Ordinary Chondrite Parent Bodies Research Articles

The anomalous polymict ordinary chondrite breccia of Elmshorn (H3‐6)—Late reaccretion after collision between two ordinary chondrite parent bodies, complete disruption, and mixing possibly about 2.8 Gyr ago

AbstractElmshorn fell April 25, 2023, about 30 km northwest of the city of Hamburg (Germany). Shortly after the fall, 21 pieces were recovered totaling a mass of 4277 g. Elmshorn is a polymict and anomalous H3‐6 chondritic, fragmental breccia. The rock is a mixture of typical H chondrite lithologies and clasts of intermediate H/L (or L, based on magnetic properties) chondrite origin. In some of the 21 pieces, the H chondrite lithologies dominate, while in others the H/L (or L) chondrite components are prevalent. The H/L chondrite assignment of these components is based on the mean composition of their olivines in equilibrated type 4 fragments (~Fa21–22). The physical properties like density (3.34 g cm−3) and magnetic susceptibility (logχ <5.0, with χ in 10−9 m3 kg−1) are typical for L chondrites, which is inconsistent with the oxygen isotope compositions: all eight O isotope analyses from two different fragments clearly fall into the H chondrite field. Thus, the fragments found in the strewn field vary in mineralogy, mineral chemistry, and physical properties but not in O isotope characteristics. The sample most intensively studied belongs to the stones dominated by H chondrite lithologies. The chemical composition and nucleosynthetic Cr and Ti isotope data are typical for ordinary chondrites. The noble gases in Elmshorn represent a mixture between cosmogenic, radiogenic, and primordially trapped noble gases, while a solar wind component can be excluded. Because the chondritic rock of Elmshorn contains (a) H chondrite parent body interior materials (of types 5 and 6), (b) chondrite parent body near‐surface materials (of types 3 and 4), (c) fragments of an H/L chondrite (dominant in many stones), (d) shock‐darkened fragments, and (e) clasts of various types of impact melts but no solar wind‐implanted noble gases, the different components cannot have been part of a parent body regolith. The most straightforward explanation is that the fragmental breccia of Elmshorn represents a reaccreted rock after a catastrophic collision between an H chondrite parent body and another body with H/L (or L) chondrite characteristics but with deviating O isotope values (i.e. that of H chondrites), complete disruption of the bodies, mixing, and reassembly. This is the only straightforward way that the implantation of solar wind gases could have been avoided in this kind of complex breccia. The gas retention ages of about 2.8 Gyr possibly indicate the closure time after the catastrophic collision between H and H/L (or L) chondrite parent bodies, while the cosmic ray exposure age for Elmshorn, which had a preatmospheric radius of 25–40 cm, is ~17–20 Myr.

3D porosity, flow, and transport characteristics of two L chondrites reveal wet accretion-related cosmic web-like porosity

Porosity, with its structure-dependent flow properties (permeability and tortuosity) and transport properties (thermal conductivity and thermal diffusivity), is closely related to the accretion, thermal metamorphism, and associated hydrothermal alteration of ordinary chondrite (OC) parent bodies. Using synchrotron radiation microtomography (SRμCT), we reveal the varying porosity structures in two L chondrite falls of low (Mezö-Madaras L3.7) and high (Bath Furnace L6) petrologic types and quantify porosity properties, such as shape and connectivity, and related effective permeability and tortuosity factor. Although the two specimens demonstrate similar effective permeabilities, they exhibit significantly different tortuosity factors and textures of porosity, which include notable differences in void throat diameters, complexity and density of the interconnected void network, heterogeneity in void distribution, and the extent of primary and secondary porosity. The complex relationships among porosity, permeability, tortuosity, and thermal conductivity can be explained by the varying void arrangements related to varying grain sizes among the petrologic types of OCs, which in turn reflect their varying evolutionary paths.Electron microprobe and attached energy-dispersive X-ray spectrometer reveal signs of hydrothermal alteration in both petrologic types. High-energy SRμCT imaging (0.65 μm voxel size) reveals the presence of a new microporosity substructure resembling a microscopic cosmic web, which may be linked to fluid-assisted metamorphism and hydrothermal alteration during wet accretion of the parent body. Furthermore, the proportion of this continuous porosity may be related to the temperatures associated with different petrologic types, and the wet accretion model may resolve the lack of correlation between petrologic types and porosity of OCs. Finally, the uncovered cosmic web-like microporosity structure may explain the observed concurrent high thermal conductivity, low permeability, and high porosity of the high-petrologic-type OCs.

