Optical Petrography Research Articles

Development of fluid pathways and associated diagenetic variations in a natural CO2 leaking fault zone.

Abstract Permeability within fault zones can vary through time due to repeated deformation events and rock–fluid interactions. Understanding the history of fault zone alteration is critical when building hydrogeologic models and evaluating the risk of mechanical rock failure during subsurface storage. Newly acquired drill core recovered within the fault damage zone and fault core of the Little Grand Wash fault (LGWF) is combined with observations from outcrop, optical petrography, computerized tomography image analysis, and ultrasonic velocity measurements to characterize the rock types and preserved structural deformation features within this fault zone. These data are used to understand the history of mechanical rock failure and mineralization associated with this fluid-charged fault system. We identify multiple structural features and use their cross-cutting relationships to understand the history of deformation and their association with changes in fault zone permeability and rock mechanical properties. At the LGWF zone, structural deformation features vary temporally and are used to recognize a decoupling between fault slip and fluid flow. The formation of most open-mode veins occurred after shear failure within the LGWF zone. Early-developed shear bands are cut by carbonate veins, that are in turn cut by shear fractures, followed by a second phase of vein formation and ultimately by folding in the fault core. This sequence of formation reflects changes in mechanical rock properties due to subsurface rock–fluid interactions and indicates that the alteration of rock matrix by secondary carbonate cement results in increased unconfined compressive strength, decreased permeability, and increased ultrasonic velocity. In this fault zone, and possibly other fault zones, the changes in rock properties associated with deformation can be detected through their geophysical response.

Passive continental margin subducted to mantle depths: Coesite-bearing metasedimentary rocks from the Neoproterozoic Brasília Orogen, West Gondwana margin

In this contribution, we investigate the ultra-high pressure metamorphism (UHPM), and subsequent pressure–temperature-time (P-T-t) exhumation path recorded by granulites (rutile-kyanite-garnet-Kfeldspar and rutile-titanite-hornblende-garnet gneisses) of a coherent thrust package (Três Pontas-Varginha Nappe) of the southernmost edge of the Brasília Orogen. The Brasília Orogen, along with Northern Borborema Province, Dahomey, and Hoggar Belts, comprise a widespread linear system of orogens developed during the West Gondwana assembly, recording the diachronic closure of the Tonian-Ediacaran long-lived Goiás-Pharusian Ocean. Optical petrography, Raman spectroscopy, mineral chemistry, Ti-in-zircon and Zr-in-rutile thermometry, and U-Pb dating (LA-ICP-MS) of zircon, monazite, and rutile were combined to identify UHP minerals and textures and to track the decompression/exhumation path. Garnet porphyroblasts preserve UHPM chemical domains and are often radially fractured around rounded quartz inclusions. Remnants of microcoesite were detected by Raman spectroscopy within these inclusions, identified by the diagnostic bands at approximately 170 cm−1, 270 cm−1, and 520 cm−1. Coesite remnants were identified across the nappe stack along with 60° angle-oriented rutile needle inclusions in garnet, which suggests exsolution from Ti-bearing UHP garnets. Soccer ball zircon crystals of Ky-bearing granulites, with flat HREE pattern and negative Eu anomaly, yielded a U-Pb age of around 620 Ma. This age is interpreted as the record of the granulite facies metamorphism (750–805 °C and 15 kbar) post-dating the UHPM from the subduction channel. Zircon and monazite record exhumation under high temperatures around 595–590 Ma, and rutile crystals record the final stages of the decompression path from 590 to 585 Ma. Monazite crystallization occurred until 570 Ma. The new data combined with previously reported metamorphic paths, record a time interval of about 25 m.y. for the exhumation of the Tres Pontas-Varginha Nappe under subsolidus conditions. Our findings represent one of the oldest reports of Neoproterozoic coesite-forming UHPM recorded in metasedimentary rocks buried to mantle depths in the subduction of the passive continental margin.

