Opposite Contributions Research Articles

First-principle study of the ground-state crystal structure and optoelectronic response of CsPbX3 (X= Cl, Br, I) for photovoltaic applications

The optoelectronic response and ground state crystal structure of tetragonal (P4/mbm), orthorhombic (Pmnb) and monoclinic (P21/m) phases of CsPbX3 (X = Cl, Br, I) are studied for optoelectronic applications using first principle simulations. Electric field gradient (EFG) and magnetic hyperfine interactions are investigated to explore the charge distributions surrounding the nucleus and local magnetic environment of the atomic nucleus. The orthorhombic phase of these compounds is more stable having lowest ground-state energy compared to tetragonal and monoclinic phases. The understudied halide perovskites have direct band gap nature and spin orbit coupling (SOC) effect splits Pb-p and X-p orbitals at the edges of conduction and valence band (CB and VB) respectively. At the edge of VB, the strongly hybridized X-p and Pb-p orbital and direct band gap nature of CsPbX3 is excellent for the light absorption and photovoltaic (PV) applications. The n-i-p configuration (FTO/ETL/CsPbX3/HTL/Au) of the simulated structure shows that CsPbI3 has improved power conversion efficiency (PCE) of 22.48 % and 22.32 % and quantum efficiency (QE) about ∼80 % in tetragonal and monoclinic phases respectively. The Pb and Cs values of EFG tensor in z-direction (Vzz) are close to each other, which show that the distribution of electronic charge density is similar near these nuclei. Moreover, Cs-s orbital has negligible contribution and Pb-p and I-p orbitals have higher contribution in the hyperfine field (HFF). The negative HFF indicates the opposite HFF contribution.

Valley-Dependent Electronic Properties of Metal Monochalcogenides GaX and Janus Ga2XY (X, Y = S, Se, and Te).

Two-dimensional (2D) materials have shown outstanding potential for new devices based on their interesting electrical properties beyond conventional 3D materials. In recent years, new concepts such as the valley degree of freedom have been studied to develop valleytronics in hexagonal lattice 2D materials. We investigated the valley degree of freedom of GaX and Janus GaXY (X, Y = S, Se, Te). By considering the spin-orbit coupling (SOC) effect in the band structure calculations, we identified the Rashba-type spin splitting in band structures of Janus Ga2SSe and Ga2STe. Further, we confirmed that the Zeeman-type spin splitting at the K and K' valleys of GaX and Janus Ga2XY show opposite spin contributions. We also calculated the Berry curvatures of GaX and Janus GaXY. In this study, we find that GaX and Janus Ga2XY have a similar magnitude of Berry curvatures, while having opposite signs at the K and K' points. In particular, GaTe and Ga2SeTe have relatively larger Berry curvatures of about 3.98 Å2 and 3.41 Å2, respectively, than other GaX and Janus Ga2XY.

Thermoelectric properties of graphene through BN-ring doping: A theoretical investigation

Although graphene presents excellent transport properties, its potential for thermoelectric applications is still limited due to its low Seebeck coefficient and high thermal conductivity. Efforts to enhance its thermoelectric properties have involved the usage of carbon-based nanoribbons (Zheng et al., 2012; Hossain et al., 2016) [1,2], strain engineering (Nguyen et al., 2015), and heteroatom co-doping, particularly with nitrogen and/or boron atoms (Wang et al., 2018) [3]. In this work, multiscale simulation approaches combining density functional theory calculations and semi-empirical models are used to investigate the thermoelectric properties of graphene via borazine (B3N3)-ring doping. In particular, the bandgap engineering obtained by this doping technique (Caputo et al., 2022) can separate opposite electron and hole contributions and therefore results in a significant enhancement of the Seebeck effect and, accordingly, of the power factor. The results obtained are not only dependent on the concentration of B3N3 rings but are also notably influenced by their orientation configuration. Furthermore, the effects of distribution and rotational disorders are also considered, clarifying the thermoelectric properties of realistic systems. Lastly, the thermal lattice conductance is estimated revealing a substantial reduction of up to 40% compared to pristine graphene opening up the possibility of enhancing the thermoelectric efficiency of BNC materials. The present theoretical approach highlights how BN-ring doping can refine the thermoelectric properties of graphene, offering a pathway for enhancing its suitability in practical thermoelectric applications.