Hydrogen in acapulcoites and lodranites: A unique source of water for planetesimals in the inner Solar System

Acapulcoites and lodranites are primitive achondrites, sampling a common planetesimal formed a few million years after calcium-aluminium rich inclusions in the inner Solar System, that provides information into melting and differentiation processes in the early inner Solar System. The chemistry and mineralogy of their chondritic parent body lies in between enstatite and ordinary chondrites. As they record a range in planetary differentiation degree, from 1% up to 20% partial melting, with lodranites experiencing the most melt extraction, we investigate (i) the behaviour of hydrogen in terms of abundance and isotopic composition during the early stages of planetary differentiation and (ii) the source(s) of hydrogen for the acapulcoite-lodranite parent body in order to place it in our current understanding of the source(s) of water in the inner Solar System. In this study, we analysed water content and hydrogen isotopic composition of phosphates and nominally anhydrous minerals in a range of acapulcoite and lodranite meteorite samples. While apatites seemed to have recorded a degassing signature, no such variations were observed in the H2O–δD systematics of the nominally anhydrous minerals suggesting that subsequent to their crystallisation, acapulcoites and lodranites experienced minimal modifications to their volatile composition during thermal metamorphism and partial melting. The low abundance of water in acapulcoite and lodranite nominally anhydrous minerals (i.e., average 5.2±1.6 μg/g H2O) suggests that their parent body was much drier than what has been estimated for enstatite and ordinary chondrite parent bodies. We estimated a bulk water content for the acapulcoite-lodranite parent body of 3 to 19 μg/g H2O, similar to the ureilite parent body. The hydrogen isotopic composition of nominally anhydrous minerals in acapulcoites and lodranites (–211±145‰), and in particular for the two falls Acapulco and Lodran (–239±149‰), matches with the hydrogen isotopic composition recorded by nominally anhydrous minerals in ordinary chondrite falls, eucrites, S–type asteroid Itokawa, consistent with a common source of water for the inner Solar System planetesimals, isotopically distinctive to bulk carbonaceous chondrites.

In-situ formation of halite in the Sidi El Habib 001 (H5) ordinary chondrite: Implications for hydrothermal alteration in ordinary chondrite parent bodies

The microstructures and chemistry of secondary feldspars and phosphates in equilibrated ordinary chondrites (OCs) suggest that fluids were involved in the formation of these phases, challenging the conventional view that secondary alteration of equilibrated OCs occur under water-absent conditions. The newly discovered Sidi El Habib 001 (SEH 001), a halite-bearing H5 OC, provides a unique opportunity to further probe the role of fluids during thermal metamorphism on the OC parent bodies. Here we report a petrographic and mineralogic study of SEH 001, with the aim of understanding the origins of halite grains and their implications for the alteration histories of equilibrated OCs. Our investigation reveals a main halite-bearing lithology and a halite-free lithology, both of which show equilibrated textures. Except for halides, no significant textural or compositional differences were observed between halite-bearing and -free lithologies. Halite occurs at all spatial scales in the main lithology and shows clear textures of replacing albitic plagioclase and Cl-apatite. Chlorapatite grains in SEH 001 are Cl-rich and many of them contain elevated amounts of “other” anions.Our observations suggest that halite grains in SEH 001 formed in situ on the parent body via precipitation from an aqueous fluid. The replacement of plagioclase and Cl-apatite by halite and the equilibrated textures of halite-bearing and halite-free lithologies point to a hydrothermal alteration history where halite formed during advanced thermal metamorphism before the fluid was completely lost. The two lithologies were likely affected by fluids with different Cl concentrations that resulted from heterogeneous distribution of HCl hydrate. Based on comparison to experimental data, halite in SEH 001 could have survived peak metamorphism because of its relatively high thermal stability. Collisional disruption of its original parent body could also facilitate the preservation of halite via release of heat. In the rubble pile model of the OC parent body formation, subsequent accretion of hot fragments into a rubble pile body could have resulted in the blurred boundaries between halite-free and -bearing lithologies now observed in our sample. The occurrence of halite in SEH 001 is clear evidence that aqueous fluids were involved in the alteration of equilibrated OCs.Combined with previous reports of hydrous minerals (such as phyllosilicates) and other related aqueous products in unequilibrated OCs, our study further suggests that S-type asteroids, the parent bodies of OCs, could be more hydrated than previously thought and might serve as a potential source of water for terrestrial planets in the inner solar system. Nevertheless, whether the proposed hydrothermal history of SEH 001 can be extrapolated to other equilibrated OCs needs to be tested. The in-situ formation origin of halite in SEH 001 contrasts with the exogeneous origin of halite in Monahans (1998) and Zag, suggesting that halites with different origins occurred on the OC parent bodies. The rarity of halite in OCs could be attributed to the heterogeneous distribution of HCl hydrate in the OC parent bodies, although the fragile nature of halite in terrestrial and laboratory environments also increases the likelihood of halite being destroyed in OC samples.

How Mössbauer spectroscopy can be of value to industry to select extraterrestrial objects for natural resources

Space agencies are working on the project of capturing asteroids which contain natural resources valuable for industry. Based on studies of meteorites samples it was determined that the most useful source of raw materials for this purpose could be parent bodies of ordinary chondrites of type H. The identification of the type of ordinary chondrites with the use of a classical method (determination of the Fa/Fs ratio (fayalite versus ferrosilite) by electron microprobe measurements) cannot be performed on the surface of asteroids due to technical reasons. It may, however, be done based on Mössbauer measurements followed by the application of the 4M method. The name of the method – 4M, comes from four words: Meteorites, Mössbauer spectroscopy, Multidimensional discriminant analysis and Mahalanobis distance. Following the success of Mössbauer spectroscopy in the mission on Mars, there are suggestions to use the same method for the investigation of the surface of asteroids. In our experimental study, in which five Mössbauer laboratories took part, we assessed the effectiveness and reliability of the 4M method by comparison of the results obtained by Mössbauer studies of ordinary chondrites of type H, L and LL. Details of the study and problems related to the effectiveness of the 4M method are discussed.