Transition from a hydrologically partitioned to an integrated lake in the Cretaceous Junggar Basin, Central Asia

We report sedimentary microfacies analysis of Lower Cretaceous algal-laminated limestones interbedded with siliciclastic sediments in the Junggar Basin. We use these data to fill a knowledge gap in the Jurassic–Late Cretaceous paleoenvironmental and paleoclimate reconstructions of Central Asia. To decipher paleoenvironments and genetic mechanisms, we applied optical petrography, cathodoluminescence and fluorescence imaging, Raman spectroscopy, stable isotopic, and scanning electron microscopic analysis. Some oncoids exhibit alternating dark organic carbon-rich micrites and light sparry calcite laminae with unequal thicknesses and binding structures of microbiota. Formed by both algal binding and inorganic calcite precipitation, in-situ mixing happened during the formation of oncoidal, ooidal, and ostracodal grainstones in an agitated lakeshore and thromobolites in a relatively low-energy environment. Sparry carbonate cortices peeled off from the oncoids were transported to the shallow lake and densely packed with micrites and mud. Based on the degree of covariance between δ18O and δ13C and the wide range of δ18O, the paleo-lake was inferred to be a semi-open, shallow, and hydrologically partitioned lake in the Early Cretaceous, but evolved into a closed but well-mixed lake in the Late Cretaceous. We infer that this change is caused by the aridification in the Late Cretaceous. The Early Cretaceous lacustrine carbonates in the Junggar Basin show overall more positive δ13C than the counterparts in the Upper Cretaceous, which is attributed to the 12CO2 absorption by microbiota. Sulfate reduction is revealed by negative sulfur isotopes of concomitant thin-layered gypsums but it exerts no measurable impact on the δ13C of the carbonates.

Petrological Evolution and Mass Redistribution in Basaltic Fault Zones: An Example From the Faroe Islands, North Atlantic Igneous Province

AbstractFault rock petrology exerts an important influence on the permeability structure and mechanical properties of fault zones. Slip‐related deformation on upper‐crustal faults in basaltic rocks is closely associated with fluid‐rock interaction, altering the distribution of physical properties within the fault. Here, we present quantitative descriptions of the geochemical and petrological evolution of basalt‐derived fault rocks from three passively exhumed fault zones in the Faroe Islands. Fault‐rock petrology is determined by optical petrography and automated phase identification based on micrometer‐scale chemical maps from scanning electron microscope X‐ray spectroscopy. Geochemical evolution is assessed from major and trace element composition measured by X‐ray fluorescence. The fault rocks show intense fluid‐mediated alteration from a tholeiitic basalt protolith in the damage zones, and mechanical mixing in the fault cores. Pervasive alteration occurs early during fault zone evolution, with incipient fault damage increasing permeability and allowing along‐fault percolation of carbonated meteoric water, increasing fluid‐rock ratios. Our results suggest that the only mobile species within the fault zones are Ca, Si, and Al, which are leached during the hydrolysis of volcanic glass and plagioclase, and CO2, which is added by percolating waters. These species are transported from the damage zones into the fault cores, where they precipitate as zeolite and calcite cement in veins and hydrothermal breccias. We propose that solutes are replenished by cement dissolution through pressure‐solution during cataclastic creep, during repeated cycles of hydrofracture and cementation. The fault zones are natural reactors for fluid‐mediated alteration by CO2 and water, while other species are redistributed within the fault zones.

Black adzes in the Early Neolithic of Belgium: Contribution of the Raman microspectrometry and petrography in characterization and sourcing

Early Neolithic (Linear Pottery Culture) adzes originate from settlements and workshops accompany the neolithization of Belgium. They are made from a wide range of extraregional lithic raw materials such as metamorphic green rocks (amphibolite) and black volcanic rocks (“basalt’) beside more local or regional raw material as flints, light-coloured (sedimentary and lightly metamorphic) quartzites, black lydites (Cambrian nodular phtanite of Céroux-Mousty and Lower Namurian banded phtanites) and dark grey Lower Namurian silicified sandstones previously called “Micaceous sandstones of Horion-Hozémont’. The discovery of the workshop of Noirfontaine near the city of Liège in the 1970s and 1980s provides exceptional assemblage available for updating analytical studies. This research focuses on the multi-scale characterization, the discrimination and sourcing both Cambrian and Namurian black sedimentary rocks rich in secondary silica composing Early Neolithic adzes found in Belgium. Their black colour results from finely dispersed organic matter, but the absence of palynomorphs does not allow a biostratigraphic ascription. Additional petrographical analyses (Optical Petrography, Scanning Electron Microscope), X-ray diffraction, chemical analyses (Energy Dispersive Spectroscopy) and measuring the degree of graphitization of the organic matter through Raman microspectrometry have been decisive in identifying the geological and geographical provenances by comparing the acquired results with geological reference samples collected in the field or through reference collections. Cambrian lydites are coming from a very restricted area and were preferred to other more local rock sources.

