Ophiolitic Peridotites Research Articles

Re−Os Isotope and PGE Abundance Systematics of Coast Range Ophiolite Peridotites and Chromitite, California: Insights into Fore-Arc Magmatic Processes

Abstract We report platinum-group element (PGE) and Re concentrations, and Re−Os isotopic data for peridotites and podiform chromitite from the mid-Jurassic Coast Range ophiolite (CRO), California. Our aim is to provide insights into the formation and evolution of the CRO in a fore-arc tectonic setting. The CRO peridotites are divided into two groups: abyssal and supra-subduction zone (SSZ). They have Ir-group PGE concentrations similar to estimates for the primitive mantle and nearly chondritic relative abundances [(Os/Ir)N ≈ 1.1]. Abyssal-type peridotites have slightly subchondritic Pd-group PGE (PPGE)−Re abundances and flat chondrite-normalized patterns, whereas the SSZ-type ones are depleted overall with highly fractionated PPGE−Re patterns. The CRO peridotites have 187Os/188Os values of 0.1188 to 0.1315 (γOs = −8.3 to 1.4) and 187Re/188Os ranging from 0.022 to 0.413. The oxygen fugacity based on the V/Yb ratios of the CRO peridotites is equivalent to the fayalite−magnetite−quartz buffer. The abyssal-type peridotites are residues after ≤5% melting of the primitive upper mantle and represent a remnant of oceanic lithosphere trapped in an SSZ setting but before it was re-melted or modified by subduction processes. The abyssal-type peridotites yield an aluminachron model age of ~1.5 Ga, implying that the CRO mantle had experienced episode(s) of melt extraction before the CRO crust was formed. The SSZ-type peridotites are refractory residues after ~5% to 15% melting. Extraction of fore-arc basalts generated mainly by decompression melting resulted in the SSZ-type peridotites. The chromitite has 187Os/188Os value of 0.1250 (γOs = −3.5) and PGE−Re patterns complementary to that of boninite, indicating a genetic link to fore-arc magmatism.

Evidence for large-scale, long-term highly siderophile element heterogeneities in the Atlantic mantle from Leg 153 and 209 peridotites

Seafloor abyssal peridotites are products after partial melting and melt-rock interaction, providing constraints on upper mantle processes and heterogeneity. Despite extensive studies of ophiolitic peridotites and a burgeoning dataset for dredged abyssal peridotites, limited studies have been undertaken on abyssal peridotite drill core samples. This omission means a lack of comparison between modern ocean mantle lithosphere and that of ophiolites, where field context is possible in the latter, but not the former. Ocean Drilling Program (ODP) Leg 153 near the Kane fracture zone, and ODP Leg 209, near the Fifteen-Twenty fracture zone, both on the mid-Atlantic Ridge but ∼1000 km distant from one another, recovered serpentinized mantle peridotites. We report whole-rock major-, trace- and highly siderophile-element (HSE: Re, Pd, Pt, Ru, Ir, Os) abundances and 187Os/188Os ratios of peridotites from three cores (maximum depth of 200.8 m) from the two Legs to explore mantle heterogeneity within the Atlantic Ocean basin. Peridotites from ODP Leg 153 are relatively fertile, with Al2O3 contents ranging from 1.1 to 2.7 wt%. They are characterized by relatively radiogenic 187Os/188Os (0.1259 ± 0.0017; 2 S.D.) and uniform HSE abundances. The ODP Leg 209 peridotites are highly refractory, with Al2O3 contents ranging from 0.1 to 0.8 wt%, and imply that they record an extensively depleted mantle. They have 187Os/188Os of 0.1207 ± 0.0023 (2 S.D.) and fractionated HSE abundances, indicative of depletion occurring > 1 billion years ago. Marked heterogeneity both in the extent and timing of depletion are therefore evident along a large segment of the mid-Atlantic ridge that produces zero-age basalts. Measurement of Os isotopes in spatially associated mid-ocean ridge basalts (MORB) is challenging due to their sub ng/g Os contents. Instead, Nd isotopes of MORB are used to show that they are unlikely to have formed directly from abyssal peridotite-like sources. Abyssal peridotites therefore represent long-lived refractory residues during mantle upwelling with the sources of MORB being more enriched. Comparison between drilled abyssal peridotites and ophiolitic mantle reveals larger compositional variations in the latter. The overall higher melting extent in ophiolite mantle is likely reflective of a more complex life cycle than the modern oceanic lithosphere.