Responses of Intraspecific and Interspecific Trait Variations to Nitrogen Addition in a Tibetan Alpine Meadow.

A community functional structure may respond to environmental changes such as nitrogen (N) enrichment by altering intraspecific and interspecific trait variations. However, the relative contributions of both components in determining the community response to N enrichment are unclear. In this study, we measured the plant height (H), leaf area (LA), leaf dry matter content (LDMC), and specific leaf area (SLA) based on a nine-year N addition gradient experiment in an alpine meadow on the Tibetan Plateau. We examined the intraspecific and interspecific variations within and among the communities, the responses of traits in terms of community weighted mean (CWM) and non-weighted mean (CM) to N addition, and the effects of these trait variations on aboveground net primary productivity (ANPP). Our results show that N addition increased the interspecific variation in H while decreasing that of LA within the community, whereas it had no significant effects on the intraspecific variations in the four traits within the community. In contrast, N addition significantly increased the intraspecific variation in H and decreased that of LA among the communities. Moreover, the contribution of intraspecific variation was greater than that of the interspecific variation in terms of CWM for all traits, while the opposite contribution was observed in terms of CM, suggesting that the dominant species would have greater resilience while subdominant species would become less resistant to N addition. Further, intraspecific variations of LA and LDMC within the community played an important role in explaining community productivity. Our results highlight the importance of both intraspecific and interspecific variations in mediating functional trait responses to N enrichment, and intraspecific variation within the communities has important implications for community functioning that should be considered to better understand and predict the responses of the alpine grasslands to N enrichment.

A disinhibitory microcircuit of the orbitofrontal cortex mediates cocaine preference in mice.

Both clinical and animal studies showed that the impaired functions of the orbitofrontal cortex (OFC) underlie the compulsive drug-seeking behavior of drug addiction. However, the functional changes of the microcircuit in the OFC and the underlying molecular mechanisms in drug addiction remain elusive, and little is known for whether microcircuits in the OFC contributed to drug addiction-related behaviors. Utilizing the cocaine-induced conditioned-place preference model, we found that the malfunction of the microcircuit led to disinhibition in the OFC after cocaine withdrawal. We further showed that enhanced Somatostatin-Parvalbumin (SST-PV) inhibitory synapse strength changed microcircuit function, and SST and PV inhibitory neurons showed opposite contributions to the drug addiction-related behavior of mice. Brevican of the perineuronal nets of PV neurons regulated SST-PV synapse strength, and the knockdown of Brevican alleviated cocaine preference. These results reveal a novel molecular mechanism of the regulation of microcircuit function and a novel circuit mechanism of the OFC in gating cocaine preference.

Entropy-Enthalpy Compensation in Electron-Transfer Processes.

Solvent reorganization energies, free energies, and entropies are obtained for photoexcitation of three molecules that exhibit strong solvatochromism [Nile red, 5-(dimethylamino)-5'-nitro-2,2-bisthiophene, and Reichardt's dye B30] by measuring their optical absorption spectra at temperatures between 150 and 300 K in solvents with a range of polarities. Energies, free energies, and entropies of solvent reorganization are also obtained from computer simulations of three intramolecular electron-transfer reactions (charge separation and recombination in Zn-porphyrin-quinone cyclophane and charge transfer in a bis-biphenylandrostane radical anion). Entropy-enthalpy compensation in the solvent reorganization free energy for photoexcitation or electron transfer is found to be essentially complete (having nearly equal and opposite contributions from entropic and enthalpic effects) for all of the processes with solvent reorganization energies less than about 0.1 eV. Compensation becomes less complete as the reorganization energy becomes larger. A semiclassical treatment of the solvent reorganization entropy can rationalize these results.