Fingerprinting construction sand-supply networks for traceable sourcing

Globally increasing demand for construction sand needs to be met with transparent and responsible supply-networks. Currently, there are few scalable methods for tracing construction sand distribution without direct observation. He wee examined sand “fingerprinting” as a tool to trace construction sand supply-networks from “source to sink” in a case study from Texas, USA. Both natural bulk major element and optical petrography fingerprints are preserved through construction sand processing and transport such that sand can be tied back to its original mining source even at the final point of distribution. Additionally, we developed an image analysis model called sandID that is ~90% effective at determining the original mining source of sand in the study area. Our results demonstrate that sand fingerprinting, has untapped potential to support traceability and certification schemes and to support monitoring and enforcement in areas where there are concerns about illegal, illicit or simply unknown construction sand sourcing.

The Stonehenge Altar Stone was probably not sourced from the Old Red Sandstone of the Anglo-Welsh Basin: Time to broaden our geographic and stratigraphic horizons?

Stone 80, the recumbent Altar Stone, is the largest of the Stonehenge foreign “bluestones”, mainly igneous rocks forming the inner Stonehenge circle. The Altar Stone’s anomalous lithology, a sandstone of continental origin, led to the previous suggestion of a provenance from the Old Red Sandstone (ORS) of west Wales, close to where the majority of the bluestones have been sourced (viz. the Mynydd Preseli area in west Wales) some 225 km west of Stonehenge. Building upon earlier investigations we have examined new samples from the Old Red Sandstone (ORS) within the Anglo-Welsh Basin (covering south Wales, the Welsh Borderland, the West Midlands and Somerset) using traditional optical petrography but additionally portable XRF, automated SEM-EDS and Raman Spectroscopic techniques. One of the key characteristics of the Altar Stone is its unusually high Ba content (all except one of 106 analyses have Ba > 1025 ppm), reflecting high modal baryte. Of the 58 ORS samples analysed to date from the Anglo-Welsh Basin, only four show analyses where Ba exceeds 1000 ppm, similar to the lower range of the Altar Stone composition. However, because of their contrasting mineralogies, combined with data collected from new automated SEM-EDS and Raman Spectroscopic analyses these four samples must be discounted as being from the source of the Altar Stone. It now seems ever more likely that the Altar Stone was not derived from the ORS of the Anglo-Welsh Basin, and therefore it is time to broaden our horizons, both geographically and stratigraphically into northern Britain and also to consider continental sandstones of a younger age. There is no doubt that considering the Altar Stone as a ‘bluestone’ has influenced thinking regarding the long-held view to a source in Wales. We therefore propose that the Altar Stone should be ‘de-classified’ as a bluestone, breaking a link to the essentially Mynydd Preseli-derived bluestones.

Porosity characterization using medical computed tomography scans of two deeply buried paleokarst aquifers in Silurian carbonates, southern Ontario, Canada

Paleokarst and paleokarst aquifers are not as well-documented as shallow karst, and studies of pores and pore networks are rare. Paleokarst lacks the open conduits typical of karst due to compaction, infilling, and diagenetic recrystallization by deep burial, so groundwater movement is through matrix porosity. In this case study, porosity networks in two saline aquifers in carbonate paleokarst of the Silurian Guelph Formation and Salina A-1 Carbonate Unit in southern Ontario (Canada) have been studied in drill cores at microscopic to macroscopic scales, utilizing medical computed tomography (CT) scans, optical petrography, macroscopic core examination, and scanning electron microscopy. The CT scans provided nondestructive three-dimensional visualization and quantification of pore distribution, size and volume, pore connections, and estimates of total porosity, similar to gas porosimetry. In the A-1 Carbonate, 50% of the pore volume comprises layers of macropores associated with algal laminations, with good horizontal connections. In the Guelph Formation, vuggy macropores contribute most of the pore volume. They are connected through subvertical fractures and rubble-filled karst conduits and by abundant small pores and micropores with poor horizontal connections. The Guelph paleokarst represents a longer period of subaerial exposure as evidenced by its greater thickness and geographic extent, former karst conduits, and near-total destruction of primary sedimentary fabrics. The findings provide real-world examples for construction of laboratory scale models of paleokarst aquifers, demonstrate the value of a multi-scale approach to porosity studies, and showcase the value of medical CT scans with its unique ability to visualize pore connections within drill cores.

