This paper proposed a novel split thermoelectric system coupled with a photovoltaic panel for electric vehicle seats. The system separates the hot and cold ends of the thermoelectric device over a long distance with the flexible intermediate conductor, which solves the problem of poor heat dissipation at the hot end resulted from the integration of traditional TEC with the vehicle seats and improves the cooling and heating performance. A three-dimensional heat transfer model was established by COMSOL software to study the temperature field and the comprehensive performance. The results demonstrate that the system can maintain the seat temperatures in 27–30 °C in summer and 18–25 °C in winter, and there exists an optimum input power to maximize the COP. In addition, the seat temperature can be reduced from 60 °C to 31 °C in just 20 min under maximum heating load. The system performance is closely linked to the structure of the middle conductors, heat dissipation, solar radiation intensity, and ambient temperature. In winter, the power consumption of the system is reduced by about 84 % compared to the positive temperature coefficient thermistor with the COP being increased by 5.17. The contribution of the photovoltaic panel based on the studied conditions can save about 215.26 kWh of energy per year, and increase the driving distance of electric vehicles by approximately 1435 km.