Onboard Refueling Vapor Recovery Research Articles

Evaporative emission characteristics of VOCs from in-use light-duty gasoline vehicles

VOCs are an important precursor pollutant of ozone (O3) and secondary organic aerosols (SOA). Vehicle evaporative emission is an essential source of VOCs in urban area, among which lack of localized tests of running loss process in China. This study tested all the evaporative emission processes of in-use light-duty gasoline vehicles (LDGVs), including refueling, running loss, hot soak, and 48-h diurnal breathing loss (DBL) based on the variable temperature Sealed Housing for Evaporative Determination (VT-SHED) of REU (China 4, China 5) vehicles and REC (China 6, with Onboard Refueling Vapor Recovery system) vehicles. The emission factors (EFs), species profiles, Ozone formation potential (OFP), and SOA formation potential (SOAP) of all evaporative emission processes of REU and REC vehicles were obtained. We found that the running loss emissions was less affected by the Onboard Refueling Vapor Recovery (ORVR) system, the average running loss EFs of REU and REC vehicles was 9.386 mg/km; refueling and DBL EFs of REC vehicles was 1.491 mg/L and 0.179 g/day, respectively, 99.8% and 56.0% lower than those of REU vehicles, the hot soak EFs was 0.087 g/h in average. The refueling emissions process was dominated by alkanes (REU: 77.8%; REC: 75.4%), and C4 and C5 species dominated (REU: 75.6%; REC: 67.6%). Among the running loss, hot soak and DBL emissions, alkanes, oxygenated VOCs (OVOCs) and aromatics were the dominant VOCs groups, OVOCs account for a higher proportion in REC vehicles than in REU vehicles. REC vehicles had higher proportion of C1–C3 than REU vehicles, it may be that ORVR has a better adsorption effect on species with large carbon numbers. Running loss VOCs species had a strong correlation with hot soak VOCs species. The OFP of running loss in REU and REC vehicles were 0.9–1.3 and 0.3–0.7 times higher than those of refueling and 48-h DBL, while the SOAP were 10.7–12.9 and both 1.1 times higher, respectively. These findings can provide valuable basis for emission estimation and characteristic analysis for evaporative process of LDGVs and support the development of appropriate pollution-control policy.

Effectiveness of emissions standards on automotive evaporative emissions in Europe under normal and extreme temperature conditions

Non-methane volatile organic compounds (NMVOCs) are primary precursors for the formation of ozone and secondary organic aerosol which contribute to increased public health risks. Throughout Europe, passenger vehicles contribute significantly to NMVOC emissions due to automotive evaporative emissions controls that are less stringent than those in the United States, Canada, China, and Brazil. Evaporative NMVOC emissions increase significantly, and associated air quality impacts are exacerbated, during periods of high temperature such as heatwaves, which continue to increase in frequency, duration, and intensity. Adoption of strict evaporative emission standards and controls such as onboard refueling vapor recovery systems (ORVR) can significantly reduce evaporative emissions during such events; however, emissions inventories used to inform policy decisions are developed using average temperature profiles which fail to capture the impact of heatwave events on evaporative emissions. This study evaluates the effectiveness of the previous generation (Euro5), current (Euro6d), and proposed (Euro7) emission control standards on evaporative emissions at high temporal and spatial resolution in western and central Europe during July 2019, a month in which a significant heatwave swept through the region. Using temperatures obtained from the Weather Research and Forecasting (WRF) model with observation data and an improved method for estimating evaporative emissions, it is estimated that per-vehicle evaporative NMVOC emissions within the study domain and period are reduced by 25.0% under current Euro6d standards and controls relative to Euro5 standards, and that proposed Euro7 controls, including ORVR, would provide an additional 35.3% emissions reduction relative to Euro6d. During heatwave periods, Euro7 controls demonstrate improved attenuation of temperature-driven emissions increases relative to Euro6d controls, with associated emissions within the study period and domain increasing by 23.4% on average under Euro7 controls versus 29.4% under Euro6d controls. While this study does not quantify the effect of heatwaves and emissions controls on total annual emissions, the results for the study period of July 2019, combined with the low implementation cost of proposed Euro7 evaporative controls and projected continued dominance of petrol vehicles in the European fleet through the middle of this century, suggest that significant NMVOC emissions reductions and associated air quality and health impacts are achievable through the adoption of these more stringent standards and control systems.

