Operational Stability Research Articles

Tetrapodal Hole-Collecting Monolayer Materials Based on Saddle-Like Cyclooctatetraene Core for Inverted Perovskite Solar Cells.

Hole-collecting monolayers have greatly advanced the development of positive-intrinsic-negative perovskite solar cells (p-i-n PSCs). To date, however, most of the anchoring groups in the reported monolayer materials are designed to bind to the transparent conductive oxide (TCO) surface, resulting in less availability for other functions such as tuning the wettability of the monolayer surface. In this work, we developed two anchorable molecules, 4PATTI-C3 and 4PATTI-C4, by employing a saddle-like indole-fused cyclooctatetraene as a p-core with four phosphonic acid anchoring groups linked through propyl or butyl chains. Both molecules form monolayers on TCO substrates. Thanks to the saddle shape of a cyclooctatetraene skeleton, two of the four phosphonic acid anchoring groups were found to point upward, resulting in hydrophilic surfaces. Compared to the devices using 4PATTI-C4 as the hole-collecting monolayer, 4PATTI-C3-based devices exhibit a faster hole-collection process, leading to higher power conversion efficiencies of up to 21.7% and 21.4% for a mini-cell (0.1 cm2) and a mini-module (1.62 cm2), respectively, together with good operational stability. This work represents how structural modification of multipodal molecules could substantially modulate the functions of the hole-collecting monolayers after being adsorbed onto TCO substrates.

In-situ interconnected 1D/2D/3D architectures of CNT/MoS2/Fe3O4 membranes for increasing degradation efficiency of penetrative electro-Fenton under low energy consumption

The electro-Fenton oxidation process for the degradation of organic pollutants in recalcitrant wastewater has garnered significant attention and research efforts in the field of advanced water treatment. This is primarily due to its highly effective degradation capabilities and the advantages it offers, including the avoidance of unsafe transportation and storage of hydrogen peroxide (H2O2). However, challenges such as relatively high energy consumption, complex operational requirements, and limited operational stability continue to pose significant economic constraints on the widespread application of electro-Fenton technology in water purification. In this study, we employed a secondary hydrothermal method to construct a multi-layered CNT/MoS2/Fe3O4 composite heterostructure in situ. Leveraging the synergistic effects of the introduced variable valence elements, Fe and Mo, and the interconnected multi-layered membrane structure, the CNT/MoS2/Fe3O4 electro-Fenton membrane holds promise in a permeable filtration system. Under the conditions of a current density of 1.50 mA/cm² and an electrolyte concentration of 0.50 mol/L, the CNT/MoS2/Fe3O4 composite membrane exhibited a degradation efficiency of over 90.00 % for 100.00 mg/L RhB within 10 minutes, and the degradation rate approached nearly 99.00 % at 60 minutes. Furthermore, the degradation efficiency for various recalcitrant organic dye wastewaters, including phenol, methyl orange, and methylene blue, could be maintained at levels ranging from 80.00 % to 97.00 %. Particularly, under optimized operating conditions, the specific energy consumption (EC) for the CNT/MoS2/Fe3O4 membrane process was measured at 0.60±0.01 kWh/m³, showcasing exceptionally low energy consumption characteristics. In conclusion, it is expected to contribute to the reduction of the overall consumption of heterogeneous electro-Fenton oxidation systems and enhance their operational efficiency. This innovative approach represents a significant advancement in the field, offering the potential to address the economic limitations associated with electro-Fenton technology in water quality purification.

Simultaneous Manipulation of Membrane Enthalpy and Entropy Barriers towards Superior Ion Separations

AbstractSub‐nanoporous membranes with ion selective transport functions are important for energy utilization, environmental remediation, and fundamental bioinspired engineering. Although mono/multivalent ions can be separated by monovalent ion selective membranes (MISMs), the current theory fails to inspire rapid advances in MISMs. Here, we apply transition state theory (TST) by regulating the enthalpy barrier (ΔH) and entropy barrier (ΔS) for designing next‐generation monovalent cation exchange membranes (MCEMs) with great improvement in ion selective separation. Using a molecule‐absorbed porous material as an interlayer to construct a denser selective layer can achieve a greater absolute value of ΔS for Li+ and Mg2+ transport, greater ΔH for Mg2+ transport and lower ΔH for Li+ transport. This recorded performance with a Li+/Mg2+ perm‐selectivity of 25.50 and a Li+ flux of 1.86 mol ⋅ m−2 ⋅ h−1 surpasses the contemporary “upper bound” plot for Li+/Mg2+ separations. Most importantly, our synthesized MCEM also demonstrates excellent operational stability during the selective electrodialysis (S‐ED) processes for realizing scalability in practical applications.

