One-dimensional Molecular Chains Research Articles

Hydrogen-bonded one-dimensional molecular chains on ultrathin insulating films: Quinacridone on KCl/Cu(111)

Hydrogen-bonded one-dimensional molecular chains on ultrathin insulating films: Quinacridone on KCl/Cu(111)

Highly effective detection of DNP and Fe3+ by designed coordination polymers containing electron rich linkers and azo functional groups

Three new coordination polymers, [Zn(BPTC)0.5(bphy)]⋅(DMF)3 (1), [Zn(HBTC)(azpd)0.5(H2O)]⋅H2O) (2), and [Cd(HBTC)(azpd)(H2O)]⋅(DMF)⋅(H2O)2 (3) (BPTC = biphenyl-3,3′,5,5′-tetracarboxylic acid, bphy = 1,2-bis(4-pyridyl)hydrazine, azpd = 4,4′-azopyridine and H3BTC = benzene-1,3,5-tricarboxylic acid), have been synthesized under solvothermal conditions. The CPs were structurally characterized by single crystal X-ray diffraction analyses and further characterized by powder X-ray diffraction (PXRD), Infrared spectra (IR), UV–visible, Thermogravimetric analysis (TGA), and Elemental analysis (EA). Complex 1 is constructed by 2D ladder chains and further extended through hydrogen bonds to generate a 3D supramolecular framework. Complex 2 and 3 are one-dimensional (1D) molecular chains and further extended via hydrogen bonding interactions to form 3D frameworks. The solid-state photoluminescence of complexes 1–3 was studied. Complex 1 exhibits strong fluorescence emission at 387 nm upon excitation at 310 nm. While complex 2 and 3 show strong emission peak at 403 and 393 nm upon excitation at 298 nm, respectively. Complexes 1–3 act as sensor for the detection of nitro compounds, especially dinitrophenol (DNP) and Fe3+ cation via quenching of their fluorescent intensity.

Making and breaking of chemical bonds in single nanoconfined molecules.

Nanoconfinement of catalytically active molecules is a powerful strategy to control their chemical activity; however, the atomic-scale mechanisms are challenging to identify. In the present study, the site-specific reactivity of a model rhenium catalyst is studied on the subnanometer scale for complexes confined within quasi–one-dimensional molecular chains on the Ag(001) surface by scanning tunneling microscopy. Injection of tunneling electrons causes ligand dissociation in single molecules. Unexpectedly, while half of the complexes show only the dissociation, the confined molecules show also the reverse reaction. On the basis of density functional theory calculations, this drastic difference can be attributed to the limited space in confinement. That is, the split-off ligand adsorbs closer to the molecule and the dissociation causes less structural disruption. Both of these facilitate the reverse reaction. We demonstrate formation and disruption of single chemical bonds of nanoconfined molecules with potential application in molecular data storage.

Inter-Spin Interactions of 1D Chains of Different-Sized Nitroxide Radicals Incorporated in the Organic 1D Nanochannels of Tris(o-phenylenedioxy)cyclotriphosphazene

Abstract Variable-temperature electron spin resonance (ESR) was measured for one-dimensional (1D) molecular chains formed using different-sized organic radicals incorporated into the 1D nanochannels of tris(o-phenylenedioxy)cyclotriphosphazene (TPP). The ESR spectra for the molecular chains of 4-oxo-2,2,6,6-tetramethyl-1-piperidinyl-1-oxyl (TEMPONE) incorporated in the TPP nanochannels ([TPP-TEMPONE]) exhibited anisotropic three-dimensional (3D) spin diffusion at temperatures close to room temperature. In contrast, 1D spin diffusion was observed even at low temperatures indicating a longer rotational diffusion correlation time or the termination of molecular motion of the guest radicals dispersed in the TPP nanochannels. The temperature range for 1D spin diffusion in [TPP-TEMPONE] was higher and wider than that of TPP inclusion compounds incorporating smaller nitroxide radicals, such as di-t-butyl nitroxide (DTBN), or 2,2,6,6-tetramethyl-1-piperidinyl-1-oxyl (TEMPO) radicals, as previously reported. Thus, inter-spin interactions of the organic-radical 1D molecular chains formed in size-adjustable nanochannels, such as TPP, are influenced by the molecular size and dynamics of guest radicals, and temperature.