High precision 26Al-26Mg chronology of chondrules in unequilibrated ordinary chondrites: Evidence for restricted formation ages

Chondrules in ordinary chondrites are considered to form in high density environments, likely related to the evolution of protoplanets and large planetesimals. In order to determine the timing of their formation at high time resolution (≤0.1 Ma), we conducted high precision Al-Mg chronology of 17 porphyritic chondrules from 6 different unequilibrated ordinary chondrites (UOCs) of low petrologic subtypes (3.00–3.05). Detailed petrology, mineralogy, and oxygen isotope ratios of individual chondrules were also obtained that include 10 additional chondrules without Al-Mg ages. Seventeen chondrules for Al-Mg chronology consist of 14 chondrules with plagioclase (An1-An87) and three chondrules with Na-rich glassy mesostasis, all of which have high 27Al/24Mg ratios (30–3000). The inferred initial (26Al/27Al)0 ratios range between (6.5 ± 0.6) × 10–6 to (9.5 ± 1.0) × 10–6, corresponding to chondrule formation ages of 1.74 ± 0.12/0.11 Ma to 2.13 ± 0.09 Ma after CAIs, which have a canonical (26Al/27Al)0 ratio of 5.25 × 10–5. Six albite-bearing chondrules (An<30) show a much more restricted ages range, spanning between 2.00 ± 0.11/0.10 Ma and 2.07 ± 0.11/0.10 Ma. Including 14 anorthite-bearing chondrules studied previously, chondrules in ordinary chondrites have a restricted range of formation ages from 1.8 Ma to 2.2. Ma after CAIs.Based on the newly acquired oxygen isotope data and previous high precision studies, chondrules in L and LL chondrites do not show systematic difference in their δ18O and δ17O signatures. Majority of plagioclase-bearing chondrules studied for Al-Mg chronology show similar oxygen isotope ratios to those of glass-bearing chondrules. There is no obvious difference in Al-Mg ages of chondrules between L and LL chondrites. Thus, chondrules in L and LL chondrites would have formed in common environments and processes, though they accreted to two separate parent bodies by 2.2 Ma after CAIs, which timing is consistent with the proposed thermal model for ordinary chondrite parent bodies. Onset of chondrule formation at 1.8 Ma after CAIs may be caused by the delay of Jupiter formation or the formation of protoplanets in ordinary chondrite chondrule forming regions if chondrules formed by large scale disk shock or impact jetting of protoplanets. Alternatively, early formed chondrules would not be preserved before 1.8 Ma if chondrules formed by the impacts of molten planetesimals.

Exsolution in alkali feldspar in ordinary chondrites: Ubiquitous evidence for rapid cooling at high temperatures

Thermal metamorphism in undisrupted ordinary chondrite (OC) parent bodies is thought to occur through the radioactive decay of 26Al, producing an onion-shell-like structure with higher peak metamorphic temperatures corresponding to increasing depth. During retrograde metamorphism, the onion-shell model predicts slower cooling rates with increasing petrologic type. However, cooling rates determined by pyroxene diffusion, metallographic, and other methods are inconsistent with onion-shell-like cooling, leading to a model of asteroid disruption and reaccretion into a rubble pile, after peak metamorphism. Potassium-feldspar exsolution in albite, in a perthite texture, has been noted in OCs and can be used as another method for determining cooling rates. We conducted a survey of K-feldspar occurrences and textures, within chondrules, in petrologic type 3.6–6 H, L, and LL OCs. Potassium-feldspar is present as a secondary feature, in primary and secondary albite, as fine-scale exsolution lamellae, 0.1–1.5 μm wide, as well as in larger patches up to 50 μm in size. Exsolution is present in all OC groups and is most common in petrologic type 4.In the H4 chondrite Avanhandava, we estimate the cooling rate from perthite to be 3–17 °C/yr over a temperature interval of 765–670 °C. Peristerite is also present in Avanhandava for which we estimate a cooling rate of 0.2–2.4 × 10−3 °C/yr from 570-540 °C. In general, the relatively fast, high-temperature cooling rate determined by perthite is similar to cooling rates recovered from two-pyroxene speedometry. The peristerite cooling rate is closer to the slow, lower temperature metallographic cooling rates. Because K-feldspar exsolution is present in similar fine-scale lamellae in all OC groups, we suggest that all OC parent bodies experienced the same cooling history at high temperatures. These results are inconsistent with predictions of OC asteroid cooling from undisturbed onion-shell metamorphism but are consistent with models involving disruption after peak metamorphism followed by reassembly.