Vaterite Optical Petrography in Lake Sturgeon Otoliths

Abstract Vaterite occurring in fish otoliths exhibits plumose and spherulitic habits, the latter being like those grown from aqueous solutions. Vaterite spherulites are known to have sheaf-like texture and can be up to 100 μm in size. In thin section, the spherulites typically show uniaxial positive interference figures between cross-polarizers using a polarizing light microscope but without conoscopic or Bertrand lenses because the spherulites mimic the effect of these lenses. Plumose vaterite can show both uniaxial (+) and biaxial (+) interference figures with a small 2V, which suggests that crystal structural models for vaterite should have the plane of the carbonate group parallel to the optic axis or acute bisectrix. Vaterite spherulites grown from aqueous solution exhibit similar structure and growth habits.

Hydrothermal Alteration in the Nevados de Chillán Geothermal System, Southern Andes: Multidisciplinary Analysis of a Fractured Reservoir

The interplay between a heat source, primary plus secondary permeability, and hydrothermal fluids makes geothermal systems a highly dynamic environment where evolving physico-chemical conditions are recorded in alteration mineralogy. A comprehensive characterization of hydrothermal alteration is therefore essential to decipher the major processes associated with geothermal system development. In this study, we defined the hydrothermal mineralogical evolution of the Nevados de Chillán Geothermal System (NChGS), located in the Southern Volcanic Zone (SVZ) of the central Andes, where the regional framework of the system is formed by a direct association with a currently active volcanic complex, a favorable structural control, and vertically inhibited fluid circulation. To characterize the secondary mineralogy present in the NChGS, we integrated optical petrography, Scanning Electron Microscopy (SEM) observations, X-ray Diffraction (XRD) analysis, and microthermometric measurements along a drill core with a depth of 1000 m at the Nieblas-1 well. These mineralogical approaches were combined with a structural field analysis to highlight the relevance of multidisciplinary study in understanding active geothermal systems. The results indicated that the evolution of the system involved four paragenetic stages, with the main processes in each phase being the heating, boiling, and mixing of fluids and re-equilibration to new physico-chemical conditions. Additionally, three hydrothermal zones were recognized: an upper argillic section, an intermediate sub-propylitic zone, and a deep propylitic domain. Sampled thermal springs are characterized by pH values of 2.4–5.9 and high SO4= concentrations (>290 ppm). These acid-sulfate steam-heated waters suggest the contribution of primary magmatic volatiles to the hydrothermal system. Alunite recorded in the alteration halos of veinlets presents at depths of 170–230 m denote the circulation of acidic fluids at these levels which were favored by reverse faults. These findings indicate that, at this depth range, the condensation of magmatic volatiles into shallow aquifers controls the recharge area of the superficial thermal manifestations. Conversely, deep-seated hydrothermal fluids correspond to near-neutral chloride fluids, with salinities ranging from 0.1 to 6.9 wt.% NaCl eq. The distribution of illite/smectite and chlorite/smectite mixed-layered minerals outline the presence of a significant clay cap, which, in this system, separates the steam-heated domain from the deep hydrothermal realm and restricts fluid circulation to existing permeable channels. Our mineralogical and structural study provides critical data for the interpretation of heat–fluid–rock interaction processes in the NChGS. The interplay between hydrothermal fluids and active faults is also discussed in the context of the complex of geological processes in active geothermal systems along the Chilean Southern Volcanic Zone.

Iron Age sites in northern Botswana’s Okavango Delta 2: the Xaro sites in the Panhandle of the river-delta system

ABSTRACT The Xaro sites are located in the Okavango Delta Panhandle of northwestern Botswana. All have an upper component with pottery identical to that made by nineteenth-century and current Mbukushu potters. Xaro 1 also has European glass beads for which cited historical documents provide calendar year dates of between 1850 and 1890. Other historical documents place the Xaro 1 Mbukushu settlement from the 1890s into the early twentieth century. All three Xaro Early Iron Age components have pottery motifs common at Tsodilo and Cubango sites on the basis of which a date range of the late sixth/early eighth centuries AD for Xaro 1 is most likely, while several pottery distinctions suggest a chronological separation within the same range for Xaro 2 and 3. Xaro Early Iron Age pottery has two unique features not discernible by the unaided eye but identified by microscopic optical petrography: 1) a red iron oxide veneer approximately two microns thick on outer surfaces; and 2) a variably thick post-deposition deposit of caliche derived from calcite suspended in Okavango water. A third uniqueness is an SEM estimated firing temperature of at least 1000˚C, much higher than the ±800˚C common for southern African vessels. Two Xaro burials provide aDNA data on Early Iron Age people in southern Africa; discriminant analysis of multiple variables determined that no present-day population sampled so far has the same ancestry mix, probably reflecting a northern genetic influence and offering genetic support to the hypothesis of a pre-Bantu expansion of pastoralists into southern Africa.

