We investigate the Green functions G(x,x^{\prime}) of some second order differential operators on R^{d+1} with singular coefficients depending only on one coordinate x_{0}. We express the Green functions by means of the Brownian motion. Applying probabilistic methods we prove that when x=(0,{\bf x}) and x^{\prime}=(0,{\bf x}^{\prime}) (here x_{0}=0) lie on the singular hyperplanes then G(0,{\bf x};0,{\bf x}^{\prime}) is more regular than the Green function of operators with regular coefficients.