We use frequency-comb-based optical two-way time-frequency transfer (O-TWTFT) to measure the optical frequency ratio of state-of-the-art ytterbium and strontium optical atomic clocks separated by a 1.5-km open-air link. Our free-space measurement is compared to a simultaneous measurement acquired via a noise-cancelled fiber link. Despite nonstationary, ps-level time-of-flight variations in the free-space link, ratio measurements obtained from the two links, averaged over 30.5 hours across six days, agree to 6×10−19, showing that O-TWTFT can support free-space atomic clock comparisons below the 10−18 level.Received 1 June 2020Accepted 4 August 2020DOI:https://doi.org/10.1103/PhysRevResearch.2.033395Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.Published by the American Physical SocietyPhysics Subject Headings (PhySH)Research AreasAtomic, optical & lattice clocksOptics & lasersAtomic, Molecular & Optical
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