Paragenesis of an Ediacaran carbonate-platform phosphorite: Constraints from optical petrography and texture-specific clumped isotope paleothermometry

The Salitre Formation is comprised of several hundred meters of primarily carbonate rocks, representing sedimentation in an intracratonic foreland basin during the Ediacaran Period (c. 600–550 Ma). The lowermost member of the Salitre Formation contains sedimentary phosphorite deposits, in which the dominant phosphate-bearing phase is cryptocrystalline carbonate-rich fluorapatite (CFA) cement. These CFA cements occur exclusively associated with digitate stromatolite buildups, decimeters to meters in vertical and lateral scale, which interfinger with cross-stratified grainstone. Notably, there are also non-phosphatic stromatolite buildups in close proximity to the phosphatic, in the same depositional facies. This implies that the mechanisms that control the distribution of phosphate cement development versus carbonate cement development are not driven by the location of depositional facies within the architecture of the Salitre paleobasin. Other models which could explain the distribution and style of phosphate mineralization there include: (1) differential diagenesis involving diagenetic fluids which infiltrate one lithofacies more pervasively than another to effect the replacement of primary cement mineralogies according to microtextural differences, and (2) differences in primary porewater chemistries over minute spatial scales which result in the formation of different primary cement phases. In this study, we present paired petrographic thin sections and novel measurements of ∆47, δ13Cmineral, and δ18Omineral. We provide a paragenetic framework for phosphatic and non-phosphatic lithofacies of the Salitre Formation which constrains the thermal and chemical alteration history of CFA, calcite, and dolomite cements. Structural carbonate in the CFA and calcite cements co-occurring in partially phosphatic digitate stromatolite buildups and adjacent carbonate grainstone generally yield similar δ13Cmineral values (0–5 ‰ VPDB), δ18Omineral values (−5–0 ‰ VPDB), as well as similar ∆47 temperatures (90–115 °C) and calculated δ18Owater (10–19 ‰ VSMOW), supporting a scenario in which CFA and calcite formed and then both recrystallized in equilibrium with the same diagenetic fluids under low water–rock ratio conditions at depth. Dolomite cements yielded similar δ18Omineral values to CFA and calcite, and similar to slightly higher temperatures (85–150 °C) — supporting a scenario in which dolomite cements were recrystallized in equilibrium with a different, and isotopically lighter, generation of fluids. Given the general absence of pervasive, fabric-destructive replacement is scarce, these geochemical data do not support later stage, differential diagenesis as a mechanism for controlling the distribution of phosphatic versus non-phosphatic cements. Rather, primary differences in porewater biogeochemistry seem the likeliest explanation. This is important, as it implies that the ecology of the Ediacaran seafloor controlled the style and quality of mineralization observed today, and that the presence of CFA cements in these rocks represents a unique taphonomic window for select microbial communities.

A Multi-proxy Provenance Study of Late Carboniferous to Middle Jurassic Sandstones in the Eastern Sverdrup Basin and Its Bearing on Arctic Palaeogeographic Reconstructions

A multi-proxy provenance study of Late Carboniferous to Middle Jurassic sandstones from the eastern Sverdrup Basin was undertaken employing optical petrography and heavy mineral analysis, chemical analysis of apatite, garnet and rutile grains, as well as detrital zircon U–Pb geochronology and Hf isotope analysis. Late Carboniferous to Middle Jurassic strata on the southern basin margin are inferred as being predominantly reworked from Silurian to Devonian strata within the adjacent Franklinian Basin succession. Higher-grade metamorphic detritus appeared during Middle to Late Triassic times and indicates exhumation and erosion of lower (Neoproterozoic to Cambrian) levels within the Franklinian Basin succession and/or a direct detrital input from the Canadian-Greenland Shield. The provenance of northern-derived sediments is more enigmatic owing to the subsequent opening of the Arctic Ocean. Northern-derived Middle Permian to Early Triassic sediments were likely derived from proximal areas of the Chukotkan part of the Arctic Alaska-Chukotka microplate. Late Triassic northern-derived sediments have different detrital zircon U–Pb age spectra from Middle Permian to Early Triassic ones and were likely derived from the Uralian orogenic belt and/or the Arctic Uralides. The loss of this sand input during latest Triassic times is interpreted to reflect drainage reorganisation farther upstream on the Barents Shelf. Middle Jurassic sands in the northern and axial parts of the basin were largely reworked from local northern-derived Late Triassic strata. This may have been facilitated by rift flank uplift of the northern basin margin in response to rifting in the adjacent proto-Amerasia Basin.