High performance bagasse based iron–nitrogen-carbon catalyst for oxygen reduction reaction

The design and synthesis of highly stable and low-cost for the oxygen reduction reactions (ORR) catalysts to replace non-noble metal catalysts is crucial for their applications in fuel cells. In this work, bagasse activated carbon (BAC) was used as the carbon source to prepare the high specific area and multi-porous carbon. The BAC@FeN catalysts derived from BAC, FeCl2 and melamine were prepared by pre-activation treatment and high-temperature pyrolysis. The BAC@FeN-900–30 catalyst encapsulated with Fe3C and Fe3O4 exhibited an outstanding catalytic activity (Eonset = 1.01 V and E1/2 = 0.87 V) and superior operational stability of 90.50 % compared to Pt/C (20 wt%) catalyst. The results demonstrated that iron, carbon and nitrogen piggybacked BAC could generate abundant Fe-Nx active sites, which greatly improved the catalytic activity of ORR and had a broad application prospect in energy conversion.

Insulating Polymer Mediated Stability and Photovoltaic Performance of Organic Solar Cells: Influence of Molecular Weight

AbstractInsulating polymers are promising components for constructing high performance organic solar cells (OSCs) due to their advantages including low cost, excellent mechanical properties, and feasibility in morphology modulation. However, few studies have been conducted on the effect of molecular weight of insulating polymers on the performance of the corresponding OSCs. In this work, polymethyl methacrylate (PMMA) with different molecular weight (named as PMMAL and PMMAH) are incorporated into a range of polymer:nonfullerene photovoltaic systems. It is found that although both PMMAL and PMMAH can suppress the energetic disorder and the nonradiative energy loss, and lead to enhanced open‐circuit voltage in their corresponding OSCs, distinct mechanical property, operational stability as well as photovoltaic performance are observed. PMMAL can modulate the molecular packing of the host components more effectively due to its superior chain segment mobility during the film‐forming process, which can drive the host components to form more ordered molecular packing and therefore superior photovoltaic performance. On the other hand, due to the better miscibility of PMMAH with the host system, especially the C5‐16 acceptor, PMMAH can be well dispersed in the host and form a stable framework that provides superior mechanical properties and operational stability.

Detecting Transitions from Stability to Instability in Robotic Grasping Based on Tactile Perception

Robots execute diverse load operations, including carrying, lifting, tilting, and moving objects, involving load changes or transfers. This dynamic process can result in the shift of interactive operations from stability to instability. In this paper, we respond to these dynamic changes by utilizing tactile images captured from tactile sensors during interactions, conducting a study on the dynamic stability and instability in operations, and propose a real-time dynamic state sensing network by integrating convolutional neural networks (CNNs) for spatial feature extraction and long short-term memory (LSTM) networks to capture temporal information. We collect a dataset capturing the entire transition from stable to unstable states during interaction. Employing a sliding window, we sample consecutive frames from the collected dataset and feed them into the network for the state change predictions of robots. The network achieves both real-time temporal sequence prediction at 31.84 ms per inference step and an average classification accuracy of 98.90%. Our experiments demonstrate the network’s robustness, maintaining high accuracy even with previously unseen objects.

Stearic acid as a potential interlayer at the FAPI/hole transport layer interface

In this study, we explore the potential of using an ultra-thin film of stearic acid (SA) as an interlayer at the interface between the active material and the hole transport layer (HTL) in perovskite solar cells (PSCs). The FAPbI3 active material thin film was fabricated under ambient conditions using the antisolvent method, followed by the deposition of stearic acid overlayers of varying coverages/thicknesses. By adjusting the coverage/thickness of the SA overlayer, the electronic structure of the perovskite surface can be finely tuned, which may potentially lead to favorable energy level alignment at the perovskite/HTL interface. The interaction between the perovskite thin film and the stearic acid overlayer is expected to involve coordination between defects on the perovskite surface and the carboxyl group of stearic acid. The presence of the nonpolar alkyl chain of stearic acid on the perovskite surface enhances material stability by preventing water and oxygen ingress. Our findings suggest that introduction of SA interlayer at the perovskite/HTL interface may enhance operational stability and efficiency of PSCs by improving the charge transfer across the interface through optimization of energy level alignment and reduction of recombination sites, and protect the absorber from environmental factors like water and oxygen.