Chronological constraints on the thermal evolution of ordinary chondrite parent bodies from the 53Mn-53Cr system

The 53Mn-53Cr isotope systematics in ordinary chondrites constrains the accretion and thermal history of their parent bodies. Mineralogical observations and olivine-spinel geothermometry suggest that chromite in ordinary chondrites formed during prograde thermal metamorphism with the amount of chromite increasing with petrologic grades in type 3 to type 6 ordinary chondrites. Assuming a chondritic evolution of the respective parent bodies, 53Cr/52Cr model ages for chromite range from 3.99-0.79+0.93 to 11.1-2.8+6.0 Ma after the formation of calcium-aluminium-rich inclusions (CAIs). Chromite and silicate-metal-sulphide isochrons define an age range from 2.78-0.50+0.55 to 15.4-1.6+2.4 Ma. Both chromite model ages and isochron ages correlate with the petrological grade of the samples, which is consistent with an onion-shell structure of the chondrite parent bodies. The study shows that unlike the isochron ages, which are prone to impact-related disturbances or partial re-equilibration during cooling from high temperatures, the chromite model ages are not easily affected by thermal metamorphism or later events and yield robust mineral growth ages. The results are consistent with a homogenous distribution of 53Mn and an initial canonical 53Mn/55Mn = 6.28 × 10−6. The estimated closure temperatures for the Mn-Cr system in chromites range from ~760 °C for type 6 to ~540–620 °C for type 3 ordinary chondrites. The high closure temperatures estimated for type 3 and type 6 ordinary chondrites imply that the chromite ages correspond to the peak metamorphic temperature reached during the thermal history of the chondrite parent bodies. The oldest chromite model age obtained for type 3 samples along with the established Al-Mg chondrule formation ages constrain the accretion of the parent bodies to >2.1 Ma after CAI formation, implying that planetesimal accretion immediately followed chondrule formation.

Thermal emission measurements of ordinary chondrite mineral analogs in a simulated asteroid environment: 2. Representative mineral mixtures

We investigate a suite of synthetic mineral mixtures designed to act as bulk mineralogical analogs to H, L, and LL ordinary chondrite meteorites in order to probe how the thermal emission characteristics of such materials change between ambient and simulated asteroid environmental conditions. Due to the parent body link with certain S-type asteroids, studying these analog mixtures in an environment that is relevant to actual asteroid surfaces advances our understanding of the thermal emission properties of one of the most common regolith types among the main-belt and near-Earth asteroid populations. The observed changes in spectral emissivity features due to cold, vacuum conditions are not as large as previously observed for single mineral (silicate) samples. We interpret this difference to be the result of metallic and opaque components weakening near-surface thermal gradients in the mixtures. As such, we predict that near-surface thermal gradients on ordinary chondrite parent bodies (e.g., S-type asteroids) are likely much weaker than would be inferred from cold, vacuum measurements of individual mineral components. We tested whether the increased spectral contrast observed in fine-grained (<25 μm) samples measured in a cold, vacuum environment increases the efficacy of least squares linear unmixing methods. It is found that the accuracy of such models does not improve relative to measurements made under ambient conditions, thus linear unmixing models are not expected to yield accurate estimates of the modal mineralogy of airless planetary surfaces if they are dominated by fine-grained regolith. Mixtures with coarse particle sizes (125–250 μm) that were modeled using the coarse particle size endmembers yielded results that were largely independent of the environmental conditions, but with larger errors in spectral fits for samples measured in a simulated asteroid environment. At simulated asteroid environmental conditions, the bulk silicate composition and metal content play a more important role in determining the thermal state and brightness temperature of the sample than at ambient conditions. Modest changes in metal content (10–25 wt%) lead to large differences in the brightness temperature of a sample. Under simulated asteroid conditions, an ~10 K increase in maximum brightness temperature that tracks with increased iron content is observed at fine particle sizes (<25 μm) between each of the analog ordinary chondrite groups. Based on these results, it may be difficult to distinguish H, L, and LL compositions of suspected ordinary chondrite parent bodies using only Earth- or space-based thermal emission spectra. This is inferred from the spectral similarity of the analog mixtures and the absence of significant variation in spectral emissivity associated with reported differences in bulk metal content for ordinary chondrites.

New constraints from 26Al-26Mg chronology of anorthite bearing chondrules in unequilibrated ordinary chondrites

26Al-26Mg ages were determined for 14 anorthite-bearing chondrules from five different unequilibrated ordinary chondrites (UOCs) with low petrologic subtypes (3.00–3.05). In addition, oxygen three isotopes of these chondrules were also measured. The selected chondrules are highly depleted in alkali elements, and anorthite is the only mesostasis phase, though they show a range of mafic mineral compositions (Mg# 76–97 mole%) that are representative of chondrules in UOCs. The mean Δ17O values in these chondrules range from −0.44 ± 0.23‰ to 0.49 ± 0.15‰, in good agreement with previous studies of plagioclase-bearing chondrules from UOCs. Anorthite in all chondrules exhibit resolvable excess 26Mg (>1.0 ± 0.4‰). Their inferred (27Al/26Al)0 range from (6.3 ± 0.7) × 10−6 to (8.9 ± 0.3) × 10−6 corresponding to a timescale for chondrule formation of 1.8 ± 0.04 Ma to 2.16 ± 0.12/0.11 Ma after CAIs using a canonical (27Al/26Al)0 value of 5.25 × 10−5. The ages from six chondrules in LL chondrites are restricted to between 1.8 Ma and 1.9 Ma, whereas eight chondrules in L chondrites show ages from 1.8 Ma to 2.2 Ma, including three chondrules at ∼2.0 Ma and two chondrules at ∼2.15 Ma.The inferred chondrule formation ages from this study are at the peak of those previously determined for UOC chondrules, though with much shorter durations. This is potentially due to the time difference between formation of anorthite-bearing chondrules and typical UOC chondrules with alkali-rich compositions. Alternatively, younger chondrules ages in previous studies could have been the result of disturbance to the Al-Mg system in glassy mesostasis even at the low degree of thermal metamorphism in the parent bodies. Nevertheless, the high precision ages from this study (with uncertainties from 0.04 Ma to 0.15 Ma) indicate that there was potentially more than one chondrule forming event represented in the studied population. Considering data from LL chondrites only, the restricted duration (≤0.1 Ma) of chondrule formation ages suggests an origin in high density environments that subsequently lead to parent body formation. However, the unusually low alkali contents of the studied chondrules compared to common alkali-rich chondrules could also represent earlier chondrule formation events under relatively lower dust densities in the disk. Major chondrule forming events for UOCs might have postdated or concurrent with the younger anorthite-bearing chondrule formation at 2.15 Ma after CAIs, which are very close to the timing of accretion of ordinary chondrite parent bodies that are expected from thermal evolution of ordinary chondrite parent bodies.