Depositional controls on diagenetic evolution of the Lower Cretaceous Wealden Sandstones (Wessex Basin, southeast England)

Depositional processes hold crucial controls on the diagenetic processes, events and evolution in sedimentary basins. Using the example of non-marine, Lower Cretaceous Wealden Sandstones from Wessex Basin in southeast England, this study reveals the depositional controls on diagenetic evolution in a sedimentary basin. Seventy-four surface samples, from 6 field locations across the Wessex Basin in Dorset and Isle of Wight were subjected to laboratory analyses such as optical petrography, scanning electron microscopy and Quantitative Evaluation of Minerals by Scanning Electron Microscopy analysis. The degree of compaction in the Wessex Basin sandstones includes moderate packing with most grains in a mix of point and long contact, with rare grains displaying concave-convex or non-grain contact and a loose packing dominated by non-grain contacts, with minor point and long contacts. The authigenic mineral phases identified in the sandstones are quartz, kaolinite, calcite and halite in decreasing abundance. The dissolution of felspars observed in the Wessex Basin sandstones possibly provided the main source of silica for the quartz overgrowths, with silica sources adjacent to the site of cementation. The small amount of quartz overgrowths may have formed during shallow burial. The partial dissolution of quartz observed in the Wessex Basin sandstones is considered likely to be the result of flushing of organic-compound rich waters derived from shale interbeds, under low temperature conditions (c. 25–50 °C). The precipitation of authigenic minerals within the Wessex Basin had a limited impact on the porosity and permeability of sandstones. Detrital mineralogy appears to be the main depositional control on diagenesis and may also explain the low abundance of authigenic kaolinite in the Wessex Basin. Similarly, the shallow burial depth of the sandstones is considered to be the main factor inhibiting more pervasive quartz cementation within the basin.

Exotic Carbonate Mineralization Recovered from a Deep Basalt Carbon Storage Demonstration.

Mitigating climate change requires transformational advances for carbon dioxide removal, including geologic carbon sequestration in reactive subsurface environments. The Wallula Basalt Carbon Storage Pilot Project demonstrated that CO2 injected into >800 m deep Columbia River Basalt Group flow top reservoirs mineralizes on month-year timescales. Herein, we present new optical petrography, micro-computed X-ray tomography, and electron microscopy results obtained from sidewall cores collected two years after CO2 injection. As no other anthropogenic carbonates from geologic carbon storage field studies have been recovered, this world-unique sample suite provides unparalleled insight for subsurface carbon mineralization products and paragenesis. Chemically zoned nodules with Ca/Mn-rich cores and Fe-dominant outer rims are prominent examples of the neoformed carbonate assemblages with ankerite-siderite compositions and exotic divalent cation correlations. Paragenetic insights for the timing of aragonite, silica, and fibrous zeolites are clarified based on mineral texture and spatial relationships, along with time-resolved downhole fluid sampling. Collectively, these results clarify the mineralogy, chemistry, and paragenesis of carbon mineralization, providing insight into the ultimate fate and transport of CO2 in reactive mafic-ultramafic reservoirs.

Depositional and diagenetic control on conglomerate reservoirs: An example from the fourth member of shahejie formation in the Lijin Sag, Bohai Bay Basin, east China

The lacustrine conglomerate reservoirs of the Lijin sag, Bohai Bay Basin, East China, were studied to understand the roles of depositional and diagenetic events on reservoir quality, using integrated seismic data, well logs, core observations, optical petrography, SEM-EDS, cathodoluminescence, and fluid inclusion microthermometry. The results show a fan delta with well-connected conglomerate bodies deposited during a highstand system tract (HST) and a nearshore subaqueous fan with weakly connected conglomerate bodies deposited in a transgressive system tract (TST). The conglomerates are mainly classified as feldspathic litharenite. The porosity and permeability of the fan delta vary from 0.1% to 17.4% and 0.01 to 457.6 mD, respectively. The porosity and permeability vary from 2.02 to 16.2% and 0.02 to 237.2 mD in the nearshore subaqueous fan. Mechanical compaction, dissolution, and cementation together are noteworthy diagenetic processes. Compaction is the dominant factor in reducing porosity; cementation has a destructive effect, while dissolution improves reservoir quality. Feldspar dissolution leads to kaolinite, illite, dickite precipitation, and deteriorating reservoir quality. The probable sources of meteoric water flux in the deep-burial environments are related to the falling lake level during the HST. Fluid inclusion analysis revealed that quartz overgrowths were formed during the mesodiagenetic stage. The depositional environment and grain sizes are essential factors controlling reservoir quality. The effect of grain size and sorting coefficients on reservoir quality varies as a function of retrogradation and progradation sequences. The higher the porosity and permeability, the coarser the particle sizes in the retrogradation sequences. In the progradation sequences, poorly sorted sediments have higher porosity and permeability than well-sorted sediments. The braided channel embodies the best reservoir quality in the TST, while the distributary channel represents the best reservoir in the HST.The formation mechanism of the high-quality reservoirs is ascribed to the sedimentary facies, compaction resistance, and mineral dissolution. Overall, the conglomerate reservoirs developed in the HST are relatively better than those in the TST because they have greater labile fragments, resulting in more dissolution. This study demonstrated that for successful assessment of conglomerate reservoirs in the Lijin area and similar reservoirs elsewhere, reservoirs characterization must link sequence stratigraphy, facies, and diagenesis to understand the high-quality reservoir distribution to support the predrill evaluation of reservoirs.