Holstein polaron at fixed temperature: influence of the chain length

Based on the semiclassical Holstein model, the dynamics of a quantum particle in one-dimensional molecular chain with a trapping site is modeled. Numerical simulation is used to investigate the dynamics of a polaron in a chain with small random Langevin-like perturbations which imitate the thermostat. Parameter values are chosen such that the polaron energy at the trapping site is much greater than the energy of temperature fluctuations. Results of modeling demonstrate that temperature decay of a polaron depends on the chain length even at very low temperatures.

Diradicals or Zwitterions: The Chemical States of m -Benzoquinone and Structural Variation after Storage of Li Ions

Diradicals or Zwitterions: The Chemical States of <i>m</i> -Benzoquinone and Structural Variation after Storage of Li Ions

Effect of compression in molecular spin-crossover chains

The thermodynamic properties of a one-dimensional spin-crossover molecular chain under constant external pressure are investigated. The effective compressible degenerate Ising model is used as a theoretical basis. Analytical results for the crossover from low to high spin are obtained using the transfer matrix formalism. Exact expressions are obtained for the fraction of molecules in the high-spin state, the correlation function, and the heat capacity. The analysis of the range of parameters in which the spin-crossover occurs is carried out, and it is shown how the pressure changes the position of the crossover.

1D spin-crossover molecular chain with degenerate states

A study of the one-dimensional molecular chain (MC) with two single-particle degenerate states is presented. We establish connection of the MC with the Ising model with phononic interactions and investigate properties of the model using a transfer-matrix method. The transfer-matrix method offers a promising pathway for simulating such materials properties. The role of degeneracy of states and phononic interaction is made explicit. We analyze regimes of the system and parameters of the occurring crossover. Here, we present exact results for the magnetization per spin, the correlation function, and the effective volume of the system. We demonstrate the possibility of the existence of two peaks in the specific heat capacity thermal behavior.

Anomalous Diffusion with an Apparently Negative Diffusion Coefficient in a One-Dimensional Quantum Molecular Chain Model

An interesting anomaly in the diffusion process with an apparently negative diffusion coefficient defined through the mean-square displacement in a one-dimensional quantum molecular chain model is shown. Nevertheless, the system satisfies the H-theorem so that the second law of thermodynamics is satisfied. The reason why the “diffusion constant” becomes negative is due to the effect of the phase mixing process, which is a characteristic result of the one-dimensionality of the system. We illustrate the situation where this negative “diffusion constant” appears.

Optoelectronic properties of one-dimensional molecular chains simulated by a tight-binding model

Studying optical properties of organic materials is important due to the rapid development of organic light-emitting diodes, solar cells, and photon detectors. Here, for the first time, we have performed tight-binding calculations for singlet excitons, in combination with first-principles calculations of the excited states in molecular dimers, to describe the optical properties of a zinc-phthalocyanine one-dimensional molecular chain. We have included the intra-molecule and charge-transfer excitations and the coupling between them. Our calculations have successfully interpreted a body of experimental UV–visible optical spectra of transition-metal phthalocyanines. Compared with the previous ab initio calculations for a molecular dimer, the optical absorptions at the split peaks of the Q-bands can be comparable, which indicates the importance of the coupling between the intra-molecular and charge-transfer excitons.

A shift in molecular devices

With the help of a gate electrode to control the charge state of individual molecules on graphene, information can be moved along a one-dimensional molecular chain, mimicking the behaviour of an electronic shift register.

Solvothermal synthesis, structural characterization and photocatalysis of fibrous cobalt(II) diphenylphosphinate

The fibrous coordination polymer cobalt(II) diphenylphosphinate was prepared by solvothermal method, and its chemical composition was characterized by XPS, ICP-MS, IC and EA. The surface morphology was analyzed by SEM and TEM. It is found that the diameter of the fiber ranges varies from hundreds of nanometers to several microns and formation of the fiber is due to the twisting of one-dimensional polymeric molecular chains. The crystalline structure of the fibrous polymer was characterized by XRD. The TG curve indicated that the fiber has a higher decomposed temperature. The fibrous compound has lower density compared with the crystalline form of the same composition. The hydrogen production activity of ethanol decomposition photocatalyzed by the cobalt(II) Diphenylphosphinate was explored under UV–visible light irradiation and the quantity of H2 evolution was ca. 165.345 μmol/g for 3 h. The catalyst showed good stability and cyclability in the photocatalytic process.