Origin and multi-episodic melt/fluid interactions revealed by the subducted serpentinites in the North Qilian Belt, NW China: Implications for the compositional heterogeneity of the fossil oceanic mantle

In nature, serpentinites act as reservoirs of water and fluid-mobile elements and play an essential role in arc magmatism, fluid metasomatism, and elemental circulation in subduction zones. This paper presents new mineral and whole-rock geochemical analyses of the Qingshuigou serpentinite massif and discusses its petrogenesis, tectonic setting, and mantle metasomatism. The chemical composition (e.g., REE, Y, Mg, and Al) and petrological observations (e.g., pseudomorph and hourglass textures) of serpentines demonstrate that the serpentinites’ protoliths belong to the peridotites. Their degrees of partial melting were estimated to be 15–20 % using Yb, Cr, Ti, and HREEs, indicating that these peridotite protoliths were residual in origin after high degrees of mantle melting. They were relics of the subducted lithospheric mantle in the subduction zone, based on their geochemical similarities with subducted serpentinites. Notably, the Qingshuigou serpentinites show several geochemical fingerprints of melt-rock interactions, such as the U-shaped REE patterns, elevated Zr/Ti, Zr/Hf, and Nb/Ta ratios; this led us to propose that the peridotite protoliths of the serpentinites were not merely melting remnants but were significantly modified by melt metasomatism. Also, they experienced two stages of fluid/rock interactions in the subduction zone: early-stage serpentinization at shallow depths and lizardite/chrysotile to antigorite transition at an elevated depth. Combined with the published data of ophiolitic peridotites from the North Qilian Belt, the compositional heterogeneity of these peridotites and associated serpentinites might be associated with the nature of melt/fluid metasomatism under different geodynamic backgrounds.

Detrital Chromian Spinel Geochemistry from Miocene Red Bed Sandstones of Northeastern Iraq: Implication for Provenance and Tectonic Setting

The provenance and tectonic setting of clastic sediments present in the Miocene Red Bed Series located in northeastern Iraq were analyzed. The analysis is based on the composition of detrital chrome spinel and represents the first examination of this topic. The detrital chrome spinel exhibits Cr # (Cr/(Cr + Al)) values ranging from 0.54 to 0.77 and Mg # (Mg/(Mg + Fe2+)) values ranging from 0.37 to 0.69. This indicates a potential incorporation of ultramafic sources, possibly including peridotites (namely Harzburgite and Lherzolite precursors), within the supra-subduction zone. The analysis of modified Cr-spinels extracted from the Red Beds indicates that the source rocks underwent a process of metamorphism and that the Cr-spinel particles were surrounded by a magnetite rim. The Cr-spinel compositions of the examined samples are situated tectonically in the fore-arc setting of peridotite protoliths, except for a small number of samples that exhibit boninite affinity. The observed resemblance in the Cr-spinel number content between the examined specimens and the Zagros Ophiolite peridotites suggests that the Red Beds may have originated from the Cretaceous Mawat Ophiolite Complex. The deposition of Paleocene Walash-Naopurdan rocks indicates that the lower allochthon served as a source during this process. The tectonic context of the Red Bed Series suggests that the allochthonous terranes in the Mawat region were transported and obducted onto the northeastern Arabian passive margin in the early Miocene period. The deposition of the Red Bed Series occurred concurrently with the closure of the Neo-Tethys Ocean in the Miocene.

Characterization of the Oman ophiolite peridotites using the relationship between clinopyroxene Nd isotopic ratios and spinel compositions

Characterization of the Oman ophiolite peridotites using the relationship between clinopyroxene Nd isotopic ratios and spinel compositions

Diamonds Discovered in the Forearc Harzburgites Hint at the Deep Mantle Source of the Skenderbeu Massif, Western Mirdita Ophiolite

The ultra-deep genesis of ophiolitic peridotite has reshaped our perception of the genesis of the oceanic mantle. Although ultra-high pressure (UHP) mineral assemblages have been unearthed in dozens of ophiolites in different orogenic belts around the world, the vast majority of them have been limited to podiform chromitites formed in suprasubduction zone (SSZ) settings, leaving uncertainty about whether such UHP minerals are intrinsic to the oceanic mantle or influenced by a specific mantle rock type. Here, we report on the occurrence of diamonds recovered from the harzburgites within the Skenderbeu massif, Mirdita ophiolite. The whole-rock, mineralogical major and trace element compositions, and redox states of the harzburgites align with modern abyssal harzburgites. Trace element modeling of clinopyroxene indicates that harzburgites have endured varying degrees of garnet-facies melting (~2%–5%) before progressing to spinel-facies melting (~10%–12%). Mineralogical characteristics further support that the Skenderbeu harzburgites underwent late-period MORB-like melt metasomatism in a forearc spreading center. An unusual mineral assemblage of diamonds has been separated from the studied harzburgites. The first occurrence of ophiolite-hosted diamonds discovered in the forearc harzburgites, together with previous similar discoveries in the SSZ ophiolitic chromitites, suggest that the ophiolite-hosted diamonds are not specific to certain mantle rocks.