Evidence for early fragmentation-reassembly of ordinary chondrite (H, L, and LL) parent bodies from REE-in-two-pyroxene thermometry

Ordinary chondrites (OCs) are variably thermally metamorphosed meteorites thought to originate from at least three different parent bodies (H, L, and LL) in the Main Belt of asteroids. The thermal evolutions of OC parent bodies are frequently explained by the onion shell model; however, a competing hypothesis is the fragmentation-reassembly model. The onion shell model proposes undisrupted, internally heated parent bodies with concentrically stratified thermal structure, and posits that OC petrologic types (i.e., 3–6) develop with increasing temperature and burial depth. In this model, petrologic types are inversely correlated with cooling rate in the parent body. The alternative fragmentation-reassembly model invokes catastrophic collisional disruption of parent bodies that initially possessed onion shell structures, followed by rapid reaccretion of hot fragments, forming rubble pile bodies. Fragmentation would result in fast cooling (quenching) of collisional fragments from the temperature experienced by the parent body at the time of collision. Discrimination between these two models may be possible via investigation of the thermal histories of OCs by application of geothermometry and geospeedometry, which are used to constrain the temperatures and rates through which igneous and metamorphic rock samples cool. Most published cooling rate data for OC parent bodies are based on methods that record rates through low closure temperatures (∼500–200 °C) rather than from peak metamorphic temperatures. Recently, a rare earth element (REE)-in-two-pyroxene thermometer has been shown to establish peak or magmatic temperatures (TREE; Liang et al. [2013]) for rocks that cooled at moderate to fast geologic rates. We applied the REE-in-two-pyroxene method to determine peak temperatures for 18 OC samples (mostly type 6), in conjunction with conventional two-pyroxene thermometry (TBKN; Brey and Köhler [1990]) and Ca-in-olivine thermometry (TCa-Ol; Köhler and Brey [1990]), to determine closure temperatures and estimate cooling rates for OC parent bodies. Inconsistent with slow cooling rates expected within an onion shell structure, we obtain fast cooling at rates ≳0.3 °C/y from peak temperatures of ∼900 °C. Corroborating the TREE and TBKN measurements, TCa-Ol suggests that the OCs cooled through TCa-Ol closure temperatures (∼700 to 800 °C) at ∼10−2 to 10−1 °C/y. These cooling rates are three to six orders of magnitude faster than rates determined using methods sensitive to low temperature (≤500 °C) cooling (e.g., metallography, 40Ar–39Ar ages, 244Pu fission track). We developed a novel numerical thermal model that incorporates fragmentation of an initial onion shell body and reassembly into a rubble pile body that reproduces both the fast cooling from high temperatures and the slow cooling through low temperatures observed in chondritic meteorites. We hypothesize that OC parent bodies initially possessed onion shell thermal structures, but later experienced collisional breakup, then reaccreted rapidly to form thermally stable rubble-pile asteroids.

In situ analysis of platinum group elements in equilibrated ordinary chondrite kamacite and taenite

AbstractPlatinum group element (PGE) concentrations have been determined in situ in ordinary chondrite kamacite and taenite grains via laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS). Results demonstrate that PGE concentrations in ordinary chondrite metal (kamacite and taenite) are similar among the three ordinary chondrite groups, in contrast to previous bulk metal studies in which PGE concentrations vary in the order H &lt; L &lt; LL. PGE concentrations are higher in taenite than kamacite, consistent with preferential PGE partitioning into taenite. PGE concentrations vary between and within metal grains, although average concentrations in kamacite broadly agree with results from bulk studies. The variability of PGE concentrations in metal decreases with increasing petrologic type; however, variability is still evident in most type six ordinary chondrites, suggesting that equilibration of PGEs does not occur between metal grains, but rather within individual metal grains via self‐diffusion during metamorphism. The constant average PGE concentrations within metal grains across different ordinary chondrite groups are consistent with the formation of metal via nebular condensation prior to the accretion of ordinary chondrite parent bodies. Post‐condensation effects, including heating during chondrule‐formation events, may have affected some element ratios, but have not significantly affected average metal PGE concentrations.