Combined use of conventional and clumped carbonate stable isotopes to identify hydrothermal isotopic alteration in cave walls

Alteration of conventional carbonate stable isotopes (δ18O, δ13C) in cave walls has been shown to be a useful tool to identify cave formation driven by deep-seated processes, i.e., hypogene karstification. If combined with a prior information on the paleowater stable isotope composition, further insights can be obtained on the temperature and the source of the paleowater. Clumped isotope composition (Δ47) of carbonates is an independent measurement of temperature, and if combined with the conventional stable isotopes, can provide information on the paleowater stable isotope composition. On the example of Provalata Cave (N. Macedonia), we apply for the first time, both conventional and clumped stable isotope analysis, and identify two different isotope alteration trends, reflecting two distinct hydrothermal events: an older, hotter one, where isotope alteration was likely related to isotope diffusion, lowering the δ18O values of the carbonate; and a younger one, related to the cave formation by low-temperature CO2-rich thermal waters, with dissolution-reprecipitation as the alteration mechanism, causing decrease in δ18O values, and unexpected increase in δ13C values. The findings are further corroborated by additional insight from optical petrography and cathodoluminescence microscopy, as well as fluid inclusion analysis of secondary calcite crystals related to the cave forming phase.

Measuring the shock stage of Itokawa and asteroid regolith grains by electron backscattered diffraction, optical petrography, and synchrotron X‐ray diffraction

AbstractOur goal was to devise a bridge between shock determinations of asteroid regolith grains by standard light optical petrography, synchrotron X‐ray diffraction (SXRD), and electron backscattered diffraction (EBSD). We determined the optimal conditions under which to measure the shock stage of olivine crystals in astromaterial grains by EBSD. We applied this EBSD procedure to the shock stage determination of four regolith grains from asteroid Itokawa, returned to earth by the Hayabusa spacecraft. Interpretation of these data required a parallel examination of three ordinary chondrite standards that exhibited shock histories ranging from stage 2 to stage 4, using all three techniques. Standard light optical petrography indicated shock stage of S2/3 for the 24 Itokawa grains analyzed. SXRD results for seven Itokawa grains indicate a shock stage of S2. EBSD maps of four Itokawa grains indicate shock stage S3. Thus, the different techniques indicate slightly different shock stages, probably due to small sampling populations for EBSD and SXRD. We therefore recommend that significantly more than seven regolith grains should be separately analyzed by any shock determination technique, probably between 10 and 20. In any case, Itokawa regolith grains have been shocked to stage S2/3, or approximately 5–10 GPa. Finally, we investigated the crystallinity of one Itokawa olivine by SXRD, determining that the 5–10 GPa shock it had experienced did not appreciably alter the size of the unit cell, contrary to some previous suggestions.