Supra-subduction melt modification of the fossil subcontinental lithospheric mantle: insights from ultra-depleted Khara-Nur ophiolitic peridotites (Eastern Sayan, central Asian orogenic belt)

Mantle peridotites from the Mesoproterozoic forearc-type ophiolites in the Eastern Sayan range (Eastern Siberia) provide insights into the nature and formation processes of the supra-subduction mantle. The peridotites are represented by porphyroclastic harzburgites and dunites. The harzburgites have strongly refractory compositions recorded in high Mg# olivine (0.912-0.927) and orthopyroxene (0.916-0.935), high Cr# spinel (0.45-0.66), low Al2O3 and Cr2O3 abundances in orthopyroxene, the lack of residual clinopyroxene, low HREE abundances in orthopyroxene, clinopyroxene and whole-rocks. Some rocks are relatively enriched in SiO2, which is a common feature of supra-subduction (arc and forearc) peridotites and suggests hydrous melting, whereas the rest resemble the chemistry of residues from anhydrous melting of depleted mantle (DM). The whole-rock Al2O3 and Cr-spinel compositions reflect high degrees of partial melting, which initiated in the garnet facies. The Khara-Nur peridotites experienced modification by high-Mg, low-Ti hydrous (boninitic or tholeiitic) arc melts, which crystallized newly-formed minerals (clinopyroxene, Cr-spinel, olivine) in harzburgites. The trace-element composition of clinopyroxene (YbN = 0.5-1.0, La/YbN = 0.05-0.5) resembles that of clinopyroxene from the forearc peridotites and reflects low melt/rock ratio. In dunites, melt percolation resulted in growth of Cr-spinel hosting multiphase inclusions (olivine + clinopyroxene + orthopyroxene + amphibole + phlogopite). Clinopyroxenes from Cr-spinel-hosted inclusions exhibit considerable variations in trace element composition due to heterogeneity of parental melts. Remarkably low Fe3+/∑Fe ratios (0.02-0.12) of Cr-spinels in both harzburgites and dunites are uncommon in SSZ mantle rocks and cannot be explained in terms of the supra-subduction processes, such as partial melting and melt percolation. The whole-rock and mineral compositions of Khara-Nur peridotites, along with previously reported Paleo- to Mesoproterozoic Re-Os model ages, suggest an affinity to ultra-depleted Proterozoic subcontinental lithospheric mantle (SCLM). Overall, the Khara-Nur mantle rocks most likely represent a block of SCLM which underwent melt interaction in a supra-subduction tectonic setting that yielded boninitic and tholeiitic melts comprising now the crustal part of Eastern Sayan ophiolites.

Influences of subduction derived fluids and melt in the genesis of Nidar ophiolite peridotites, Ladakh Himalaya, India: Evidence from mineralogy, PGE and Nd isotopic compositions