A Study on the Influence of Radial Spoiler Arrangement on the Combustion Process of Wankel Rotor Engines

Wankel rotor engines are widely used in various fields due to their high power density and simple structure. This paper presents the optimisation of the Wankel rotor engine by simple modifications of the structure. We propose a radial spoiler arrangement scheme that can affect the flame propagation speed and reaction severity by altering the flow field distribution and pre-reaction distribution in the cylinder. By comparing the effects of four layout schemes on flame propagation speed and reaction intensity, including no spoilers, radial spoilers deflected at an angle of 10° in the negative direction of the Z-axis, radial spoilers deflected at an angle of 10° in the positive direction of the Z-axis, and radial spoilers arranged at the centre of the rotor combustion chamber, the benefits of different layout schemes were evaluated. We conducted a study on the influence of the arrangement of radial spoilers on the combustion process of a Wankel rotary engine through theoretical calculations. This helps to reduce engine vibration, improve engine operation stability, and enhance engine performance.

Development and Evaluation of Ferrite Core Inductively Coupled Plasma Radio Frequency Ion Source for High-Current Ion Implanters in Semiconductor Applications

This study presents the development of a ferrite core inductively coupled plasma (ICP) radio frequency (RF) ion source designed to improve the lifetime of ion sources in commercial ion implanters. Unlike existing DC methods, this novel approach aims to enhance the performance and lifetime of the ion source. We constructed a high-vacuum evaluation chamber to thoroughly examine RF ion source characteristics using a Langmuir probe. Comparative experiments assessed the extraction current of two upgraded ferrite core RF ion sources in a commercial ion implanter setting. Additionally, we tested the plasma lifetime of the ICP source and took temperature measurements of various components to verify the operational stability and efficiency of the innovative design. This study confirmed that the ICP RF ion source operated effectively under a high vacuum of 10−5 torr and in a high-voltage environment of 30 kV. We observed that the extraction current increased linearly with RF power. We also confirmed that BF3 gas, which presents challenging conditions, was stably ionized in the ICP RF ion sources.

Rotating machine bearing health prognosis using a data driven approach based on KS‐density and BiLSTM

AbstractRolling element bearings are vital components within rotating machinery, making them a central focus of maintenance in the prognostics and health management sector. This involves closely monitoring their condition to accurately predict the remaining useful life, increasing reliability while minimizing unexpected breakdowns, thereby enabling cost savings through planned maintenance, and enhancing operational stability and security. To achieve this goal, it is necessary to build an online intelligent system for degradation monitoring and failure prognosis by the construction of a robust health indicator and making quantitative measure for bearing degradation. In this paper, an efficient and reliable approach is proposed to estimate the remaining useful life of bearing. A new prediction method is presented by the combination of kernel smoothing density (KS‐density) and bidirectional long short‐term memory (BiLSTM). Firstly, KS‐density smoothens the preliminarily estimated probability distribution function using machinery degradation data. Secondly, the obtained KS‐density is used in feed deep learning technique based on BiLSTM models. On this basis, the variation of the signal distribution models between the current faulty state and the normal conditions state is quantified for bearing health assessment. The effective recognition of bearing degradation by the proposed Weibull‐based health index is demonstrated through experimental validations utilizing run‐to‐failure datasets, provided by the centre for intelligent maintenance systems. The comparison with the literature's review show that the prediction results of the proposed approach are more accurate.