Uncertain Benefits of Using Remotely Sensed Evapotranspiration for Streamflow Estimation—Insights From a Randomized, Large-Sample Experiment

Remotely sensed evapotranspiration (ETRS) shows promise for enhancing hydrological models, especially in regions lacking in situ streamflow observations. However, model calibration studies showed conflicting results regarding the ability of ETRS products to improve streamflow simulation. Rather than relying on model calibration, here we produce the first randomized experiment that explores the full streamflow–ET skill distribution, and also the first probabilistic assessment of the value of different global ETRS products for streamflow simulation. Using 280,000 randomized SWAT (Soil and Water Assessment Tool) model runs across seven catchments and four ETRS products, we show that the relationship between ET and streamflow skills is complex, and simultaneous improvement in both skills is only possible in a limited range. Parameter sensitivity analysis indicates that the most sensitive parameters can have opposite contributions to ET and streamflow skills, leading to skill trade-offs. Conditional probability assessment reveals that models with good ET skills are likely to produce good streamflow skills, but not vice versa. We suggest that randomized experiments such as ours should be performed before model calibration to determine whether using ETRS is worthwhile, and to help in interpreting the calibration results.

Impacts of global biogenic isoprene emissions on surface ozone during 2000–2019

Biogenic isoprene is an important precursor of tropospheric ozone (O3). Here, a coupled chemistry–vegetation model was used to quantify the contributions of isoprene emissions to surface O3 pollution on the global scale during 2000–2019. The biogenic isoprene emissions showed high values in mid–low latitudes and seasonal peaks in the summer hemispheres. They promote global surface O3 concentrations by 1.75 ppbv annually with regional hotspots of 4.39 ppbv (8.8%) in China and 5.36 ppbv (11.1%) in the U.S. in boreal summer. In the past two decades, isoprene emissions increased by 1.32 TgC yr−1 (0.67% yr−1) in the Northern Hemisphere but decreased by 0.71 TgC yr−1 (0.44% yr−1) in the Southern Hemisphere. Such changes of isoprene made opposite contributions to the surface O3 trend, with 0.26 ppbv yr−1 in eastern China but −0.32 ppbv yr−1 in the southeastern U.S. due to the changes in the background regime of chemical reactions. The impact of anthropogenic changes on the O3 trend is consistent with that of biogenic isoprene, but two to four times stronger in magnitude. This study revealed that the effective control of anthropogenic NOx emissions could mitigate regional O3 pollution even with the increased isoprene emissions under global warming.

Effects of Storage in an Active and Spontaneous Controlled O2/CO2 Atmosphere on Volatile Flavor Components and the Microbiome of Truffles.

This study explored the potential to improve the storage quality and prolong the shelf life of truffles by storing them in a modified atmosphere fresh-keeping box with sealed gas components of Active Modified Atmosphere Packaging (AMAP, 40% O2 + 60% CO2) at 4 °C. During the storage period, a total of 63 volatile components in 10 categories were detected, with aldehydes being the most abundant and the relative content of ethers being the highest. The relative odor activity value and principal component analysis revealed that isovaleraldehyde, 1-octen-3-ol, 1-octen-3-one, and dimethyl sulfide were the characteristic flavor components of fresh truffles. However, 3-methylthiopropionaldehyde and (E, E)-2,4-nonadienal were the components that caused the deterioration of truffle flavor and could potentially serve as markers of truffle decay characteristics. 16S rDNA high-throughput sequencing showed that Leuconostoc and Lactococcus were dominant in the truffle samples stored for 14 days, but the abundance of putrefactive pathogenic bacteria showed an increasing trend in the truffle samples stored for 28 days. During the whole storage period, the common fungi detected in the different treatment groups were Candida and Aspergillus. The relative abundance of the former decreased, while the relative abundance of the latter decreased initially and then increased. The correlation between volatile components and the microbial flora was further analyzed, which indicated that Lactococcus and Lactobacillus had the same contributions to the same flavor, while Pseudomonas and Glutamicibacter had the opposite contributions to the same flavor. The results provide a reference for the storage and preservation of truffles.