The Nidar ophiolite is one of the well-preserved and almost complete ophiolite sections of the Neo-Tethyan oceanic lithosphere, obducted along the continental margin between the Indian and the Eurasian plate. This ophiolite sequence is mostly dominated by ultramafic rocks, consisting of forearc-related refractory, mainly harzburgite, dunite, and serpentinite, with minor intrusions of lherzolite, chromitites, and pyroxenites. In this present study, detailed mineralogical, whole rock geochemistry (major oxides, trace elements, PGE), and Nd isotopic composition of mantle-derived peridotites have been carried out to constrain the petrogenesis and melt evolution. These peridotites are depleted in nature due to the low modal composition of clinopyroxene, high forsterite content in olivine, and wide variation in Cr# and bulk rock chemistry, indicating variable degree of partial melting. The spoon-shaped rare earth element (REE) patterns indicate metasomatism by fluids derived from a subducting slab enriched in light REEs. Geochemical composition of the studied peridotites rocks is marked by high ratio of Al2O3/TiO2, LILE-LREE enrichment, HFSE depletion, and spoon-shaped chondrite-normalized REE patterns and (La/Sm)N > 1 and (Gd/Yb)N < 1, indicates some involvement of boninitic mantle melts and validate a subduction initiation process. The total PGE of the peridotites (ΣPGE = 33–337 ppb) is much more enriched than that of the primitive mantle and other ophiolite peridotites. The PGE distribution displays a concave upward pattern with higher PPGE/IPGE ratios (i.e., 0.11–1.45), suggesting that partial melting is not the only process for the evolution of the Nidar ophiolite peridotites. Enrichment of PPGE and incompatible elements (like LREE) and higher Pd/Ir ratio (0.69–8.26) indicates that these peridotites have undergone fluid/melt interaction in a supra-subduction zone (SSZ) tectonic setting. PGE concentrations of these depleted harzburgites and dunites, formed by partial melting of cpx–harzburgites in an SSZ that produced the boninitic-like melt. The enrichment of incompatible elements like the PPGE is mainly due to the circulation of fluids in the subduction zone, which leads to the PGE fractionation in mantle peridotites. Also, these peridotites have 143Nd/144Nd ratios (0.51148–0.51262) and εNd(t) (t = 140 Ma) values (i.e., +0.97 to −21.3), indicating derivation from depleted mantle sources within an intra-oceanic arc setting. The geochemical behavior exhibited by the Nidar ophiolite peridotites suggests the evolution of a highly depleted fore-arc mantle wedge significantly modified by various fluids and melts during subduction. The mineralogical, geochemical, and Nd isotopic composition of these peridotites and dunites mutually depict the diverse mantle compositions, suggesting insights into the interactions between the oceanic crust and mantle as well as associated geochemical cycling in an SSZ environment.

The Burmese Jade Mines belt: origins of jadeitites, serpentinites, and ophiolitic peridotites and gabbros

Ophiolitic peridotites in Myanmar (Burma) occur along three major tectonic zones: the Kaleymyo–Nagaland suture along the Indo-Burman Ranges, the Jade Mines belt and the Tagaung–Mytkyina belt. These belts all show harzburgite–lherzolite–dunite peridotites, but the Hpakan-Taw Maw region (Jade Mines belt) also hosts jadeitites, including pure jadeite, mawsitsit (Cr-rich jadeite) kosmochlore (Cr-rich clinopyroxene) and albitite. Jadeitites with high Na and Al contents require either very unusual Al-rich, Si-poor protoliths or extensive fluid metasomatism, or both. The Hpakan jadeitites formed by Na-, Al- (and Si-) metasomatic alteration of pyroxenite–wehrlite intrusions into harzburgite–dunite from widespread fluid alteration. The fluids could have been derived from a mid-Jurassic intermediate pressure subduction event during ophiolite formation and emplacement. In the Lake Indawgyi area, normal ophiolitic peridotites, including harzburgite and dunite with pyroxenite veins, have not been jadeitized. Gabbros related to the Jade Mines ophiolite gave a U–Pb zircon age of 169.71 ± 1.3 Ma (MSWD 2.2), a similar timing to the Myitkyina ophiolite (173 Ma) to the east, suggesting that the ophiolite belts were originally continuous. The jade ‘boulders’ in the Uru conglomerate beds at Hpakan have also resulted from normal in situ serpentinization weathering processes, followed by limited fluvial mass transport processes along the Uru River. Supplementary material: U–Pb zircon data are available at https://doi.org/10.6084/m9.figshare.c.6655269

Geochemical and remote sensing integrated with satellite gravity data of Darhib and Atshan talc deposits, South Eastern Desert, Egypt