Beyond the empirical pillar design method: The strain criterion and the pillar load inversion concepts

Pillar design is a crucial aspect of underground mining engineering, as it directly impacts the safety, stability, and overall effectiveness of mining operations. In this paper we present a method to calculate pillar stability based on the strain criterion and pillar load inversion concept, which complements the empirical pillar strength formulae. Those formulae do not account for certain parameters that can affect the stability of the pillars, e.g. weak layers, changes in stress orientations due to mining, orebody dip, mining layout complexity, and the influence of regional stabilizing pillars. The approach presented here is not intended to replace the empirical method; rather, we suggest using it as the initial step in the pillar design process. This should be followed by iterative numerical modelling to study pillar behaviour, define pillar stability, and optimize the pillar design by considering site-specific and representative rock mass properties and criteria.

Innovative process for sulphur recovery from waste incineration flue gases: production of marketable sodium bisulphite solution

ABSTRACT This study presents an innovative process for recovering sulphur from hazardous waste incineration flue gases, designed to produce a marketable sodium bisulphite solution while ensuring complete SO2 removal. This new process is characterized by a double absorption strategy at two different pH levels. The first step, at an acidic pH, generates the desired bisulphite solution, while the second step, at a basic pH, produces the sulphite solution for recycling into the first step and ensures total SO2 removal. The process’s performance and feasibility were evaluated on a laboratory scale using a batch reactor with synthetic gas. The parametric study focused on the initial sulphite concentration in the absorption solution and the reactor temperature. A removal efficiency exceeding 95% was achieved across all initial sulphite concentrations and temperature ranges, when the pH was maintained above 6. At pH 5, where bisulphites are the predominant sulphur species, the removal efficiency remained substantial at approximately 70%. The oxidation of sulphites/bisulphites by oxygen in the flue gases was minimal, with less than 5% conversion to sulphate. Additionally, pH-controlled experiments were conducted to optimize plant start-up procedures. For the basic reactor, starting with water and adjusting the pH to 8 during SO2 absorption effectively minimized sodium hydroxide consumption. In contrast, for the acidic reactor at pH 5, initiating the process with a concentrated sulphite solution resulted in more stable absorption rates. These findings underscore the process's potential for efficient sulphur recovery and highlight the importance of pH management in optimizing operational stability and chemical consumption.

Thermal management towards ultra-bright and stable perovskite nanocrystal-based pure red light-emitting diodes

Despite the promising candidacy of perovskite nanocrystals for light-emitting diodes, their pure red electroluminescence is hindered by low saturated luminance, severe external quantum efficiency roll-off, and inferior operational stability. Here, we report ultra-bright and stable pure red light-emitting diodes by manipulating Joule heat generation in the nanocrystal emissive layer and thermal management within the device. Diphenylphosphoryl azide-mediated regulation of the nanocrystal surface synergistically enhances the optical properties and carrier transport of the emissive layer, enabling reduced Joule heat generation and thus lowering the working temperature. These merits inhibit ion migration of the CsPb(Br/I)3 nanocrystal film, promising excellent spectra stability. Combined with the highly thermal-conductive sapphire substrates and implementation of pulse-driving mode, the pure red light-emitting diodes exhibit an ultra-bright luminance of 390,000 cd m−2, a peak external quantum efficiency of 25%, suppressed efficiency roll-off, an operational half-life of 20 hours, and superior spectral stability within 15 A cm−2.

NiOx Passivation in Perovskite Solar Cells: From Surface Reactivity to Device Performance.

Nonstoichiometric nickel oxide (NiOx) is one of the very few metal oxides successfully used as hole extraction layer in p-i-n type perovskite solar cells (PSCs). Its favorable optoelectronic properties and facile large-scale preparation methods are potentially relevant for future commercialization of PSCs, though currently low operational stability of PSCs is reported when a NiOx hole extraction layer is used in direct contact with the perovskite absorber. Poorly understood degradation reactions at this interface are seen as cause for the inferior stability, and a variety of interface passivation approaches have been shown to be effective in improving the overall solar cell performance. To gain a better understanding of the processes happening at this interface, we systematically passivated specific defects on NiOx with three different categories of organic/inorganic compounds. The effects on NiOx and the perovskite (MAPbI3) deposited on top were investigated using X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and scanning electron microscopy (SEM). Here, we find that the perovskite's structural stability and film formation can be significantly affected by the passivation treatment of the NiOx surface. In combination with density functional theory (DFT) calculations, a likely origin of NiOx-perovskite degradation interactions is proposed. The surface passivated NiOx layers were incorporated into MAPbI3-based PSCs, and the influence on device performance and operational stability was investigated by current-voltage (J-V) characterization, impedance spectroscopy (IS), and open circuit voltage decay (OCVD) measurements. Interestingly, we find that a superior structural stability due to interface passivation must not relate to high operational stability. The discrepancy comes from the formation of excess ions at the interface, which negatively impacts all solar cell parameters.