Molecular Simulation Study on the Effect of Co-Associated Minerals on Methane Adsorption and Mechanical Properties of Coal

When rockbursts and coal and gas outbursts simultaneously occur in a coal mine, changes in gas adsorption (concentration of ambient methane) and displacement of coal and rock must occur. The co-associated minerals in coal reservoirs can affect the mechanical properties and methane adsorption capacity, which are commonly disregarded. It is important to construct compound molecular structure models of coal and rock and conduct molecular dynamic simulations to gain a microscopic understanding of underground disasters. In this work, the molecular structure models of anthracite and coking coal–rock compound models containing different contents of calcite and kaolinite were constructed, and the methane adsorption amount and mechanical properties considering temperature, pressure, and mineral contents were simulated and analysed. The results showed that the methane adsorption amount of the compound models increased rapidly, then increased moderately, and stabilized eventually with increasing adsorption pressure, and the Langmuir fitting findings were good. The saturation adsorption amount of methane in the coal models linearly decreased with increasing temperature, while the methane adsorption heat increased. The presence of minerals adsorbed a certain amount of methane, and the methane adsorption amount increased with increasing mineral contents. The mechanical properties of coal molecules changed when mineral molecules such as calcite and kaolinite were present, which had opposite contribution effects. The addition of kaolinite minerals to the coal molecular model always increased the bulk modulus and shear modulus, while the addition of calcite decreased the bulk modulus of the anthracite, causing an increase in the brittleness of the models. The results of the study further explain the adsorption behaviour and mechanical properties of methane in coal and minerals.

Neutron stars as photon double-lenses: Constraining resonant conversion into ALPs

Axion-photon conversion is a prime mechanism to detect axion-like particles that share a coupling to the photon. We point out that in the vicinity of neutron stars with strong magnetic fields, magnetars, the effective photon mass receives comparable but opposite contributions from free electrons and the radiation field. This leads to an energy-dependent resonance condition for conversion that can be met for arbitrary light axions and leveraged when using systems with detected radio component. Using the magnetar SGR J1745-2900 as an exemplary source, we demonstrate that sensitivity to |gaγ|∼10−12GeV−1 or better can be gained for ma≲10−6eV, with the potential to improve current constraints on the axion-photon coupling by more than one order of magnitude over a broad mass range. With growing insights into the physical conditions of magnetospheres of magnetars, the method hosts the potential to become a serious competitor to future experiments such as ALPS-II and IAXO in the search for axion-like particles.

Effect of xenon, an apolar general anaesthetic on the properties of the DPPC bilayer

The effect of xenon, a general anaesthetic, on the properties of the fully hydrated dipalmitoylphosphatidylcholine (DPPC) bilayer is investigated by molecular dynamics simulations with two different force fields. Considering the well-known pressure reversal of the anaesthetic effect, we are looking for such changes that are reverted by the increase of the pressure, and hence can be relevant in explaining the molecular mechanism of general anesthesia. The results show that, besides its main preference for staying in the middle of the membrane, xenon also has a secondary preference for positions at the outer boundary of the hydrocarbon region, close to the crowded domain of the polar headgroups. This outer preference is a result of the interplay of the increasing attraction the xenon atoms experience and the decreasing free volume available for them upon going away from the middle of the membrane. It also turns out that any change that might be relevant in explaining the anaesthetic effect is related to xenon atoms staying in this outer preferred position. Since the model we employed does not account for the polarizability of the xenon atoms, and hence misses a part of the thermodynamic driving force of the preference for this outer position, all results should be considered as a lower bound estimate of the real effect. It is found that the xenon atoms induce a lateral swelling of the membrane by pushing the DPPC molecules farther away from each other, which, due to the insensitivity of the membrane thickness to the presence of xenon, naturally results in an increase of also the membrane volume. On the other hand, pressure increases the membrane thickness by increasing the order of the lipid tails, while it also causes a lateral shrinking of the bilayer. The net effect of these two opposite contributions is still a decrease of the membrane volume. In the light of these results, we propose to refine the 70 years old ‘critical volume hypothesis’ to a ‘critical surface area hypothesis’, claiming that general anesthesia occurs if the molar surface area of the membrane exceeds a critical value. Finally, the xenon-induced lateral swelling results in an increase of the empty space in the hydrocarbon region, allowing the DPPC molecules to move more freely, and hence increasing their lateral diffusion coefficient. All these changes are clearly reverted by pressure, and thus may well be relevant in respect of the molecular mechanism of general anesthesia.

