grey information matrix by using the method of increasing information and taking large, and the principal gradient grey information of modelling samples is calculated by using the method of pro-information interpolation and straight-line interpolation, respectively, and the hyperspectral estimation model of soil organic matter content is established. Then, the positive and inverse grey relational degree are used to identify the principal gradient information quantity of the test samples corresponding to the known patterns, and the cubic polynomial method is used to optimize the principal gradient information quantity for improving estimation accuracy. Finally, the established model is used to estimate the soil organic matter content of Zhangqiu and Jiyang District of Jinan City, Shandong Province.FindingsThe results show that the model has the higher estimation accuracy, among the average relative error of 23 test samples is 5.7524%, and the determination coefficient is 0.9002. Compared with the commonly used methods such as multiple linear regression, support vector machine and BP neural network, the hyperspectral estimation accuracy of soil organic matter content is significantly improved. The application example shows that the estimation model proposed in this paper is feasible and effective.Practical implicationsThe estimation model in this paper not only fully excavates and utilizes the internal grey information of known samples with “insufficient and incomplete information”, but also effectively overcomes the randomness and grey uncertainty in the spectral estimation. The research results not only enrich the grey system theory and methods, but also provide a new approach for hyperspectral estimation of soil properties such as soil organic matter content, water content and so on.Originality/valueThe paper succeeds in realizing both a new hyperspectral estimation model of soil organic matter content based on the principal gradient grey information and effectively dealing with the randomness and grey uncertainty in spectral estimation.

Improving grape fruit quality through soil conditioner: Insights from RNA-seq analysis of Cabernet Sauvignon roots.

The application of fertilizers and soil quality are crucial for grape fruit quality. However, the molecular data linking different fertilizer (or soil conditioner [SC]) treatments with grape fruit quality is still lacking. In this study, we investigated three soil treatments, namely inorganic fertilizer (NPK, 343.5 kg/hm2 urea [N ≥ 46%]; 166.5 kg/hm2 P2O5 [P2O5 ≥ 64%]; 318 kg/hm2 K2O [K2O ≥ 50%]), organic fertilizer (Org, 9 t/hm2 [organic matter content ≥ 35%, N + P2O5 + K2O ≥ 13%]), and SC (SC, 3 t/hm2 [humic acid ≥ 38.5%; C, 56.1%; H, 3.7%; N, 1.5%; O, 38%; S, 0.6%]), on 4-year-old Cabernet Sauvignon grapevines. Compared with the NPK- and Org-treated groups, the SC significantly improved the levels of soluble solids, tannins, anthocyanins, and total phenols in the grape berries, which are important biochemical indicators that affect wine quality. Furthermore, we conducted RNA-seq analysis on the grapevine roots from each of the three treatments and used weighted gene co-expression network analysis to identify five hub genes that were associated with the biochemical indicators of the grape berries. Furthermore, we validated the expression levels of three hub genes (ERF, JP, and SF3B) and five selected genes related to anthocyanin biosynthesis (UFGT1, UFGT2, UFGT3, GST, and AT) by using quantitative reverse transcription-polymerase chain reaction. Compared to the NPK and Org treatment groups, the SC treatment resulted in a significant increase in the transcription levels of three hub genes as well as VvUFGT1, VvUFGT3, VvGST, and VvAT. These results suggest that the SC can improve grape fruit quality by altering gene transcription patterns in grapevine roots and further influence the biochemical indices of grape fruits, particularly anthocyanin content. This study reveals that the application of SC can serve as an important measure for enhancing vineyard SC and elevating grape quality.

Does biochar combined with cover crops improve health and productivity of sandy, sloping, and semi‐arid soils?

AbstractBiochar may improve the health of environmentally sensitive soils (i.e., low C, sandy, sloping) especially if combined with cover crops (CCs), but research is scant. We assessed how wood biochar (836 g C kg−1) applied at 0, 6.25, 12.5, 25, and 50 Mg ha−1 to sandy, sloping, and semi‐arid soils with and without CCs affects soils and crop yields in the central US Great Plains for 3 years. We measured crop yields and CC biomass each year, and most soil properties in Years 1 and 3. Biochar did not interact with CCs, suggesting the combination was no better than biochar or CC alone. In the semi‐arid soil, crop and CC did not establish due to persistent droughts. Biochar benefits were highly site‐specific. Biochar improved some soil properties but only in the sandy and sloping soils and at the biochar application depth (0‐ to 15‐cm soil depth). The 50 Mg biochar ha−1 improved the soil's ability to sorb water (0.08 cm s−1/2). Also, in the sandy soil, it increased soil organic matter concentration (2.5 g kg−1), soil pH (0.65 units), and available water (0.07 m3 m−3) only in Year 1, suggesting a biochar benefit in sandy soils is short‐lived. In the sloping soil, >25 Mg biochar ha−1 reduced bulk density (0.16 Mg m−3) and increased soil mean weight diameter of water‐stable aggregates (0.58 mm), organic matter concentration (11.42 g kg−1), infiltration (9.35 cm), CC biomass production (0.27 Mg ha−1), and some microbial biomass groups. Biochar did not affect crop yields. Overall, >25 Mg biochar ha−1 improved properties in some soils without interacting with CCs.