Colorimetric IPN hydrogels embedded with colloidal photonic crystals: A novel approach for the detection of ethanol and Ba2+ ions in water

A critical bottleneck in sensor technology is the rapid and precise detection of specific analytes in complex matrices, hindering advancements in environmental monitoring, healthcare, and industrial process control. This study addresses this challenge by introducing a novel composite hydrogel sensor designed for rapid and selective detection of ethanol and barium ions (Ba2+) in aqueous environments. The sensor integrates interpenetrating network (IPN) hydrogels with embedded colloidal photonic crystals (CPCs), synthesized via a solution-based polymerization approach. This innovative configuration allows CPCs to dynamically adjust their photonic bandgap in response to environmental changes, manifesting as a visible, colorimetric shift. This response stems from the synergy between the mechanical properties of the IPN hydrogel and the optical sensitivity of CPCs. Upon exposure to analytes such as ethanol and Ba2+, the sensor exhibits a rapid and reversible color transition that is directly proportional to their concentration. Notably, ethanol (0 vol%–80 vol%) and Ba2+ (5–17.5 mM) induce a distinct blueshift in the photonic bandgap and trigger a color change from red–orange to green due to the alteration in the swelling behavior of the IPN hydrogel, affecting its lattice constant. The IPN hydrogel–CPC composite demonstrates exceptional operational stability and facilitates rapid detection, making it ideal for on-site applications without the need for complex equipment. These characteristics make the composite hydrogel sensor a promising candidate for environmental monitoring, industrial process control, and public health diagnostics, paving the way for the development of next-generation responsive sensor materials.

Design and optimization of zero-carbon integrated energy system for highway service area

Abstract The challenge of achieving dual-carbon targets arises from the issue of high carbon emissions in Chinese highway service areas. To address this, a comprehensive electric-thermal-hydrogen energy system is proposed, consisting of a new energy generation system, heat pumps, electrolyzers, hydrogen fuel cells, energy storage devices, and charging stations. A dispatch model for the integrated energy system is established, with the objective of minimizing the total operating cost while satisfying the constraints of each device and the electric-thermal-hydrogen balance. The model is implemented in MATLAB, and the ideal optimal solution for each decision variable is obtained using the Gurobi solver. The investment and operating costs, as well as the scheduling results for electricity, heat, and cooling, are analyzed. The results indicate that the electrolyzer-fuel cell system can improve the system’s operational stability and flexibility in dispatch optimization. Due to the instability of photovoltaic and wind power devices and the fluctuating nature of loads, energy storage devices are required for peak load shaving in the system. The zero-carbon integrated energy system model can calculate the most economical investment plan based on the load and meteorological conditions of different service areas.

Photocontrolled interfacial defect passivation of coumarin 151 with enhanced hydrophobicity for stable perovskite solar cell

Defect passivation has been recognized as an efficient strategy to boost the performance of perovskite solar cells (PSCs) for commercial applications. However, most reported strategies overly emphasize passivation of undesirable defects, while ignoring the inherent instability of perovskite materials caused by environmental risks. In this study, we explore a groundbreaking strategy to integrate various functions of defect passivation, photoresponsivity and photocontrolled hydrophobicity in one device via the surface engineering of 7-amino-4-trifluoromethylcoumarin (C151). The detailed experiments demonstrate that C151 based PSCs have regulated power conversion efficiency and stability responding to UV illumination due to the photodimerization of coumarin. On the one hand, the photodimer of C151 (C151-L) can form stronger chelation with various defect sites in comparison with C151, resulting in optimized energy level arrangement, superior charge extraction/transport and significantly inhibited nonradivation recombination. One the other hand, morphological changes of the perovskite film triggered by UV illumination also bring convertible surface hydrophobicity transition. As a result, the unpackaged C151-L modified device exhibits excellent stability maintaining 91 % of its initial PCE after aging for 1000 h under a relative humidity of 30 %–40 % at 20 °C. Moreover, C151-L plays a positive role in improving the operation stability against high humidity, continuous UV radiation, and heating stress. This work may offer more choices for materials with tunable properties in high-efficiency optoelectronic devices.