Dual Properties of Microwave Absorption and Thermal Protection in La0.5Sr0.5FeO3–Al2O3 Pseudobinary Composites

As multifunctional material for microwave absorption and thermal protection, the dielectric and thermophysical properties of equilibrium phases in LSF(La0.5Sr0.5FeO3)–Al2O3 pseudobinary phase diagram are investigated herein. Four pseudobinary composites are obtained by sintering at 1400 °C for 10 h with different raw components (x wt% LSF‐(100−x) wt% Al2O3, x = 20, 40, 60 and 80), labeled as LSFA20, LSFA40, LSFA60, and LSFA80, respectively. After sintering, the main equilibrium phase in LSFA20 and LSFA40 composites is SrAl12O19‐based solid solution. For LSFA60 and LSFA80, however, LSF‐based and SrAl12O19‐based solid solutions are the main equilibrium phases. The increase of conductive LSF content results in the highest dielectric loss tangent and the best microwave absorbing property in LSFA80, in which the bandwidths for reflection loss less than −10 and −5 dB are about 2.37 and 7.7 GHz, respectively, when the thickness is only 1.5 mm. The thermophysical properties reveal that the thermal conductivity in LSF‐Al2O3 pseudobinary composites shows weak temperature dependence because of the opposite contribution between phonons and electrons. It is lower than that of the traditional thermal barrier coating material of 8 wt% Y2O3‐stabilized zirconia (8YSZ).

Evaluation of contributors to amide proton transfer-weighted imaging and nuclear Overhauser enhancement-weighted imaging contrast in tumors at a high magnetic field.

The purpose is to evaluate the relative contribution from confounding factors (T1 weighting and magnetization transfer) to the CEST ratio (CESTR)-quantified amide proton transfer (APT) and nuclear Overhauser enhancement (NOE) (-3.5) in tumors as well as whether the CESTR can reflect the distribution of the solute concentration (fs ). We first provided a signal model that shows the separate dependence of CESTR on these confounding factors and the clean CEST/NOE effects quantified by an apparent exchange-dependent relaxation (AREX) method. We then measured the change in these effects in the 9-L tumor model in rats, through which we calculated the relative contribution of each confounding factor. fs was also fitted, and its correlations with the CESTR and AREX were assessed to evaluate their capabilities to reflect fs . The CESTR-quantified APT shows "positive" contrast in tumors, which arises primarily from R1w at low powers and both R1w and magnetization transfer at high powers. CESTR-quantified NOE (-3.5) shows no or weak contrast in tumors, which is due to the cancelation of R1w and NOE (-3.5), which have opposite contributions. CESTR-quantified APT has a stronger correlation with APT fs than AREX-quantified APT. CESTR-quantified NOE (-3.5) has a weaker correlation with NOE (-3.5) fs than AREX-quantified NOE (-3.5). CESTR reflects a combined effect of T1 weighting and CEST/NOE. Both factors depend on fs , which contributes positively to the dependence of CESTR on fs in APT imaging and enhances its correlation with fs . In contrast, these factors have opposite contributions to its dependence on fs in NOE (-3.5) imaging, thereby weakening the correlation.