Characterization of Soils in Coffee Productive Areas in the Provinces of Cocle and Veraguas-Republic of Panama

The objective of the work was to characterize the properties of the soils of coffee-producing farms in the provinces of Cocle and Veraguas that allow the preparation of regionalized fertilization cards according to the edaphoclimatic characteristics of each area. Planting robusta coffee is gaining greater interest among Panamanian farmers as an alternative for soil conservation. On 16 farms in the province of Coclé and 18 in Veraguas, samples were taken (0-20 cm) to understand their properties and initiate a sustainable fertilization program that contributes to improving productivity. Digital maps were created using the Q-Gis v.3.32.1 program and regionalized fertilization cards for each zone. The soils of the province of Coclé presented a high percentage of aluminum saturation, 88% with low porosity problems, average pH of 4.9, low levels of organic matter and phosphorus (100%), and 75% low in potassium. 56% low in calcium. Imbalances were found in the Ca/Mg and Ca + Mg/K ratios, which causes nutritional problems. In Veraguas soils, 22% presented a high percentage of aluminum saturation, 67% average acid pH, 94% low organic matter and phosphorus content, 89% low in potassium, medium and high levels of magnesium and calcium. A positive and statistically significant correlation was found between % clay, organic matter, pH, and calcium. It is expected that this soil characterization and regionalized fertilization cards will contribute to improving soil properties and achieving sustainable production. Fertilization recommendation cards have been prepared for these two provinces and they take into account this entire situation and physical problems found in the soils. Much emphasis is also placed on organic fertilization of plantations as a complement to traditional fertilization, seeking more balanced nutrition.

Assessment of Effects of Amended Bioremediation of Toxic Metal-polluted Soil using Organic Composites and Bacillus sp on Plant Growth Parameters

It has become pertinent to develop improved bioremediation techniques, to avert the deleterious effects of heavy metal pollution on agricultural productivity, and safety of its produce. In this study, cow dung, poultry wastes and their composites used as organic amendments were collected and processed, while Bacillus sp used as plant growth promoting rhizosphere was isolated and identified. Then 24 kg of fertile soil was polluted by introducing 20 mL of 0.1M lead acetate solution, before bagging 5 kg of polluted soil into ten perforated nylons. Soil sample was then analyzed before and after treatment. After mixing with Bacillus sp suspension, two of the pot experiments were amended with each of 0.5 kg cow dung only, 0.5 kg poultry wastes only and 1:1 ratio of their composites. Control samples were set up without amendment, and they were bioremediated for 25 days. Following germination of sown corn seedlings, heights of their shoots and number of leaves were monitored on day 4, weeks 2, 4 and 7, before harvesting for analysis together with soil samples. Results obtained revealed that seedlings grown on treated samples as well as properties of treatment of soil were generally better than those of control samples. Highest percentage increase in organic matter content of soil was recorded in treatment with mixture of cow dung only and Bacillus sp, with 9.28% and 7.63% increase at 33.75 mg/kg and 52.55 mg/kg of lead (Pb) pollution. Seedlings grown on samples treated with poultry wastes only, recorded the highest protein content of 161.25±5.5 mg/g, 104.99±4.95 mg/g and 79.75±3.2 mg/g protein contents, at 32.75 mg/kg, 42.02 mg/kg and 52.44 mg/kg levels of Pb pollution, respectively. The amendments also reduced bioaccumulation of Pb in corn seedlings, which was in the order; stem<leaf<root. Therefore, these amendments can be exploited for improved bioremediation of heavy metals.

Evolution of black shale sedimentary environment and its impact on organic matter content and mineral composition: a case study from Wufeng-Longmaxi Formation in Southern and Eastern Sichuan Basin

Due to global geological events and differences in regional sedimentary environments, marine shale reservoirs of Wufeng-Longmaxi Formation in Eastern and Southern Sichuan Basin exhibit significant heterogeneity in organic matter content and mineral composition. In order to reveal the influence of paleoenvironment evolution on reservoir heterogeneity, key geochemical indicators of elements were used to reconstruct the sedimentary environment of marine shale in Eastern and Southern Sichuan Basin. The influence mechanism of paleoenvironment on organic matter content and mineral components was also explored. The results indicate that the Wufeng-Longmaxi Formation in the Southern and Eastern Sichuan Basin can be divided into two third-order sequences (Sq 1 and Sq 2). Each third-order sequence is divided into a transgressive system tract (TST) and a highstand system tract (HST). The average TOC content in the Eastern Sichuan Basin is the highest during the TST1 period with reaching 4.2%, while reached its maximum at 3.9% during the TST2 period in the Southern Sichuan Basin. Due to the influence of high paleo-productivity, the organic matter accumulation and quartz content in the eastern Sichuan region were higher than those in the southern Sichuan region from the TST1 to the middle TST2 period. However, the organic matter accumulation and quartz content in the late TST2 period were lower than those in the southern Sichuan region due to the dilution of terrestrial debris. During the HST2 period, due to the influence of higher paleo-productivity, clay adsorption and preservation condition, the TOC content in the eastern Sichuan region slightly increased in the early stage. At the same time, the marine shale in the southern Sichuan region has a high content of quartz minerals and a low content of clay minerals due to strong weathering intensity and input of coarse-grained debris (silt-size quartz).