Refueling emission of volatile organic compounds from China 6 gasoline vehicles

Vehicular refueling emission is a potential source of urban atmospheric volatile organic compounds (VOCs) that is not well understood and controlled. China 6 vehicles have been equipped with the onboard refueling vapor recovery (ORVR) system to cut down refueling emissions, while the emission characteristics and reduction effectiveness are rarely reported. In this study, we conducted laboratory tests to measure the refueling emissions from ten China 6 vehicles and three China 5 vehicles (refueling-emission-uncontrolled, REU) and developed an inventory in a typical middle-sized Chinese city (Langfang) to explore the emission reduction resulted from relevant policies. Compared with headspace vapor and refueling vapor from REU vehicles, the emission profiles for China 6 vehicles are consist of considerably higher proportions of small alkanes and alkenes (C2-C3) and lower proportions of C6-C8 hydrocarbons. Such differences indicate that the headspace vapor profiles are incapable of representing the refueling emission for China 6 vehicles. The market-share-weighting emission factors (EFs) of total hydrocarbons (THCs) and total VOCs for China 6 vehicles are 11.2 mg/L and 6.4 mg/L, respectively, corresponding to control efficiency of approximately 98.8% compared with the REU vehicles. Based on the real-world EFs and the fuel consumption in Langfang, a refueling emission inventory with high spatiotemporal resolution is developed. The total refueling emission of THCs in Langfang is approximately 190.6 tons in 2018 and will likely decline to 25.0 tons in 2035. The implementation of the ORVR will contribute to 90% of the refueling emission reduction in 2035.

State-of-the-art outlook for light-duty vehicle emission control standards and technologies in China

A surge in the size of the automobile population has caused vehicular emissions to become a major source of urban atmospheric pollution. Elevating standards is an effective method of controlling vehicular emissions and improving air quality. Light-duty vehicles are the major contributors to HC and CO emissions as they constitute a large proportion of all vehicles. Consequently, controlling light-duty vehicular emissions has been the primary means of air pollution prevention in China. This paper first reviews the progress of emission control standards in mainland China. Second, it analyzes features of the China 6 emissions standards, namely the continuation of European standards, the harmony of global technology regulations, and fusion with the standards of the USA. This is followed by a description and discussion of the status of research on mainstream after-treatment technologies such as the gasoline particulate filter, lean-NOx trap, and selective catalytic reduction. Finally, this study argues that the technical routes for implementing three-way catalysts, gasoline particulate filters, and onboard refueling vapor recovery in gasoline vehicles and diesel oxidation catalysts, diesel particulate filters, and selective catalyst reduction in diesel vehicles meet China 6 standards. Moreover, onboard diagnostics-based control of light vehicle emissions is introduced, and the development directions of vehicle gasoline (the reduction in sulfur, olefin, and aromatic content and vapor pressure control in summer) and vehicle diesel (an increase in the Cetane number and reduction in the forecasted polycyclic aromatic content) are discussed. State-of-the-art outlook for light-duty vehicle emission control standards in China

Gasoline Vapor Emissions During Vehicle Refueling Events in a Vehicle Fleet Saturated With Onboard Refueling Vapor Recovery Systems: Need for an Exposure Assessment

Background: Gasoline contains large proportions of harmful chemicals, which can be released during vehicle refueling. Onboard Refueling Vapor Recovery (ORVR) can reduce these emissions, but there is limited research on the system's efficacy over time in an actual vehicle fleet. The aims of this study are: (1) determine the feasibility of using an infrared camera to view vapor emissions from refueling; (2) examine the magnitude of refueling-related emissions in an ORVR-saturated fleet, to determine need for an exposure-assessment.Methods: Using an infrared camera optimized for optical gas imaging of volatile organic chemicals, refueling was recorded for 16 vehicles at six gas stations. Pumps were inspected for damage, refueling shut-off valve functioning, and presence of Stage II Vapor Recovery. Vehicle make/model and age were recorded or estimated.Results: Vapor emissions were observed for 14 of 16 vehicles at each station, with severity varying substantially by vehicle make/model and age. Use of an infrared camera allowed for identification of vapor sources and timing of release, and for visualizing vapor trajectories.Discussion: Notably emissions occurred not only at the beginning and end of refueling but also throughout, in contrast to a prior study which did not detect increases in atmospheric hydrocarbon levels mid-refueling. Future studies are vitally needed to determine the risk to individuals during typical refueling in an ORVR saturated vehicle fleet. We recommend comprehensive exposure-assessment including real-time monitoring of emitted volatile organic compounds paired with infrared gas-imaging and measurement of internal dose and health effects of gas station customers.