The current contribution conducted new geochemical, remote sensing integrated with gravity detailed studies of talc deposits to identify the talc protolith as well as its extension, depth, and structures. There are two examined areas, distributed from north to south, Atshan and Darhib and both belong to the southern sector of the Egyptian Eastern Desert. They occur as individual lenses or pocket bodies in ultramafic-metavolcanics following NNW-SSE and E-W shear zones. Geochemically, among the investigated talc, Atshan samples have high contents of SiO2 (av. 60.73 wt.%), and higher concentrations of transition elements such as Co (av. 53.92 ppm), Cr (781 ppm), Ni (av. 1303.6 ppm), V (av. 16.67 ppm), and Zn (av. 55.7 ppm). Notably, the examined talc deposits contain low contents of CaO (av. 0.32 wt.%), TiO2 (av. 0.04 wt.%), SiO2/MgO (av. 2.15), and Al2O3 (av. 0.72 wt.%), which is comparable with ophiolitic peridotite and forearc setting. False color composite (FCC), principal component analysis (PCA), minimum noise fraction (MNF), and band ratio (BR) have been used to distinguish talc deposits in the investigated areas. Two new proposed band ratios were created to separate talc deposits. FCC band ratios (2/4, 4/7, 6/5) and (4 + 3/5, 5/7, 2 + 1/3) have been derived to focus on talc deposits in two case studies, Atshan and Darhib areas. The application of regional, residual, horizontal gradient (HG), and analytical signal (AS) techniques to gravity data are used in interpreting the structural directions of the study area. The analysis of this technique displays several notable faults trending in NW–SE, NE–SW, NNW–SSE, and E–W directions. Two techniques of gravity depth calculation were applied in the study areas, namely source parameter image (SPI), and Euler deconvolution (EU). The analysis of these techniques reflects that the depth of subsurface sources ranges between 383 and 3560 m. Talc deposits may be attributed to greenschist facies metamorphism or to a magmatic solution that is (associated with granitic intrusions) interacted with the surrounding volcanic rocks forming metasomatic minerals.

Formation and implication of a Cr-bearing spinel seam by interaction between alkali basaltic melt and lherzolite

It has long been known that an indisputable fact that chromite/spinel deposits are genetically related exclusively with komatiitic, tholeiitic or boninitic magmas derived from high-degree mantle melting. Here we report formation of a seam of Cr-bearing spinel through interaction between an alkali basaltic magma and fertile lherzolite. The thin seam occurrence of spinel resembles concordant podiform chromitites in ophiolites and stratiform chromitites in layered intrusions. We show that the Cr-bearing spinel seam formed by melt-rock reaction that observed in ophiolitic peridotites. The most significant difference is that the Cr-bearing spinel produced from the alkali basaltic melt-lherzolite interaction is extremely rich in Al with Cr# values of 3–6. We consequently re-classify chromitite into four types based on their Cr# values namely: high-Cr (chromite Cr# > 70), intermediate (Cr# = 70–50), high-Al (Cr# = 50–40), and extremely high-Al (Cr# < 10) with a Cr# gap between 40 and 10. The chromite/spinel compositions correspond closely to diagnostic parental magmas and the lithologies of the host peridotites.

From rifting to emplacement: Variable mantle melting preserved in the central Palawan Ophiolite peridotites, Philippines

ABSTRACT The mantle section of the central Palawan Ophiolite (CPO) in western Philippines is dominantly composed of dunites and harzburgites. Basal lherzolites and harzburgites juxtaposed with the metamorphic sole of the CPO are also exposed within the vicinity of Ulugan Bay, Puerto Princesa. These basal peridotites provide novel information regarding the processes transpiring in the upper mantle during the evolution of this preserved oceanic lithosphere. The Nasuduan lherzolite is characterized by low Cr# of spinel and high concentrations of REEs in clinopyroxenes. The Oyster Bay lherzolite displays similar fertile characteristics and occurs with harzburgites. Both contain fine-grained and interstitial clinopyroxenes derived from interstitial melts. Tremolite and talc in the Oyster Bay lherzolite and harzburgite and in other CPO harzburgites are attributed to slab-fluid metasomatism. Harzburgites and dunites from Bentoan Beach and other CPO harzburgites have high spinel Cr# and low clinopyroxene REE concentrations. These indicate that these peridotites have undergone extensive degrees of melting facilitated by fluids. The petrological and geochemical signatures of the CPO peridotites record the transition of a supra-subduction zone from back-arc spreading, incipient subduction, to the obduction of an ancient oceanic lithosphere.

Ultra-depleted melt product preserved in the Ladong ophiolitic peridotites of the North Qilian Orogenic Belt, Northern Tibet

In Earths upper mantle, the compositions of both migrating magmas and solid residues are basically controlled by source materials and melting behavior which are related to tectonic dynamics. Thus, infrequent geochemical signatures recorded by ophiolitic lithologies may reflect a unique source or specific melting history. Here, we report whole-rock and mineral compositions of the harzburgite, wehrlite, and olivine websterite in the Ladong ophiolite complex of the North Qilian Orogen Belt (northern Tibet). The dominant spinel harzburgite has high spinel Cr# values of 65–70 and light rare earth element (LREE) depleted patterns (LaN/YbN = 0.04–0.12), resembling the residua after 20% or more of melt extraction. Wehrlite lenses within the harzburgite display extremely depleted LREE patterns (whole-rock LaN/YbN = 0.04–0.05) and low Na and Ti contents in clinopyroxene. They are interpreted as products of reaction between the host harzburgite and an ultra-depleted melt produced by asthenospheric decompression melting. Outcrops of olivine websterite have well-equilibrated triple junction textures between pyroxene grains and high-Mg olivine (Fo = 85–86; bulk rock Mg# = 93), consistent with a cumulate origin. In the olivine websterite, the depleted LREE concentrations (LaN/YbN = 0.05–0.18) in clinopyroxene suggest a less depleted nature than the wehrlite-forming melt. Thus, the Ladong ophiolite records two episodes of melt activity that produced depleted to ultra-depleted magmas, which may have been generated during subduction initiation in eastern Proto-Tethyan belt.