Mapping soil trace metal distribution using remote sensing and multivariate analysis.

Trace metal soil contamination poses significant risks to human health and ecosystems, necessitating thorough investigation and management strategies. Researchers have increasingly utilized advanced techniques like remote sensing (RS), geographic information systems (GIS), geostatistical analysis, and multivariate analysis to address this issue. RS tools play a crucial role in collecting spectral data aiding in the analysis of trace metal distribution in soil. Spectroscopy offers an effective understanding of environmental contamination by analyzing trace metal distribution in soil. The spatial distribution of trace metals in soil has been a key focus of these studies, with factors influencing this distribution identified as soil type, pH levels, organic matter content, land use patterns, and concentrations of trace metals. While progress has been made, further research is needed to fully recognize the potential of integrated geospatial imaging spectroscopy and multivariate statistical analysis for assessing trace metal distribution in soils. Future directions include mapping multivariate results in GIS, identifying specific anthropogenic sources, analyzing temporal trends, and exploring alternative multivariate analysis tools. In conclusion, this review highlights the significance of integrated GIS and multivariate analysis in addressing trace metal contamination in soils, advocating for continued research to enhance assessment and management strategies.

Anthropogenic soil as an environmental material, as exemplified with improved growth of rice seedlings

Herein, the feasibility of artificial black soil (ABS) derived from hydrothermal humification-hydrothermal carbonization (HTH-HTC) for restructuration of weak soil was verified. This study breaks through the long history of soil formation and evolution, and obtains reconstructed anthropogenic soil (AS) system which only takes one month, for the further application of rice seedlings. HTH-HTC derived by-products are slightly acidic, which facilitates the effective nutrient uptake and prevention of wilt diseases for acid-loving rice seedlings. AS mainly consists of the inherent components retained from weak soil such as SiO2 and minerals, and exogenous components such as artificial humic substances and hydrochar, as introduced by hydrothermal humification processes. Results exhibit that AS has high contents of ammonium nitrogen, organic matter, organic carbon, and abundant porous structure for nutrient transport and water holding, especially, the community diversity and richness of microbial system gets the expected recovery and new beneficial bacteria (such as Caballeronia calidae) or fungi (such as Humicola) appear. Positive effects of AS on agronomic traits in rice seedlings are quantified. As a general result, this study supports the application of AS in sustainable agriculture, and provides a novel strategy to tackle the already-omnipresent land degradation by anthropogenic misuse and larger scale accidents.

New insights into antifouling property and interfacial mechanism in photo-Fenton membrane distillation

Membrane distillation (MD), boasting high interception efficiency and low operational pressures, emerges as an innovative membrane technology. However, the occurrence of membrane fouling due to interaction between natural organic matter (NOM) and inorganic ions during the MD process curtails water purification efficiency, thereby constraining its potential applications. To address this quandary, this study integrates sulfate radical-based advanced oxidation processes (SR-AOPs) into MD technology to bolster membrane fouling control. A straightforward hydrothermal method coupled with vacuum filtration was employed to synthesize a Co3O4/Nitrogen-modified carbon quantum dots (NCDs)/PVDF (CN-PVDF) membrane for the first time, which was utilized in the MD treatment of simulated humic acid (HA) wastewater. Under visible light irradiation (1.9 kW/m2), CN-PVDF membrane activation of peroxymonosulfate (PMS) effectively altered the chemical attributes of the MD feed solution and reduced organic matter concentration. Moreover, it dismantled the carboxyl sites on HA that interact with Ca2+, consequently attenuating the formation of organic–inorganic complex pollutants. The XDLVO analysis showcased that photo-Fenton oxidation led to a diminishment in pollutant hydrophobicity, correlating with a 17.59 kT reduction in pollutant-membrane adsorption and a 7.47 kT amplification in adhesion barriers. This strategy transformed the initial two-stage fouling mode into a singular one, which significantly decreased the flux decline and the fouling layer thickness. Furthermore, the CN-PVDF membrane demonstrated self-cleaning capabilities via photo-Fenton. This study advances an innovative approach to bolster the fouling resistance of MD membranes and provides substantial theoretical support for the integration of SR-AOPs and MD technologies.