Two Types of Oscillations of the Holstein Polaron Uniformly Moving Along a Polynucleotide Chain in a Constant Electric Field

In connection with the development of molecular nanobioelectronics, the main task of which is the construction of electronic devices based on biological molecules, the problems of charge transfer in such extended molecules as DNA are of increasing interest. The relevance of studying the charges motion in one-dimensional molecular chains is primarily associated with the possibility of using these chains as wires in nanoelectronic devices. Current carriers in one-dimensional chains are self-trapped electronic states, which have the form of polaron formations. In this paper we investigate the motion of the Holstein polaron in the process of its uniform motion along the chain in a constant electric field. It is known that during uniform motion along the chain in a weak electric field, the polaron experiences small oscillations of its shape. These oscillations are associated with the discreteness of the chain and are due to the presence of the Peierls-Nabarro potential in the discrete chain. Previous investigations have shown that for certain parameters of the chain, there is the possibility of uniform charge motion in a constant electric field over very large distances. The charge motion with a constant velocity is possible for small values of the electric field intensity. With an increase in the electric field intensity, the charge goes into an oscillatory regime of motion with Bloch oscillations. The calculations performed in this work showed that the elements of Bloch oscillations also appear during stationary motion of the polaron along the chain. Thus, it is shown that the Holstein polaron, uniformly moving along the chain in a constant electric field, experiences not only Peierls-Nabarro oscillations, but also low-amplitude oscillations with a Bloch period.

Два типа осцилляций холстейновского полярона, равномерно движущегося в полинуклеотидной цепочке в постоянном электрическом поле

In connection with the development of molecular nanobioelectronics, the main task of which is the construction of electronic devices based on biological molecules, the problems of charge transfer in such extended molecules as DNA are of increasing interest. The relevance of studying the charges motion in one-dimensional molecular chains is primarily associated with the possibility of using these chains as wires in nanoelectronic devices. Current carriers in one-dimensional chains are self-trapped electronic states, which have the form of polaron formations. In this paper we investigate the motion of the Holstein polaron in the process of its uniform motion along the chain in a constant electric field. It is known that during uniform motion along the chain in a weak electric field, the polaron experiences small oscillations of its shape. These oscillations are associated with the discreteness of the chain and are due to the presence of the Peierls-Nabarro potential in the discrete chain. Previous investigations have shown that for certain parameters of the chain, there is the possibility of uniform charge motion in a constant electric field over very large distances. The charge motion with a constant velocity is possible for small values of the electric field intensity. With an increase in the electric field intensity, the charge goes into an oscillatory regime of motion with Bloch oscillations. The calculations performed in this work showed that the elements of Bloch oscillations also appear during stationary motion of the polaron along the chain. Thus, it is shown that the Holstein polaron, uniformly moving along the chain in a constant electric field, experiences not only Peierls-Nabarro oscillations, but also low-amplitude oscillations with a Bloch period.

Design of dispersant for highly concentrated one-dimensional Nb2Se9 inorganic molecular chains from bulk crystal

We determined the optimum dispersant to separate bulk Nb2Se9 material into 1D chain units. The Nb2Se9, which had a negative zeta potential (−43.3 mV), showed acidic characteristics and strongly bonded with the amine head of octadecyl amine through a charge transfer (from the amine to Se atoms) reaction. The steric hindrance of the octadecyl tail resulted in excellent dispersion of Nb2Se9 (down to nanometre-sized mono-chains).

Probing magnetic order and disorder in the one-dimensional molecular spin chains CuF2(pyz) and [Ln(hfac)3(boaDTDA)]n (Ln = Sm, La) using implanted muons

We present the results of muon-spin relaxation (SR) measurements on antiferromagnetic and ferromagnetic spin chains. In antiferromagnetic CuF2(pyz) we identify a transition to long range magnetic order taking place at K, allowing us to estimate a ratio with the intrachain exchange of and the ratio of interchain to intrachain exchange coupling as . The ferromagnetic chain [Sm(hfac)3(boaDTDA)]n undergoes an ordering transition at K, seen via a broad freezing of dynamic fluctuations on the muon (microsecond) timescale and implying . The ordered radical moment continues to fluctuate on this timescale down to 0.3 K, while the Sm moments remain disordered. In contrast, the radical spins in [La(hfac)3(boaDTDA)]n remain magnetically disordered down to T = 0.1 K suggesting .