Geochemistry of Plastic Deformed Olivine from Ophiolite Peridotites and Dunites of Kraka Massifs (Southern Urals)

Geochemistry of Plastic Deformed Olivine from Ophiolite Peridotites and Dunites of Kraka Massifs (Southern Urals)

Petrogenesis of arc-related serpentinized peridotites (Egypt): Insights into Neoproterozoic mantle evolution beneath the Arabian-Nubian Shield

• Two ophiolitic peridotites in the SE Desert of Egypt provide a window into the Neoproterzoic mantle. • Geochemistry of peridotite and its mineral chemistry suggest an origin in the arc-related setting. • SED peridotites are refractory mantle residues (25–40% melting), like modern fore-arc peridotites. • Geochemical aspects of peridotite indicate changing from extension during subduction initiation. Korab Kansi and Abu Dahr Neoproterozoic ophiolitic peridotites in the Southern Eastern Desert (SED) of Egypt, are parts of the largest ophiolitic nappes in the Arabian-Nubian Shield. They mainly comprise refractory harzburgites with minor dunites that are commonly altered to serpentinites and talc carbonates. Olivine relics in serpentinized peridotites of the two complexes have olivines with high forsterite (Fo 90.6-92.2 ) and NiO (0.39 wt%) and low MnO (0. 13 wt%) contents, similar to those of mantle olivines. High Mg# (0.91–0.95) of orthopyroxene is consistent with that of depleted harzburgites. Primary spinel Cr# (0.55–0.75) and TiO 2 contents (<0.04 wt%) of the two peridotite complexes are similar to forearc peridotite spinels. The estimated degree of partial melting of Korab Kansi peridotites (25–40% melting) is slightly lower than that of Abu Dahr (30–40% melting), consistent with modern forearc peridotites. Korab Kansi peridotites exhibit lower oxygen fugacity (Δlog ƒO 2 , FMQ + 0.7 on average) and equilibrium temperature (610–710 °C) than those of Abu Dahr ( T , 750–900 °C at Δlog ƒO 2 , FMQ + 2.1), both suggesting subduction-modified peridotites. The low concentrations of incompatible elements, U-shaped REE patterns and high spinel Cr# of both peridotites indicate highly depleted mantle protoliths, reflecting multiple metasomatic and melting episodes in the mantle wedge. Enrichment of fluid mobile elements (e.g. B, Li, Th, U, Pb) relative to high-field strength elements (e.g. Nb, Ta, Ti, Zr) may reflect interaction between slab-derived fluids and peridotites. Calculated parental melts in equilibrium with Korab Kansi and Abu Dahr peridotite spinels have tholeiitic (MORB-like) and boninitic affinities, which were generated during proto-forearc spreading to a mature arc stage. Variations in melt compositions suggest a transitional setting from early proto-forearc spreading of mantle beneath Korab Kansi to the mature arc stage of Abu Dahr peridotites. Subduction initiation possibly started in the W and/or SW with proto-forearc spreading, and progressed to the E and/or NE where a mature arc stage with boninitic melts above an E- and/or SE-dipping subduction zone.

Temperatures and Cooling Rates Recorded by the New Caledonia Ophiolite: Implications for Cooling Mechanisms in Young Forearc Sequences