TO EXPLAIN THE NATURE OF CORE POROSITY USING RESULTS OF PETROGRAPHY ANALYSIS

The Permian to Triassic Tirrawarra Sandstone succession in the Cooper Basin of CentralAustralia is characterized by its low permeability. Ambient core porosity averages8.96% and ambient permeability 0.9 mD. Most samples studied have permeabilities lessthan 3mD. Despite its overall poor reservoir characteristics, the Tirrawarra Sandstone isone of the major oil and gas targets in Australia. A total of 17 core plugs from 6 wellswere studied petrographically using optical petrography, SEM and XRD. These resultswere integrated with core analysis data.Petrographic study revealed the diagenetic events, mainly mechanical and chemicalcompaction, cementation and alteration have modified the reservoir quality. Ductile componentssuch as rock fragments, clay and matrix influence mechanical compaction, whichare the main cause of reservoir quality reduction. Quartz cementation and clay distributionalso affected the porosity, but particularly permeability. Mechanical compaction aswell as quartz cementation have reduced and blocked pore-throats to isolate intergranularpores. The alteration of feldspar to kaolin has changed intergranular porosity tomicroporosity. Illite occurs as either cement, alteration of rock fragments or kaolinite. Allof these diagenetic events also affect fluid movement in the reservoir.This paper presents the evaluation of the determination of effectiveness of porosity inthe delivery of gas from sandstone reservoir in the Cooper Basin using integrated petrographyanalysis and core measurements.

DEVELOPMENT OF FIBROUS CALCITE VEINS RELATED TO HYDROCARBON GENERATION AND OVERPRESSURING IN ORGANIC‐RICH SHALE SOURCE ROCKS: THE VACA MUERTA FORMATION, NEUQUÉN BASIN, ARGENTINA

Fibrous calcite bed‐parallel veins (BPVs) are a typical feature of the Upper Jurassic – Lower Cretaceous Vaca Muerta Formation in the subsurface of the Neuquén Basin (Argentina). The formation is considered to be the main source rock in the basin as well as an important unconventional play. This study examines the growth of BPVs through an analysis of core from three wells located along a transect extending for some 150 km from the NE Platform near the basin margin in the east to the Agrio fold‐and‐thrust belt at the Andean deformation front in the west. The main objective is to integrate fluid inclusion data with the palaeothermal and palaeopresure evolution obtained from a regional‐scale 2D basin and petroleum systems model to examine the timing of fracture development and its relationship with hydrocarbon generation in the Vaca Muerta Formation through time.The apertures of BPVs were measured in more than 360 m of core from three wells (wells A, D and E). This data was combined with optical petrography to investigate the number of calcite cementation events, and the temperature of cement precipitation based on fluid inclusion data. The organic geochemical and mineralogical characteristics of the Vaca Muerta source rock were also analysed. The integrated results were incorporated into a poro‐elastic basin model to investigate the impact of horizontal shortening due to Andean compression on pore pressure development and fracturing in the Vaca Muerta Formation. This framework allowed the timing of BPV formation to be determined together with possible mechanisms governing overpressure conditions through time.Near the Andean deformation front in the west of the modelled section where the Vaca Muerta Formation is in the wet gas window (well D) and dry gas window (well A), BPVs are characterized by two or more generations of calcite fibres indicating multiple growth phases. Calcite which precipitated during cementation event 1 (E1) in the internal zones of BPVs consists of crystals oriented perpendicular to fracture walls, indicating perpendicular vein opening. Calcite precipitated during cementation event 2 (E2) in the outer zones of BPVs includes curved and oblique crystals. During this phase, shear occurred between the opening vein walls as a result of horizontal shortening. Cementation event 3 (E3) is characterized by an equant mosaic of calcite crystals which preserve intracrystalline porosity. E1cements formed between 110 and 90 Ma with trapping temperatures of ∼112 °C (upper Vaca Muerta, well A) and ∼125 °C (lower Vaca Muerta, well D). Fracturing resulted from disequilibrium compaction and from volumetric expansion due to primary cracking of kerogen within the oil window. E2 cements record a trapping temperature of ∼159 °C and formed between 70 and 55 Ma (lower Vaca Muerta, well D) during maximum burial of the Vaca Muerta Formation, synchronous with the secondary cracking of retained liquid hydrocarbons and the beginning of Andean compression. E3 cements (upper Vaca Muerta, well A) have a trapping temperature of ∼162 °C, and formed between 65 Ma and 53 Ma synchronous with the generation of thermogenic gas.By contrast, in the east of the modelled section in the less deformed foreland area of the Neuquén Basin where the Vaca Muerta Formation is in the early oil window (well E), BPVs are composed of a single generation of calcite fibres (E1)with a trapping temperature of ∼118 °C. The E1 cement is characterized by calcite crystals which are oriented perpendicular to fracture walls with no evidence of shearing. According to model simulations, cementation here occurred between 64 Ma and 53 Ma during maximum burial and was related to overpressures which resulted from both disequilibrium compaction and primary transformation of kerogen into oil.The data presented suggests that in some intervals of the Vaca Muerta Formation, a slight increase in TOC content is accompanied by an increase in vein thickness, with the highest number of cementation events occurring towards the Andean deformation front in the west of the study area compared to the foreland in the east.