Solution-Processed Thick Hole-Transport Layer for Reliable Quantum-Dot Light-Emitting Diodes Based on an Alternatingly Doped Structure.

The operating lifetime of quantum-dot light-emitting diodes (QLED) is a bottleneck for commercial display applications. To enhance the operational stability of QLEDs, we developed a robust solution-processed highly conductive hole-transport-layer (HTL) structure, which enables a thick HTL structure to mitigate the electric field. An alternating doping strategy, which involves multiple alternating stacks of N4,N4'-di(naphthalen-1-yl)-N4,N4'-bis(4-vinylphenyl)biphenyl-4,4'-diamine and phosphomolybdic acid layers, could provide significantly improved conductivity; more specifically, the 90 nm-thick alternatingly doped HTL exhibited higher conductivity than the 45 nm-thick undoped HTL. Therefore, when applied to a QLED, the increase in the thickness of the alternatingly doped HTL increased device reliability. As a result, the lifetime of the QLED with a thick, alternatingly doped HTL was 48-fold higher than that of the QLED with a thin undoped HTL. This alternating doping strategy provides a new paradigm for increasing the stability of solution-based optoelectronic devices in addition to QLEDs.

Study on the stability and ultra-low frequency oscillation suppression method of pumped storage power plant with dual units sharing one pipeline

This paper aims to investigate the stability of the pumped storage power plant (PSPP) with dual units sharing one pipeline (DUSOP) and the method of suppressing the ultra-low frequency oscillation (ULFO) characteristics. Firstly, four nonlinear models of pumped storage regulation system (PSRS) with DUSOP are established under the design scenarios of no surge tank, upstream surge tank (UST), downstream surge tank, and upstream and downstream dual surge tanks. Then the stability of the PSRS under different surge tank arrangements (STAs) in the long diversion system design scenarios (LDSDS) is comparatively analyzed. Finally, based on the concept of stability margin, the influence mechanism of the operating points on the ULFO characteristics is investigated in the LDSDS with UST, and the influence of the governor parameters, hydrodynamic parameters, and mechanical parameters on the damping ratio and frequency of the system is also analyzed. The results show that among STAs, the design scheme of arranging the UST is more reasonable for PSPP with LDSDS from the comprehensive consideration of the economy of the project and the stability of the system. For PSPP with UST, on the line of equal stability margin, increasing the proportional gain, reducing the unit inertia time constant, reducing the water flow inertia time constant, and appropriately increasing the area of the surge tank can increase the frequency and reduce the amplitude, which is conducive to the suppression of ULFO. In the stability domain range, increasing the proportional gain increases the frequency and the system stability increases and then decreases. Increasing the integral gain decreases the frequency and then increases the system stability. At the same time, the frequency of the unit can be changed by adjusting the parameters of the system to avoid resonance between the frequency of the unit and the frequency of the power grid and to ensure the stability and safety of the unit operation.

Influence of axial clearance on load distribution in double supported tapered roller bearings of wind turbine main shaft

The operational safety and stability of wind turbines are highly determined by the characteristics of main bearings, which are influenced by the axial clearance. In this paper, for the arrangement type of double-supported tapered roller bearings on the wind turbine main shaft, the actual clearance distribution assumption is established, and a new method of calculating the internal load distribution taking into account the axial clearance is proposed. Firstly, the mathematical relationship between the clearance of tapered roller bearings and ring displacement, contact deformation, and load interval is described. Secondly, the load components of main bearings are calculated by force balance equation and load-displacement condition. Finally, a mathematical model of main bearings including axial clearance is established, and it is numerically solved to obtain the internal load distribution of the bearings. The calculation results of a large megawatt wind turbine example show that: the axial load of both main bearings is negatively correlated with the sum of axial clearances; the number of loaded rolling elements is negatively correlated with the sum of axial clearances; and there exists an optimal value of the sum of axial clearances for main bearings to reach the optimal load carrying state.