Evaluation of Evaporative Emission and Feasibility of an Onboard Refueling Vapor Recovery System for Scooters

This paper aims at the development of a novel onboard refueling vapor recovery (ORVR) system for scooters. The corresponding feasibility and evaporative emission are evaluated so that this preliminary study may offer important contributions for developing an effective ORVR system in Taiwan. A survey of research is initially conducted to compare the evaporative emission of the ORVR systems mounted on vehicles with that of the vapor recovery systems of Stage II installed at gas stations. The results show that the ORVR technology possesses better controllability and lower cost. Then, a novel ORVR system for scooters consisting of a self-made fuel tank, a self-made carbon canister, a vapor pipe, a fuel limit vent valve, and a surge protector etc. is developed and tested. The proposed self-made carbon canister possesses the storage capacity of fuel vapor large enough to perform the adsorption tests of diurnal and hot soak for as long as three consecutive days. Finally, the designed ORVR system is installed on a scooter and tested for evaporative emission under the regulation of Taiwan so as to check if it fulfills the requirements. The results are further compared with those with the evaporative emission control system (EVAP). A significant improvement on the leaking problem of fuel vapor is gained by using the proposed ORVR system. Consequently, the study can offer a valuable reference for developing an economical and effective ORVR system in the future.

VOCs Emission Inventory of Service Stations in a Subcenter (Tongzhou District) of the City of Beijing

As a subcenter of the city of Beijing, Tongzhou District is faced with enormous pressure from the rapid growth of VOCs emissions from service stations. In this study, a set of bottom-up VOCs inventory estimation methods for service stations in Tongzhou District is established. Using local VOCs emission factors of service stations in Beijing, combined with gasoline and diesel sales from every service station, a high resolution VOCs emission inventory of service stations in Tongzhou District from 2015 to 2022 was established. The results showed the following. ①An online monitoring system (OMS) based on unloading, refueling, and tank pressure vapor emission control measures can reduce the VOCs emission factor from 190 mg·L-1 to 115 mg·L-1, and when the percent onboard refueling vapor recovery system (ORVR) Penetration reaches to about 50%, the emission factors can be reduced to 131 mg·L-1 and 96 mg·L-1, respectively. The VOCs emission factor (13 mg·L-1) of diesel from the service station is 0.8% of the uncontrolled emission factor (1552 mg·L-1) of gasoline. ②The amount of VOCs emissions from service stations in Tongzhou District was 97.8 t·a-1 in 2015, and the emissions of gasoline and diesel were 96.2 t·a-1 and 1.6 t·a-1, respectively, accounting for 98.4% and 1.6%. The emissions were mainly concentrated in the area surrounding the new Beijing Municipal Government site. ③After implementation of the vapor recovery requirements of "Beijing's Clean Air Action Plan from 2013-2017," considering the increase in oil sales from 2017 to 2022, VOCs emissions of gasoline and diesel from service stations will decrease by 9% and 6%, respectively, compared to those of 2015 in Tongzhou District. Assuming that the OMS will also be installed at 28 (2000-5000) t·a-1 service stations by the end of 2022, VOCs emissions of service stations will be reduce by 13% compared to those of 2015. ④The measure of restricting the number of vehicles in operation by 50% can reduce VOCs emissions of service stations by (22±12)% every day during 2014 Asia-Pacific Economic Cooperation conference (APEC). ⑤It is suggested to strengthen vapor recovery supervision on service stations in the area surrounding the new Beijing Municipal Government site, and in summer and refueling idle such as in noon.

Estimation of refueling emissions based on theoretical model and effects of E10 fuel on refueling and evaporative emissions from gasoline cars

The effects of Reid vapor pressure (RVP) on refueling emissions and the effects of ethanol 10% (E10) fuel on refueling and evaporative emissions were observed using six cars and seven fuels. The results indicated that refueling emissions can be reproduced by a simple theoretical model in which fuel vapor in the empty space in the tank is pushed out by the refueling process. In this model, the vapor pressures of fuels can be estimated by the Clausius–Clapeyron equation as a function of temperature. We also evaluated E10 fuel in terms of refueling and evaporative emissions, excluding the effect of contamination of ethanol in the canister. E10 fuel had no effect on the refueling emissions in cases without onboard refueling vapor recovery. E10 showed increased permeation emissions in evaporative emissions because of the high permeability of ethanol. And with E10 fuel, breakthrough emissions appeared earlier but broke through slower than normal fuel. Finally, canisters could store more fuel vapor with E10 fuel.