AbstractTo unveil how forearc lithosphere cools and re‐equilibrates, we carried out a comprehensive geothermometric investigation of the New Caledonia ophiolite, which represents a rare example of proto‐arc section generated during subduction infancy. A large data set, including more than 80 samples (peridotites and mafic‐ultramafic intrusives), was considered. Closure temperatures calculated for the lherzolites using slow (TREE‐Y) and fast diffusing (TCa‐in‐Opx, TBKN, TCa‐in‐Ol, TOl‐Sp) geothermometers provide some of the highest values ever documented for ophiolitic peridotites, akin to modern sub‐oceanic mantle. Cooling rates deduced from TREE‐Y and TBKN yield values of ≈10−3°C/y, similar to those obtained with TCa‐in‐Ol. These features are consistent with a post‐melting history of emplacement, possibly along a transform fault, and thermal re‐equilibration via conduction. Cpx‐free harzburgites register a high‐T evolution, followed by quenching and obduction. The relatively high TCa‐in‐Ol, TOl‐Sp and cooling rates computed from TCa‐in‐Ol (≈10−3°C/y) are atypical for this geodynamic setting, mirroring the development of an ephemeral subduction system, uplift and emplacement of the Peridotite Nappe. Temperature profiles across the crust‐mantle transect point to high closure temperatures, with limited variations with depth. These results are indicative of injection and crystallization of non‐cogenetic magma batches in the forearc lithosphere, followed by thermal re‐equilibration at rates of ≈10−4–10−3°C/y. Our study shows that the thermal conditions recorded by forearc sequences are intimately related to specific areal processes and previous lithospheric evolution. Thus, detailed sampling and exhaustive knowledge of the geological background are critical to unravel the cooling mechanisms in this geodynamic setting.

The kabr El-Bonaya peridotites, Southeastern Sinai, Egypt: petrology, geochemistry, and metamorphism of Neoproterozoic arc ultramafic cumulates

Two small, isolated ultramafic masses in the northeastern part of the Wadi Kid area, southeast Sinai, are composed of variably serpentinized harzburgite and lherzolite with minor talc-anthophyllite rock. The primary phases are dominantly olivine, orthopyroxene and Cr-spinel; clinopyroxene, amphibole, and phlogopite are also found in lherzolite samples. The whole-rock Mg# of harzburgite samples (89–91) is higher than that of lherzolite (average 82). The harzburgite samples contain olivine with higher Mg and Ni contents, orthopyroxene with higher Mg#, and Cr-spinel with higher Cr content than do the lherzolite samples. The REE patterns of clinopyroxene and amphibole in lherzolite are most consistent with a cumulate origin. Although several compositional characteristics of the harzburgites resemble those of residual mantle, in detail the Cr₂O₃ and Al₂O₃ contents of fresh Cr-spinel in harzburgite are different from those found in mantle samples or in any of the Neoproterozoic ophiolitic peridotites throughout the Arabian-Nubian Shield. Thus, all the ultramafic rocks at Kabr El-Bonaya are best explained as ultramafic cumulates, with harzburgite consisting of early-formed cumulate phases and lherzolite containing later-formed cumulate phases with higher REE abundances, primary hydrous minerals, evolved primary silicates, and high TiO₂ (0.77 wt.%) and Al₂O₃ (18 wt.%) contents in Cr-spinel. The trace-element characteristics of the rocks indicate a subduction-related parental magma: whole-rock chondrite-normalized REE patterns are LREE-enriched; calculated <i>f</i>O₂ values are elevated (+2.47 to +3.39 log units above the fayalite-magnetite-quartz buffer); and computed N-MORB-normalized trace element patterns for melts in equilibrium with clinopyroxene and amphibole have negative Nb-Ta anomalies and enrichment in large-ion lithophile elements. The low Al₂O₃/SiO₂ ratios (0.007–0.040) of harzburgite samples and the low TiO₂ contents and high Cr# of their Cr-spinel indicate derivation from a mantle source that experienced high-degree partial melting. From these characteristics, we infer a boninitic parental melt for the harzburgite. We offer an illustrative quantitative fractionation model that can explain the successive derivation of harzburgite and lherzolite cumulates along a single equilibrium, polybaric cooling path. We conclude that the Kabr El-Bonaya ultramafic cumulates represent the exposed roots of a Neoproterozoic island arc that was caught in the collision between East and West Gondwana.