Emission and influences of non-road mobile sources on air quality in China, 2000–2019

Non-road mobile sources (NRMS) are potential important contributors to air pollution in China. However, their extreme impact on air quality had been seldom studied. In this study, the emission inventory of NRMS in mainland China during 2000–2019 was established. Then, the validated WRF-CAMx-PSAT model was applied to simulate the contribution to the atmospheric PM2.5, NO3−, and NOx. Results showed that emissions increased rapidly since 2000 and reached a peak in 2014–2015, with an annual average change rate (AACR) of 8.7–10.0%; after then, the emissions were relatively stable (AACR, −1.4–1.5%). The modeling results indicated that NRMS has become a crucial contributor to the air quality in China: from 2000 to 2019, the contribution to PM2.5, NOx, and NO3− significantly increased by 131.1%, 43.9%, and 61.7%; and for NOx, the contribution ratio in 2019 reached 24.1%. Further analysis showed that the reduction (−0.8% and −0.5%) of the NOx and NO3− contribution ratios was much lower than that (−4.8%) of NOx emissions from 2015 to 2019, implying that the control of NRMS lagged behind the national overall pollution control level. The contribution ratio of agricultural machinery (AM) and construction machinery (CM) to PM2.5, NOx, NO3− in 2019 was 2.6%, 11.3%, 8.3% and 2.5%, 12.6%, 6.8%, respectively. Although the contribution was much lower, the contribution ratio of civil aircraft had the fastest growth (202–447%). Moreover, an interesting phenomenon was that AM and CM had opposite contribution sensitivity characteristics for air pollutants: CM had a higher Contribution Sensitivity Index (CSI) for primary pollutants (e.g., NOx), ∼1.1 times that of AM; while AM had a higher CSI for secondary pollutants (e.g., NO3−), ∼1.5 times that of CM. This work can provide a deeper understanding for the environmental impact of NRMS emissions and for the control strategy formulation of NRMS.

Effect of Phanerochaete chrysosporium inoculation on manganese passivation and microbial community succession during electrical manganese residue composting

Electrolytic manganese residue poses potentially threats to the environment and therefore needs eco-friendly treatment. Composting has been reported to effectively passivate heavy metals and alleviate their ecotoxicity. Observation of the Mn concentration during composting indicated that the mobility of Mn was significantly reduced, with the easily extraction fraction (acid extractable and easily reduction fraction) of Mn in the control pile (pile 1 without Phanerochaete chrysosporium inoculation) and treat pile (pile 2 with Phanerochaete chrysosporium inoculation) decreasing by 17% and 29%, respectively. The inoculation of Phanerochaete chrysosporium prompted the passivation of manganese, prolonged the thermophilic period, and enriched the microbial community structure, which was attributed to the rapid growth and reproduction of thermophilic bacteria. Moreover, Phanerochaete chrysosporium inoculation promoted the effect of pH on the stabilization of Mn, but the opposite contribution of organic matter. This study would provide a new perspective for remediating EMR contaminated soil via composting.

Bulk generalized Dzyaloshinskii-Moriya interaction in PT -symmetric antiferromagnets

The Dzyaloshinskii-Moriya interaction (DMI) in magnetic materials plays an important role in spintronics, giving rise to chiral spin textures such as the nucleation and propagation of domain walls and skyrmions. The necessary ingredient for the emergence of the DMI is the lack of inversion symmetry combined with elements with strong spin-orbit coupling. We report on a first-principles investigation of generalized DMIs in bulk centrosymmetric crystals with noncentrosymmetric local sublattices, where we consider a prototype family of $\mathcal{PT}$-symmetric antiferromagnets, including, ${\mathrm{Mn}}_{2}\mathrm{Au}$, ${\mathrm{MnPd}}_{2}$ and MnCuAs in the tetragonal and orthorhombic phases. We employ a Green's function approach to calculate the interatomic relativistic exchange coupling which can, in turn, determine the sublattice elements of the generalized fifth-order DMI tensor ${D}_{\ensuremath{\alpha}\ensuremath{\beta},\ensuremath{\gamma}}^{s{s}^{\ensuremath{'}}}$. We demonstrate that the breaking of the local mirror symmetry and the resulting local Rashba-type spin-momentum locking yield local DMIs with opposite signs on the two antiparallel sublattices. We present numerical results and provide analytical expressions for the magnon dispersion in the presence of the sublattice DMI and show that the intra- (inter-) sublattice DMIs result in identical (opposite) contributions to the nonreciprocal components of the two low-frequency antiferromagnetic magnon modes.