Low-Dimensional Metal-Organic Coordination Structures on Graphene.

We report the formation of one- and two-dimensional metal–organic coordination structures from para-hexaphenyl-dicarbonitrile (NC–Ph6–CN) molecules and Cu atoms on graphene epitaxially grown on Ir(111). By varying the stoichiometry between the NC–Ph6–CN molecules and Cu atoms, the dimensionality of the metal–organic coordination structures could be tuned: for a 3:2 ratio, a two-dimensional hexagonal porous network based on threefold Cu coordination was observed, while for a 1:1 ratio, one-dimensional chains based on twofold Cu coordination were formed. The formation of metal–ligand bonds was supported by imaging the Cu atoms within the metal–organic coordination structures with scanning tunneling microscopy. Scanning tunneling spectroscopy measurements demonstrated that the electronic properties of NC–Ph6–CN molecules and Cu atoms were different between the two-dimensional porous network and one-dimensional molecular chains.

Dynamics of Water Molecules in a 3-Fold Interpenetrated Hydrogen-Bonded Organic Framework Based on Tetrakis(4-pyridyl)methane

The 3-fold interpenetration of the β-quartz-type hydrogen-bonded organic framework (HOF) from the dication salts of tetrakis(4-pyridyl)methane develops a host–guest system featuring flexibility and durability in accordance with the state change of guest molecules. Water molecules are incorporated into HOF and form a one-dimensional helical-shaped molecular chain in nanopores. X-ray crystallographic analysis and the dielectric dispersion in the impedance measurements revealed that guest water molecules behave dynamically and show a concerted freezing process to produce water pentamers at 100 K. Structural changes in the host framework mediate interactions between guest water molecules within and between the nanopores through the weak host–guest interactions based on hydrogen-bonding interaction. In addition, the triangular arrangement of nanopores gives rise to the topologically unsettled guest molecules in the freezing process.

Charge and energy transport by Holstein solitons in anharmonic one-dimensional systems

We consider the problem of electron transport and energy transfer in a one-dimensional molecular chain with non-dipole optical phonon mode. We take into account the dispersion of optical phonons, anharmonicity of the lattice on-site potential and electron-lattice interaction. In the lowest order linear approximation such a system admits solutions in the form of the Holstein polaron. Here, within the traveling wave formalism for the corresponding non-linear equations of motion in the long-wave limit, we show the existence of three particular types of exact analytical localized solutions. Two of them, here referred to as Holstein solitons of the first and second kind, respectively, describe a one-hump localized electron wave functions, while the third one displays two humps in the envelope of the wave function. We use the variational approach to reproduce the exact analytical profiles in the three cases of the particular normalized solutions and to variationally predict the existence of branches of normalized solutions for the three types of profiles. We confirm our findings by numerically continuing, in the parameter of velocity of propagation, the analytically exact particular solutions.

Hydrogen bond induced molecular orbital shift in one-dimensional molecular self-assemblies on Au(111)

The self-assembly of indeno[1,2-b]fluorene-6,12-dione (IFDO) absorbed on Au(111) was investigated by scanning tunneling microscopy, scanning tunneling spectroscopy, and density functional theory calculations. It was found that IFDO molecules assembled into one-dimensional molecular chains along the herringbone structures on the Au(111) surface. The lowest unoccupied molecular orbital of IFDO molecules in the assembled structures, relative to isolated molecules, shifts towards Fermi level. The degree of molecular orbital shift, varying from 0.16 to 0.32 eV, depends on the pattern and number of hydrogen bonds formed between the detected IFDO molecule and its neighboring ones. Both transient and induced polarization of neighboring IFDO molecules contribute to the total polarization energy which leads to molecular orbital shift observed by experiments. The former makes the dominant contribution, while the effect of the latter is appreciable especially for molecules composing the defect structures.