The relative entropy of certain states on the algebra of canonical anticommutation relations (CAR) is studied in the present work. The CAR algebra is used to describe fermionic degrees of freedom in quantum mechanics and quantum field theory. The states for which the relative entropy is investigated are multi-excitation states (similar to multi-particle states) with respect to KMS states defined with respect to a time-evolution induced by a unitary dynamical group on the one-particle Hilbert space of the CAR algebra. If the KMS state is quasifree, the relative entropy of multi-excitation states can be explicitly calculated in terms of 2-point functions, which are defined entirely by the one-particle Hilbert space defining the CAR algebra and the Hamilton operator of the dynamical group on the one-particle Hilbert space. This applies also in the case that the one-particle Hilbert space Hamilton operator has a continuous spectrum so that the relative entropy of multi-excitation states cannot be defined in terms of von Neumann entropies. The results obtained here for the relative entropy of multi-excitation states on the CAR algebra can be viewed as counterparts of results for the relative entropy of coherent states on the algebra of canonical commutation relations which have appeared recently. It turns out to be useful to employ the setting of a self-dual CAR algebra introduced by Araki.
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