The mathematical models for distribution processes related to organizing precautionary measures in the event of threats or occurrences of man-made emergencies are presented. The tasks include optimal zoning of territories with the fixing of zones by objects of social purpose for service provision. Provision is made for: the possibility of overlapping zones in case the nearest center cannot provide the service; optimal placement of a certain number of new cen-ters of emergency logistics systems with simultaneous redistribution of the load on all their structural elements; the selection of locations of structural subdivisions based on existing fa-cilities. The optimality criteria involve minimizing either the time to provide the service even to the most remote object in the given territory, or the total distance to the nearest centers from consumers that are densely distributed in the given territory, and/or the organizational costs associated with the arrangement of new centers. Mathematical models are proposed in the form of continuous problems of optimal multiplex partitioning of sets with a linear or minimax functional of quality. The latter provides such placement of centers that provides op-timal multiple coverage of the territory (with a minimum radius of multiple coverage). Meth-ods for solving the formulated problems were developed using LP-relaxation of linear prob-lems with Boolean variables, duality theory to reduce the initial problems of infinite-dimensional programming to problems of conditional optimization of a non-smooth function of several variables, and modern methods of non-differentiated optimization.