Energy transition and green innovation have appeared as new hopes for environmental impact due to human activity, which has destroyed biodiversity and increased environmental degradation. Therefore, developed and emerging economies are focusing on green innovation and energy transition to tackle the environmental impact. Thus, this study was initiated to provoke a meaningful relationship between energy transition, economic growth, trade, green innovation, and good governance to measure the role of concerning factors in achieving environmental sustainability. For this objective, dynamic econometric approaches such as cointegration, heteroskedastic OLS estimation using GMM (HOLS-GMM), AMG, and Driscoll–Kraay were implemented to estimate the Asian dataset between 1990 and 2022. The result indicates that concerning factors have a significant influence on environmental impact. The findings specify that a 1% rise in the energy transition and green innovation will influence the environment by 0.0517% and 3.051%, respectively. Further, AMG and Driscoll–Kraay validate the findings of HOLS-GMM. The robust tests indicate that the factors, which are concerning, significantly impact environmental sustainability. Consequently, the energy transition, trade, and green innovation significantly contribute to attaining ecological sustainability in the long term, and the Sustainable Development Theory prevails in the economy. Thus, innovative policy implications, including energy transition, green innovation, trade, and economic growth, are required to make Asia prominent in achieving environmental sustainability via implementing sustainable and green technologies and clean energy sources.