IDP-like Asteroids Formed Later than 5 Myr After Ca–Al-rich Inclusions

Abstract The parent bodies of ordinary chondrites, carbonaceous CM chondrites, and interplanetary dust particles (IDPs) represent most of the mass of the solar system’s small (D ≤ 250 km) bodies. The times of formation of the ordinary and carbonaceous CM chondrite parent bodies have previously been pinpointed, respectively, to ≈2 and 3–4 million years after calcium–aluminum-rich inclusions (CAIs). However, the timing of the formation of IDP parent bodies such as P- and D-type main-belt asteroids and Jupiter Trojans has not been tightly constrained. Here, we show that they formed later than 5–6 million years after CAIs. We use models of their thermal and structural evolution to show that their anhydrous surface composition would otherwise have been lost due to melting and ice-rock differentiation driven by heating from the short-lived radionuclide 26Al. This suggests that IDP-like volatile-rich small bodies may have formed after the gas of the protoplanetary disk dissipated and thus later than the massive cores of the giant planets. It also confirms an intuitive increase in formation times with increased heliocentric distance, and suggests that there may have been a gap in time between the formation of carbonaceous chondrite (chondrule-rich) and IDP (chondrule-poor) parent bodies.

Potential deposits of selected metallic resources on L chondrite parent bodies

The authors have undertaken research aimed at determining the abundance of metallic resources on parent bodies of ordinary chondrites. In this report, they present their findings concerning L chondrites, whose parent S asteroids make about 17% of all asteroids in the main belt and ca. 66% of NEAs. The abundances, and their variations, of selected metals in the rocks of L chondrites were studied based on a bulk chemical composition analysis. The authors also analysed the abundances of selected metals in FeNi alloy grains crystallizing in the forms of kamacite, taenite and tetrataenite. These are the only minerals that they considered to be ore minerals forming potential deposits of metallic resources on L chondrite parent bodies. Further analyses focused on the distribution and concentration of FeNi alloy grains in L chondrite rocks, and finally also on the influence of the structure of rocks building the surfaces of asteroids on the feasibility and the method of extracting metallic resources from these bodies. The conducted analyses demonstrated that the abundances of Fe, Ni, Cr, Co, Cu and Au on L chondrite parent bodies are higher, and the abundances of REE – much lower than those in the Earth's crust, where the majority of the currently mined metallic resources are found. Ni content in L chondrite rocks is 1.7 times as high as that in terrestrial nickel deposits, and Co content – 2.5 times as high as its minimum abundance in terrestrial deposits. As Fe, Ni, Co, Cr, Cu and Au occur in parent bodies in mineral association, they form polymetallic deposits. Co and Ni could be considered the main mineral resource on the parent asteroids of L chondrites, while Fe, Au, Cu and Cr could be accompanying minerals.Rocks with the composition of L chondrites contain 9.2 wt% of FeNi grains distributed evenly throughout the rock. Ore mineral content does not change with depth on ordinary chondrite parent bodies with onion shell structure and it is the same in pieces of regolith from the rubble pile asteroids. The high abundance of ore minerals and their even distribution in space make it possible to regard the whole asteroid as an abundant deposit of metallic resources. Metallic resources are also found on asteroid surfaces, which could enable open-pit mining at any place without previous prospection work or the need to remove the overburden. The presence of regolith and the high porosity of rocks underlying it directly will considerably facilitate the crushing of the excavated material and processing the ore. The estimated Ni and Co resources on 4179 Toutatis asteroid, being the most likely the parent body of L chondrites, would satisfy the current needs of the humankind for the nearest 200 years, and Cr, Fe, and Au resources – for a few years.

Brecciation among 2280 ordinary chondrites – Constraints on the evolution of their parent bodies

After accretion of meteorite parent bodies, larger and smaller collisions have led to significant modifications of these bodies. Involved processes include excavation of material, thermal metamorphism, melting, mixing of different materials, re-accretion, and re-lithification. All these processes can be repeated several times. In this study polished thin sections (PTS) of 2280 chondrites (1193 H, 947 L, and 140 LL chondrites) were investigated in order to obtain the abundance of brecciated rocks among the ordinary chondrites. In addition, we have determined the abundance and characteristics of shock vein-bearing H, L, and LL chondrites and of impact melt rock clasts. We also recognized xenolithic components based on O-isotope studies. Noble gas data were considered in order to detect regolith breccias and to discuss late impact histories. The investigation of 2280 samples shows that 23% (276 of 1193) of the H chondrites, 23% (220 of 947) of the L chondrites, and 79 % (110 of 140) of the LL chondrites are brecciated. Considering the heavily-brecciated LL chondrites in 63 of the 140 chondrites (45%) shock veins were clearly detected. 57 of these 63 chondrites are brecciated rocks. The investigation of the H and L chondrites has shown that about 26% (310 of 1193) of the H chondrites and 40% (379 of 947) of the L chondrites contain shock veins. In our data-set 20% of the H chondrites and 8.3% of the LL chondrites, but only 3.0% of the L chondrites contain solar noble gases. Remarkably, about 62% of all brecciated H chondrites (with noble gases analyzed) contain solar noble gases compared to only around 11% and 10% of the brecciated L and LL chondrites, respectively. The identification of xenolithic clasts (e.g., CI-, CM-, and ureilite-like lithologies) in primitive type 3 chondrites indicates simultaneous accretion of clasts and chondrules. These clasts must have been formed early within the first 2 Ma on subsequently-destroyed precursor, first generation parent bodies. The formation of complex breccias witnesses the collisions between asteroids of very different lithologies and heritage. Although the onion-shell configuration of primordial parent bodies is necessary in order to form the chondrites with different degrees of metamorphic overprint (petrologic types 3–6) subsequent catastrophic fragmentation and reassembly to form asteroids with a rubble-pile structure are required to explain certain features discussed in this work. However, distinct peaks in the cosmic ray exposure age distributions indicate that not too many impacts in the last 100 Ma were responsible to deliver the majority of the ordinary chondritic meteoroids to Earth. Yet, this certainly does not tell anything about the number of “last-generation” parent bodies that exist in the asteroid belt, since S-type asteroids are the most abundant type of asteroid in the inner main belt and thought to be the parent bodies of ordinary chondrites.