VOC from Vehicular Evaporation Emissions: Status and Control Strategy.

Vehicular evaporative emissions is an important source of volatile organic carbon (VOC), however, accurate estimation of emission amounts and scientific evaluation of control strategy for these emissions have been neglected outside of the United States. This study provides four kinds of basic emission factors: diurnal, hot soak, permeation, and refueling. Evaporative emissions from the Euro 4 vehicles (1.6 kg/year/car) are about four times those of U.S. vehicles (0.4 kg/year/car). Closing this emissions gap would have a larger impact than the progression from Euro 3 to Euro 6 tailpipe HC emission controls. Even in the first 24 h of parking, China's current reliance upon the European 24 h diurnal standard results in 508 g/vehicle/year emissions, higher than 32 g/vehicle/year from Tier 2 vehicles. The U.S. driving cycle matches Beijing real-world conditions much better on both typical trip length and average speed than current European driving cycles. At least two requirements should be added to the Chinese emissions standards: an onboard refueling vapor recovery to force the canister to be sized sufficiently large, and a 48-h evaporation test requirement to ensure that adequate purging occurs over a shorter drive sequence.

Refueling emissions from cars in Japan: Compositions, temperature dependence and effect of vapor liquefied collection system

Refueling emissions from cars available on the Japanese market, which were not equipped with specific controlling devices, were investigated. For the composition analysis, a proton transfer reaction plus switchable reagent ion mass spectrometry (PTR + SRI-MS), which is capable of real-time measurement, was used. In addition, the performance of a vapor liquefied collection system (VLCS), which is a recently developed controlling device, was evaluated and compared with an onboard refueling vapor recovery (ORVR) system. The refueling emission factor of uncontrolled vehicles at 20 °C was 1.02 ± 0.40 g/L in the case dispensing 20 L of fuel. The results of composition analysis indicated that the maximum incremental reactivity (MIR) of refueling emissions in Japan was 3.49 ± 0.83. The emissions consist of 80% alkanes and 20% alkenes, and aromatics and di-enes were negligible. C4 alkene had the highest impact on the MIR of refueling emissions. The amounts of refueling emissions were well reproduced by a function developed by MOVE2010 in the temperature range of 5–35 °C. The compositions of the refueling emissions varied in this temperature range, but the change in MIR was negligible. The trapping efficiency of VLCS was the same level as that of the ORVR (over 95%). The MIRs of refueling and evaporative emissions were strongly affected by that of the test fuel. This study and our previous study indicated that MIRbreakthrough ≈ MIRrefueling ≈ MIRfuel + 0.5 and MIRpermeation ≈ MIRfuel. The real-world estimated average MIRfuel in Japan was about 3.0.

Vehicular volatile organic compounds losses due to refueling and diurnal process in China: 2010–2050

Volatile organic compounds (VOCs) are crucial to control air pollution in major Chinese cities since VOCs are the dominant factor influencing ambient ozone level, and also an important precursor of secondary organic aerosols. Vehicular evaporative emissions have become a major and growing source of VOC emissions in China. This study consists of lab tests, technology evaluation, emissions modeling, policy projections and cost-benefit analysis to draw a roadmap for China for controlling vehicular evaporative emissions. The analysis suggests that evaporative VOC emissions from China's light-duty gasoline vehicles were approximately 185,000ton in 2010 and would peak at 1,200,000ton in 2040 without control. The current control strategy implemented in China, as shown in business as usual (BAU) scenario, will barely reduce the long-term growth in emissions. Even if Stage II gasoline station vapor control policies were extended national wide (BAU+extended Stage II), there would still be over 400,000ton fuel loss in 2050. In contrast, the implementation of on-board refueling vapor recovery (ORVR) on new cars could reduce 97.5% of evaporative VOCs by 2050 (BAU+ORVR/BAU+delayed ORVR). According to the results, a combined Stage II and ORVR program is a comprehensive solution that provides both short-term and long-term benefits. The net cost to achieve the optimal total evaporative VOC control is approximately 62 billion CNY in 2025 and 149 billion CNY in 2050.