Development of a complex arc–back-arc basin system within the South Tianshan Ocean: Insights from the Wuwamen ophiolitic peridotites

Ophiolites within the South Tianshan orogenic belt directly record the nature and tectonic evolution of the South Tianshan Ocean (STO), which is key for understanding the accretionary history of the Central Asian Orogenic Belt. Here we present petrological and Os isotopic data for the Wuwamen mantle peridotites from the South Tianshan orogenic belt, which provide new insights into the tectonic origin of this ophiolite and evolution of the STO. The lherzolites have low spinel Cr# (0.1–0.2), similar to those of fertile oceanic or continental peridotites that have undergone low degrees of melting. However, the extremely high Na2O (1.5–1.8 wt%) and Al2O3 (5.5–6.2 wt%) contents of the clinopyroxenes are atypical of oceanic peridotites, and resemble those of subcontinental peridotites. The harzburgites have more refractory compositions, suggesting higher degrees of melt extraction. Both the lherzolites and harzburgites have low initial 187Os/188Os ratios (< 0.121), which reflect Proterozoic melt depletion and a long-term lithospheric evolution. These data confirm an ancient subcontinental lithospheric mantle origin for the Wuwamen peridotites. The replacive dunites have moderate spinel Cr# (0.3–0.4), reduced Os and enriched 187Os/188Os (0.142–0.160), indicative of reaction between host lherzolites and percolating mid-ocean ridge basalt (MORB)-type melts with radiogenic Os isotopic signatures, presumably in a subduction-related setting. This and the associated back-arc basin basalt (BABB)–type mafic crust suggest the Wuwamen ophiolite formed in a continental margin back-arc setting. A comparison with other ophiolites in the South Tianshan orogenic belt further indicates that a complex arc–back-arc system existed along the southern margin of the Central Tianshan, which was associated with northward subduction within the STO.

Modification of Lithospheric Mantle by Melts/Fluids With Different Sulfur Fugacities During the Wilson Cycle: Insights From Lesvos and Global Ophiolitic Peridotites

AbstractThe Lesvos ophiolite, Greece, was recently identified as an analog to the External Liguride Unit formed at an ocean‐continent‐transition (OCT) setting. To further study the evolutionary history of this body, we analyzed highly siderophile element abundances and Re‐Os isotopic compositions of 14 Lesvos peridotites, in combination with petrology, bulk‐rock major, and trace element geochemistry. Almost all the Lesvos peridotites fall within the field of global OCT and mid‐ocean‐ridge (MOR) peridotites, indicating that these rocks have not experienced subduction‐related processes. The near‐horizontal 187Os/188Os versus Al2O3 trend over a wide range of Al2O3 (0.45–3.66 wt. %) may have been caused by recent melt depletion during rifting and thinning of the Lesvos lithosphere. Combining data from available global ophiolitic peridotites, we find that a large proportion of the more Al‐depleted supra‐subduction‐zone (SSZ) peridotites show lower Os/Ir, higher Pd/Ir and remarkably elevated radiogenic Os relative to other tectonic environments (OCT and MOR). By linking this kind of geochemical evolution to the Wilson Cycle, a complete picture emerges: (a) In the OCT to MOR stages, the extensional rifting environment may lead to mild to moderate melt depletion, followed by, or associated with, infiltration of S‐saturated (high fS2) basaltic magmas; (b) when progressing into the SSZ stage, more extreme degrees of mantle melt depletion may be driven by aqueous fluids in the sub‐arc mantle. During this stage, high‐fO2 slab‐derived fluids and/or S‐undersaturated (low fS2) boninitic magmas may infiltrate the sub‐arc mantle, followed by subsequent S‐saturated forearc basaltic magma infiltration.

Chromite Paleoplacer in the Permian Sediments at the East Edge of the East European Platform: Composition and Potential Sources

A chromite occurrence called the Sabantuy paleoplacer was discovered in the Southern Pre-Ural region, at the east edge of the East-European Platform in the transitional zone to the Ural Foredeep. A ca. 1 m-thick chromite-bearing horizon is traced at a depth of 0.7–1.5 m from the earth’s surface for the area of ca. 15,000 m2. The chromspinel content in sandstones reaches 30–35%, maximum values of Cr2O3 are 16–17 wt.%. The grain size of detrital chromspinel ranges from 0.15 to 0.25 mm. Subangular octahedral crystals dominate; rounded grains and debris are rare. The composition of detrital chromspinel varies widely and is constrained by the substitution of Al3+ and Cr3+, Fe2+ and Mg2+ cations. Chemically, low-Al (Al2O3 = 12 wt.%) and high-Cr (Cr2O3 = 52–56 wt.%) chromspinel prevail. The compositional analysis using discrimination diagrams showed that most chromites correspond to mantle peridotites of subduction settings. Volcanic rocks could be an additional source for detrital chromites. It is confirmed by compositions of monomineralic, polymineralic and melt inclusions in chromspinels. The presented data indicates that ophiolite peridotites and related chromite ore associated with oceanic and island-arc volcanic rocks, widespread in the Ural orogen, could be the main sources of the detrital chromspinel of the Sabantuy paleoplacer.