Intermineral oxygen three-isotope systematics of silicate minerals in equilibrated ordinary chondrites.

High precision oxygen three-isotope ratios were measured for four mineral phases (olivine, low-Ca and high-Ca pyroxene, and plagioclase) in equilibrated ordinary chondrites (EOC) using a secondary ion mass spectrometer. Eleven EOCs were studied that cover all groups (H, L, LL) and petrologic types (4, 5, 6), including S1-S4 shock stages, as well as unbrecciated and brecciated meteorites. SIMS analyses of multiple minerals were made in close proximity (mostly <100 μm) from several areas in each meteorite thin section, to evaluate isotope exchange among minerals. Oxygen isotope ratios in each mineral become more homogenized as petrologic type increases with the notable exception of brecciated samples. In type 4 chondrites, oxygen isotope ratios of olivine and low-Ca pyroxene are heterogeneous in both δ18O and Δ17O, showing similar systematics to those in type 3 chondrites. In types 5 and 6 chondrites, oxygen isotope ratios of the four mineral phases plot along mass dependent fractionation lines that are consistent with the bulk average Δ17O of each chondrite group. The δ18O of three minerals, low-Ca and high-Ca pyroxene and plagioclase, are consistent with equilibrium fractionation at temperatures of 700-1000°C. In most cases the δ18O values of olivine are higher than those expected from pyroxene and plagioclase, suggesting partial retention of premetamorphic values due to slower oxygen isotope diffusion in olivine than pyroxene during thermal metamorphism in ordinary chondrite parent bodies.

Young asteroid mixing revealed in ordinary chondrites: The case of NWA 5764, a polymict LL breccia with L clasts

AbstractPolymict chondritic breccias—rocks composed of fragments originating from different chondritic parent bodies—are of particular interest because they give insights into the mixing of asteroids in the main asteroid belt (occurrence, encounter velocity, transfer time). We describe Northwest Africa (NWA) 5764, a brecciated LL6 chondrite that contains a &gt;16 cm3 L4 clast. The L clast was incorporated in the breccia through a nondestructive, low‐velocity impact. Identical cosmic‐ray exposure ages of the L clast and the LL host (36.6 ± 5.8 Myr), suggest a short transfer time of the L meteoroid to the LL parent body of 0.1 ± 8.1 Myr, if that meteoroid was no larger than a few meters. NWA 5764 (together with St. Mesmin, Dimmitt, and Glanerbrug) shows that effective mixing is possible between ordinary chondrite parent bodies. In NWA 5764 this mixing occurred after the peak of thermal metamorphism on the LL parent body, i.e., at least several tens of Myr after the formation of the solar system. The U,Th‐He ages of the L clast and LL host, identical at about 2.9 Ga, might date the final assembly of the breccia, indicating relatively young mixing in the main asteroid belt as previously evidenced in St. Mesmin.

Long-lived magnetism on chondrite parent bodies

We present evidence for both early- and late-stage magnetic activity on the CV and L/LL parent bodies respectively from chondrules in Vigarano and Bjurböle. Using micro-CT scans to re-orientate chondrules to their in-situ positions, we present a new micron-scale protocol for the paleomagnetic conglomerate test. The paleomagnetic conglomerate test determines at 95% confidence, whether clasts within a conglomerate were magnetized before or after agglomeration, i.e., for a chondritic meteorite whether the chondrules carry a pre- or post-accretionary remanent magnetization. We found both meteorites passed the conglomerate test, i.e., the chondrules had randomly orientated magnetizations. Vigarano's heterogeneous magnetization is likely of shock origin, due to the 10 to 20 GPa impacts that brecciated its precursor material on the parent body and transported it to re-accrete as the Vigarano breccia. The magnetization was likely acquired during the break-up of the original body, indicating a CV parent body dynamo was active ∼9 Ma after Solar System formation. Bjurböle's magnetization is due to tetrataenite, which transformed from taenite as the parent body cooled to below 320 °C, when an ambient magnetic field imparted a remanence. We argue either the high intrinsic anisotropy of tetrataenite or brecciation on the parent body manifests as a randomly orientated distribution, and a L/LL parent body dynamo must have been active at least 80 to 140 Ma after peak metamorphism. Primitive chondrites did not originate from entirely primitive, never molten and/or differentiated parent bodies. Primitive chondrite parent bodies consisted of a differentiated interior sustaining a long-lived magnetic dynamo, encrusted by a layer of incrementally accreted primitive meteoritic material. The different ages of carbonaceous and ordinary chondrite parent bodies might indicate a general difference between carbonaceous and ordinary chondrite parent bodies, and/or formation location in the protoplanetary disk.

