The petrochemical industry is an important guarantee for the development of people’s lives, and the operational risk assessment method of personnel in the operation of petrochemical enterprises is the most important. Based on a deep learning algorithm, a new method based on the micro-Doppler effect and fuzzy analytic hierarchy process is proposed to evaluate the operational risk of personnel in petrochemical enterprises. The original monitoring image of petrochemical equipment is invoked, and micro-Doppler analysis is performed based on the original image to identify the activity target of the personnel on the job site and generate the activity map of the petrochemical plant operators. Based on the analysis data of the micro-Doppler effect, the fuzzy function and hierarchical analysis method are combined. The fuzzy theory is introduced into the analytic hierarchy process, and the inherent expert evaluation scores are transformed into fuzzy numbers. It makes the expert evaluation of petrochemical plants more accurate in the subsequent coupling and improves the objectivity of the traditional analytic hierarchy process. The scheme proposed in this paper can monitor real-time operation safety and provide a guarantee for the personal safety of field operators. This method plays an important role in improving the safety of petrochemical plants.