The Significant Influence of Cooling Rate and Intercritical Annealing Temperature on Austenite Stability and Relationship to Mechanical Behavior in Medium Manganese Steel

The influence of cooling rate and intercritical annealing temperature on austenite stability and mechanical properties of cold rolled Fe‐11Mn‐4Al‐0.2C steel are elucidated. The samples are intercritical annealed in the range of 700–900 °C for 5 min followed by either water‐quenched or furnace‐cooled. For 700–750 °C samples, the cooling rate has an insignificant influence on the mechanical properties. However, austenite in 800–900 °C water‐quenched samples is characterized by smaller grain size, lower Mn and C content and higher residual stress than the furnace‐cooled samples, which result in lower austenite stability, stronger transformation‐induced plasticity effect and higher ultimate tensile strength in water‐quenched samples. The specific contribution of factors relates to austenite stability is quantified. The contribution of grain size and elements is much higher than the residual stress. However, residual stress becomes a decisive factor because the opposite contribution of grain size and elements is almost offset.

Confidence and Uncertainty in Simulating Tropical Cyclone Long-Term Variability Using the CMIP6-HighResMIP

Abstract Confidence and uncertainty issues of simulations were seldom evaluated in previous studies although the climate models are widely used. This study evaluates the performance of the CMIP6-HighResMIP simulations in presenting long-term variability of tropical cyclone (TC) genesis frequency (TCGF) and track density (TCTD) and quantifies the relative contributions of internal and external forcing to TC activities during the 1950–2014. There is overall poor model performance in simulating long-term changes in TC activities over the Northern Hemisphere, including interdecadal variabilities and long-term linear trends. The simulated long-term changes in TCGF and TCTD over the eastern North Pacific (ENP) in six high-resolution models show opposite characteristics to the observations. Moreover, most models cannot capture the variabilities of TCGF and TCTD over the western part of the western North Pacific (WNP) and northern part of the North Atlantic (NA). However, these models show a high degree of confidence in reproducing the interdecadal variabilities and linear trends of TCGF and TCTD over the eastern part of the WNP and the tropical NA. Quantitative evaluations further show that there are the opposite relative contributions of long-term climate variabilities to TCGF and TCTD changes over the ENP between the observations and the multimodel ensemble mean, followed by large model biases over the western WNP and the northern NA, but relatively consistent contributions over the southern NA and the Caribbean. These results help us cope with contrasting and consistent future TC changes among the model projections. Significance Statement While climate models have been widely used to project future changes in tropical cyclone (TC) activity, few studies have examined to what extent we can trust these model projections. We used the CMIP6-HighResMIP simulations to quantify the model biases in presenting TC activity, and evaluate the relative contributions of internal and external forcing to TC activities. In general, the HighResMIP has large discrepancies in representing longer-term climate variability of TC activity. However, the models can capture well TC activity over the eastern part of the western North Pacific and tropical Atlantic, which is attributed to good performance of models in reproducing the relationship between long-term climate variabilities beyond interannual scale and TC activity. These results highlight confidence and uncertainty in future TC changes among the model projections.

Bilinear Magnetoresistance in HgTe Topological Insulator: Opposite Signs at Opposite Surfaces Demonstrated by Gate Control.

Spin-orbit effects appearing in topological insulators (TI) and at Rashba interfaces are currently revolutionizing how we can manipulate spins and have led to several newly discovered effects, from spin-charge interconversion and spin-orbit torques to novel magnetoresistance phenomena. In particular, a puzzling magnetoresistance has been evidenced as bilinear in electric and magnetic fields. Here, we report the observation of bilinear magnetoresistance (BMR) in strained HgTe, a prototypical TI. We show that both the amplitude and sign of this BMR can be tuned by controlling with an electric gate the relative proportions of the opposite contributions of opposite surfaces. At magnetic fields of 1 T, the magnetoresistance is of the order of 1% and has a larger figure of merit than previously measured TIs. We propose a theoretical model giving a quantitative account of our experimental data. This phenomenon, unique to TI, offers novel opportunities to tune their electrical response for spintronics.