Neodymium isotope heterogeneity of ordinary and carbonaceous chondrites and the origin of non-chondritic 142Nd compositions in the Earth

We present high-precision Nd isotope compositions for ordinary and carbonaceous chondrites determined using thermal ionization mass spectrometry with dynamic and multistatic methods. The ordinary chondrites had uniform and non-terrestrial μ142Nd, μ148Nd, and μ150Nd values, with data that plot along the mixing line between s-process and terrestrial components in μ150Nd versus μ148Nd and μ142Nd versus μ148,150Nd diagrams. In contrast, the carbonaceous chondrites were characterized by larger anomalies in their μ142Nd, μ148Nd, and μ150Nd values compared to ordinary chondrites. Importantly, the data for carbonaceous chondrites plot along the s-process and terrestrial mixing line in a μ150Nd versus μ148Nd diagram, whereas they have systematically lower μ142Nd values than the s-process and terrestrial mixing line in μ142Nd versus μ148,150Nd diagrams. This shift likely results from the incorporation of calcium- and aluminum-rich inclusions (CAIs), indicating that the Nd isotopic variability in the ordinary chondrites and CAI-free carbonaceous chondrites was caused solely by the heterogeneous distribution of s-process nuclides. The isotopic variation most likely results from nebular thermal processing that caused selective destruction of s-process-depleted (or r-process-enriched) dust grains in the inner Solar System where the parent bodies of ordinary chondrites formed, whereas such grains were preserved in the region of carbonaceous chondrite parent body formation. The Nd isotope dichotomy between ordinary and bulk aliquots of carbonaceous chondrites can be related to the presence of Jupiter, which may have separated two isotopically distinct reservoirs that were present in the solar nebula. After correcting for s-process anomalies and CAI contributions to the Nd isotopes observed in the chondrites, we obtained a μ142Nd value (−2.4±4.8 ppm) that was indistinguishable from the terrestrial value. Our results corroborate the interpretation that a missing reservoir (e.g., a hidden enriched reservoir, erosional loss of crust) is not required to explain the observed differences in 142Nd/144Nd ratios between chondrites and terrestrial materials.

The accretion and impact history of the ordinary chondrite parent bodies

A working timeline for the history of ordinary chondrites includes chondrule formation as early as 0–2Ma after our Solar System’s earliest forming solids (CAIs), followed by rapid accretion into undifferentiated planetesimals that were heated internally by 26Al decay and cooled over a period of tens of millions of years. There remains conflict, however, between metallographic cooling rate (Ni-metal) and radioisotopic thermochronometric data over the sizes and lifetimes of the chondrite parent bodies, as well as the timing of impact related disruptions. The importance of establishing the timing of parent body disruption is heightened by the use of meteorites as recorders of asteroid belt wide disruption events and their use to interpret Solar System dynamical models. Here we attempt to resolve these records by contributing new 207Pb–206Pb data obtained on phosphates isolated from nine previously unstudied ordinary chondrites. These new results, along with previously published Pb-phosphate, Ni-metal and thermometry data, are interpreted with a series of numerical models designed to simulate the thermal evolution for a chondrite parent body that either remains intact or is disrupted by impact prior to forming smaller unsorted “rubble piles”.Our thermal model and previously published thermometry data limit accretion time to 2.05–2.25Ma after CAIs. Measured Pb-phosphate data place minimum estimates on parent body diameters of ∼260–280km for both the L and H chondrite parent bodies. They also consistently show that petrologic Type 6 (highest thermal metamorphism) chondrites from both the H and L bodies have younger ages and, therefore, cooled more slowly than Type 5 (lesser metamorphism) chondrites. This is interpreted as evidence for Type 5 chondrite origination from shallower depths than Type 6 chondrites within initially concentrically zoned bodies. This contrasts metallographic cooling rate data that are inconsistent with such a simple onion shell scenario. One model that can reconcile these two data sets takes into account subtle differences in temperature to which each system responds. This working model requires that disruption occur early enough such that the Ni-metal system can record the cooling rate associated with a rubble pile (<70Ma), yet late enough that the Pb-phosphate system can record an onion shell structure (>30Ma). For this 30–70Ma timeline, reaccretion into smaller rubble piles will ensure that the originally deeply buried and hot Type 6 samples will always cool faster as a result of disruption, yielding nearly uniform ages that record the time of parent body disruption. This is consistent with the available Pb-phosphate data, where all but one Type 6 chondrite (H, n=3; L, n=4) yields a cooling age within a narrow 4505±5Ma timeframe. These data collectively imply that both the H and L chondrite parent bodies were catastrophically disrupted at ∼60Ma. In addition, combined Ni-metal and Pb-phosphate models confirm that a subset of Type 4 chondrites record early rapid cooling likely associated with erosional impacting of the H and L parent bodies on ∼5Ma timescales.